arXiv subjects

Sheng-Li Qin

Publications and source records attributed to Sheng-Li Qin.

At least 37 records · Page 2Linked to original sources

arXiv2024

A survey of sulfur-bearing molecular lines toward the dense cores in eleven massive protoclusters

Sulfur-bearing molecules are commonly detected in dense cores within star-forming regions, but the total sulfur budget is significantly low, when compared to the interstellar medium (ISM) value. The properties of sulfur-bearing molecules are not well understood due to the absence of large sample studies with uniform observational configurations. To deepen our understanding of this subject, we conducted a study using ALMA 870 \micron~observations of 11 massive protoclusters. By checking the spectra of 248 dense cores in 11 massive protoclusters, a total of 10 sulfur-bearing species (CS, SO, \htcs, NS, \sot, \ttso, \tfsot, \ttsot, \seoo, \octfs) were identified. The parameters including systemic velocities, line widths, gas temperatures, column densities, and abundances were derived. Our results indicate that SO appears to be more easily detected in a wider range of physical environments than \htcs, despite these two species show similarities in gas distributions and abundances. \tfsot~and \htcs~are good tracers of the temperature of sulfur-bearing species, in which \htcs~traces the outer warm envelope and \tfsot~is associated with high-temperature central-regions. High-mass star-forming feedback (outflow and other non-thermal motions) significantly elevates the sulfur-bearing molecular abundances and detection rates specifically for \sot~and SO. A positive correlation between the \sot~abundance increasing factor ($F$) and temperatures suggests that \sot~could serve as a sulfur reservoir on the grain mantles of dense cores and then can be desorbed from dust to gas phase as the temperature rises. This work shows the importance of a large and unbiased survey to understand the sulfur depletion in dense cores.

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arXiv2024

Correlations of Methyl Formate (CH3OCHO), Dimethyl Ether (CH3OCH3) and Ketene (H2CCO) in High-mass Star-forming Regions

We present high-spatial-resolution (0.7 to 1.0 arcsec) submillimeter observations of continuum and molecular lines of CH3OCHO, CH3OCH3, and H2CCO toward 11 high-mass star-forming regions using the Atacama Large Millimetre/submillimetre Array (ALMA). A total of 19 separate cores from 9 high-mass star-forming regions are found to be line-rich, including high-, intermediate-, and low-mass line-rich cores. The three molecules are detected in these line-rich cores. We map the emission of CH3OCHO, CH3OCH3, and H2CCO in 9 high-mass star-forming regions. The spatial distribution of the three molecules is very similar and concentrated in the areas of intense continuum emission. We also calculate the rotation temperatures, column densities, and abundances of CH3OCHO, CH3OCH3, and H2CCO under the local thermodynamic equilibrium (LTE) assumption. The abundances relative to H2 and CH3OH, and line widths of the three molecules are significantly correlated. The abundances relative to H2, temperatures and line widths of the three molecules tend to be higher in cores with higher mass and outflows detected. The possible chemical links of the three molecules are discussed.

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arXiv2024

Implication of the velocity dispersion scalings on high-mass star formation in molecular clouds

This paper is aimed at exploring implications of velocity dispersion scalings on high-mass star formation in molecular clouds, including the scalings of Larson's linewidth--size ($σ$--$R$) and ratio--mass surface density ($\cal{L}$--$Σ$; here $\cal{L}$$=σ/R^{0.5}$). We have systematically analyzed the $σ$ parameter of well-selected 221 massive clumps, complemented with published samples of other hierarchical density structures of molecular clouds over spatial scales of 0.01--10 pc. Those massive clumps are classified into four phases: quiescent, protostellar, HII region, and PDR clumps in an evolutionary sequence. The velocity dispersion of clumps increases overall with the evolutionary sequence, reflecting enhanced stellar feedback in more evolved phases. The relations of $σ$--$R$ and $\cal{L}$--$Σ$ are weak with the clump sample alone, but become evident when combined with others spanning a much wider spatial scales. For $σ$--$R$, its tight relation indicates a kinematic connection between hierarchical density structures, supporting theoretical models of multiscale high-mass star formation. From the $\cal{L}$--$Σ$ relation, cloud structures can be found to transition from over-virial state ($α_\mathrm{vir} > 2$) to sub-virial state ($α_\mathrm{vir} < 2$) as they become smaller and denser, indicating a possible shift in the governing force from turbulence to gravity. This implies that the multiscale physical process of high-mass star formation hinges on the self-gravity of sub-virial molecular clouds. However, the influence of turbulence may not be dismissed until large-scale clouds attain a sub-virial state. This is pending confirmation from future multiscale kinematic observations of molecular clouds with uniform observing settings.

