arXiv subjects

Serena Eley

Publications and source records attributed to Serena Eley.

At least 19 recordsLinked to original sources

arXiv2026

Fabrication and Structural Analysis of Trilayers for Tantalum Josephson Junctions with Ta$_2$O$_5$ Barriers

Tantalum (Ta) has emerged as a promising low-loss material, enabling record coherence times in superconducting qubits. This enhanced performance is largely attributed to its stable native oxide, which may host fewer two-level system (TLS) defects, which are the key contributors to decoherence in superconducting circuits. Nevertheless, aluminum oxide remains the predominant choice for Josephson junction (JJ) barriers in most qubit architectures. Here, we investigate techniques for forming high-quality oxide layers on $α$-phase tantalum films to develop tantalum-oxide JJ barriers. We explore thermal oxidation in a tube furnace, rapid thermal annealing, and plasma oxidation of both room-temperature and heated Ta films, characterize the resulting structures using X-ray techniques and electron microscopy, and propose a mechanistic picture of the oxidation pathways. We find that plasma oxidation provides the smoothest Ta$_2$O$_5$ layers, is compatible with in situ Ta deposition, and offers thickness control through the annealing temperature, advantageous for JJ fabrication. Lastly, we evaluate methods for growing Ta/TaO$_x$/Ta trilayers. All trilayers showed c-axis-oriented columnar growth of the bottom Ta layer, with sapphire substrates producing larger, better-aligned grains yet higher dislocation densities than silicon. Nucleation of c-axis-oriented $α$-Ta on tantalum-oxide required an Nb seed layer, as direct Ta deposition yielded amorphous Ta. These results demonstrate the feasibility of $α$-Ta/Nb/TaO$_x$/$α$-Ta stacks for JJs with clean interfaces.

cond-mat.supr-con↗

arXiv2026

Higher critical currents yet faster vortex creep in EuBa$_2$Cu$_3$O$_y$ films containing coherent artificial pinning centers

The electromagnetic properties of type-II superconductors depend on vortices -- magnetic flux lines whose motion introduces dissipation that can be mitigated by pinning from material defects. The material disorder landscape is tuned by the choice of materials growth technique and incorporation of impurities that serve as vortex pinning centers. For example, metal organic deposition (MOD) and pulsed laser deposition (PLD) produce high-quality superconducting films with uncorrelated versus correlated disorder, respectively. Here, we study vortex dynamics in PLD-grown EuBa$_2$Cu$_3$O$_y$ films containing varying concentrations of BaHfO$_3$ inclusions and compare our results with those of MOD-grown (Y,Gd)Ba$_2$Cu$_3$O$_y$ films. Despite both systems exhibiting behavior consistent with strong pinning theory, which predicts the critical current density $J_c$ based on vortex trapping by randomly distributed spherical inclusions, we find striking differences in the vortex dynamics owing to the correlated versus uncorrelated disorder. Specifically, we find that the EuBa$_2$Cu$_3$O$_y$ films grown without inclusions exhibit surprisingly slow vortex creep, comparable to the slowest creep rates achieved in (Y,Gd)Ba$_2$Cu$_3$O$_y$ films containing high concentrations of BaHfO$_3$. Whereas adding inclusions to (Y,Gd)Ba$_2$Cu$_3$O$_y$ is effective in slowing creep, BaHfO$_3$ increases creep in EuBa$_2$Cu$_3$O$_y$ even while concomitantly improving $J_c$. Lastly, we find evidence of variable range hopping and that $J_c$ is maximized at the BaHfO$_3$ concentration that hosts creep of large vortex bundles or a Bose glass state.

cond-mat.supr-con↗

arXiv2026

Tripling of the Superconducting Critical Current Density in BaFe$_2$(As$_{1-x}$P$_x$)$_2$ Retained After Pressure Release

