arXiv subjects

Sergey Novikov

Publications and source records attributed to Sergey Novikov.

15 recordsLinked to original sources

arXiv2026

Nonlocal Optomechanics: Hybrid Anapole Opens a New Route to Optical Tweezing

Optical tweezers confine a particle in an intensity-defined potential well by engaging its local multipoles. In this picture, eliminating far-field scattering from the particle should cancel the optical force, as the multipole moments underpinning the conventional optomechanical response vanish. We show that certain resonant states, such as, e.g., the hybrid anapole state, enable qualitatively different optical manipulation, nonlocal by nature, where the optical force exhibits nontrivial spatial variations absent in conventional tweezing, establishing a new framework for manipulating resonant nanoparticles.

physics.optics↗

arXiv2025

Solvent-Directed Femtosecond Laser Ablation: Tuning Phase and Defect Engineering in Hybrid CdPS3/CdS Nanostructures

The limited visible-light absorption of wide-bandgap van der Waals crystals fundamentally restricts their utility in solar energy conversion. Here, we report a surfactant-free, solvent-directed laser synthesis strategy to engineer the phase and optoelectronic properties of Cadmium Phosphorus Trisulfide (CdPS3). By exploiting the non-equilibrium thermodynamics of femtosecond pulsed laser ablation in liquid (fs-PLAL), we demonstrate a tunable transition from the stoichiometric ternary phase to a highly active binary-rich heterostructure. While ablation in water preserves the monoclinic CdPS3 lattice, the reducing environment of isopropanol triggers the formation of CdS quantum dots and metallic cadmium defect sites. This solvent-induced phase engineering transforms the ultraviolet-active host into a robust visible-light photocatalyst. The resulting hybrid CdPS3/CdS nanocolloids exhibit superior charge separation efficiency, driven by Schottky-like metal-semiconductor junctions, achieving ~ 90% degradation of Methylene Blue under 532 nm irradiation within 30 minutes. This work establishes fs-PLAL as a scalable defect-engineering tool for complex ternary layered materials, offering a new design of high-performance metal-thiophosphate-based photocatalysts.

physics.app-ph↗

arXiv2025

Targeted synthesis of polycrystalline vanadium dioxide thin films via post-deposition annealing

Implementation of neuromorphic hardware is a promising way to improve the computing efficiency and decrease the energy consumption of artificial neural networks. For this purpose, electronic elements emulating the behavior of synapses and neurons have to be developed. In order to realize electronic artificial neurons, threshold resistive switches or memristors can be efficiently used. One of the most widespread materials for threshold switches is vanadium dioxide due to its property to demonstrate the metal-insulator transition at a temperature about 70 {\deg}C. However, the processes of VO$_{2}$ synthesis are quite restrictive in temperature and gas atmosphere conditions, which hinders its integration into CMOS fabrication. In this work, we propose a new method of VO$_{2}$ synthesis: reactive pulsed laser deposition from metallic V target in oxygen atmosphere at room temperature, followed by vacuum annealing. Our method enables target synthesis of an appropriate VO$_{2}$ phase in a polycrystalline thin film form by finely tuning oxygen pressure during room temperature deposition, which allows to relax the equipment demands, such as high temperature heating in oxygen. Successful targeted VO$_{2}$ synthesis under fabrication conditions close to back-end-of-line CMOS production, achieved in this work, show the way toward its large-scale microelectronic integration for neuromorphic hardware creation.

cond-mat.mtrl-sci↗

arXiv2025

Laser-Synthesized Amorphous PdSe$_{\mathrm{2-x}}$ Nanoparticles: A Defect-Rich Platform for High-Efficiency SERS, Photocatalysis, and Photothermal Conversion

