arXiv subjects

Sergio Ulloa

Publications and source records attributed to Sergio Ulloa.

8 recordsLinked to original sources

arXiv2025

Exploring the Kondo Effect in Strained Kagome Nanoribbons

Metallic kagome systems have attracted considerable interest in recent years, as they provide a rich platform for studying phenomena associated with their distinctive band structure. The coexistence of bands with Dirac points similar to those in graphene, along with a completely flat band, makes this an ideal structure for investigating how lattice symmetries may protect topological and many-body correlation effects. Since applied strain can break lattice symmetries and modify the electronic structure, understanding how strain influences phenomena such as the Kondo effect in kagome materials may provide essential insights into correlated-electron behavior. We employ the single-impurity Anderson model and the numerical renormalization group to analyze the Kondo effect in kagome zigzag nanoribbons under uniaxial strain. We find that strain manipulation enables precise control over the strength of the Kondo effect on an impurity hybridized on the ribbon with different coordination environments, and that symmetric local environments may result in strong suppression of the effective hybridization due to orbital interference. We find that the specific location of the impurity on the ribbon, especially when the Fermi energy lies close to weakly dispersive edge states, can lead to significant changes in the characteristic Kondo temperature. Such sensitivity may be used to provide unique information on the local density of states of a system. These results demonstrate that strain is a powerful tuning parameter in kagome nanoribbons, strongly modifying the screening of magnetic impurities.

cond-mat.str-el↗

arXiv2024

Exploring the Coexistence of Spin States in [Fe-(tpy-ph)$_2$]$^{2+}$ Complexes on Au(111) using ab initio calculations

In this work, we systematically study the electronic structure and stability of spin states of the [Fe-(tpy-ph)$_2$]$^{2+}$ molecule in both gas phase and on a Au(111) substrate using density functional theory +U (DFT+U) calculations. We find that the stability of the Fe$^{2+}$ ion's spin states is significantly influenced by the Hubbard U parameter. In the gas phase, the low-spin (LS, S=0) state is found to be energetically favorable for U(Fe) $\leq$ 3 eV, whereas the high-spin (HS, S=2) state is stabilized for U(Fe) > 3 eV. Interaction with the Au(111) substrate is found to elevate the critical U for the spin-state transition to 3.5 eV. Additionally, we perform L-edge X-ray absorption spectroscopy (XAS) calculations based on time-dependent DFT (TD-DFT) for both HS and LS states. The calculated XAS suggests that the HS state more closely aligns with the experimental observations, indicating the potential coexistence of the HS state as the initial state during the X-ray excitation process. These findings enrich our understanding of spin-state dynamics in [Fe-(tpy-ph)$_2$]$^{2+}$.

cond-mat.mtrl-sci↗

arXiv2015

Hybridization and anisotropy in the exchange interaction in 3D Dirac semimetals

We study the Ruderman-Kittel-Kasuya-Yosida interaction in 3D Dirac semimetals. Using retarded Green's functions in real space, we obtain and analyze asymptotic expressions for the interaction, with magnetic impurities at different distances and relative angle with respect to high symmetry directions on the lattice. We show that the Fermi velocity anisotropy in these materials produces a strong renormalization of the magnitude of the interaction, as well as a correction to the frequency of oscillation in real space. Hybridization of the impurities to different conduction electron orbitals are shown to result in interesting anisotropic spin-spin interactions which can generate spiral spin structures in doped samples.

cond-mat.mes-hall↗

arXiv2014

Kondo effect in graphene with Rashba spin-orbit coupling

We study the Kondo screening of a magnetic impurity adsorbed in graphene in the presence of Rashba spin-orbit interaction. The system is described by an effective single-channel Anderson impurity model, which we analyze using the numerical renormalization group. The nontrivial energy dependence of the host density of states gives rise to interesting behaviors under variation of the chemical potential or the spin-orbit coupling. Varying the Rashba coupling produces strong changes in the Kondo temperature characterizing the many-body screening of the impurity spin, and at half filling allows approach to a quantum phase transition separating the strong-coupling Kondo phase from a free-moment phase. Tuning the chemical potential close to sharp features of the hybridization function results in striking features in the temperature dependences of thermodynamic quantities and in the frequency dependence of the impurity spectral function.

cond-mat.str-el↗

arXiv2013

Quantum phase transitions into Kondo states in bilayer graphene

We study a magnetic impurity intercalated in bilayer graphene. A representative configuration generates a hybridization function with strong dependence on the conduction-electron energy, including a full gap with one hard and one soft edge. Shifts of the chemical potential via gating or doping drive the system between non-Kondo (free-moment) and Kondo-screened phases, with strong variation of the Kondo scale. Quantum phase transitions near the soft edge are of Kosterlitz-Thouless type, while others are first order. Near the hard edge, a bound-state singlet appears inside the gap; although of single-particle character, its signatures in scanning tunneling spectroscopy are very similar to those arising from a many-body Kondo resonance.

cond-mat.str-el↗

arXiv2009

Lateral spin-orbit interaction and spin polarization in quantum point contacts

We study ballistic transport through semiconductor quantum point contact systems under different confinement geometries and applied fields. In particular, we investigate how the {\em lateral} spin-orbit coupling, introduced by asymmetric lateral confinement potentials, affects the spin polarization of the current. We find that even in the absence of external magnetic fields, a variable {\em non-zero spin polarization} can be obtained by controlling the asymmetric shape of the confinement potential. These results suggest a new approach to produce spin polarized electron sources and we study the dependence of this phenomenon on structural parameters and applied magnetic fields. This asymmetry-induced polarization provides also a plausible explanation of our recent observations of a 0.5 conductance plateau (in units of $2e^2/h$) in quantum point contacts made on InAs quantum-well structures. Although our estimates of the required spin-orbit interaction strength in these systems do not support this explanation, they likely play a role in the effects enhanced by electron-electron interactions.

cond-mat.mes-hall↗

arXiv2008

Finite-temperature conductance signatures of quantum criticality in double quantum dots

We study the linear conductance through a double-quantum-dot system consisting of an interacting dot in its Kondo regime and an effectively noninteracting dot, connected in parallel to metallic leads. Signatures in the zero-bias conductance at temperatures $T>0$ mark a pair of quantum (T=0) phase transitions between a Kondo-screened many-body ground state and non-Kondo ground states. Notably, the conductance features become more prominent with increasing $T$, which enhances the experimental prospects for accessing the quantum-critical region through tuning of gate voltages in a single device.

cond-mat.mes-hall↗

arXiv2006

Zero-field Kondo splitting and quantum-critical transition in double quantum dots

Double quantum dots offer unique possibilities for the study of many-body correlations. A system containing one Kondo dot and one effectively noninteracting dot maps onto a single-impurity Anderson model with a structured (nonconstant) density of states. Numerical renormalization-group calculations show that while band filtering through the resonant dot splits the Kondo resonance, the singlet ground state is robust. The system can also be continuously tuned to create a pseudogapped density of states and access a quantum critical point separating Kondo and non-Kondo phases.

cond-mat.mes-hall↗