arXiv subjects

Shigeki Miyasaka

Publications and source records attributed to Shigeki Miyasaka.

At least 19 recordsLinked to original sources

arXiv2025

Growth of uniform helium submonolayers adsorbed on single-surface graphite observed by surface X-ray diffraction

We observed surface X-ray diffraction from He-4 submonolayers adsorbed on a single-surface graphite using synchrotron X-rays. Time evolutions of scattering intensities along the crystal truncation rod (CTR) were observed even after reaching the base low temperature in a selected condition of sample preparation. Our simulations for CTR scatterings based on the random double-layer model, in which helium atoms are distributed randomly in the first and second layers with a certain occupancy ratio, can consistently explain the observed intensity changes. These results support the scenario that He atoms are stratified initially as a nonequilibrium state and then relaxed into a uniform monolayer by surface diffusion, where the relaxation process was observed as a decrease in CTR scattering intensity. The observed time constant was, however, much longer than those estimated from quantum and thermal surface diffusions. This implies homogeneous processes in surface diffusions were strongly suppressed by local potentials in such as atomic steps or microcrystalline boundaries.

cond-mat.mtrl-sci↗

arXiv2025

Suppression of ferromagnetism in rippled La$_{2/3}$Sr$_{1/3}$MnO$_3$ membrane with process-induced strain prepared by epitaxial lift-off technique

Transition metal oxides are a platform for exploring strain-engineered intriguing physical properties and developing spintronic or flexible electronic functionalities owing to strong coupling of spin, charge and lattice degrees of freedom. In this study, we exemplify the strain-engineered magnetism of La$_{2/3}$Sr$_{1/3}$MnO$_3$ in freestanding and rippled membrane forms without and with process-induced strain, respectively, prepared by epitaxial lift-off technique. We find that the deposition of Pt/Ti stressor suppresses the crack formation in the lift-off process and induces a ripple structure in the La$_{2/3}$Sr$_{1/3}$MnO$_3$ membrane. Laser micrograph and Raman spectroscopy show a ripple period of about 30 um and a height of a few um, where alternating convex and concave structures are subjected to tensile strain of 0.6% and compressive strain of 0.5%, respectively. While the freestanding La$_{2/3}$Sr$_{1/3}$MnO$_3$ membrane exhibits room-temperature ferromagnetism, the macroscopic magnetic transition temperature (TC) of the rippled membrane is reduced by as large as 27%. Temperature-variable Kerr microscopy observation in the rippled membrane reveals that the spatial variation of TC to be approximately 4% of the macroscopic TC, which coincides with the local strains at convex and concave structures. The large reduction of macroscopic TC in the rippled membrane may be ascribed to the lattice disorders due to strain gradient. Our demonstration of tuning ferromagnetism by the ripple structure validates the high potential of the process-induced strain in epitaxial lift-off technique and paves the way for strain-mediated emerging physical properties in various transition metal oxides.

cond-mat.mtrl-sci↗

arXiv2024

Correlation between $T_{\mathrm{c}}$ and the Pseudogap Observed in the Optical Spectra of High $T_{\mathrm{c}}$ Superconducting Cuprates

We studied the temperature dependences of the optical spectra for optimally and underdoped Bi$_2$Sr$_2$Ca$_2$Cu$_3$O$_{10+z}$ single crystals. Similarly to the other cuprates' cases, a gap-like conductivity suppression was observed with reducing the temperature from above $T_{\mathrm{c}}$, creating a peak in the conductivity spectrum. The conductivity peak energy was insensitive to the doping level, namely $T_{\mathrm{c}}$, which suggests that this gap is not a superconducting gap but is related to the pseudogap. Comparing the data of various mono-, double-, and triple-layer cuprates, we found a clear correlation between the optimal $T_{\mathrm{c}}$ of each material and the pseudogap-related conductivity peak energy.