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arXiv2024

A Machine Learning made Catalog of FR-II Radio Galaxies from the FIRST Survey

We present an independent catalog (FRIIRGcat) of 45,241 Fanaroff-Riley Type II (FR-II) radio galaxies compiled from the Very Large Array Faint Images of the Radio Sky at Twenty-centimeters (FIRST) survey and employed the deep learning method. Among them, optical and/or infrared counterparts are identified for 41,425 FR-IIs. This catalog spans luminosities $2.63\times10^{22}\leq L_{\rm rad}\leq6.76\times10^{29}\,{\rm W}\,{\rm Hz}^{-1}$ and redshifts up to $z=5.01$. The spectroscopic classification indicates that there are 1431 low-excitation radio galaxies and 260 high-excitation radio galaxies. Among the spectroscopically identified sources, black hole masses are estimated for 4837 FR-IIs, which are in $10^{7.5}\lesssim M_{\rm BH}\lesssim 10^{9.5}$ $M_{\odot}$. Interestingly, this catalog reveals a couple of giant radio galaxies (GRGs), which are already in the existing GRG catalog, confirming the efficiency of this FR-II catalog. Furthermore, 284 new GRGs are unveiled in this new FR-II sample; they have the largest projected sizes ranging from 701 to 1209 kpc and are located at redshifts $0.31<z<2.42$. Finally, we explore the distribution of the jet position angle and it shows that the faint Images of the FIRST images are significantly affected by the systematic effect (the observing beams). The method presented in this work is expected to be applicable to the radio sky surveys that are currently being conducted because they have finely refined telescope arrays. On the other hand, we are expecting that further new methods will be dedicated to solving this problem.

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arXiv2024

The ALMA-QUARKS survey: Detection of two extremely dense substructures in a massive prestellar core

Only a handful of massive starless core candidates have been discovered so far, but none of them have been fully confirmed. Within the MM1 clump in the filamentary infrared dark cloud G34.43+0.24 that was covered by the ALMA-ATOMS survey at Band 3 ($\sim2\arcsec$, 6000\,au) and the ALMA-QUARKS survey at Band 6 ($\sim 0.3\arcsec$, 900\,au), two prestellar core candidates MM1-C and E1 with masses of 71 and 20 \solarmass~and radii of 2100--4400\,au were discovered. The two cores show no obvious sign of star-formation activities. In particular, MM1-C is a very promising massive prestellar core candidate with a total gas mass of 71\,\solarmass. Within MM1-C, we detected two extremely dense substructures, C1 and C2, as characterized by their high densities of $\rm n_{H_2}\sim 10^{8-9} cm^{-3}$. Moreover, evidence of further fragmentation in C2 was also revealed. We have detected the primordial fragmentation in the earliest stage of massive star formation, and we speculate that MM1-C would be the birthplace of a massive multiple system. However, we cannot fully rule out the possibility that the massive prestellar core MM1-C will just form a cluster of low-mass stars if it undergoes further fragmentation.

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arXiv2024

Multiscale Dynamical Scenario of High-mass Star Formation in an IRDC Filament G34

There is growing evidence that high-mass star formation (HMSF) is a multiscale, dynamical process in molecular clouds, where filaments transport gas material between larger and smaller scales. We analyze here multiscale gas dynamics in an HMSF filamentary cloud, G034.43+00.24 (G34), using APEX observations of the C18O (2-1), HCO+/H13CO+ (3-2), and HCN/H13CN (3-2) lines. We find large-scale, filament-aligned velocity gradients from C18O emission, which drive filamentary gas inflows onto dense clumps in the middle ridge of G34. The nature of these inflows is gravity driven. We also find clump-scale gas infall in the middle ridge of the MM2, MM4, and MM5 clumps from other lines. Their gas infall rates could depend on large-scale filamentary gas inflows since the infall/inflow rates on these two scales are comparable. We confirm that the multiscale, dynamical HMSF scenario is at work in G34. It could be driven by gravity up to the filament scale, beyond which turbulence originating from several sources, including gravity, could be in effect in G34.

