arXiv subjects

Seokho Lee

Publications and source records attributed to Seokho Lee.

At least 19 recordsLinked to original sources

arXiv2026

Origins of complex organic molecules in L1551 IRS 5: Interplay of thermal heating and accretion shocks

Complex organic molecules (COMs) are typically observed in the warm inner envelopes of Class 0 protostars. In more evolved Class I sources, COM emission is confined to the compact inner disk and obscured by high dust opacity, but the FU Orionis-type binary L1551 IRS 5 offers a valuable opportunity to probe disk chemistry, as its outburst luminosity thermally sublimates ices out to large radii. We sought to spatially resolve the origins of COMs in this system to distinguish between central radiative heating and shock-induced chemistry driven by heterogeneous accretion pathways. We analyzed high-angular-resolution ALMA archival data, focusing on COMs (e.g., CH3OH, CH3OCHO) and the shock tracer SO, and compared their spatial morphologies and kinematics to diagnose the excitation conditions associated with different accretion flows. We find that the COM emission in L1551 IRS 5 arises from both radiative heating and localized accretion shocks. In the northern source, the widespread low-excitation COM emission is primarily consistent with thermal heating by the recent outburst. This source also exhibits dual-mode accretion with distinct chemical signatures, with COMs along the spiral arm tracing steady equatorial circumbinary disk-to-circumstellar disk accretion and high-excitation COMs with bright SO along the eastern disk surface tracing a vertical envelope-to-disk streamer impact. In the southern source, methanol is confined to the southeastern streamer impact site, whereas SO forms a ring-like structure at the tidal truncation radius. We attribute this difference to differential chemical survival timescales. L1551 IRS 5 thus serves as an ideal laboratory to investigate how shock chemistry and binary-regulated accretion shape the chemical structure of protostellar disks.

astro-ph.GA↗

arXiv2026

Accretion Burst Crystallizes Silicates in a Planet-Forming Disk

Crystalline silicates form at high temperatures (> 900 K; Fabian et al. 2000; Hallenbeck et al. 1998). Their presence in comets (Hanner et al. 1994; Hayward et al. 2000; Wooden et al. 2002; Shinnaka et al. 2018) suggests that high-temperature dust processing occurred in the early Solar System and was subsequently transported outward to comet-forming regions. However, direct evidence for this crystallization and redistribution in Sun-like protostars has remained elusive. By comparing James Webb Space Telescope (JWST) mid-infrared spectra of the periodically bursting protostar EC 53 (Lee et al. 2020), we detect crystalline silicate (forsterite and enstatite) emission features that appear only during the burst. The emergence of these features indicates active crystal formation via thermal annealing in the hot inner disk during the accretion burst. We also detect a nested outflow-a collimated atomic jet enclosed by slower molecular outflows, consistent with magnetohydrodynamic (MHD) wind models (Pascucci et al. 2025). This configuration provides a mechanism for outward transport of freshly crystallized silicates (Giacalone et al. 2019). Our results provide the first direct observational evidence of in-situ silicate crystallization during episodic accretion bursts in a very young star still embedded in its dense envelope. Although we do not directly detect grains transported to the outer disk, the observed trends are consistent with outward redistribution, indicating that both dust processing and transport occur during the earliest and most dynamic stages of star formation.

astro-ph.EP↗

arXiv2026

EPISODE II: Variability in the CO and H$_2$O rovibrational absorption lines in a periodically variable protostar EC 53

We present two-epoch JWST NIRSpec and MIRI observations of the young protostar EC 53 (V371 Ser), a periodically variable source with well-characterized quiescent and burst phases. The spectra in both epochs show absorption in the CO overtone ($\sim$2.3 $\mu$m) and fundamental ($\sim$4.6 $\mu$m) bands and the H$_2$O stretching ($\sim$2.7 $\mu$m) and bending ($\sim$6.0 $\mu$m) modes. We also obtained high-resolution ($R\approx45{,}000$) IGRINS spectra during the burst to constrain the CO overtone line profiles. LTE slab modeling yields gas temperatures of $\sim$1800 K (CO overtone) and $\sim$1200 K (CO fundamental), consistent with the overtone tracing hotter gas at smaller radii. The H$_2$O stretching-mode absorption shows no compelling evidence for variability, and the current JWST CO overtone data do not provide a robust constraint on overtone variability. In contrast, the CO fundamental and H$_2$O bending-mode features weaken by a factor of $\sim$2 during the burst, which is most naturally explained by continuum changes rather than large variations in absorbing gas. To quantify continuum dilution, we introduce a ``relative veiling'' that treats the quiescent spectrum as an internal reference and measures the change in the continuum excess between the two epochs. This formalism yields burst-to-quiescent hot-continuum ratios of $2.9\pm0.2$ for the CO overtone and $1.71\pm0.11$ for the CO fundamental. Using a viscous-disk prescription, these imply representative accretion-rate ratios of $\sim$3.6 and $\sim$2.0, respectively. The differing ratios suggest that inner-disk regions traced at different temperatures, and thus radii, respond differently across the burst cycle, consistent with episodic mass buildup in the inner disk during quiescence followed by more efficient transport through the innermost disk onto the protostar during the burst.

