Searcharxiv⌕ Search

arXiv subjects

Sergey V. Buldyrev

Publications and source records attributed to Sergey V. Buldyrev.

At least 55 records · Page 3Linked to original sources

Phase diagram of a two-dimensional system with anomalous liquid properties

Using Monte Carlo simulation techniques, we calculate the phase diagram for a square shoulder-square well potential in two dimensions that has been previously shown to exhibit liquid anomalies consistent with a metastable liquid-liquid critical point. We consider the liquid, gas and five crystal phases, and find that all the melting lines are first order, despite a small range of metastability. One melting line exhibits a temperature maximum, as well as a pressure maximum that implies inverse melting over a small range in pressure.

cond-mat.soft↗

Modeling Amphiphilic Solutes in a Jagla Solvent

Methanol is an amphiphilic solute whose aqueous solutions exhibit distinctive physical properties. The volume change upon mixing, for example, is negative across the entire composition range, indicating strong association. We explore the corresponding behavior of a Jagla solvent, which has been previously shown to exhibit many of the anomalous properties of water. We consider two models of an amphiphilic solute: (i) a "dimer" model, which consists of one hydrophobic hard sphere linked to a Jagla particle with a permanent bond, and (ii) a "monomer" model, which is a limiting case of the dimer, formed by concentrically overlapping a hard sphere and a Jagla particle. Using discrete molecular dynamics, we calculate the thermodynamic properties of the resulting solutions. We systematically vary the set of parameters of the dimer and monomer models and find that one can readily reproduce the experimental behavior of the excess volume of the methanolwater system as a function of methanol volume fraction. We compare the pressure and temperature dependence of the excess volume and the excess enthalpy of both models with experimental data on methanol-water solutions and find qualitative agreement in most cases. We also investigate the solute effect on the temperature of maximum density and find that the effect of concentration isorders of magnitude stronger than measured experimentally.

cond-mat.soft↗

Communication activity in social networks: growth and correlations

We investigate the timing of messages sent in two online communities with respect to growth fluctuations and long-term correlations. We find that the timing of sending and receiving messages comprises pronounced long-term persistence. Considering the activity of the community members as growing entities, i.e. the cumulative number of messages sent (or received) by the individuals, we identify non-trivial scaling in the growth fluctuations which we relate to the long-term correlations. We find a connection between the scaling exponents of the growth and the long-term correlations which is supported by numerical simulations based on peaks over threshold. In addition, we find that the activity on directed links between pairs of members exhibits long-term correlations, indicating that communication activity with the most liked partners may be responsible for the long-term persistence in the timing of messages. Finally, we show that the number of messages, $M$, and the number of communication partners, $K$, of the individual members are correlated following a power-law, $K\sim M^λ$, with exponent $λ\approx 3/4$.

physics.soc-ph↗

Dynamics of the contact between a ruthenium surface with a single nanoasperity and a flat ruthenium surface: Molecular dynamics simulations

We study the dynamics of the contact between a pair of surfaces (with properties designed to mimic ruthenium) via molecular dynamics simulations. In particular, we study the contact between a ruthenium surface with a single nanoasperity and a flat ruthenium surface. The results of such simulations suggest that contact behavior is highly variable. The goal of this study is to investigate the source and degree of this variability. We find that during compression, the behavior of the contact force displacement curves is reproducible, while during contact separation, the behavior is highly variable. Examination of the contact surfaces suggest that two separation mechanism are in operation and give rise to this variability. One mechanism corresponds to the formation of a bridge between the two surfaces that plastically stretches as the surfaces are drawn apart and eventually separates in shear. This leads to a morphology after separation in which there are opposing asperities on the two surfaces. This plastic separation/bridge formation mechanism leads to a large work of separation. The other mechanism is a more brittle-like mode in which a crack propagates across the base of the asperity (slightly below the asperity/substrate junction) leading to most of the asperity on one surface or the other after separation and a slight depression facing this asperity on the opposing surface. This failure mode corresponds to a smaller work of separation. those in which a single mechanism operates. Furthermore, contacts made from materials that exhibit predominantly brittle-like behavior will tend to require lower work of separation than those made from ductile-like contact materials.

cond-mat.mes-hall↗

Robustness of interdependent networks under targeted attack

When an initial failure of nodes occurs in interdependent networks, a cascade of failure between the networks occurs. Earlier studies focused on random initial failures. Here we study the robustness of interdependent networks under targeted attack on high or low degree nodes. We introduce a general technique and show that the {\it targeted-attack} problem in interdependent networks can be mapped to the {\it random-attack} problem in a transformed pair of interdependent networks. We find that when the highly connected nodes are protected and have lower probability to fail, in contrast to single scale free (SF) networks where the percolation threshold $p_c=0$, coupled SF networks are significantly more vulnerable with $p_c$ significantly larger than zero. The result implies that interdependent networks are difficult to defend by strategies such as protecting the high degree nodes that have been found useful to significantly improve robustness of single networks.