Superconducting performance is tunable not only via chemical modification or defect engineering, but also through external parameters such as pressure, though this method remains less readily accessible. In this work, we study how compression influences vortex dynamics and critical currents in an iron-based superconductor. Specifically, we perform magnetization measurements using an off-the-shelf pressure cell to investigate the effects of hydrostatic pressures up to 1.08 GPa on the magnetic properties of BaFe$_2$(As$_{0.62}$P$_{0.38}$)$_2$ crystals across a range of temperatures $T$ and magnetic fields $H$. Although these pressures minimally affect the superconducting critical temperature, they produce a clear increase in the critical current density $J_c(T,H)$, a pronounced reduction in the rate of thermally activated vortex motion $S(T,H)$, and can change the dominant vortex pinning mechanism. Furthermore, the effects of pressure are irreversible: after pressurization and subsequent release at room temperature, high-density microcracks are observed and the crystals retain their enhanced critical current densities. The second magnetization peak vanishes above 18 K after the pressure cycle, which we attribute to a transition from predominantly $\delta \kappa$ pinning to a mixed mechanism of $\delta T_c$ and surface pinning. Lastly, a threefold increase in $J_c$, a more than 40\% reduction in $S$ at 8~K and 0.5~T, and an expanded elastic-creep region were achieved after $1-2$ pressure cycles. These findings demonstrate the potential utility of pressure cycling for improving $J_c$, which may offer a simpler alternative compared to approaches such as chemical doping or the introduction of artificial pinning centers.

cond-mat.supr-con↗

arXiv2025

Disorder-broadened topological Hall phase and anomalous Hall scaling in FeGe

Magnetic skyrmions are topologically protected spin textures that are promising candidates for low-power spintronic memory and logic devices. Realizing skyrmion-based devices requires an understanding of how structural disorder affects their stability and transport properties. This study uses Ne$^{+}$ ion irradiation at fluences from $10^{11}$ to $10^{14}$ ions-cm$^{-2}$ to systematically vary defect densities in 80 nm epitaxial FeGe films and quantify the resulting modifications to magnetic phase boundaries and electronic scattering. Temperature- and field-dependent Hall measurements reveal that increasing disorder progressively extends the topological Hall signal from a narrow window near 200\~K in pristine films down to 4\~K at the highest fluence, with peak amplitude more than doubling. Simultaneously, the anomalous Hall effect transitions from quadratic Berry curvature scaling to linear skew scattering behavior, with the skew coefficient increasing threefold. These results establish quantitative correlations between defect concentration, skyrmion phase space, and transport mechanisms in a chiral magnet. It demonstrates that ion-beam modification provides systematic control over both topological texture stability and electrical detectability.

cond-mat.mtrl-sci↗

arXiv2024

Structural Properties and Recrystallization Effects in Ion Beam Modified B20-type FeGe Films

Disordered iron germanium (FeGe) has recently garnered interest as a testbed for a variety of magnetic phenomena as well as for use in magnetic memory and logic applications. This is partially owing to its ability to host skyrmions and antiskyrmions -- nanoscale whirlpools of magnetic moments that could serve as information carriers in spintronic devices. In particular, a tunable skyrmion-antiskyrmion system may be created through precise control of the defect landscape in B20-phase FeGe, motivating developing methods to systematically tune disorder in this material and understand the ensuing structural properties. To this end, we investigate a route for modifying magnetic properties in FeGe. Specifically, we irradiate epitaxial B20-phase FeGe films with 2.8 MeV Au$^{4+}$ ions, which creates a dispersion of amorphized regions that may preferentially host antiskyrmions at densities controlled by the irradiation fluence. To further tune the disorder landscape, we conduct a systematic electron diffraction study with in-situ annealing, demonstrating the ability to recrystallize controllable fractions of the material at temperatures ranging from approximately 150$^{\circ}$ C to 250$^{\circ}$C. Finally, we describe the crystallization kinetics using the Johnson-Mehl-Avrami-Kolmogorov model, finding that the growth of crystalline grains is consistent with diffusion-controlled one-to-two dimensional growth with a decreasing nucleation rate.

cond-mat.mtrl-sci↗

arXiv2024

Inducing a Tunable Skyrmion-Antiskyrmion System through Ion Beam Modification of FeGe Films