astro-ph.GA↗

arXiv2026

EPISODE IV: Ice Inventory in the Envelope of EC 53

We present the 1.6$-$28 $\mu$m spectra of the young protostar EC 53, obtained with JWST NIRSpec IFU and MIRI MRS during the quiescent and burst phases of its periodic brightness variations. To isolate ice absorption features, we modeled and removed the mid-infrared silicate dust absorption using a dedicated continuum-fitting procedure. In the optical depth spectrum, we first fit the broad H$_2$O ice features and then decomposed the major ice components, including NH$_3$, CO$_2$, CH$_3$OH, CO, and CH$_4$, by matching laboratory profiles for both pure and H$_2$O-mixed ices. The 4.62 $\mu$m and 6.85 $\mu$m bands are attributed to OCN$^-$ and NH$_4^+$ ions, respectively. Minor or tentative contributions from complex species (HCOOH, H$_2$CO, CH$_3$COOH, CH$_3$CHO, CH$_3$CH$_2$OH, and NH$_2$CHO) are also considered to our global ice analysis. The silicate-corrected spectra reveal no measurable change in any ice absorption band between the two phases, indicating that moderate and short-period accretion bursts in EC~53 do not significantly alter the physical or chemical state of the ices within its envelope. The derived abundances of these major species relative to H$_2$O significantly exceed the values typically observed toward other embedded protostars. Finally, we place the ice inventory of EC~53 in the context of other protostellar systems observed with JWST, highlighting that its chemically rich, thermally quiescent ice reservoir provides a benchmark for studying ice evolution under episodic accretion.

astro-ph.SR↗

arXiv2026

EPISODE III: The Nested Jet/Outflow Morphology of EC 53 Revealed by JWST and ALMA

We present an extensive study of the structure and kinematics of the jet and outflow of EC 53, a Class I protostar with a quasi-periodic variability, using combined James Webb Space Telescope (JWST) and Atacama Large Millimeter/submillimeter Array (ALMA) observations. ALMA continuum observations resolve a compact disk with a radius of $\sim$0.14\arcsec\ (60\,au). Scattered light from the outflow cavity is prominent in the short-wavelength NIRCam and NIRSpec observations, revealing only the southeast nearside lobe. We detected 27 H$_2$ emission lines tracing a narrow, cone-shaped structure within the outflow cavity. A high-velocity ionized jet is detected in several forbidden atomic lines, characterized by a position angle of 142\degree, an opening angle of 1.4\degree, and an estimated geometric launching radius of at most $\sim$40\,au. Mid-infrared CO ro-vibrational emission lines, stronger in the P-branch, show a similar distribution to the H$_2$ emission and are likely to originate from hot gas within the outflow cavity. CO and C$_2$H emission lines detected by ALMA trace slower, colder outflow components and cavity walls. The spatial and kinematic stratification between the hot atomic and molecular components and the colder molecular gas is consistent with predictions from MHD disk wind models, although envelope material entrained by a wide-angle wind or jet may also contribute. Our analysis highlights the powerful synergy between JWST and ALMA in advancing the understanding of protostellar jets and outflows across multiple spatial and physical scales.

