arXiv subjects

Serena Viti

Publications and source records attributed to Serena Viti.

At least 37 records · Page 2Linked to original sources

arXiv2025

ALMA uncovers optically thin and multi-component CO gas in the outflowing circumnuclear disk of NGC1068

Active galactic nuclei (AGNs) influence their host galaxies through winds and jets that can drive molecular outflows, traceable with CO line emissions using the Atacama Large Millimeter Array (ALMA). Recent studies leveraging ALMA data have proposed a three-dimensional outflow geometry in the nearby Seyfert II galaxy NGC 1068, a key target for AGN unification theories. Using ALMA observations of CO(2-1), CO(3-2), and CO(6-5) transitions at roughly 0.1 arcseconds (approximately 7 parsecs) resolution, we analyzed the temperature, density, and kinematics of NGC 1068's circumnuclear disk (CND), focusing on the molecular outflow. Through local thermodynamic equilibrium (LTE) analysis, we derived column densities and rotational temperatures, indicating optically thin gas and CO-to-H2 (XCO) conversion factors between 4.8 and 9.6 times smaller than the Milky Way value. The inferred molecular mass outflow rate is mostly below 5.5 solar masses per year, with the dominant contribution northeast of the AGN. After subtracting the rotation curve of the CND, we modeled averaged line profiles in each region using single and multi-component Gaussian fits. Several profiles within or near the AGN wind bicone required multiple components with significant velocity shifts, suggesting multi-component complex outflow kinematics. We observe lateral variation in CO kinematics along the AGN wind bicone and a misalignment between the molecular and ionized outflow directions. These results imply that the dynamic impact of the ionized AGN wind on the molecular gas in the CND may be limited. However, the molecular outflow shows a complex, asymmetric structure.

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arXiv2025

Hydrodynamic simulations of the Disc of Gas Around Supermassive black holes (HDGAS) -II; The transition from neutral atomic to molecular gas phases

We use HDGAS hydrodynamic simulations to study the impact of active galactic nucleus (AGN) feedback on the conversion of atomic-gas to molecular-gas within the circumnuclear-disc (CND) of a typical AGN-dominated galaxy. The comparison of CI, CII, and CO line intensities and their ratios in the HDGAS post-processing radiative-transfer analysis reveals the complex interplay between AGN-activity, cold molecular gas properties, and the physical processes governing the evolution of star-formation in galaxies. Our results demonstrate that the CI/CO intensity ratio serves as a reliable indicator of the atomic-to-molecular gas transition. We present the probability distribution function (PDF) and abundance trends of various metal species related to molecular H$2$ gas, highlighting differences in clumpiness and intensity maps between AGN feedback and NoAGN models. The profile of the integrated intensity (moment-0) maps shows that the AGN-feedback model exhibits a lower CI/CO intensity ratio in the vicinity of the supermassive black hole (< 50 pc), indicating a smaller atomic-gas abundance and the presence of positive AGN-feedback. Our simulations have successfully predicted the presence of faint-CO emissions extending to larger radii from the galactic center. We also explore the relationships between CII/CO and CI/CII intensity ratios, as well as the ratios versus CO intensity, which provides insights into the "CO-dark" issues. One notable feature in the later time-scale of the AGN model is the presence of a "CO-dark" region, where the intensity of CO emission ($\rm I_{CO}$) is depleted relative to the H$_2$ column density ($N_{\rm H_2}$) compared to the NoAGN model.