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arXiv2023

ALMA High-resolution Spectral Survey of Thioformaldehyde (H2CS) Towards Massive Protoclusters

Investigating the temperature and density structures of gas in massive protoclusters is crucial for understanding the chemical properties therein. In this study, we present observations of the continuum and thioformaldehyde (H2CS) lines at 345 GHz of 11 massive protoclusters using the Atacama Large Millimeter/submillimeter Array (ALMA) telescope. High spatial resolution and sensitivity observations have detected 145 continuum cores from the 11 sources. H2CS line transitions are observed in 72 out of 145 cores, including line-rich cores, warm cores and cold cores. The H2 column densities of the 72 cores are estimated from the continuum emission which are larger than the density threshold value for star formation, suggesting that H2CS can be widely distributed in star-forming cores with different physical environments. Rotation temperature and column density of H2CS are derived by use of the XCLASS software. The results show the H2CS abundances increase as temperature rises and higher gas temperatures are usually associated with higher H2CS column densities. The abundances of H2CS are positively correlated with its column density, suggesting that the H2CS abundances are enhanced from cold cores, warm cores to line-rich cores in star forming regions.

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arXiv2023

The first Ka-band (26.1-35 GHz) blind line survey towards Orion KL

We conducted a Ka-band (26.1--35 GHz) line survey towards Orion KL using the TianMa 65-m Radio Telescope (TMRT). It is the first blind line survey in the Ka band, and achieves a sensitivity of mK level (1--3 mK at a spectral resolution of $\sim$1 km s$^{-1}$). In total, 592 Gaussian features are extracted. Among them, 257 radio recombination lines (RRLs) are identified. The maximum $Δn$ of RRLs of H, He and C are 20, 15, and 5, respectively. Through stacking, we have detected the $β$ lines of ion RRLs (RRLs of C$^+$ with possible contribution of other ions like O$^+$) for the first time, and tentative signal of the $γ$ lines of ion RRLs can also be seen on the stacked spectrum. Besides, 318 other line features were assigned to 37 molecular species, and ten of these species were not detected in the Q-band survey of TMRT. The vibrationally excited states of nine species were also detected. Emission of most species can be modeled under LTE. A number of transitions of E-CH3OH ($J_2-J_1$) display maser effects, which are confirmed by our modeling, and besides the bumping peak at $J\sim 6$ there is another peak at $J\sim 13$. Methylcyanoacetylene (CH$_3$C$_3$N) is detected in Orion KL for the first time. This work emphasizes that the Ka band, which was long-ignored for spectral line surveys, is very useful for surveying RRLs and molecular lines simultaneously.

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arXiv2023

The ALMA-QUARKS survey: -- I. Survey description and data reduction

This paper presents an overview of the QUARKS survey, which stands for `Querying Underlying mechanisms of massive star formation with ALMA-Resolved gas Kinematics and Structures'. The QUARKS survey is observing 139 massive clumps covered by 156 pointings at ALMA Band 6 ($λ\sim$ 1.3 mm). In conjunction with data obtained from the ALMA-ATOMS survey at Band 3 ($λ\sim$ 3 mm), QUARKS aims to carry out an unbiased statistical investigation of massive star formation process within protoclusters down to a scale of 1000 au. This overview paper describes the observations and data reduction of the QUARKS survey, and gives a first look at an exemplar source, the mini-starburst Sgr B2(M). The wide-bandwidth (7.5 GHz) and high-angular-resolution (~0.3 arcsec) observations of the QUARKS survey allow to resolve much more compact cores than could be done by the ATOMS survey, and to detect previously unrevealed fainter filamentary structures. The spectral windows cover transitions of species including CO, SO, N$_2$D$^+$, SiO, H$_{30}α$, H$_2$CO, CH$_3$CN and many other complex organic molecules, tracing gas components with different temperatures and spatial extents. QUARKS aims to deepen our understanding of several scientific topics of massive star formation, such as the mass transport within protoclusters by (hub-)filamentary structures, the existence of massive starless cores, the physical and chemical properties of dense cores within protoclusters, and the feedback from already formed high-mass young protostars.