astro-ph.SR↗

arXiv2026

CH3CCH as a thermometer in warm molecular gas

Kinetic temperature is a fundamental parameter in molecular clouds. Symmetric top molecules, such as NH$_3$ and CH$_3$CCH, are often used as thermometers. However, at high temperatures, NH$_3$(2,2) can be collisionally excited to NH$_3$(2,1) and rapidly decay to NH$_3$(1,1), which can lead to an underestimation of the kinetic temperature when using rotation temperatures derived from NH$_3$(1,1) and NH$_3$(2,2). In contrast, CH$_3$CCH is a symmetric top molecule with lower critical densities of its rotational levels than those of NH$_3$, which can be thermalized close to the kinetic temperature at relatively low densities of about 10$^{4}$ cm$^{-3}$. To compare the rotation temperatures derived from NH$_3$(1,1)$\&$(2,2) and CH$_3$CCH rotational levels in warm molecular gas, we used observational data toward 55 massive star-forming regions obtained with Yebes 40m and TMRT 65m. Our results show that rotation temperatures derived from NH$_3$(1,1)$\&$(2,2) are systematically lower than those from CH$_3$CCH 5-4. This suggests that CH$_3$CCH rotational lines with the same $J$+1$\rightarrow$$J$ quantum number may be a more reliable thermometer than NH$_3$(1,1)$\&$(2,2) in warm molecular gas located in the surroundings of massive young stellar objects or, more generally, in massive star-forming regions.

astro-ph.GA↗

arXiv2025

$\ell_0$-Regularized Item Response Theory Model for Robust Ideal Point Estimation

Ideal point estimation methods face a significant challenge when legislators engage in protest voting -- strategically voting against their party to express dissatisfaction. Such votes introduce attenuation bias, making ideologically extreme legislators appear artificially moderate. We propose a novel statistical framework that extends the fast EM-based estimation approach of \cite{Imai2016} using $\ell_0$ regularization method to handle protest votes. Through simulation studies, we demonstrate that our proposed method maintains estimation accuracy even with high proportions of protest votes, while being substantially faster than MCMC-based methods. Applying our method to the 116th and 117th U.S. House of Representatives, we successfully recover the extreme liberal positions of ``the Squad'', whose protest votes had caused conventional methods to misclassify them as moderates. While conventional methods rank Ocasio-Cortez as more conservative than 69\% of Democrats, our method places her firmly in the progressive wing, aligning with her documented policy positions. This approach provides both robust ideal point estimates and systematic identification of protest votes, facilitating deeper analysis of strategic voting behavior in legislatures.

stat.AP↗

arXiv2025

ALMA Band 7 Observations of Water Lines in the Protoplanetary Disk of V883 Ori

The FU Orionis star V883 Ori provides a unique opportunity to probe the water snowline in a protoplanetary disk. During an accretion burst, the enhanced stellar luminosity heats the disk, sublimating ices and bringing volatile species into the gas-phase. The water snowline, located at $\sim$80 au in the midplane, represents a key boundary for dust growth and volatile delivery to forming planets. We present Atacama Large Millimeter/submillimeter Array Band 7 observations of V883 Ori that detect two targeted water isotopologue transitions: para-H$_2$$^{18}$O $5_{1,5}$-$4_{2,2}$ at 322 GHz and HDO $3_{3,1}$-$4_{2,2}$ at 335 GHz. After correcting for Keplerian rotation, we detect HDO and H$_2$$^{18}$O at 23.6$\sigma$ and 9.3$\sigma$, respectively. Rotational-diagram analysis using a Markov Chain Monte Carlo approach yields $T_\mathrm{rot}=116.89\pm12.81$ K and $N=(4.90\pm1.69)\times10^{15}\,\mathrm{cm}^{-2}$ for H$_2$$^{18}$O, and $T_\mathrm{rot}=87.46\pm4.95$ K and $N=(4.47\pm0.62)\times10^{15}\,\mathrm{cm}^{-2}$ for HDO. These results imply water vapor abundances of $N_{\mathrm{H_2O}}/N_{\mathrm{H_2}}\sim3\times10^{-7}$-$5\times10^{-6}$ and an HDO/H$_2$O ratio of $(0.4$-$2.0)\times10^{-3}$ just inside the water snowline, broadly consistent with inheritance from protostellar envelopes. The HDO line in Band 7 is significantly weaker than predicted from Band 6 extrapolation, showing only $\sim$26% of the expected strength. This attenuation can be explained by a more compact, hotter emitting region with an effective radius of $\sim$53 au and/or frequency-dependent dust absorption that enlarges the apparent inner cavity at higher frequency. Our results highlight both the diagnostic power of water isotopologue lines and the need for higher angular resolution observations to resolve the water snowline and test these scenarios.

astro-ph.EP↗

arXiv2025

Water Snowline in Young Stellar Objects with Various Density Structures Using Radiative Transfer Models

