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Shengxiang Wu

Publications and source records attributed to Shengxiang Wu.

4 recordsLinked to original sources

Less is more: Not all samples are effective for evaluation

The versatility of Large Language Models (LLMs) in vertical domains has spurred the development of numerous specialized evaluation benchmarks. However, these benchmarks often suffer from significant semantic redundancy and impose high computational costs during evaluation. Existing compression methods, such as tinyBenchmarks depend critically on correctness labels from multiple historical models evaluated on the full test set, making them inapplicable in cold-start scenarios, such as the introduction of a new task, domain, or model with no prior evaluation history. To address this limitation, we propose a history-free test set compression framework that requires no prior model performance data. Our method begins by fine-tuning a base LLM on a small amount of domain-specific data to internalize task-relevant semantics. It then generates high-level semantic embeddings for all original test samples using only their raw textual content. In this domain-adapted embedding space, we perform task-aware clustering and introduce a novel dataset X-ray mechanism that analyzes cluster geometry to dynamically calibrate the compression intensity based on the intrinsic redundancy of the benchmark. Experiments on professional-domain dataset, notably a large-scale 3GPP communications benchmark, demonstrate that our approach effectively identifies and removes redundant samples, reducing evaluation cost by over 90% while preserving high fidelity to the full benchmark.

cs.CL

Unified description of thermal and nonthermal hot carriers in plasmonic photocatalysis

The damping of surface plasmons generates hot carriers, which holds promise for photoelectric conversion and photocatalysis. Recent studies have revealed the nonequilibrium characters of the plasmonic hot carriers and their nonadiabatic coupling to molecular vibrations. Yet, the precise mechanism of plasmonic photocatalysis remains elusive and controversial. Here, we present a unified description of thermal and nonthermal hot carriers in the dynamics of vibrational excitation and photodissocation, where a quantitative comparison between the two mechanisms can be made. We revisit a well-studied system, O$_2$ dissociation on silver nanoparticles. The nonthermal hot carriers are found to promote molecular dissociation in the low-temperature or high-intensity regime. With increasing laser intensity, the dissociation rate exhibits a transition from a linear to nonlinear dependence due to the onset of vibrational heating as observed in experiment. Our model provides a unified framework to understand the mechanism and dynamics of photocatalysis and reveals the nonthermal pathways for energy harvesting and conversion with surface plasmons.

cond-mat.mtrl-sci

The Connection Between Plasmon Decay Dynamics and the SERS background: Inelastic Scattering from Non-Thermal and Hot Carriers

Recent studies have established that the anti-Stokes Raman signal from plasmonic metal nanostructures can be used to determine the two separate temperatures that characterize carriers inside the metal -- the temperature of photoexcited "hot carriers" and carriers that are thermalized with the metal lattice. However, the related signal in the Stokes spectral region has historically impeded surface enhanced Raman spectroscopy (SERS), as the vibrational peaks of adsorbed molecules are always accompanied by the broad background of the metal substrate. The fundamental source of the metal signal, and hence its contribution to the spectrum, has been unclear. Here, we outline a unified theoretical model that describes both the temperature-dependent behavior and the broad spectral distribution. We suggest that the majority of the Raman signal is from inelastic scattering directly with non-thermal carriers that have been excited via damping of the surface plasmon. In addition, a significant spectral component (~ 1%) is due to a sub-population of hot carriers in an elevated thermal distribution. We have performed temperature and power-dependent Raman experiments to show how a simple fitting procedure reveals the plasmon dephasing time, as well as the temperatures of the hot carriers and the metal lattice, in order to correlate these parameters with quantitative Raman analysis of chemical species adsorbed on metal surface.

physics.app-ph

Hot Electron Dynamics in Plasmonic Thermionic Emitters

Thermionic converters generate electricity from thermal energy in a power cycle based on vacuum emission of electrons. While thermodynamically efficient, practical implementations are limited by the extreme temperatures required for electron emission (> 1500 K). Here, we show how metal nanostructures that support resonant plasmonic absorption enable an alternative strategy. High electronic temperatures required for efficient vacuum emission can be maintained during steady-state optical absorption while the lattice temperature remains within the range of thermal stability, below 600 K. We have also developed an optical thermometry technique based on anti-Stokes Raman spectroscopy that confirms these unique electron dynamics. Thermionic devices constructed from plasmonic absorbers show performance that can out-compete other strategies of concentrated solar power conversion in terms of efficiency and thermal stability.

physics.app-ph