arXiv subjects

Shangjr Gwo

Publications and source records attributed to Shangjr Gwo.

7 recordsLinked to original sources

arXiv2025

Confinement-Induced Nonlocality and Optical Nonlinearity of Transdimensional Titanium Nitride in the Epsilon-Near-Zero Region

Ultrathin plasmonic films that approach the trans-dimensional (TD) thickness limit provide a promising route for light_matter interaction control and manipulation, yet their nonlinear optical response near the epsilon_near_zero (ENZ) condition remains poorly understood. Here, we report the strongly enhanced optical nonlinearity for their typical representative high quality TiN epitaxial films with thicknesses down to a few nanometers. Systematic Z_scan measurements reveal a pronounced increase in nonlinear absorption with decreasing thickness. Especially in the ENZ spectral region, the TD TiN films exhibit nearly two orders of magnitude stronger nonlinear absorption over a broad range of incidence angles as compared to conventional thin films. The enhanced nonlinear absorption observed is well described by a nonlinear nonlocal electromagnetic response model that accounts for electron confinement effects unique to the TD plasmonic systems. Comparison with Ti1_xAlxN highlights the necessity of low-loss ENZ response for nonlinear enhancement. These findings identify TiN and similar TD plasmonic systems as a robust refractory platform for exploiting ENZ mediated nonlinear processes in ultrathin photonic material structures.

physics.optics↗

arXiv2023

Superior visible photoelectric response with Au/Cu2NiSnS4 core-shell nanocrystals

The incorporation of plasmonic metal nanostructures into semiconducting chalcogenides, in the form of core-shell structures, represents a promising approach to boosting the performance of photodetectors. In this study, we combined Au nanoparticles with newly developed copper-based chalcogenides Cu2NiSnS4 (Au/CNTS), to achieve an ultrahigh optoelectronic response in the visible regime. The high-quality Au/CNTS core-shell structure was synthesized by developing a unique colloidal hot-injection method, which allowed excellent control over sizes, shapes, and elemental compositions. The fabricated Au/CNTS hybrid core-shell structure exhibited enhanced optical absorption, carrier extraction efficiency, and improved photo-sensing performance, owing to the plasmonic-induced resonance energy transfer effect of the Au core. This effect led to a significant increase in carrier density between the Au core and CNTS shell. These values outperformed a CNTS-based gate-free visible photodetector.

cond-mat.mtrl-sci↗

arXiv2019

Moiré Potential Impedes Interlayer Exciton Diffusion in van der Waals Heterostructures

The properties of van der Waals (vdW) heterostructures are drastically altered by a tunable moiré superlattice arising from periodic variations of atomic alignment between the layers. Exciton diffusion represents an important channel of energy transport in semiconducting transition metal dichalcogenides (TMDs). While early studies performed on TMD heterobilayers have suggested that carriers and excitons exhibit long diffusion lengths, a rich variety of scenarios can exist. In a moiré crystal with a large supercell size and deep potential, interlayer excitons may be completely localized. As the moiré period reduces at a larger twist angle, excitons can tunnel between supercells and diffuse over a longer lifetime. The diffusion length should be the longest in commensurate heterostructures where the moiré superlattice is completely absent. In this study, we experimentally demonstrate that the moiré potential impedes interlayer exciton diffusion by comparing a number of WSe2/MoSe2 heterostructures prepared with chemical vapor deposition and mechanical stacking with accurately controlled twist angles. Our results provide critical guidance to developing 'twistronic' devices that explore the moiré superlattice to engineer material properties.

cond-mat.mes-hall↗

arXiv2018

Single Crystalline Silver Films for Plasmonics: From Monolayer to Optically Thick Film