The control of material properties at the atomic scale remains a central challenge in materials science. Transition metal dichalcogenides (TMDCs) offer remarkable electronic and optical properties, but their functionality is largely dictated by their stable crystalline phases. Here we demonstrate a single-step, ligand-free strategy using femtosecond laser ablation in liquid to transform crystalline, stoichiometric palladium diselenide (PdSe$_{\mathrm{2}}$) into highly stable, amorphous, and non-stoichiometric nanoparticles (PdSe$_{\mathrm{2-x}}$, with x$\approx$1). This laser-driven amorphization creates a high density of selenium vacancies and coordinatively unsaturated sites, which unlock a range of emergent functions absent in the crystalline precursor, including plasmon-free surface-enhanced Raman scattering with an enhancement factor exceeding 10$^\mathrm{6}$, a 50-fold increase in photocatalytic activity, and near-infrared photothermal conversion efficiency reaching 83$\%$. Our findings establish laser-induced amorphization as a powerful top-down approach for defect-engineered TMDCs and advances their practical usage in optics, catalysis, and nanomedicine.

cond-mat.mtrl-sci↗

arXiv2024

Anisotropic van der Waals Crystal with High Refractive Index and Transparency for UV-Visible Range Applications

Thanks to their record high refractive index and giant optical anisotropy, van der Waals (vdW) materials have accelerated the development of nanophotonics. However, traditional high refractive index materials, such as titanium dioxide (TiO2), still dominate in the most important visible range. This is due to the current lack of transparent vdW materials across the entire visible spectrum. In this context, we propose that germanium disulfide (GeS2) could offer a significant breakthrough. With its high refractive index, negligible losses, and biaxial optical anisotropy across the whole visible range, GeS2 has the potential to complement TiO2 and close the application gap of vdW materials in the visible spectrum. The addition of GeS2 could have a profound impact on the design of van der Waals nanophotonic circuits for any operation wavelength from ultraviolet to infrared, emphasizing the significance of the potential impact of GeS2 on the field of nanophotonics.

physics.optics↗

arXiv2022

Influence of Bi substitution with rare-earth elements on the transport properties of BiCuSeO oxyselenides

In this study, we demonstrate that introducing of rare-earth elements, $R$ = La or Pr, into the Bi-O charge reservoir layer of BiCuSeO leads to an increase of both, the charge carrier concentration and the effective mass. Although the charge carrier mobility slightly decreases upon Bi$^{3+}$ to $R^{3+}$ substitution, the electronic transport properties are significantly improved in a broad temperature range from 100 K to 800 K. In particular, the electrical resistivity decreases by two times, while the Seebeck coefficient drops from 323 $μ$V K$^{-1}$ to 238 $μ$V K$^{-1}$ at 800 K. Thus, a power factor of nearly 3 $μ$W cm$^{-1}$ K$^{-2}$ is achieved for Bi$_{0.92}$La$_{0.08}$CuSeO sample at 800 K. Meanwhile, a noticeable decrease of the lattice thermal conductivity is observed for the substituted samples, which can be attributed to the enhanced point defect scattering mostly originated from atomic mass fluctuations between $R$ and Bi. Ultimately, a maximum $zT$ value of nearly 0.34 at 800 K is obtained for the Bi$_{0.92}$La$_{0.08}$CuSeO sample, which is ~30% higher than that of pristine BiCuSeO.

cond-mat.mtrl-sci↗

arXiv2022

Thermoelectric properties of Sm-doped BiCuSeO oxyselenides fabricated by two-step reactive sintering

Among layered oxygen-containing compounds, BiCuSeO is one of the most promising candidates for thermoelectric applications due to its intrinsically low thermal conductivity and good thermal stability. However, the rather poor electrical conductivity of pristine BiCuSeO hinders its potential. Further enhancement of the thermoelectric performance by single doping at Bi site is limited mainly due to dramatic decrease of carrier mobility. Thus, new strategies, such as dual doping or doping with variable-valence elements seem to be promising. Along with that, the development of a fast and scalable synthesis route is essential for the industrial-scale fabrication of thermoelectric materials. Hence, in this paper, Bi$_{1-x}$Sm$_{x}$CuSeO samples (0 $\leq$ $x$ $\leq$ 0.08) have been synthesized with a simple and scalable reactive sintering process. For comparison, Bi$_{1-x}$Sm$_{x}$CuSeO oxyselenides were also obtained by the conventional solid-state route. Our results highlight that, Sm for Bi substitution increases the electrical conductivity by 1.5 - 2 times and decreases the Seebeck coefficient by ~1.4 times at 873 K for both series. Overall, considering the increase of lattice thermal conductivity upon doping and not optimized power factor, the figure of merit $zT$ is reducing upon doping.