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arXiv2025

Modelling methanol and hydride formation in the JWST Ice Age era

(Abridged) JWST observations have measured the ice composition toward two highly-extinguished field stars in the Chamaeleon I cloud. The observed extinction excess on the long-wavelength side of the H2O ice band at 3 micron has been attributed to a mixture of CH3OH with ammonia hydrates, which suggests that CH3OH ice could have formed in a water-rich environment with little CO depletion. Laboratory experiments and quantum chemical calculations suggest that CH3OH could form via the grain surface reactions CH3+OH and/or C+H2O in water-rich ices. However, no dedicated chemical modelling has been carried out thus far to test their efficiency and dependence on the astrochemical code employed. We model the ice chemistry in the Chamaeleon I cloud using a set of astrochemical codes (MAGICKAL, MONACO, Nautilus, UCLCHEM, and KMC simulations) to test the effects of the different code architectures and of the assumed ice chemistry. Our models show that the JWST ice observations are better reproduced for gas densities >1e5 cm-3 and collapse times >1e5 yr. CH3OH ice forms predominantly (>99%) via CO hydrogenation. The contribution of reactions CH3+OH and C+H2O, is negligible. The CO2 ice may form either via CO+OH or CO+O depending on the code. However, KMC simulations reveal that both mechanisms are efficient despite the low rate constant of the CO+O surface reaction. CH4 is largely underproduced for all codes except for UCLCHEM, for which a higher amount of atomic C is available during the initial translucent cloud phase. Large differences in the ice abundances are found at Tdust<12 K between diffusive and non-diffusive chemistry codes. This is due to the fact that non-diffusive chemistry takes over diffusive chemistry at such low Tdust. This could explain the rather constant ice chemical composition found in Chamaeleon I and other dense cores despite the different visual extinctions probed.

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arXiv2025

The JCMT Gould Belt Survey: First results from the Corona Australis molecular cloud and evidence of variable dust emissivity indices in the Coronet region

We present 450$μ$m and 850$μ$m James Clerk Maxwell Telescope (JCMT) observations of the Corona Australis (CrA) molecular cloud taken as part of the JCMT Gould Belt Legacy Survey (GBLS). We present a catalogue of 39 starless and protostellar sources, for which we determine source temperatures and masses using SCUBA-2 450$μ$m/850$μ$m flux density ratios for sources with reliable 450$μ$m detections, and compare these to values determined using temperatures measured by the Herschel Gould Belt Survey (HGBS). In keeping with previous studies, we find that SCUBA-2 preferentially detects high-volume-density starless cores, which are most likely to be prestellar (gravitationally bound). We do not observe any anti-correlation between temperature and volume density in the starless cores in our sample. Finally, we combine our SCUBA-2 and Herschel data to perform SED fitting from 160-850$μ$m across the central Coronet region, thereby measuring dust temperature $T$, dust emissivity index $β$ and column density $N({\rm H}_2)$ across the Coronet. We find that $β$ varies across the Coronet, particularly measuring $β= 1.55 \pm 0.35$ in the colder starless SMM-6 clump to the north of the B star R CrA. This relatively low value of $β$ is suggestive of the presence of large dust grains in SMM-6, even when considering the effects of $T-β$ fitting degeneracy and $^{12}$CO contamination of SCUBA-2 850$μ$m data on the measured $β$ values.

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arXiv2024

3D-PDR Orion dataset and NeuralPDR: Neural Differential Equations for Photodissociation Regions

We present a novel dataset of simulations of the photodissociation region (PDR) in the Orion Bar and provide benchmarks of emulators for the dataset. Numerical models of PDRs are computationally expensive since the modeling of these changing regions requires resolving the thermal balance and chemical composition along a line-of-sight into an interstellar cloud. This often makes it a bottleneck for 3D simulations of these regions. In this work, we provide a dataset of 8192 models with different initial conditions simulated with 3D-PDR. We then benchmark different architectures, focusing on Augmented Neural Ordinary Differential Equation (ANODE) based models (Code be found at https://github.com/uclchem/neuralpdr). Obtaining fast and robust emulators that can be included as preconditioners of classical codes or full emulators into 3D simulations of PDRs.

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arXiv2024

Components of star formation in NGC 253 : Non-negative Matrix Factorization Analysis with the ALCHEMI integrated intensity images