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arXiv2023

A low-mass line-rich core found in Massive Star-forming Region IRAS 16351-4722

We present ALMA sub-arcsecond-resolution observations of both continuum and molecular lines at 345 GHz towards the massive star-forming region IRAS 16351-4722 (hereafter I16351). A total of 12 dust cores were detected based on high spatial resolution observations of the continuum. Among them, a high-mass core (11.6 Msun) and a low-mass core (1.7 Msun) show abundant molecular line emissions. 164 molecular transitions from 29 species and 104 molecular transitions from 25 species are identified in the high-mass and low-mass cores, respectively. Complex organic molecules (COMs) such as CH3OH, CH3OCHO, CH3OCH3, C2H5OH, and C2H5CN are detected in the two cores. Under the assumption of local thermodynamic equilibrium (LTE), rotational temperatures and column densities of the COMs are derived with the XCLASS software. The maximum rotation temperature values in the low-mass core and the high-mass core were found to be approximately 130 K and 198 K, respectively. Additionally, the line widths in the high-mass core are larger than those in the low-mass one. Abundant complex organic molecular line transitions, high gas temperatures, and smaller line widths indicate the presence of a low-mass line-rich core in the massive star formation region for the first time, while the high-mass line-rich core shows hot core property. When comparing the molecular abundances of CH3OH, CH3OCHO, CH3OCH3 and C2H5OH of the two cores with other hot cores and hot corinos reported in the literature, we further confirm that both a hot core and a low-mass line-rich core are simultaneously detected in I16351.

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arXiv2023

Investigating a Global Collapsing Hub-Filament Cloud G326.611+0.811

We present the dynamics study toward the G326.611+0.811 (G326) hub-filament-system (HFS) cloud using the new APEX observations of both $^{13}$CO and C$^{18}$O (J = 2-1). The G326 HFS cloud constitutes a central hub and at least four hub-composing filaments that are divided into a major branch of filaments (F1, and F2) and a side branch (F3-F5). The cloud holds ongoing high-mass star formation as characterised by three massive dense clumps (i.e., 370-1100 $M_{\odot}$ and 0.14-0.16 g cm$^{-2}$ for C1-C3) with the high clump-averaged mass infalling rates ($>10^{-3}$ $M_{\odot}$ yr$^{-1}$) within in the major filament branch, and the associated point sources bright at 70 $μ$m typical of young protostars. Along the five filaments, the velocity gradients are found in both $^{13}$CO and C$^{18}$O (J = 2-1) emission, suggesting that the filament-aligned gravitational collapse toward the central hub (i.e., C2) is being at work for high-mass star formation therein. Moreover, a periodic velocity oscillation along the major filament branch is revealed in both $^{13}$CO and C$^{18}$O (J = 2-1) emission with a characteristic wavelength of $\sim$3.5 pc and an amplitude of $\sim$0.31-0.38 km s$^{-1}$. We suggest that this pattern of velocity oscillation in G326 could arise from the clump-forming gas motions induced by gravitational instability. Taking into account the prevalent velocity gradients, the fragmentation of the major branch of filaments, and the ongoing collapse of the three massive dense clumps, it is indicative that G326 is a HFS undergoing global collapse.

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arXiv2023

ALMA Survey of Orion Planck Galactic Cold Clumps (ALMASOP): The Warm-Envelope Origin of Hot Corinos

Hot corinos are of great interest due to their richness in interstellar complex organic molecules (COMs) and the consequent potential prebiotic connection to solar-like planetary systems. Recent surveys have reported an increasing number of hot corino detections in Class 0/I protostars; however, the relationships between their physical properties and the hot-corino signatures remain elusive. In this study, our objective is to establish a general picture of the detectability of the hot corinos by identifying the origin of the hot-corino signatures in the sample of young stellar objects (YSOs) obtained from the Atacama Large Millimeter/submillimeter Array Survey of Orion Planck Galactic Cold Clumps (ALMASOP) project. We apply spectral energy distribution (SED) modeling to our sample and identify the physical parameters of the modeled YSOs directly, linking the detection of hot-corino signatures to the envelope properties of the YSOs. Imaging simulations of the methanol emission further support this scenario. We, therefore, posit that the observed COM emission originates from the warm inner envelopes of the sample YSOs, based on both the warm region size and the envelope density profile. The former is governed by the source luminosity and is additionally affected by the disk and cavity properties, while the latter is related to the evolutionary stages. This scenario provides a framework for detecting hot-corino signatures toward luminous Class 0 YSOs, with fewer detections observed toward similarly luminous Class I sources.