Skyrmions and antiskyrmions are nanoscale swirling textures of magnetic moments formed by chiral interactions between atomic spins in magnetic non-centrosymmetric materials and multilayer films with broken inversion symmetry. These quasiparticles are of interest for use as information carriers in next-generation, low-energy spintronic applications. To develop skyrmion-based memory and logic, we must understand skyrmion-defect interactions with two main goals -- determining how skyrmions navigate intrinsic material defects and determining how to engineer disorder for optimal device operation. Here, we introduce a tunable means of creating a skyrmion-antiskyrmion system by engineering the disorder landscape in FeGe using ion irradiation. Specifically, we irradiate epitaxial B20-phase FeGe films with 2.8 MeV Au$^{4+}$ ions at varying fluences, inducing amorphous regions within the crystalline matrix. Using low-temperature electrical transport and magnetization measurements, we observe a strong topological Hall effect with a double-peak feature that serves as a signature of skyrmions and antiskyrmions. These results are a step towards the development of information storage devices that use skyrmions and anitskyrmions as storage bits and our system may serve as a testbed for theoretically predicted phenomena in skyrmion-antiskyrmion crystals.

cond-mat.mtrl-sci↗

arXiv2024

Biodegradable Interactive Materials

The sense of touch is fundamental to how we interact with the physical and digital world. Conventional interactive surfaces and tactile interfaces use electronic sensors embedded into objects, however this approach poses serious challenges both for environmental sustainability and a future of truly ubiquitous interaction systems where information is encoded into everyday objects. In this work, we present Biodegradable Interactive Materials: backyard-compostable interactive interfaces that leverage information encoded in material properties. Inspired by natural systems, we propose an architecture that programmatically encodes multidimensional information into materials themselves and combines them with wearable devices that extend human senses to perceive the embedded data. We combine unrefined biological matter from plants and algae like chlorella with natural minerals like graphite and magnetite to produce materials with varying electrical, magnetic, and surface properties. We perform in-depth analysis using physics models, computational simulations, and real-world experiments to characterize their information density and develop decoding methods. Our passive, chip-less materials can robustly encode 12 bits of information, equivalent to 4096 unique classes. We further develop wearable device prototypes that can decode this information during touch interactions using off-the-shelf sensors. We demonstrate sample applications such as customized buttons, tactile maps, and interactive surfaces. We further demonstrate the natural degradation of these interactive materials in degrade outdoors within 21 days and perform a comparative environmental analysis of the benefits of this approach.

cs.HC↗

arXiv2023

Structural and Optoelectronic Properties of Thin Film LaWN$_3$

Nitride perovskites are an emerging class of materials that have been predicted to display a range of interesting physics and functional properties, but they are under-explored due to the difficulty of synthesizing oxygen-free nitrides. LaWN3, recently reported as the first oxygen-free nitride perovskite, exhibited polar symmetry and a large piezoelectric coefficient. However, the predicted ferroelectric switching was hindered by large leakage current, which motivates better understanding of its electronic structure and optical properties. Here, we study the structure and optoelectronic properties of thin film LaWN3 in greater detail, employing combinatorial techniques to correlate these properties with cation stoichiometry. We report a two-step synthesis that utilizes a more common RF substrate bias instead of a nitrogen plasma source, yielding nanocrystalline films that are crystallized by ex-situ annealing. We investigate the structure and composition of these films, finding polycrystalline La-rich and highly textured W-rich films. The optical absorption onset and temperature- and magnetic field-dependent resistivity are consistent with semiconducting behavior and are highly sensitive to cation stoichiometry, which may be related to amorphous impurities: metallic W or WNx in W-rich samples and insulating La2O3 in La-rich samples. The fractional magnetoresistance is linear and small, consistent with defect scattering, and a W-rich sample has n-type carriers with high densities and low mobilities. We demonstrate a photoresponse in LaWN3: the resistivity of a La-rich sample is enhanced by 28% at low temperature, likely due to a defect trapping mechanism. The physical properties of LaWN3 are highly sensitive to cation stoichiometry, like many oxide perovskites, which therefore calls for precise composition control to utilize the interesting properties observed in this nitride perovskite.

cond-mat.mtrl-sci↗

arXiv2021

Plastic vortex creep and dimensional crossovers in the highly anisotropic superconductor HgBa$_2$CuO$_{4+x}$