It is essential to examine the physical or chemical properties of molecular gas in starburst galaxies to reveal the underlying mechanisms characterizing starbursts. We used non-negative matrix factorization (NMF) to extract individual molecular or physical components involved in the star formation process in NGC\,253. We used images of 148 transitions from 44 different species of the ALMA large program ALCHEMI. Additionally, we included the continuum images at ALMA Bands 3 and 7 from the same dataset. For the five NMF components (NF1--5), we obtained that their distributions correspond to various basic phenomena related to star formation: i) low-density gas extended through the galactic central molecular zone (NF2), ii) shocks (NF3), iii) starburst regions (NF4), and iv) young star-forming regions (NF5). The other component (NF1) is related to excitation; three components obtained by NMF (NF3, 1, and 5) show a strong dependence upon the upper state energies of transitions, and represent low-, intermediate-, and high-excitation, respectively. We also compared our results using principal component analysis (PCA) previously applied to the same dataset. Molecular components extracted from NMF are similar to the ones obtained from PCA. However, NMF is better at extracting components associated with a single physical component, while a single component in PCA usually contains information on multiple physical components. This is especially true for features with weak intensities like emission from outflows. Our results suggest that NMF can be one of promising methods interpreting molecular line survey data, especially in the upcoming era of wide-band receivers.

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arXiv2024

Neural Network Constraints on the Cosmic-Ray Ionization Rate and Other Physical Conditions in NGC 253 with ALCHEMI Measurements of HCN and HNC

We use a neural network model and ALMA observations of HCN and HNC to constrain the physical conditions, most notably the cosmic-ray ionization rate (CRIR, zeta), in the Central Molecular Zone (CMZ) of the starburst galaxy NGC 253. Using output from the chemical code UCLCHEM, we train a neural network model to emulate UCLCHEM and derive HCN and HNC molecular abundances from a given set of physical conditions. We combine the neural network with radiative transfer modeling to generate modeled integrated intensities, which we compare to measurements of HCN and HNC from the ALMA Large Program ALCHEMI. Using a Bayesian nested sampling framework, we constrain the CRIR, molecular gas volume and column densities, kinetic temperature, and beam-filling factor across NGC 253's CMZ. The neural network model successfully recovers UCLCHEM molecular abundances with about 3 percent error and, when used with our Bayesian inference algorithm, increases the parameter inference speed tenfold. We create images of these physical parameters across NGC 253's CMZ at 50 pc resolution and find that the CRIR, in addition to the other gas parameters, is spatially variable with zeta a few times 10^{14} s^{-1} at greater than 100 pc from the nucleus, increasing to zeta greater than 10^{-13} s^{-1} at its center. These inferred CRIRs are consistent within 1 dex with theoretical predictions based on non-thermal emission. Additionally, the high CRIRs estimated in NGC 253's CMZ can be explained by the large number of cosmic-ray-producing sources as well as a potential suppression of cosmic-ray diffusion near their injection sites.

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arXiv2024

Detection of antifreeze molecule ethylene glycol in the hot molecular core G358.93$-$0.03 MM1

The identification of complex prebiotic molecules using millimeter and submillimeter telescopes allows us to understand how the basic building blocks of life are formed in the universe. In the interstellar medium (ISM), ethylene glycol ((CH$_{2}$OH)$_{2}$) is the simplest sugar alcohol molecule, and it is the reduced alcohol of the simplest sugar-like molecule, glycolaldehyde (CH$_{2}$OHCHO). We present the first detection of the rotational emission lines of $aGg^{\prime}$ conformer of ethylene glycol ((CH$_{2}$OH)$_{2}$) towards the hot molecular core G358.93$-$0.03 MM1 using the Atacama Large Millimeter/Submillimeter Array (ALMA). The estimated column density of $aGg^{\prime}$-(CH$_{2}$OH)$_{2}$ towards the G358.93$-$0.03 MM1 is (4.5$\pm$0.1)$\times$10$^{16}$ cm$^{-2}$ with an excitation temperature of 155$\pm$35 K. The abundance of $aGg^{\prime}$-(CH$_{2}$OH)$_{2}$ with respect to H$_{2}$ is (1.4$\pm$0.5)$\times$10$^{-8}$. Similarly, the abundances of $aGg^{\prime}$-(CH$_{2}$OH)$_{2}$ with respect to CH$_{2}$OHCHO and CH$_{3}$OH are 3.1$\pm$0.5 and (6.1$\pm$0.3)$\times$10$^{-3}$. We compare the estimated abundance of $aGg^{\prime}$-(CH$_{2}$OH)$_{2}$ with the existing three-phase warm-up chemical model abundance of (CH$_{2}$OH)$_{2}$, and we notice the observed abundance and modelled abundance are nearly similar. We discuss the possible formation pathways of $aGg^{\prime}$-(CH$_{2}$OH)$_{2}$ towards the hot molecular cores, and we find that $aGg^{\prime}$-(CH$_{2}$OH)$_{2}$ is probably created via the recombination of two CH$_{2}$OH radicals on the grain surface of G358.93$-$0.03 MM1.

