arXiv subjects

Sergei Trofimov

Publications and source records attributed to Sergei Trofimov.

3 recordsLinked to original sources

arXiv2025

Digital Twin Simulations Toolbox of the Nitrogen-Vacancy Center in Diamond

The nitrogen-vacancy (NV) center in diamond is a crucial platform for quantum technologies, where its precise numerical modeling is indispensable for the continued advancement of the field. We present here a Python library for simulating the NV spin dynamics under general experimental conditions, i.e. a digital twin. Our library accounts for electromagnetic pulses and other environmental inputs, which are used to solve the system's time evolution, resulting in a physical output in the form of a quantum observable given by fluorescence. The simulation framework is based on a non-perturbative time-dependent Hamiltonian model, where the states initialization and readout are postulated from the interaction with optical fields. By eliminating oversimplifications such as the adoption of rotating frames for the microwave and radio frequency fields, our simulations reveal subtle dynamics emerging from realistic pulse constraints. The software is illustrated with three examples and validated by comparing the simulations with experimental reports, relevant to the fields of quantum computing (conditional logic gates), sensing (dynamical decoupling sequences with coupled spins) and networks (state teleportation). Overall, this digital twin delivers a robust numerical modeling of the NV spin dynamics, with simple and accessible usability, which can be used for a wide range of applications.

quant-ph↗

arXiv2025

Local nanoscale probing of electron spins using NV centers in diamond

Substitutional nitrogen atoms in a diamond crystal (P1 centers) are, on one hand, a resource for creation of nitrogen-vacancy (NV) centers, that have been widely employed as nanoscale quantum sensors. On the other hand, P1's electron spin is a source of paramagnetic noise that degrades the NV's performance by shortening its coherence time. Accurate quantification of nitrogen concentration is therefore essential for optimizing diamond-based quantum devices. However, bulk characterization methods based on optical absorption or electron paramagnetic resonance often overlook local variations in nitrogen content. In this work, we use a helium ion microscope to fabricate nanoscale NV center ensembles at predefined sites in a diamond crystal containing low concentrations of nitrogen. We then utilize these NV-based probes to measure the local nitrogen concentration on the level of 230 ppb (atomic parts per billion) using the double electron-electron resonance (DEER) technique. Moreover, by comparing the DEER spectra with numerical simulations, we managed to determine the concentration of other unknown paramagnetic defects created during the ion implantation, reaching 15 ppb depending on the implantation dose.

quant-ph↗

arXiv2024

Ambiguous Resonances in Multipulse Quantum Sensing with Nitrogen Vacancy Centers

Dynamical decoupling multipulse sequences can be applied to solid state spins for sensing weak oscillating fields from nearby single nuclear spins. By periodically reversing the probing system's evolution, other noises are counteracted and filtered out over the total evolution. However, the technique is subject to intricate interactions resulting in additional resonant responses, which can be misinterpreted with the actual signal intended to be measured. We experimentally characterized three of these effects present in single nitrogen vacancy centers in diamond, where we also developed a numerical simulations model without rotating wave approximation, showing robust correlation to the experimental data. Regarding centers with the $^{15}$N nitrogen isotope, we observed that a small misalignment in the bias magnetic field causes the precession of the nitrogen nuclear spin to be sensed by the electronic spin of the center. Another studied case of ambiguous resonances comes from the coupling with lattice $^{13}$C nuclei, where we used the echo modulation frequencies to obtain the interaction Hamiltonian and then utilized the latter to simulate multipulse sequences. Finally, we also measured and simulated the effects from the free evolution of the quantum system during finite pulse durations. Due to the large data volume and the strong dependency of these ambiguous resonances with specific experimental parameters, we provide a simulations dataset with a user-friendly graphical interface, where users can compare simulations with their own experimental data for spectral disambiguation. Although focused with nitrogen vacancy centers and dynamical decoupling sequences, these results and the developed model can potentially be applied to other solid state spins and quantum sensing techniques.

quant-ph↗