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arXiv2023

Direct observational evidence of the multi-scale, dynamical mass accretion toward a high-mass star forming hub-filament system

There is growing evidence that high-mass star formation and hub-filament systems (HFS) are intricately linked. The gas kinematics along the filaments and the forming high-mass star(s) in the central hub are in excellent agreement with the new generation of global hierarchical high-mass star formation models. In this paper, we present an observational investigation of a typical HFS cloud, G310.142+0.758 (G310 hereafter) which reveals unambiguous evidence of mass inflow from the cloud scale via the filaments onto the forming protostar(s) at the hub conforming with the model predictions. Continuum and molecular line data from the ATOMS and MALT90 surveys are used that cover different spatial scales. Three filaments (with total mass $5.7\pm1.1\times 10^3~M_{\odot}$) are identified converging toward the central hub region where several signposts of high-mass star formation have been observed. The hub region contains a massive clump ($1280\pm260~M_{\odot}$) harbouring a central massive core. Additionally, five outflow lobes are associated with the central massive core implying a forming cluster. The observed large-scale, smooth and coherent velocity gradients from the cloud down to the core scale, and the signatures of infall motion seen in the central massive clump and core, clearly unveil a nearly-continuous, multi-scale mass accretion/transfer process at a similar mass infall rate of $\sim 10^{-3}~M_{\odot}~yr^{-1}$ over all scales, feeding the central forming high-mass protostar(s) in the G310 HFS cloud.

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arXiv2023

ALMA Survey of Orion Planck Galactic Cold Clumps (ALMASOP): A forming quadruple system with continuum `ribbons' and intricate outflows

One of the most poorly understood aspects of low-mass star formation is how multiple-star systems are formed. Here we present the results of Atacama Large Millimeter/submillimeter Array (ALMA) Band-6 observations towards a forming quadruple protostellar system, G206.93-16.61E2, in the Orion B molecular cloud. ALMA 1.3 mm continuum emission reveals four compact objects, of which two are Class I young stellar objects (YSOs), and the other two are likely in prestellar phase. The 1.3 mm continuum emission also shows three asymmetric ribbon-like structures that are connected to the four objects, with lengths ranging from $\sim$500 au to $\sim$2200 au. By comparing our data with magneto-hydrodynamic (MHD) simulations, we suggest that these ribbons trace accretion flows and also function as gas bridges connecting the member protostars. Additionally, ALMA CO J=2-1 line emission reveals a complicated molecular outflow associated with G206.93-16.61E2 with arc-like structures suggestive of an outflow cavity viewed pole-on.

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arXiv2023

ALMA Survey of Orion Planck Galactic Cold Clumps (ALMASOP): Detection of extremely high density compact structure of prestellar cores and multiple substructures within

Prestellar cores are self-gravitating dense and cold structures within molecular clouds where future stars are born. They are expected, at the stage of transitioning to the protostellar phase, to harbor centrally concentrated dense (sub)structures that will seed the formation of a new star or the binary/multiple stellar systems. Characterizing this critical stage of evolution is key to our understanding of star formation. In this work, we report the detection of high density (sub)structures on the thousand-au scale in a sample of dense prestellar cores. Through our recent ALMA observations towards the Orion molecular cloud, we have found five extremely dense prestellar cores, which have centrally concentrated regions $\sim$ 2000 au in size, and several $10^7$ $cm^{-3}$ in average density. Masses of these centrally dense regions are in the range of 0.30 to 6.89 M$_\odot$. {\it For the first time}, our higher resolution observations (0.8$'' \sim $ 320 au) further reveal that one of the cores shows clear signatures of fragmentation; such individual substructures/fragments have sizes of 800 -1700 au, masses of 0.08 to 0.84 M$_\odot$, densities of $2 - 8\times 10^7$ $cm^{-3}$ and separations of $\sim 1200$ au. The substructures are massive enough ($\gtrsim 0.1~M_\odot$) to form young stellar objects and are likely examples of the earliest stage of stellar embryos which can lead to widely ($\sim$ 1200 au) separated multiple systems.