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arXiv2024

Multiple chemical tracers finally unveil the intricate NGC\,1333 IRAS\,4A outflow system. FAUST XVI

The exploration of outflows in protobinary systems presents a challenging yet crucial endeavour, offering valuable insights into the dynamic interplay between protostars and their evolution. In this study, we examine the morphology and dynamics of jets and outflows within the IRAS\,4A protobinary system. This analysis is based on ALMA observations of SiO(5--4), H$_2$CO(3$_{0,3}$--2$_{0,3}$), and HDCO(4$_{1,4}$--3$_{1,3}$) with a spatial resolution of $\sim$150\,au. Leveraging an astrochemical approach involving the use of diverse tracers beyond traditional ones has enabled the identification of novel features and a comprehensive understanding of the broader outflow dynamics. Our analysis reveals the presence of two jets in the redshifted emission, emanating from IRAS\,4A1 and IRAS\,4A2, respectively. Furthermore, we identify four distinct outflows in the region for the first time, with each protostar, 4A1 and 4A2, contributing to two of them. We characterise the morphology and orientation of each outflow, challenging previous suggestions of bends in their trajectories. The outflow cavities of IRAS\,4A1 exhibit extensions of 10$''$ and 13$''$ with position angles (PA) of 0$^{\circ}$ and -12$^{\circ}$, respectively, while those of IRAS\,4A2 are more extended, spanning 18$''$ and 25$''$ with PAs of 29$^{\circ}$ and 26$^{\circ}$. We propose that the misalignment of the cavities is due to a jet precession in each protostar, a notion supported by the observation that the more extended cavities of the same source exhibit lower velocities, indicating they may stem from older ejection events.

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arXiv2024

A broad linewidth, compact, millimeter-bright molecular emission line source near the Galactic Center

A compact source, G0.02467-0.0727, was detected in ALMA \threemm observations in continuum and very broad line emission. The continuum emission has a spectral index $α\approx3.3$, suggesting that the emission is from dust. The line emission is detected in several transitions of CS, SO, and SO$_2$ and exhibits a line width FWHM $\approx160$ \kms. The line profile appears Gaussian. The emission is weakly spatially resolved, coming from an area on the sky $\lesssim1"$ in diameter ($\lesssim10^4$ AU at the distance of the Galactic Center; GC). The centroid velocity is $v_{LSR}\approx40$-$50$ \kms, which is consistent with a location in the Galactic Center. With multiple SO lines detected, and assuming local thermodynamic equilibrium (LTE) conditions, $T_\mathrm{LTE} = 13$ K, which is colder than seen in typical GC clouds, though we cannot rule out low-density, subthermally excited, warmer gas. Despite the high velocity dispersion, no emission is observed from SiO, suggesting that there are no strong ($\gtrsim10~\mathrm{km~s}^{-1}$) shocks in the molecular gas. There are no detections at other wavelengths, including X-ray, infrared, and radio. We consider several explanations for the Millimeter Ultra-Broad Line Object (MUBLO), including protostellar outflow, explosive outflow, collapsing cloud, evolved star, stellar merger, high-velocity compact cloud, intermediate mass black hole, and background galaxy. Most of these conceptual models are either inconsistent with the data or do not fully explain it. The MUBLO is, at present, an observationally unique object.