physics.soc-ph↗

Cascade of failures in coupled network systems with multiple support-dependent relations

We study, both analytically and numerically, the cascade of failures in two coupled network systems A and B, where multiple support-dependent relations are randomly built between nodes of networks A and B. In our model we assume that each node in one network can function only if it has at least a single support node in the other network. If both networks A and B are Erdős-Rényi networks, A and B, with (i) sizes $N^A$ and $N^B$, (ii) average degrees $a$ and $b$, and (iii) $c^{AB}_0N^B$ support links from network A to B and $c^{BA}_0N^B$ support links from network B to A, we find that under random attack with removal of fractions $(1-R^A)N^A$ and $(1-R^B)N^B$ nodes respectively, the percolating giant components of both networks at the end of the cascading failures, $μ^A_\infty$ and $μ^B_\infty$, are given by the percolation laws $μ^A_\infty = R^A [1-\exp{({-c^{BA}_0μ^B_\infty})}] [1-\exp{({-aμ^A_\infty})}]$ and $μ^B_\infty = R^B [1-\exp{({-c^{AB}_0μ^A_\infty})}] [1-\exp{({-bμ^B_\infty})}]$. In the limit of $c^{BA}_0 \to \infty$ and $c^{AB}_0 \to \infty$, both networks become independent, and the giant components are equivalent to a random attack on a single Erdős-Rényi network. We also test our theory on two coupled scale-free networks, and find good agreement with the simulations.

physics.data-an↗

Robustness of a Network of Networks

Almost all network research has been focused on the properties of a single network that does not interact and depends on other networks. In reality, many real-world networks interact with other networks. Here we develop an analytical framework for studying interacting networks and present an exact percolation law for a network of $n$ interdependent networks. In particular, we find that for $n$ Erdős-Rényi networks each of average degree $k$, the giant component, $P_{\infty}$, is given by $P_{\infty}=p[1-\exp(-kP_{\infty})]^n$ where $1-p$ is the initial fraction of removed nodes. Our general result coincides for $n=1$ with the known Erdős-Rényi second-order phase transition for a single network. For any $n \geq 2$ cascading failures occur and the transition becomes a first-order percolation transition. The new law for $P_{\infty}$ shows that percolation theory that is extensively studied in physics and mathematics is a limiting case ($n=1$) of a more general general and different percolation law for interdependent networks.

physics.data-an↗

The critical effect of dependency groups on the function of networks

Current network models assume one type of links to define the relations between the network entities. However, many real networks can only be correctly described using two different types of relations. Connectivity links that enable the nodes to function cooperatively as a network and dependency links that bind the failure of one network element to the failure of other network elements. Here we present for the first time an analytical framework for studying the robustness of networks that include both connectivity and dependency links. We show that the synergy between the two types of failures leads to an iterative process of cascading failures that has a devastating effect on the network stability and completely alters the known assumptions regarding the robustness of networks. We present exact analytical results for the dramatic change in the network behavior when introducing dependency links. For a high density of dependency links the network disintegrates in a form of a first order phase transition while for a low density of dependency links the network disintegrates in a second order transition. Moreover, opposed to networks containing only connectivity links where a broader degree distribution results in a more robust network, when both types of links are present a broad degree distribution leads to higher vulnerability.

physics.data-an↗

Interdependent networks with correlated degrees of mutually dependent nodes

We study a problem of failure of two interdependent networks in the case of correlated degrees of mutually dependent nodes. We assume that both networks (A and B) have the same number of nodes $N$ connected by the bidirectional dependency links establishing a one-to-one correspondence between the nodes of the two networks in a such a way that the mutually dependent nodes have the same number of connectivity links, i.e. their degrees coincide. This implies that both networks have the same degree distribution $P(k)$. We call such networks correspondently coupled networks (CCN). We assume that the nodes in each network are randomly connected. We define the mutually connected clusters and the mutual giant component as in earlier works on randomly coupled interdependent networks and assume that only the nodes which belong to the mutual giant component remain functional. We assume that initially a $1-p$ fraction of nodes are randomly removed due to an attack or failure and find analytically, for an arbitrary $P(k)$, the fraction of nodes $μ(p)$ which belong to the mutual giant component. We find that the system undergoes a percolation transition at certain fraction $p=p_c$ which is always smaller than the $p_c$ for randomly coupled networks with the same $P(k)$. We also find that the system undergoes a first order transition at $p_c>0$ if $P(k)$ has a finite second moment. For the case of scale free networks with $2<λ\leq 3$, the transition becomes a second order transition. Moreover, if $λ<3$ we find $p_c=0$ as in percolation of a single network. For $λ=3$ we find an exact analytical expression for $p_c>0$. Finally, we find that the robustness of CCN increases with the broadness of their degree distribution.