In type-II superconductors exposed to magnetic fields between upper and lower critical values, $H_{c1}$ and $H_{c2}$, penetrating magnetic flux forms a lattice of vortices whose motion can induce dissipation. Consequently, the magnetization $M$ of superconductors is typically progressively weakened with increasing magnetic field $B \propto n_v$ (for vortex density $n_v$). However, some materials exhibit a non-monotonic $M(B)$, presenting a maximum in $M$ at what is known as the second magnetization peak. This phenomenon appears in most classes of superconductors, including low $T_c$ materials, iron-based, and cuprates, complicating pinpointing its origin and garnering intense interest. Here, we report on vortex dynamics in optimally doped and overdoped HgBa$_2$CuO$_{4+x}$ crystals, with a focus on a regime in which plastic deformations of the vortex lattice govern magnetic properties. Specifically, we find that both crystals exhibit conspicuous second magnetization peaks and, from measurements of the field- and temperature- dependent vortex creep rates, identify and characterize phase boundaries between elastic and plastic vortex dynamics, as well as multiple previously unreported transitions within the plastic flow regime. We find that the second magnetization peak coincides with the elastic-to-plastic crossover for a very small range of high fields, and a sharp crossover within the plastic flow regime for a wider range of lower fields. We find evidence that this transition in the plastic flow regime is due to a dimensional crossover, specifically a transition from 3D to 2D plastic dynamics.

cond-mat.supr-con↗

arXiv2021

Designing high-performance superconductors with nanoparticle inclusions: comparisons to strong pinning theory

One of the most promising routes for achieving unprecedentedly high critical currents in superconductors is to incorporate dispersed, non-superconducting nanoparticles to control the dissipative motion of vortices. However, these inclusions reduce the overall superconducting volume and can strain the interlaying superconducting matrix, which can detrimentally reduce $T_c$. Consequently, an optimal balance must be achieved between the nanoparticle density $n_p$ and size $d$. Determining this balance requires garnering a better understanding of vortex-nanoparticle interactions, described by strong pinning theory. Here, we map the dependence of the critical current on nanoparticle size and density in (Y$_{0.77}$,Gd$_{0.23}$)Ba$_2$Cu$_3$O$_{7-δ}$ films in magnetic fields up to 35 T, and compare the trends to recent results from time-dependent Ginzburg-Landau simulations. We identify consistencies between the field-dependent critical current $J_c(B)$ and expectations from strong pinning theory. Specifically, we find that that $J_c \propto B^{-α}$, where $α$ decreases from $0.66$ to $0.2$ with increasing density of nanoparticles and increases roughly linearly with nanoparticle size $d/ξ$ (normalized to the coherence length). At high fields, the critical current decays faster ($\sim B^{-1}$), suggestive that each nanoparticle has captured a vortex. When nanoparticles capture more than one vortex, a small, high-field peak is expected in $J_c(B)$. Due to a spread in defect sizes, this novel peak effect remains unresolved here. Lastly, we reveal that the dependence of the vortex creep rate $S$ on nanoparticle size and density roughly mirrors that of $α$, and compare our results to low-$T$ nonlinearities in $S(T)$ that are predicted by strong pinning theory.

cond-mat.supr-con↗

arXiv2021

Perspective: Challenges and Transformative Opportunities in Superconductor Vortex Physics

In superconductors, the motion of vortices introduces unwanted dissipation that is disruptive to applications. Fortunately, material defects can immobilize vortices, acting as vortex pinning centers, which engenders dramatic improvements in superconductor material properties and device operation. This has motivated decades of research into developing methods of tailoring the disorder landscape in superconductors to increase the strength of vortex pinning. Yet efficacious materials engineering still alludes us. The electromagnetic properties of real (disordered) superconducting materials cannot yet be reliably predicted, such that designing superconductors for applications remains a largely inefficient process of trial and error. This is ultimately due to large gaps in our knowledge of vortex dynamics: the field is challenged by the extremely complex interplay between vortex elasticity, vortex-vortex interactions, and material disorder. In this Perspective, we review obstacles and recent successes in understanding and controlling vortex dynamics in superconducting materials and devices. We further identify major open questions and discuss opportunities for transformative research in the field. This includes improving our understanding of vortex creep, determining and reaching the ceiling for the critical current, advanced microscopy to garner accurate structure-property relationships, frontiers in predictive simulations and the benefits of artificial intelligence, as well as controlling and exploiting vortices in quantum information applications.