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arXiv2024

Physical Properties of the Southwest Outflow Streamer in the Starburst Galaxy NGC 253 with ALCHEMI

The physical properties of galactic molecular outflows are important as they could constrain outflow formation mechanisms. We study the properties of the southwest (SW) outflow streamer including gas kinematics, optical depth, dense gas fraction, and shock strength in the central molecular zone of the starburst galaxy NGC 253. We image the molecular emission at a spatial resolution of $\sim$27 pc based on data from the ALCHEMI program. We trace the kinematics of molecular gas with CO(1-0) line. We constrain the optical depth of CO emission with CO/$^{13}$CO(1-0) ratio, the dense gas fraction with HCN/CO(1-0) ratio, as well as the shock strength with SiO(2-1)/$^{13}$CO(1-0) ratio. The CO/$^{13}$CO(1-0) integrated intensity ratio is $\sim$21 in the SW streamer region, which approximates the C/$^{13}$C isotopic abundance ratio. The higher integrated intensity ratio compared to the disk can be attributed to the optically thinner environment for CO(1-0) emission inside the SW streamer. The HCN/CO(1-0) and SiO(2-1)/$^{13}$CO(1-0) integrated intensity ratios both approach $\sim$0.2 in three giant molecular clouds (GMCs) at the base of the outflow streamers, which implies the higher dense gas fraction and enhanced strength of fast shocks in those GMCs than in the disk. The contours of those two integrated intensity ratios are extended towards the directions of outflow streamers, which connects the enhanced dense gas fraction and shock strength with molecular outflow. Moreover, the molecular gas with enhanced dense gas fraction and shock strength located at the base of the SW streamer shares the same velocity with the outflow. These phenomena suggest that the star formation inside the GMCs can trigger the shocks and further drive the molecular outflow.

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arXiv2024

GOALS-JWST: Mid-Infrared Molecular Gas Excitation Probes the Local Conditions of Nuclear Star Clusters and the AGN in the LIRG VV 114

The enormous increase in mid-IR sensitivity and spatial and spectral resolution provided by the JWST spectrographs enables, for the first time, detailed extragalactic studies of molecular vibrational bands. This opens an entirely new window for the study of the molecular interstellar medium in luminous infrared galaxies (LIRGs). We present a detailed analysis of rovibrational bands of gas-phase CO, H$_2$O, C$_2$H$_2$ and HCN towards the heavily-obscured eastern nucleus of the LIRG VV 114, as observed by NIRSpec and MIRI MRS. Spectra extracted from apertures of 130 pc in radius show a clear dichotomy between the obscured AGN and two intense starburst regions. We detect the 2.3 $μ$m CO bandheads, characteristic of cool stellar atmospheres, in the star-forming regions, but not towards the AGN. Surprisingly, at 4.7 $\mathrmμ$m we find highly-excited CO ($T_\mathrm{ex} \approx 700-800$ K out to at least rotational level $J = 27$) towards the star-forming regions, but only cooler gas ($T_\mathrm{ex} \approx 200$ K) towards the AGN. We conclude that only mid-infrared pumping through the rovibrational lines can account for the equilibrium conditions found for CO and H$_2$O in the deeply-embedded starbursts. Here the CO bands probe regions with an intense local radiation field inside dusty young massive star clusters or near the most massive young stars. The lack of high-excitation molecular gas towards the AGN is attributed to geometric dilution of the intense radiation from the bright point source. An overview of the relevant excitation and radiative transfer physics is provided in an appendix.

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arXiv2024

Atacama Large Aperture Submillimeter Telescope (AtLAST) science: Gas and dust in nearby galaxies

Understanding the physical processes that regulate star formation and galaxy evolution are major areas of activity in modern astrophysics. Nearby galaxies offer unique opportunities to inspect interstellar medium (ISM), star formation (SF), radiative, dynamic and magnetic physics in great detail from sub-galactic (kpc) scales to sub-cloud (sub-pc) scales, from quiescent galaxies to starbursts, and from field galaxies to overdensities. In this case study, we discuss the major breakthroughs in this area of research that will be enabled by the Atacama Large Aperture Submillimeter Telescope (AtLAST), a proposed 50-m single-dish submillimeter telescope. The new discovery space of AtLAST comes from its exceptional sensitivity, in particular to extended low surface brightness emission, a very large 2 degree field of view, and correspondingly high mapping efficiency. This paper focuses on four themes which will particularly benefit from AtLAST: 1) the LMC and SMC, 2) extragalactic magnetic fields, 3) the physics and chemistry of the interstellar medium, and 4) star formation and galaxy evolution. With ~1000-2000h surveys each, AtLAST could deliver deep dust continuum maps of the entire LMC and SMC fields at parsec-scale resolution, high-resolution maps of the magnetic field structure, gas density, temperature and composition of the dense and diffuse ISM in ~100 nearby galaxies, as well as the first large-scale blind CO survey in the nearby Universe, delivering molecular gas masses for up to 10^6 galaxies (3 orders of magnitude more than current samples). Through such observing campaigns, AtLAST will have a profound impact on our understanding of the baryon cycle and star formation across a wide range of environments.