cond-mat.supr-con↗

arXiv2024

Closing of the Mott gap near step edges in NiS2

A prototypical charge-transfer type Mott insulator NiS2 pyrite exhibits a metal-insulator transition with bandwidth control. Recent discoveries on surface-specific electronic states on other 3d transition-metal disulfide pyrites motivate us to further investigate the surface of NiS2, where metallic surface conduction is discussed. Here, the spectroscopic-imaging scanning-tunneling-microscopy observations revealed that the surface is not metallic, contrary to the expectation. Instead, the Mott gap is closed near step edges, suggesting possible electrical conduction from one-dimensional channels. The edge anomaly was observed irrespective of its magnetic order and is limited to the insulator phases.

cond-mat.str-el↗

arXiv2024

Toward the theoretically observable limit of electron density distribution by single-crystal synchrotron X-ray diffraction: The case of orbitally ordered Ti-3d^1 in YTiO_3

The theoretically observable limit of electron density distribution by single-crystal X-ray diffraction is discussed. When F_{orb} and δF are defined as, respectively, the partial structure factor for an orbital and the deviation of the observed F from the true F, the accuracy of electron density attributable to F_{orb} is chiefly determined by the number of reflections satisfying the condition F_{orb}/F > δF/F. Since F_{orb}/F, which is generally small for crystals with large F(0,0,0), is constant under a given set of experimental conditions, δF/F must be reduced to increase the number of reflections satisfying F_{orb}/F > δF/F. The present paper demonstrates how to reduce δF mathematically and experimentally, and the following topics are covered: the Poisson statistics, accumulation of errors in the data collection and reduction procedure, multiple diffraction, conversion error from F^2 to F in refinement programs, which is unavoidable when the input quantities have different dimension from F, weighting of reflections, and tips. For demonstration, observation of the electron density of the Ti-3d^1 orbital in YTiO_3 by synchrotron single-crystal X-ray diffraction is presented.

cond-mat.mtrl-sci↗

arXiv2024

Role of Vanadium-Oxide Layer in Electronic State of Sr$_2$VFeAsO$_{3-δ}$ with Oxygen Deficiency

Iron-based superconductor Sr$_2$VFeAsO$_3$ is composed of alternate stacking of a superconducting FeAs layer and an insulating vanadium-oxide layer with a perovskite-type structure. Electronic orders stemming from the spin and orbital degrees of freedom of V $3d$ electrons can arise in the vanadium-oxide layer, but such orders have not been confirmed so far. Here, we systematically investigate the electronic state of Sr$_2$VFeAsO$_{3-δ}$ with oxygen deficiency and demonstrate the phase diagram of Sr$_2$VFeAsO$_{3-δ}$ as a function of the $c$-axis lattice parameter, which has turned out to be a suitable measure of the amount of oxygen deficiency. We found a magnetic and structural anomaly at $\sim 100$ K with a thermal hysteresis, which is manifested with the introduction of oxygen deficiency. The presence of orthorhombic distortion was revealed below the temperature at which the anomaly appears, suggestive of V orbital ordering involving the $d_{xz}$ and $d_{yz}$ orbitals. It seems that substantial fluctuations associated with the orthorhombic distortion significantly influence the electronic state of the FeAs layer. Our findings indicate that the vanadium-oxide layer plays a significant role in the electronic state of Sr$_2$VFeAsO$_{3-δ}$.

cond-mat.supr-con↗

arXiv2023

The impact of the near-surface region on the interpretation of x-ray absorption spectroscopy

Transition metal oxides (TMOs) exhibit a broad spectrum of electronic, magnetic, and optical properties, making them intriguing materials for various technological applications. Soft x-ray absorption spectroscopy (XAS) is widely used to study TMOs, shedding light on their chemical state, electronic structure, orbital polarization, element-specific magnetism, and more. Different XAS acquisition modes feature different information depth regimes in the sample. Here, we employ two XAS acquisition modes, having surface-sensitive versus bulk probing depths, on the prototypical TMO SrVO3. We illustrate and elucidate a strong apparent discrepancy between the different modes, emphasizing the impact of the near-surface region on the interpretation of XAS data. These findings highlight the importance of the acquisition mode selection in XAS analysis. Moreover, the results highlight the role of the near-surface region not only in the characterization of TMOs, but also in the design of future nanoscale oxide electronics.