cond-mat.mtrl-sci↗

arXiv2021

Topological phase singularities in atomically thin high-refractive-index materials

Atomically thin transition metal dichalcogenides (TMDCs) present a promising platform for numerous photonic applications due to excitonic spectral features, possibility to tune their constants by external gating, doping, or light, and mechanical stability. Utilization of such materials for sensing or optical modulation purposes would require a clever optical design, as by itself the 2D materials can offer only a small optical phase delay - consequence of the atomic thickness. To address this issue, we combine films of 2D semiconductors which exhibit excitonic lines with the Fabry-Perot resonators of the standard commercial SiO$_2$/Si substrate, in order to realize topological phase singularities in reflection. Around these singularities, reflection spectra demonstrate rapid phase changes while the structure behaves as a perfect absorber. Furthermore, we demonstrate that such topological phase singularities are ubiquitous for the entire class of atomically thin TMDCs and other high-refractive-index materials, making it a powerful tool for phase engineering in flat optics. As a practical demonstration, we employ PdSe$_2$ topological phase singularities for a refractive index sensor and demonstrate its superior phase sensitivity compared to typical surface plasmon resonance sensors.

physics.optics↗

arXiv2021

Anneal-path correction in flux qubits

Quantum annealers require accurate control and optimized operation schemes to reduce noise levels, in order to eventually demonstrate a computational advantage over classical algorithms. We study a high coherence four-junction capacitively shunted flux qubit (CSFQ), using dispersive measurements to extract system parameters and model the device. Josephson junction asymmetry inherent to the device causes a deleterious nonlinear cross-talk when annealing the qubit. We implement a nonlinear annealing path to correct the asymmetry in-situ, resulting in a substantial increase in the probability of the qubit being in the correct state given an applied flux bias. We also confirm the multi-level structure of our CSFQ circuit model by annealing it through small spectral gaps and observing quantum signatures of energy level crossings. Our results demonstrate an anneal-path correction scheme designed and implemented to improve control accuracy for high-coherence and high-control quantum annealers, which leads to an enhancement of success probability in annealing protocols.

quant-ph↗

arXiv2020

Fast, Lifetime-Preserving Readout for High-Coherence Quantum Annealers

We demonstrate, for the first time, that a quantum flux parametron (QFP) is capable of acting as both isolator and amplifier in the readout circuit of a capacitively shunted flux qubit (CSFQ). By treating the QFP like a tunable coupler and biasing it such that the coupling is off, we show that $T_1$ of the CSFQ is not impacted by Purcell loss from its low-Q readout resonator ($Q_e = 760$) despite being detuned by only $40$ MHz. When annealed, the QFP amplifies the qubit's persistent current signal such that it generates a flux qubit-state-dependent frequency shift of $85$ MHz in the readout resonator, which is over $9$ times its linewidth. The device is shown to read out a flux qubit in the persistent current basis with fidelities surpassing $98.6\%$ with only $80$ ns integration, and reaches fidelities of $99.6\%$ when integrated for $1$ $μ$s. This combination of speed and isolation is critical to the readout of high-coherence quantum annealers.

quant-ph↗

arXiv2018

Exploring More-Coherent Quantum Annealing

In the quest to reboot computing, quantum annealing (QA) is an interesting candidate for a new capability. While it has not demonstrated an advantage over classical computing on a real-world application, many important regions of the QA design space have yet to be explored. In IARPA's Quantum Enhanced Optimization (QEO) program, we have opened some new lines of inquiry to get to the heart of QA, and are designing testbed superconducting circuits and conducting key experiments. In this paper, we discuss recent experimental progress related to one of the key design dimensions: qubit coherence. Using MIT Lincoln Laboratory's qubit fabrication process and extending recent progress in flux qubits, we are implementing and measuring QA-capable flux qubits. Achieving high coherence in a QA context presents significant new engineering challenges. We report on techniques and preliminary measurement results addressing two of the challenges: crosstalk calibration and qubit readout. This groundwork enables exploration of other promising features and provides a path to understanding the physics and the viability of quantum annealing as a computing resource.