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arXiv2024

The ALCHEMI atlas: principal component analysis reveals starburst evolution in NGC 253

Molecular lines are powerful diagnostics of the physical and chemical properties of the interstellar medium (ISM). These ISM properties, which affect future star formation, are expected to differ in starburst galaxies from those of more quiescent galaxies. We investigate the ISM properties in the central molecular zone of the nearby starburst galaxy NGC 253 using the ultra-wide millimeter spectral scan survey from the ALMA Large Program ALCHEMI. We present an atlas of velocity-integrated images at a 1".6 resolution of 148 unblended transitions from 44 species, including the first extragalactic detection of HCNH$^+$ and the first interferometric images of C$_3$H$^+$, NO, HCS$^+$. We conduct a principal component analysis (PCA) on these images to extract correlated chemical species and to identify key groups of diagnostic transitions. To the best of our knowledge, our dataset is currently the largest astronomical set of molecular lines to which PCA has been applied. The PCA can categorize transitions coming from different physical components in NGC 253 such as i) young starburst tracers characterized by high-excitation transitions of HC$_3$N and complex organic molecules (COMs) versus tracers of on-going star formation (radio recombination lines) and high-excitation transitions of CCH and CN tracing PDRs, ii) tracers of cloud-collision-induced shocks (low-excitation transitions of CH$_3$OH, HNCO, HOCO$^+$, and OCS) versus shocks from star-formation-induced outflows (high-excitation transitions of SiO), as well as iii) outflows showing emission from HOC$^+$, CCH, H$_3$O$^+$, CO isotopologues, HCN, HCO$^+$, CS, and CN. Our findings show these intensities vary with galactic dynamics, star formation activities, and stellar feedback.

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arXiv2023

Disentangling Multiple Emitting Components in Molecular Observations with Non-negative Matrix Factorization

Molecular emission from the galactic and extragalactic interstellar medium (ISM) is often used to determine the physical conditions of the dense gas. However, even from spatially resolved regions, the observed molecules are not necessarily arising from a single component. Disentangling multiple gas components is often a degenerate problem in radiative transfer studies. In this paper we investigate the use of the non-negative matrix factorization (NMF) approach as a means to recover gas components from a set of blended line intensity maps of molecular transitions which may trace different physical conditions. We run a series of experiments on synthetic datasets designed to replicate conditions in two very different environments: galactic pre-stellar cores and the ISM in high redshift galaxies. We find that the NMF algorithm often recovers the multiple components resembling those used in the data-generating process, provided that the different components have similar column densities. When NMF fails to recover all the individual components it does however group together the most similarly emitting ones. We further found that initialisation and regularisation are key factors in the efficiency of the NMF algorithm.