Tracing the water snowline in low-mass young stellar objects (YSOs) is important because dust grain growth is promoted and the chemical composition varies at the water snowline, which influences planet formation and its properties. In protostellar envelopes, the water snowline can be estimated as a function of luminosity using a relation derived from radiative transfer models, and these predictions are consistent with observations. However, accurately estimating the water snowline in protoplanetary disks requires new relations that account for the disk structure. We present the relations between luminosity and water snowline using the dust continuum radiative transfer models with various density structures. We adopt two-dimensional density structures for an envelope-only model (Model E), an envelope+disk+cavity model (Model E+D), and a protoplanetary disk model (Model PPD). The relations between the water snowline, where T_dust = 100 K, and the total luminosity, ranging 0.1-1,000 solar luminosity, are well fitted by a power-law relation, R_snow=a * (L/L_solar)^p au. The factor a decreases with increasing disk density, while the power index p has values around 0.5 in all models. As the disk becomes denser, the water snowline forms at smaller radii even at the same luminosity, since dense dust hinders photon propagation. We also explore the effect of viscous heating on the water snowline. In Model PPD with viscous heating, the water snowline shifts outward by a few au up to 15 au, increasing the factor a and decreasing the power index p. In Model E+D with lower disk mass, the effect of viscous heating is negligible, indicating that the disk mass controls the effect. The discrepancy between our models and direct observations provides insights into the recent outburst event and the presence of a disk structure in low-mass YSOs.

astro-ph.SR↗

arXiv2024

ALMA Spectral Survey of An eruptive Young star, V883 Ori (ASSAY): II. Freshly Sublimated Complex Organic Molecules (COMs) in the Keplerian Disk

We present an investigation of Complex Organic Molecules (COMs) in the spatially resolved Keplerian disk around V883 Ori, an eruptive young star, based on a spectral survey carried out with ALMA in Band 6 (220.7$-$274.9 GHz). We identified about 3,700 molecular emission lines and discovered 23 COMs in the disk. We estimated the column densities of COMs detected through the iterative LTE line fitting method. According to our analyses, using only optically thin lines is critical to deriving the reliable column densities of COMs. Therefore, covering a large frequency range is important for the studies of COMs. The most distinct phenomenon found from the spectra of the V883 Ori disk is that nitrogen-bearing COMs other than CH$_{3}$CN are missing, whereas various oxygen-bearing COMs, except for the CH$_2$OH-bearing molecules, are detected. The missing CH$_2$OH-bearing COMs may indicate the warm water-ice dominant environment for forming COMs. We compared our results with various objects in different evolutionary stages, from Class 0 hot corinos to a Solar System comet 67P/Churyumov-Gerasimenko, to examine the effect of evolution on the COM compositions. In general, the COMs abundances relative to methanol in V883 Ori are higher than in the hot corinos and hot cores, while they are comparable to the cometary values. This may indicate the planet-forming material chemically evolves in the disk midplane after being accreted from the envelope. In addition, as found in the comet 67P/Churyumov-Gerasimenko, nitrogen might also be trapped as ammonium salt within the dust grains in the V883 Ori disk.

astro-ph.SR↗

arXiv2024

HCN and HNC in the Disk of an Outbursting Young Star, V883 Ori

Hydrogen cyanide (HCN) and hydrogen isocyanide (HNC) are isomers with similar chemical properties. However, HNC can be converted into other molecules by reactions with atomic hydrogen (H) and atomic oxygen (O), resulting in a variation of the HCN/HNC abundance ratio. These reaction rates are sensitive to gas temperature, resulting in different abundance ratios in different temperature environments. The emission of HCN and HNC was found to distribute along ring structures in the protoplanetary disk of V883 Ori. HCN exhibits a multi-ring structure consisting of inner and outer rings. The outer ring represents a genuine chemical structure, whereas the inner ring appears to display such characteristics due to the high dust continuum optical depth at the center. However, HNC is entirely depleted in the warmer inner ring, while its line intensity is similar to that of HCN in the colder outer ring. In this study, we present a chemical calculation that reproduces the observed HCN/HNC abundance ratio in the inner and outer rings. This calculation suggests that the distinct emission distribution between HCN and HNC results from a currently ongoing outburst in V883 Ori. The sublimation of HCN and HNC from grain surfaces and the conversion of HNC to HCN determine their chemical distribution in the heated, warm inner disk.

