A Description of the Quantum Mpemba Effect using the Steepest-Entropy-Ascent Quantum Thermodynamics Framework
The quantum Mpemba effect describes the unusual relaxation of a quantum system where if starting from a state far from equilibrium reaches equilibrium faster than starting from a closer state. In this work, the steepest-entropy ascent quantum thermodynamics framework is used to model this effect in a three-level ion system coupled to a short-life level which acts as an environment. The four-level Hilbert space is reduced to an effective three-dimensional description via the Feshbach projection, where the resulting model parameters are determined by a differential evolution algorithm. Predictions of both the steepest-entropy-ascent and Lindblad frameworks agree well with experimental data for all three initial conditions considered. In addition it is shown that, independently of the Mpemba condition, the relaxation parameter $τ_D$ is an emergent thermodynamic quantity whose step-function time dependence arises from a near-indetermination at the metastable state, resolved by the two-timescale structure of the dissipative dynamics, with a step height $τ_D^{+}/τ_D^{-} (|λ_f|/|λ_s|)\,\mathfrak{r}$ set by the ratio of the linearised relaxation rates at the metastable state times a geometric factor $\mathfrak{r}$ fixed by the curvature of the entropy and free-energy-variance surfaces there. Furthermore, it is also established the correspondence between the Lindblad and steepest-entropy-ascent order parameters as spectral and geometric suppression of the same slow dissipative mode, and it is shown that for isolated systems with a negative nonequilibrium inverse temperature, as realized in the case studied here, the genuine Mpemba free-energy ordering is equivalent to an entropy ordering.