cond-mat.dis-nn↗

Effect of hydrophobic solutes on the liquid-liquid critical point

Jagla ramp particles, interacting through a ramp potential with two characteristic length scales, are known to show in their bulk phase thermodynamic and dynamic anomalies, similar to what is found in water. Jagla particles also exhibit a line of phase transitions separating a low density liquid phase and a high density liquid phase, terminating in a liquid-liquid critical point in a region of the phase diagram that can be studied by simulations. Employing molecular dynamics computer simulations, we study the thermodynamics and the dynamics of solutions of hard spheres (HS) in a solvent formed by Jagla ramp particles. We consider the cases of HS mole fraction x = 0.10, 0.15 and 0.20, and also the case x = 0.50 (a 1:1 mixture of HS and Jagla particles). We find a liquid-liquid critical point, up to the highest HS mole fraction; its position shifts to higher pressures and lower temperatures upon increasing x. We also find that the diffusion coefficient anomalies appear to be preserved for all the mole fractions studied.

cond-mat.soft↗

Interdependent networks: Reducing the coupling strength leads to a change from a first to second order percolation transition

We study a system composed from two interdependent networks A and B, where a fraction of the nodes in network A depends on the nodes of network B and a fraction of the nodes in network B depends on the nodes of network A. Due to the coupling between the networks when nodes in one network fail they cause dependent nodes in the other network to also fail. This invokes an iterative cascade of failures in both networks. When a critical fraction of nodes fail the iterative process results in a percolation phase transition that completely fragments both networks. We show both analytically and numerically that reducing the coupling between the networks leads to a change from a first order percolation phase transition to a second order percolation transition at a critical point. The scaling of the percolation order parameter near the critical point is characterized by the critical exponent beta=1.

physics.data-an↗

Scaling laws of human interaction activity

Even though people in our contemporary, technological society are depending on communication, our understanding of the underlying laws of human communicational behavior continues to be poorly understood. Here we investigate the communication patterns in two social Internet communities in search of statistical laws in human interaction activity. This research reveals that human communication networks dynamically follow scaling laws that may also explain the observed trends in economic growth. Specifically, we identify a generalized version of Gibrat's law of social activity expressed as a scaling law between the fluctuations in the number of messages sent by members and their level of activity. Gibrat's law has been essential in understanding economic growth patterns, yet without an underlying general principle for its origin. We attribute this scaling law to long-term correlation patterns in human activity, which surprisingly span from days to the entire period of the available data of more than one year. Further, we provide a mathematical framework that relates the generalized version of Gibrat's law to the long-term correlated dynamics, which suggests that the same underlying mechanism could be the source of Gibrat's law in economics, ranging from large firms, research and development expenditures, gross domestic product of countries, to city population growth. These findings are also of importance for designing communication networks and for the understanding of the dynamics of social systems in which communication plays a role, such as economic markets and political systems.

physics.soc-ph↗

Catastrophic cascade of failures in interdependent networks

Many systems, ranging from engineering to medical to societal, can only be properly characterized by multiple interdependent networks whose normal functioning depends on one another. Failure of a fraction of nodes in one network may lead to a failure in another network. This in turn may cause further malfunction of additional nodes in the first network and so on. Such a cascade of failures, triggered by a failure of a small faction of nodes in only one network, may lead to the complete fragmentation of all networks. We introduce a model and an analytical framework for studying interdependent networks. We obtain interesting and surprising results that should significantly effect the design of robust real-world networks. For two interdependent Erdos-Renyi (ER) networks, we find that the critical average degree below which both networks collapse is =2.445, compared to =1 for a single ER network. Furthermore, while for a single network a broader degree distribution of the network nodes results in higher robustness to random failure, for interdependent networks, the broader the distribution is, the more vulnerable the networks become to random failure.

cond-mat.dis-nn↗

The Size Variance Relationship of Business Firm Growth Rates

The relationship between the size and the variance of firm growth rates is known to follow an approximate power-law behavior $σ(S) \sim S^{-β(S)}$ where $S$ is the firm size and $β(S)\approx 0.2$ is an exponent weakly dependent on $S$. Here we show how a model of proportional growth which treats firms as classes composed of various number of units of variable size, can explain this size-variance dependence. In general, the model predicts that $β(S)$ must exhibit a crossover from $β(0)=0$ to $β(\infty)=1/2$. For a realistic set of parameters, $β(S)$ is approximately constant and can vary in the range from 0.14 to 0.2 depending on the average number of units in the firm. We test the model with a unique industry specific database in which firm sales are given in terms of the sum of the sales of all their products. We find that the model is consistent with the empirically observed size-variance relationship.