cond-mat.supr-con↗

arXiv2020

Observation of anti-damping spin-orbit torques generated by in-plane and out-of-plane spin polarizations in MnPd3

High spin-orbit torques (SOTs) generated by topological materials and heavy metals interfaced with a ferromagnetic layer show promise for next generation magnetic memory and logic devices. SOTs generated from the in-plane spin polarization along y-axis originated by the spin Hall and Edelstein effects can switch magnetization collinear with the spin polarization in the absence of external magnetic fields. However, an external magnetic field is required to switch the magnetization along x and z-axes via SOT generated by y-spin polarization. Here, we present that the above limitation can be circumvented by unconventional SOT in magnetron-sputtered thin film MnPd3. In addition to the conventional in-plane anti-damping-like torque due to the y-spin polarization, out-of-plane and in-plane anti-damping-like torques originating from z-spin and x-spin polarizations, respectively have been observed at room temperature. The spin torque efficiency corresponding to the y-spin polarization from MnPd3 thin films grown on thermally oxidized silicon substrate and post annealed at 400 Deg C is 0.34 - 0.44. Remarkably, we have demonstrated complete external magnetic field-free switching of perpendicular Co layer via unconventional out-of-plane anti-damping-like torque from z-spin polarization. Based on the density functional theory calculations, we determine that the observed x- and z- spin polarizations with the in-plane charge current are due to the low symmetry of the (114) oriented MnPd3 thin films. Taken together, the new material reported here provides a path to realize a practical spin channel in ultrafast magnetic memory and logic devices.

cond-mat.mtrl-sci↗

arXiv2019

Vortex phases and glassy dynamics in the highly anisotropic superconductor HgBa$_2$CuO$_{4+δ}$

We present an extensive study of vortex dynamics in a high-quality single crystal of HgBa$_2$CuO$_{4+δ}$ (Hg1201), a highly anisotropic superconductor that is a model system for studying the effects of anisotropy. From magnetization $M$ measurements over a wide range of temperatures $T$ and fields $H$, we construct a detailed vortex phase diagram. We find that the temperature-dependent vortex penetration field $H_p(T)$, second magnetization peak $H_{smp}(T)$, and irreversibility field $H_{irr}(T)$ all decay exponentially at low temperatures and exhibit an abrupt change in behavior at high temperatures $T/T_c \gtrsim 0.5$. By measuring the rates of thermally activated vortex motion (creep) $S(T,H)=|d \ln M(T,H) / d \ln t|$, we reveal glassy behavior involving collective creep of bundles of 2D pancake vortices as well as temperature- and time-tuned crossovers from elastic (collective) dynamics to plastic flow. Based on the creep results, we show that the second magnetization peak coincides with the elastic-to-plastic crossover at low $T$, yet the mechanism changes at higher temperatures.

cond-mat.supr-con↗

arXiv2018

Accelerated vortex dynamics across the magnetic 3D-to-2D crossover in disordered superconductors

Disorder can have remarkably disparate consequences in superconductors, driving superconductor-insulator transitions in ultrathin films by localizing electron pairs and boosting the supercurrent carrying capacity of thick films by localizing vortices (magnetic flux lines). Though the electronic 3D-to-2D crossover at material thicknesses $d \sim ξ$ (coherence length) is well studied, a similarly consequential magnetic crossover at $d \sim L_c$ (pinning length) that should drastically alter material properties remains largely underexamined. According to collective pinning theory, vortex segments of length $L_c$ bend to adjust to energy wells provided by point defects. Consequently, if $d$ truncates $L_c$, a change from elastic to rigid vortex dynamics should increase the rate of thermally activated vortex motion $S$. Here, we characterize the dependence of $S$ on sample thickness in Nb and cuprate films. The results for Nb are consistent with collective pinning theory, whereas creep in the cuprate is strongly influenced by sparse large precipitates. We leverage the sensitivity of $S$ to $d$ to determine the generally unknown scale $L_c$, establishing a new route for extracting pinning lengths in heterogeneously disordered materials.