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arXiv2023

Volume density structure of the NGC253 CMZ through ALCHEMI excitation analysis

We present a spatially-resolved excitation analysis for the central molecular zone (CMZ) of the starburst galaxy NGC 253 using the data from the ALMA Large program ALCHEMI, whereby we explore parameters distinguishing NGC 253 from the quiescent Milky Way's Galactic Center (GC). Non-LTE analyses employing a hierarchical Bayesian framework are applied to Band 3-7 transitions from nine molecular species to delineate the position-position-velocity distributions of column density ($N_\mathrm{H_2}$), volume density ($n_\mathrm{H_2}$), and temperature ($T_\mathrm{kin}$) at 27 pc resolution. Two distinct components are detected: a low-density component with $(n_\mathrm{H_2},\ T_\mathrm{kin})\sim(10^{3.3}\ \mathrm{cm}^{-3}, 85 K)$ and a high-density component with $(n_\mathrm{H_2},\ T_\mathrm{kin})\sim (10^{4.4}\ \mathrm{cm}^{-3}, 110\ \mathrm{K})$, separated at $n_\mathrm{H_2}\sim10^{3.8}\ \mathrm{cm}^{-3}$. NGC 253 has $\sim10$ times the high-density gas mass and $\sim3$ times the dense-gas mass fraction of the GC. These properties are consistent with their HCN/CO ratio but cannot alone explain the factor of $\sim30$ difference in their star formation efficiencies (SFEs), contradicting the dense-gas mass to star formation rate scaling law. The $n_\mathrm{H_2}$ histogram toward NGC 253 exhibits a shallow declining slope up to $n_\mathrm{H_2}\sim10^6\ \mathrm{cm}^{-3}$, while that of the GC steeply drops in $n_\mathrm{H_2}\gtrsim10^{4.5}\ \mathrm{cm}^{-3}$ and vanishes at $10^5\ \mathrm{cm}^{-3}$. Their dense-gas mass fraction ratio becomes consistent with their SFEs when the threshold $n_\mathrm{H_2}$ for the dense gas is taken at $\sim 10^{4.2\mbox{-}4.6}\ \mathrm{cm}^{-3}$. The rich abundance of gas above this density range in the NGC 253 CMZ, or its scarcity in the GC, is likely to be the critical difference characterizing the contrasting star formation in the centers of the two galaxies.

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arXiv2023

Understanding Molecular Abundances in Star-Forming Regions Using Interpretable Machine Learning

Astrochemical modelling of the interstellar medium typically makes use of complex computational codes with parameters whose values can be varied. It is not always clear what the exact nature of the relationship is between these input parameters and the output molecular abundances. In this work, a feature importance analysis is conducted using SHapley Additive exPlanations (SHAP), an interpretable machine learning technique, to identify the most important physical parameters as well as their relationship with each output. The outputs are the abundances of species and ratios of abundances. In order to reduce the time taken for this process, a neural network emulator is trained to model each species' output abundance and this emulator is used to perform the interpretable machine learning. SHAP is then used to further explore the relationship between the physical features and the abundances for the various species and ratios we considered. \ce{H2O} and CO's gas phase abundances are found to strongly depend on the metallicity. \ce{NH3} has a strong temperature dependence, with there being two temperature regimes (< 100 K and > 100K). By analysing the chemical network, we relate this to the chemical reactions in our network and find the increased temperature results in increased efficiency of destruction pathways. We investigate the HCN/HNC ratio and show that it can be used as a cosmic thermometer, agreeing with the literature. This ratio is also found to be correlated with the metallicity. The HCN/CS ratio serves as a density tracer, but also has three separate temperature-dependence regimes, which are linked to the chemistry of the two molecules.

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arXiv2023

Identification of the simplest sugar-like molecule glycolaldehyde towards the hot molecular core G358.93-0.03 MM1

Glycolaldehyde (CH$_{2}$OHCHO) is the simplest monosaccharide sugar in the interstellar medium, and it is directly involved in the origin of life via the 'RNA world' hypothesis. We present the first detection of glycolaldehyde (CH$_{2}$OHCHO) towards the hot molecular core G358.93-0.03 MM1 using the Atacama Large Millimeter/Submillimeter Array (ALMA). The calculated column density of CH$_{2}$OHCHO towards G358.93-0.03 MM1 is (1.52$\pm$0.9)$\times$10$^{16}$ cm$^{-2}$ with an excitation temperature of 300$\pm$68.5 K. The derived fractional abundance of CH$_{2}$OHCHO with respect to H$_{2}$ is (4.90$\pm$2.92)$\times$10$^{-9}$, which is consistent with that estimated by existing two-phase warm-up chemical models. We discuss the possible formation pathways of CH$_{2}$OHCHO within the context of hot molecular cores and hot corinos and find that CH$_{2}$OHCHO is likely formed via the reactions of radical HCO and radical CH$_{2}$OH on the grain surface of G358.93-0.03 MM1.

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