Sharidya Rahman | Searcharxiv

arXiv2026

Hybrid Improper Ferroelectricity and Moir\'e Superlattices-induced Exciton Quantization in Layered 2D Halide Perovskite

2D Ruddlesden-Popper perovskites are compelling platforms for quantum-confined optoelectronics. However, polar order in iodide composition remains rare under ambient conditions, and the mechanistic origin of anomalous photoluminescence in this class of perovskite is still speculative. Here, we demonstrate that solution-grown $(PA)_2FAPb_2I_7$ single crystals develop an inadvertent moir\'e superlattice through pseudo-merohedral twinning, driven by hybrid improper ferroelectricity in which trilinear mode coupling between two primary zone-boundary modes ($X_2^+$ and $X_3^-$) and a secondary $\Gamma_4^-$ polar displacement simultaneously breaks inversion symmetry and imposes a ca. 5.17{\deg} rotational misalignment between adjacent layers. This symmetry breaking activates one of the highest piezoelectric coefficients $d_{33}$ (ca. 20 pm/V) reported among 2D perovskites. This misalignment generates a moir\'e superlattice that undergoes a thermally driven commensurate-incommensurate transition, switching between a periodic confinement potential that quantizes excitons into an equidistant photoluminescence ladder at 123 K and a disordered incommensurate phase with broadened emission at 298 K. These emissions are attributed to moir\'e-confined excitons, resolving a longstanding debate on anomalous secondary photoluminescence in layered 2D perovskites and opening pathways to twistronics, photoferroelectrics and piezo-optoelectronic devices.

cond-mat.mtrl-sci↗

arXiv2023

Twisted van der Waals Quantum Materials: Fundamentals, Tunability and Applications

Twisted vdW quantum materials have emerged as a rapidly developing field of 2D semiconductors. These materials establish a new central research area and provide a promising platform for studying quantum phenomena and investigating the engineering of novel optoelectronic properties such as single-photon emission, non-linear optical response, magnon physics, and topological superconductivity. These captivating electronic and optical properties result from, and can be tailored by, the interlayer coupling using moiré patterns formed by vertically stacking atomic layers with controlled angle misorientation or lattice mismatch. Their outstanding properties and the high degree of tunability position them as compelling building blocks for both compact quantum-enabled devices and classical optoelectronics. This article offers a comprehensive review of recent advancements in the understanding and manipulation of twisted van der Waals structures and presents a survey of the state-of-the-art research on moiré superlattices, encompassing interdisciplinary interests. It delves into fundamental theories, synthesis and fabrication, and visualization techniques, and the wide range of novel physical phenomena exhibited by these structures, with a focus on their potential for practical device integration in applications ranging from quantum information to biosensors, and including classical optoelectronics such as modulators, light emitting diodes (LEDs), lasers, and photodetectors. It highlights the unique ability of moiré superlattices to connect multiple disciplines, covering chemistry, electronics, optics, photonics, magnetism, topological and quantum physics. This comprehensive review provides a valuable resource for researchers interested in moiré superlattices, shedding light on their fundamental characteristics and their potential for transformative applications in various fields.

cond-mat.mtrl-sci↗