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arXiv2023

First Detection of Radio Recombination Lines of Ions Heavier than Helium

We report the first detection of radio recombination lines (RRLs) of ions heavier than helium. In a highly sensitive multi-band (12--50 GHz) line survey toward Orion KL with the TianMa 65-m Radio Telescope (TMRT), we successfully detected more than fifteen unblended $α$ lines of RRLs of singly ionized species (XII) recombined from XIII. The Ka-band (35--50 GHz) spectrum also shows tentative signals of $β$ lines of ions. The detected lines can be successfully crossmatched with the the rest frequencies of RRLs of CII and/or OII. This finding greatly expands the connotation of ion RRLs, since before this work only two blended lines (105$α$ and 121$α$) of HeII had been reported. Our detected lines can be fitted simultaneously under assumption of local thermodynamic equilibrium (LTE). An abundance of CIII and OIII of 8.8$\times$10$^{-4}$ is obtained, avoiding the complexities of optical/infrared observations and the blending of RRLs of atoms. It is consistent with but approaches the upper bound of the value (10$^{-4}$--$10^{-3}$) estimated from optical/infrared observations. The effects of dielectronic recombination may contribute to enhancing the level populations even at large $n$. We expect future observations using radio interferometers could break the degeneracy between C and O, and help to reveal the ionization structure and dynamical evolution of various ionized regions.

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arXiv2023

ATOMS: ALMA Three-millimeter Observations of Massive Star-forming regions -- XV. Steady Accretion from Global Collapse to Core Feeding in Massive Hub-filament System SDC335

We present ALMA Band-3/7 observations towards "the Heart" of a massive hub-filament system (HFS) SDC335, to investigate its fragmentation and accretion. At a resolution of $\sim0.03$ pc, 3 mm continuum emission resolves two massive dense cores MM1 and MM2, with $383(^{+234}_{-120})$ $M_\odot$ (10-24% mass of "the Heart") and $74(^{+47}_{-24})$ $M_\odot$, respectively. With a resolution down to 0.01 pc, 0.87 mm continuum emission shows MM1 further fragments into six condensations and multi-transition lines of H$_2$CS provide temperature estimation. The relation between separation and mass of condensations at a scale of 0.01 pc favors turbulent Jeans fragmentation where the turbulence seems to be scale-free rather than scale-dependent. We use the H$^{13}$CO$^+$ (1-0) emission line to resolve the complex gas motion inside "the Heart" in position-position-velocity space. We identify four major gas streams connected to large-scale filaments, inheriting the anti-clockwise spiral pattern. Along these streams, gas feeds the central massive core MM1. Assuming an inclination angle of $45(\pm15)^{\circ}$ and a H$^{13}$CO$^+$ abundance of $5(\pm3)\times10^{-11}$, the total mass infall rate is estimated to be $2.40(\pm0.78)\times10^{-3}$ $M_\odot$ yr$^{-1}$, numerically consistent with the accretion rates derived from the clump-scale spherical infall model and the core-scale outflows. The consistency suggests a continuous, near steady-state, and efficient accretion from global collapse, therefore ensuring core feeding. Our comprehensive study of SDC335 showcases the detailed gas kinematics in a prototypical massive infalling clump and calls for further systematic and statistical analyses in a large sample.

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arXiv2022

A Q-band line survey towards Orion KL using the Tianma radio telescope

We have conducted a line survey towards Orion KL using the Q-band receiver of Tianma 65 m radio telescope (TMRT), covering 34.8--50 GHz with a velocity resolution between 0.79 km s$^{-1}$ and 0.55 km s$^{-1}$ respectively. The observations reach a sensitivity on the level of 1-8 mK, proving that the TMRT is sensitive for conducting deep line surveys. In total, 597 Gaussian features are extracted. Among them, 177 radio recombination lines (RRLs) are identified, including 126, 40 and 11 RRLs of hydrogen, helium and carbon, with a maximum $Δn$ of 16, 7, and 3, respectively. The carbon RRLs are confirmed to originate from photodissociation regions with a $V_{\rm LSR}\sim$9 km s$^{-1}$. In addition, 371 molecular transitions of 53 molecular species are identified. Twenty-one molecular species of this survey were not firmly detected in the Q band by Rizzo et al. (2017), including species such as H$_2$CS, HCOOH, C$_2$H$_5$OH, H$_2^{13}$CO, H$_2$CCO, CH$_3$CHO, CH$_2$OCH$_2$, HCN $v_2=1$, and CH$_3$OCHO $v_t=1$. In particular, the vibrationally excited states of ethyl cyanide (C$_2$H$_5$CN $v$13/$v$21) are for the first time firmly detected in the Q band. NH$_3$ (15,15) and (16,16) are identified, and they are so far the highest transitions of the NH$_3$ inversion lines detected towards Orion KL. All the identified lines can be reproduced by a radiative transfer model.

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