Epitaxial growth of single crystalline noble metals on dielectric substrates has received tremendous attention recently due to their technological potentials as low loss plasmonic materials. Currently there are two different growth approaches, each with its strengths and weaknesses. One adopts a sophisticated molecular beam epitaxial procedure to grow atomically smooth epitaxial Ag films. However, the procedure is rather slow and becomes impractical to grow films with thickness > 50 nm. Another approach adopts a growth process using rapid e-beam deposition which is capable of growing single crystalline Ag films in the thick regime (> 300 nm). However, the rapid growth procedure makes it difficult to control film thickness precisely, i.e., the method is not applicable to growing thin epitaxial films. Here we report a universal approach to grow atomically smooth epitaxial Ag films with precise thickness control from a few monolayers to the optically thick regime, overcoming the limitations of the two aforementioned methods. In addition, we develop an in-situ growth of aluminum oxide as the capping layer which exhibits excellent properties protecting the epitaxial Ag films. The performance of the epitaxial Ag films as a function of the film thickness is investigated by directly measuring the propagation length of the surface plasmon polaritons (SPPs) as well as their device performance to support a waveguide plasmonic nanolaser in infrared incorporating an InGaAsP quantum well as the gain media.

cond-mat.mtrl-sci↗

arXiv2018

Routing Valley Excitons in a Monolayer MoS2 with a Metasurface

Excitons in monolayer transition metal dichalcogenides (TMDs) are formed at K and K' points at the boundary of the Brillouin zone. They acquire a valley degree of freedom, which may be used as a complementary platform for information transport and processing. In a different context, metasurfaces consisting of engineered arrays of polarizable inclusions have enabled the manipulation of light in unprecedented ways, and found applications in imaging, optical information processing, and cloaking. Here, we demonstrate that, by coupling a MoS2 monolayer to a suitably designed metasurface consisting of asymmetric grooves, valley polarized excitons can be sorted and spatially separated even at room temperature. Emission from valley excitons is also separated in K-space, i.e., photons with opposite helicity are emitted to different directions. Our work demonstrates that metasurfaces can facilitate valley transport and establish an interface between valleytronic and photonic devices, thus addressing outstanding challenges in the nascent field of valleytronics.

cond-mat.mes-hall↗

arXiv2016

Magnetic MoS2 Interface Monolayer on CdS Nanowire by Cation Exchange

MoS2 atomic layers have recently attracted much interest because of their two-dimensional structure as well as tunable optical, electrical, and mechanical properties for next generation electronic and electro-optical devices. Here we have achieved facile fabrication of MoS2 thin films on CdS nanowires by cation exchange in solution at room temperature and importantly observed their extraordinary magnetic properties. We establish the atomic structure of the MoS2/CdS heterostructure by taking atomic images of the MoS2/CdS interface as well as performing first-principles density functional geometry optimizations and STEM-ADF image simulations. Furthermore, our first principles density functional calculations for the MoS2/CdS heterostructure reveal that the magnetism in the MoS2/CdS heterostructure stems from the ferromagnetic MoS2 monolayer next to the MoS2/CdS interface. The ferromagnetism is attributed to the partial occupation of the Mo dx2-y2/dxy conduction band in the interfacial MoS2 monolayer caused by the mixed covalent-ionic bonding among the MoS2 and CdS monolayers near the MoS2/CdS interface. The present findings of the ferromagnetic MoS2 monolayer with large spin polarization at the MoS2-semiconductor interface suggest a new route for fabrication of the transition metal dichalcogenide-based magnetic semiconductor multilayers for applications in spintronic devices.

cond-mat.mtrl-sci↗

arXiv2013

Influence of morphology on the plasmonic enhancement effect of Au@TiO2 core-shell nanoparticles in dye-sensitized solar cells

Plasmonic core-shell nanoparticles (PCSNPs) can function as nanoantennas and improve the efficiency of dye-sensitized solar cells (DSSCs). To achieve maximum enhancement, the morphology of PCSNPs need to be optimized. Here we precisely control the morphology of Au@TiO2 PCSNPs and systematically study its influence on the plasmonic enhancement effect. Enhancement mechanism was found to vary with the thickness of TiO2 shell. PCSNPs with thinner shell enhance the current due to plasmonic effect, whereas particles with thicker shell improve the voltage due to increasing semiconducting character. Wavelength-independent enhancement in the visible range was observed and attributed to plasmonic heating effect. PCSNPs with 5-nm shell give highest efficiency enhancement of 23%. Our work provides a new synthesis route for well-controlled Au@TiO2 core-shell nanoparticles and gains insight into the plasmonic enhancement in DSSCs.

cond-mat.mtrl-sci↗