astro-ph.SR↗

arXiv2024

Carbon isotope chemistry in protoplanetary disks: Effects of C/O ratios

Carbon isotope fractionation of CO has been reported in the disk around TW Hya,where elemental carbon is more abundant than elemental oxygen ([C/O]$_{\rm elem}$> 1). We investigated the effects of the [C/O]$_{\rm elem}$ ratio on carbon fractionation using astrochemical models that incorporate isotope-selective photodissociation and isotope-exchange reactions. The $^{12}$CO/$^{13}$CO ratio could be lower than the elemental carbon isotope ratio due to isotope exchange reactions when the [C/O]$_{\rm elem}$ ratio exceeds unity. The observed $^{12}$CO/$^{13}$CO and H$^{12}$CN/H$^{13}$CN ratios around TW Hya could be reproduced when the [C/O]$_{\rm elem}$ ratio is 2~5. In the vicinity of the lower boundary of the warm molecular layer, the formation of ices leads to the gas phase [C/O]$_{\rm elem}$ ratio approaching unity, irrespective of the total (gas + ice) [C/O]$_{\rm elem}$ ratio. This phenomenon reduces the variation in the $^{12}$CO/$^{13}$CO ratio across different [C/O]$_{\rm elem}$ ratios.

astro-ph.GA↗

arXiv2024

ALMA Spectral Survey of An eruptive Young star, V883 Ori (ASSAY): I. What triggered the current episode of eruption?

An unbiased spectral survey of V883 Ori, an eruptive young star, was carried out with the Atacama Large Millimeter/submillimeter Array (ALMA) in Band 6. The detected line emission from various molecules reveals morphological/kinematical features in both the Keplerian disk and the infalling envelope. A direct infall signature, red-shifted absorption against continuum, has been detected in CO, HCO$^+$, HCN, HNC, and H$_2$CO. HCO$^+$ and SO show large arm-like structures that probably connect from an infalling envelope to the disk. HCN and H$_2$CO reveal a distinct boundary between the inner and outer disk and reveal tentative spiral structures connecting the outer disk to the inner disk. HNC shows a large central emission hole (r $\sim$0.3\arcsec) due to its chemical conversion to HCN at high temperatures. The HDO emission, a direct tracer of the water sublimation region, has been detected in the disk. Molecular emission from complex organic molecules (COMs) is confined within the HDO emission boundary, and HCO$^+$ has an emission hole in its distribution due to its destruction by water. Together, these features suggest that the current episode of eruption in V883 Ori may be triggered by the infall from the envelope to the outer disk, generating a spiral wave, which propagates inward and greatly enhances the accretion onto the central star.

astro-ph.SR↗

arXiv2024

The First Spatially-resolved Detection of $^{13}$CN in a Protoplanetary Disk and Evidence for Complex Carbon Isotope Fractionation

Recent measurements of carbon isotope ratios in both protoplanetary disks and exoplanet atmospheres have suggested a possible transfer of significant carbon isotope fractionation from disks to planets. For a clearer understanding of the isotopic link between disks and planets, it is important to measure the carbon isotope ratios in various species. In this paper, we present a detection of the $^{13}$CN $N=2-1$ hyperfine lines in the TW Hya disk with the Atacama Large Millimeter/submillimeter Array. This is the first spatially-resolved detection of $^{13}$CN in disks, which enables us to measure the spatially resolved $^{12}$CN/$^{13}$CN ratio for the first time. We conducted non-local thermal equilibrium modeling of the $^{13}$CN lines in conjunction with previously observed $^{12}$CN lines to derive the kinetic temperature, ${\rm H_2}$ volume density, and column densities of $^{12}$CN and $^{13}$CN. The ${\rm H_2}$ volume density is found to range between $ (4 - 10)\times10^7 \ {\rm cm^{-3}}$, suggesting that CN molecules mainly reside in the disk upper layer. The $^{12}$CN/$^{13}$CN ratio is measured to be $ 70^{+9}_{-6}$ at $30 < r < 80$ au from the central star, which is similar to the $\rm ^{12}C/^{13}C$ ratio in the interstellar medium. However, this value differs from the previously reported values found for other carbon-bearing molecules (CO and HCN) in the TW Hya disk. This could be self-consistently explained by different emission layer heights for different molecules combined with preferential sequestration of $\rm ^{12}C$ into the solid phase towards the disk midplane. This study reveals the complexity of the carbon isotope fractionation operating in disks.