q-fin.ST↗

Structure of shells in complex networks

In a network, we define shell $\ell$ as the set of nodes at distance $\ell$ with respect to a given node and define $r_\ell$ as the fraction of nodes outside shell $\ell$. In a transport process, information or disease usually diffuses from a random node and reach nodes shell after shell. Thus, understanding the shell structure is crucial for the study of the transport property of networks. For a randomly connected network with given degree distribution, we derive analytically the degree distribution and average degree of the nodes residing outside shell $\ell$ as a function of $r_\ell$. Further, we find that $r_\ell$ follows an iterative functional form $r_\ell=ϕ(r_{\ell-1})$, where $ϕ$ is expressed in terms of the generating function of the original degree distribution of the network. Our results can explain the power-law distribution of the number of nodes $B_\ell$ found in shells with $\ell$ larger than the network diameter $d$, which is the average distance between all pairs of nodes. For real world networks the theoretical prediction of $r_\ell$ deviates from the empirical $r_\ell$. We introduce a network correlation function $c(r_\ell)\equiv r_{\ell+1}/ϕ(r_\ell)$ to characterize the correlations in the network, where $r_{\ell+1}$ is the empirical value and $ϕ(r_\ell)$ is the theoretical prediction. $c(r_\ell)=1$ indicates perfect agreement between empirical results and theory. We apply $c(r_\ell)$ to several model and real world networks. We find that the networks fall into two distinct classes: (i) a class of {\it poorly-connected} networks with $c(r_\ell)>1$, which have larger average distances compared with randomly connected networks with the same degree distributions; and (ii) a class of {\it well-connected} networks with $c(r_\ell)<1$.

physics.data-an↗

Space-Time Correlations in the Orientational Order Parameter and the Orientational Entropy of Water

We introduce the spatial correlation function $C_Q(r)$ and temporal autocorrelation function $C_Q(t)$ of the local tetrahedral order parameter $Q\equiv Q(r,t)$. Using computer simulations of the TIP5P model of water, we investigate $C_Q(r)$ in a broad region of the phase diagram. First we show that $C_Q(r)$ displays anticorrelation at $r\approx 0.32$nm at high temperatures $T>T_W\approx 250$ K, which changes to positive correlation below the Widom line $T_W$. Further we find that at low temperatures $C_Q(t)$ exhibits a two-step temporal decay similar to the self intermediate scattering function, and that the corresponding correlation time $τ_Q$ displays a dynamic crossover from non-Arrhenius behavior for $T>T_W$ to Arrhenius behavior for $T<T_W$. Finally, we define an orientational entropy $S_Q$ associated with the {\it local} orientational order of water molecules, and show that $τ_Q$ can be extracted from $S_Q$ using an analog of the Adam-Gibbs relation.

cond-mat.soft↗

Fractal Boundaries of Complex Networks

We introduce the concept of boundaries of a complex network as the set of nodes at distance larger than the mean distance from a given node in the network. We study the statistical properties of the boundaries nodes of complex networks. We find that for both Erdös-Rényi and scale-free model networks, as well as for several real networks, the boundaries have fractal properties. In particular, the number of boundaries nodes {\it B} follows a power-law probability density function which scales as $B^{-2}$. The clusters formed by the boundary nodes are fractals with a fractal dimension $d_{f} \approx 2$. We present analytical and numerical evidence supporting these results for a broad class of networks. Our findings imply potential applications for epidemic spreading.

math-ph↗

Correspondence Between the Phase Diagrams of TIP5P Water and a Spherically Symmetric Repulsive Ramp Potential

We perform molecular dynamics simulations of a well-known water model (the TIP5P pair potential) and a simple liquid model (a two-scale repulsive ramp potential) to compare the regions of anomalous behavior in their phase diagrams. We select the parameters of the ramp potential by mapping it to an effective pair potential derived from the TIP5P model. We find that the regions of anomalous behavior in the phase diagrams of both systems can be mapped onto each other if (i) pressure $P$ and temperature $T$ are replaced by $T-T_{C}$ and $P-P_{C}$, respectively, where $(T_{C},P_{C})$ are the coordinates of the liquid-liquid critical point of the corresponding system; and (ii) a single ramp particle corresponds to two TIP5P molecules. We present heuristic arguments supporting point (ii). We also argue that the water-like anomalies in the ramp potential are due to the ability of the particles to reproduce, upon compression or heating, the migration of water molecules from the second shell to its first shell.

cond-mat.soft↗