quant-ph↗

arXiv2015

Nonlinear microwave photon-occupancy of a driven resonator strongly coupled to a transmon qubit

We measure photon-occupancy in a thin-film superconducting lumped element resonator coupled to a transmon qubit at 20$\,$mK and find a nonlinear dependence on the applied microwave power. The transmon-resonator system was operated in the strong dispersive regime, where the ac Stark shift ($2χ$) due to a single microwave photon present in the resonator was larger than the linewidth ($Γ$) of the qubit transition. When the resonator was coherently driven at $5.474325\,$GHz, the transition spectrum of the transmon at $4.982\,$GHz revealed well-resolved peaks, each corresponding to an individual photon number-state of the resonator. From the relative peak-heights we obtain the occupancy of the photon-states and the average photon-occupancy $\bar{n}$ of the resonator. We observed a nonlinear variation of $\bar{n}$ with the applied drive power $P_{rf}$ for $\bar{n} < 5$ and compare our results to numerical simulations of the system-bath master equation in the steady state, as well as to a semi-classical model for the resonator that includes the Jaynes-Cummings interaction between the transmon and the resonator. We find good quantitative agreement using both models and analysis reveals that the nonlinear behavior is principally due to shifts in the resonant frequency caused by a qubit-induced Jaynes-Cummings nonlinearity.

cond-mat.mes-hall↗

arXiv2015

Far tails of the density of states in amorphous organic semiconductors

Far tails of the density of state (DOS) are calculated for the simple models of organic amorphous material, the model of dipolar glass and model of quadrupolar glass. It was found that in both models far tails are non-Gaussian. In the dipolar glass model the DOS is symmetric around zero energy, while for the model of quadrupolar glass the DOS is generally asymmetric and its asymmetry is directly related to the particular geometry of quadrupoles. Far tails of the DOS are relevant for the quasi-equilibrium transport of the charge carriers at low temperature. Asymmetry of DOS in quadrupolar glasses means a principal inequivalence of the random energy landscape for the transport of electrons and holes. Possible effect of the non-Gaussian shape of the far tails of the DOS on the temperature dependence of carrier drift mobility is discussed.

cond-mat.dis-nn↗

arXiv2009

Structure of Quasi-One Dimensional Ribbon Colloid Suspensions

We report the results of an experimental study of a colloid fluid confined to a quasi-one dimensional (q1D) ribbon channel as a function of channel width and colloid density. Our findings confirm the principal predictions of previous theoretical studies of such systems. These are (1) that the density distribution of the liquid transverse to the ribbon channel exhibits stratification; (2) that even at the highest density the order along the strata, as measured by the longitudinal pair correlation function, is characteristic of a liquid; and (3) the q1D pair correlation functions in different strata exhibits anisotropic behavior, resembling that found in a Monte Carlo simulation for the in-plane pair correlation function of a hard sphere fluid in a planar slit.

cond-mat.soft↗

arXiv2000

Charge induced energy fluctuations in thin organic films: effect on charge transport

Effect of static charges on charge carrier transport in disordered organic materials is considered. Long range nature of Coulomb interaction requires to take into consideration a finite thickness of the transport layer. Presence of conducting electrodes significantly modifies properties of organic medium, removes a long range Coulomb divergence, and makes it possible to calculate in finite form statistical properties of organic medium (with nonzero total charge density), relevant for transport characteristics. A special attention is paid to the particular case of charge induced disorder - a disorder originated from the surface charge located at the rough surface of electrode. We present also a generalization of 1D model of charge carrier transport to the case of inhomogeneous energetic disorder that realizes in for charge induced disorder.

cond-mat.dis-nn↗