astro-ph.EP↗

arXiv2024

Multiple Jets in the bursting protostar HOPS 373SW

We present the outflows detected in HOPS 373SW, a protostar undergoing a modest $30\%$ brightness increase at 850 $μ$m. Atacama Large Millimeter/submillimeter Array (ALMA) observations of shock tracers, including SiO 8--7, CH$_3$OH 7$_{\rm k}$--6$_{\rm k}$, and $^{12}$CO 3--2 emission, reveal several outflow features around HOPS 373SW. The knots in the extremely high-velocity SiO emission reveal the wiggle of the jet, for which a simple model derives a 37$^\circ$ inclination angle of the jet to the plane of the sky, a jet velocity of 90 km s$^{-1}$, and a period of 50 years. The slow SiO and CH$_3$OH emission traces U-shaped bow shocks surrounding the two CO outflows. One outflow is associated with the high-velocity jets, while the other is observed to be close to the plane of the sky. The misaligned outflows imply that previous episodic accretion events have either reoriented HOPS 373SW or that it is an unresolved protostellar binary system with misaligned outflows.

astro-ph.GA↗

arXiv2023

Complex Organic Molecules in a Very Young Hot Corino, HOPS 373SW

We present the spectra of Complex Organic Molecules (COMs) detected in HOPS 373SW with the Atacama Large Millimeter/submillimeter Array (ALMA). HOPS 373SW, which is a component of a protostellar binary with a separation of 1500 au, has been discovered as a variable protostar by the JCMT Transient monitoring survey with a modest ~30% brightness increase at submillimeter wavelengths. Our ALMA Target of Opportunity (ToO) observation at ~345 GHz for HOPS 373SW revealed extremely young chemical characteristics with strong deuteration of methanol. The dust continuum opacity is very high toward the source center, obscuring line emission from within 0.03 arcsec. The other binary component, HOPS 373NE, was detected only in C17O in our observation, implying a cold and quiescent environment. We compare the COMs abundances relative to CH3OH in HOPS 373SW with those of V883 Ori, which is an eruptive disk object, as well as other hot corinos, to demonstrate the chemical evolution from envelope to disk. High abundances of singly, doubly, and triply deuterated methanol (CH2DOH, CHD2OH, and CD3OH) and a low CH3CN abundance in HOPS 373SW compared to other hot corinos suggest a very early evolutionary stage of HOPS 373SW in the hot corino phase. Since the COMs detected in HOPS 373SW would have been sublimated very recently from grain surfaces, HOPS 373SW is a promising place to study the surface chemistry of COMs in the cold prestellar phase, before sublimation.

astro-ph.SR↗

arXiv2023

Triple spiral arms of a triple protostar system imaged in molecular lines

Most stars form in multiple star systems. For a better understanding of their formation processes, it is important to resolve the individual protostellar components and the surrounding envelope and disk material at the earliest possible formation epoch because the formation history can be lost in a few orbital timescales. Here we present the ALMA observational results of a young multiple protostellar system, IRAS 04239+2436, where three well-developed large spiral arms were detected in the shocked SO emission. Along the most conspicuous arm, the accretion streamer was also detected in the SO$_2$ emission. The observational results are complemented by numerical magneto-hydrodynamic simulations, where those large arms only appear in magnetically weakened clouds. The numerical simulations also suggest that the large triple spiral arms are the result of gravitational interactions between compact triple protostars and the turbulent infalling envelope.

astro-ph.GA↗

arXiv2022

Different degrees of nitrogen and carbon depletion in the warm molecular layers of protoplanetary disks

Observations have revealed that the elemental abundances of carbon and oxygen in the warm molecular layers of some protoplanetary disks are depleted compared to those is the interstellar medium by a factor of ~10-100. Meanwhile, little is known about nitrogen. To investigate the time evolution of nitrogen, carbon, and oxygen elemental abundances in disks, we develop a one-dimensional model that incorporates dust settling, turbulent diffusion of dust and ices, as well as gas-ice chemistry including the chemistry driven by stellar UV/X-rays and the galactic cosmic rays. We find that gaseous CO in the warm molecular layer is converted to CO2 ice and locked up near the midplane via the combination of turbulent mixing (i.e., the vertical cold finger effect) and ice chemistry driven by stellar UV photons. On the other hand, gaseous N2, the main nitrogen reservoir in the warm molecular layer, is less processed by ice chemistry, and exists as it is. Then the nitrogen depletion occurs solely by the vertical cold finger effect of N2. As the binding energy of N2 is lower than that of CO and CO2, the degree of nitrogen depletion is smaller than that of carbon and oxygen depletion, leading to higher elemental abundance of nitrogen than that of carbon and oxygen. This evolution occurs within 1 Myr and proceeds further, when the $α$ parameter for the diffusion coefficient is ~0.001. Consequently, the N2H+/CO column density ratio increases with time. How the vertical transport affects the midplane ice composition is briefly discussed.

astro-ph.EP↗