cond-mat.supr-con↗

arXiv2018

Glassy Dynamics in a heavy ion irradiated NbSe2 crystal

Fascination with glassy states has persisted since Fisher introduced the vortex-glass as a new thermodynamic phase that is a true superconductor that lacks conventional long-range order. Though Fisher's original model considered point disorder, it was later predicted that columnar defects (CDs) could also induce glassiness -- specifically, a Bose-glass phase. In YBa$_2$Cu$_3$O$_{7-x}$ (YBCO), glassy states can cause distinct behavior in the temperature ($T$) dependent rate of thermally activated vortex motion ($S$). The vortex-glass state produces a plateau in $S(T)$ whereas a Bose-glass can transition into a state hosting vortex excitations called double-kinks that can expand, creating a large peak in $S(T)$. Although glass phases have been well-studied in YBCO, few studies exist of other materials containing CDs that could contribute to distinguishing universal behavior. Here, we report on the effectiveness of CDs tilted ~30$°$ from the c-axis in reducing $S$ in a NbSe$_2$ crystal. The magnetization is 5 times higher and $S$ is minimized when the field is parallel to the defects versus aligned with the c-axis. We see signatures of glassiness in both field orientations, but do not observe a peak in $S(T)$ nor a plateau at values observed in YBCO. We discuss the possibility that competing disorder induces a field-orientation-driven transition from a Bose-glass to an anisotropic glass involving both point and columnar disorder.

cond-mat.supr-con↗

arXiv2016

Universal Lower Limit on Vortex Creep in Superconductors

Superconductors are excellent testbeds for studying vortices, topological excitations that also appear in superfluids, liquid crystals, and Bose-Einstein condensates. Vortex motion can be disruptive; it can cause phase transitions, glitches in pulsars, and losses in superconducting microwave circuits, and it limits the current carrying capacity of superconductors. Understanding vortex dynamics is therefore of fundamental and technological importance, and the competition between the effects of thermal energy and energy barriers defined by material disorder is not completely understood. In particular, early measurements of thermally-activated vortex motion (creep) in iron-based superconductors unveiled fast rates (S) comparable to measurements of YBa2Cu3O7 (YBCO). This was puzzling because S is thought to somehow positively correlate with the Ginzburg number (Gi), and Gi is orders of magnitude lower in most iron-based superconductors than in YBCO. Here, we report very slow creep in BaFe2(As0.67P0.33)2 films, and propose that there is a universal minimum realizable (where Tc is the superconducting transition temperature) that has been achieved in our films, few other materials, and violated by none. This limitation provides new clues on how to design materials with slow creep and helps elucidate open questions regarding the interplay between system-specific length scales and vortex dynamics.

cond-mat.supr-con↗

arXiv2016

History-dependent dissipative vortex dynamics in superconducting arrays

We perform current(I)-voltage(V) measurements on low resistance superconductor-normal-superconductor arrays in finite magnetic fields, focusing on the dilute vortex population regime. We observe significant deviations from predicted behavior, notably the absence of a differential resistance peak near the vortex de-pinning current, and a broad linear I-V region with an extrapolated I intercept equal to the de-pinning current. Comparing these results to an overdamped molecular vortex model, we find that this behavior can be explained by the presence of a history dependent dissipative force. This approach has not been considered previously, yet is crucial for obtaining a correct description of the vortex dynamics in superconducting arrays.

cond-mat.supr-con↗

arXiv2015

Rapid Doubling of the Critical Current of YBa$_2$Cu$_3$O$_{7-δ}$ Coated Conductors for Viable High-Speed Industrial Processing

We demonstrate that 3.5-MeV oxygen irradiation can markedly enhance the in-field critical current of commercial 2nd generation superconducting tapes with an exposure time of just one second per 0.8 cm2. The speed demonstrated here is now at the level required for an industrial reel-to-reel post-processing. The irradiation is made on production line samples through the protective silver coating and does not require any modification of the growth process. From TEM imaging, we identify small clusters as the main source of increased vortex pinning.

cond-mat.supr-con↗