cond-mat.mtrl-sci↗

arXiv2023

Near-infrared light-induced superconducting-like state in underdoped YBa$_2$Cu$_3$O$_y$ studied by $c$-axis terahertz third-harmonic generation

Recent observation of the light-induced superconducting (SC)-like transient response in the $c$-axis optical conductivity far above the SC transition temperature $T_{\mathrm{c}}$ in underdoped YBa$_2$Cu$_3$O$_y$ (YBCO) has attracted great attention in the field of high-$T_{\mathrm{c}}$ superconductors. Since then, various theoretical and experimental studies have been devoted to elucidating its microscopic origin. One prominent fingerprint of the light-induced superconductivity is the emergence of $1/ω$-like spectral behavior in the imaginary part of the optical conductivity in the terahertz (THz) frequency range. However, the spectral profile can also be described by the Drude response of the quasiparticles (QPs) with a substantially low scattering rate. To circumvent this critical ambiguity, we investigated the light-induced nonequilibrium state in an underdoped YBCO sample with $T_{\mathrm{c}}$ of 61 K using the nonlinear THz optical response originating from the SC collective excitation of the ac-driven Josephson current. Upon the near-infrared (NIR) photoexcitation above $T_{\mathrm{c}}$ in the YBCO sample, the $1/ω$-like spectral behavior in the imaginary part of the optical conductivity emerges, consistent with the previous studies. However, the THz third-harmonic generation arising from the ac-driven Josephson current along the $c$-axis was absent in the NIR photoexcited state. These results indicate that the NIR-pump induced state exhibiting the $1/ω$-like response above $T_{\mathrm{c}}$ is distinct from the long-range ordered SC state in equilibrium. Based on these observations, the possible origins of the irregularly coherent charge carrier response along the $c$-axis induced by the photoexcitation are discussed.

cond-mat.supr-con↗

arXiv2021

$B_{\rm 1g}$ phonon anomaly driven by Fermi surface instability at intermediate temperature in YBa$_2$Cu$_3$O$_{7-δ}$

We performed temperature- and doping-dependent high-resolution Raman spectroscopy experiments on YBa$_2$Cu$_3$O$_{7-δ}$ to study $B$$_{\rm 1g}$ phonons. The temperature dependence of the real part of the phonon self-energy shows a distinct kink at $T=T_{\rm B1g}$ above $T$$_{\rm c}$ due to softening, in addition to the one due to the onset of the superconductivity. $T$$_{\rm B1g}$ is clearly different from the pseudogap temperature with a maximum in the underdoped region. The region between $T$$_{\rm B1g}$ and $T$$_{\rm c}$ resembles that of superconducting fluctuation or charge density wave order. While the true origin of the $B$$_{\rm 1g}$ phonon softening is not known, we can attribute it to a gap on the Fermi surface due to an electronic order. Our results may reveal the role of the $B$$_{\rm 1g}$ phonon not only in the superconducting state but also in the intertwined orders in multilayer copper oxide high-$T$$_{\rm c}$ superconductors.

cond-mat.supr-con↗

arXiv2020

Electronic Structure of $\mathrm{Sr}_{1-y}\mathrm{Ca}_{y}\mathrm{Fe_{2}}(\mathrm{As}_{1-x}\mathrm{P}_{x}\mathrm{)_{2}}$ ($x$ = 0.25, $y$ = 0.08) Revealed by Angle-Resolved Photoemission Spectroscopy

We have investigated the electronic structure of $\mathrm{Sr}_{1-y}\mathrm{Ca}_{y}\mathrm{Fe_{2}}(\mathrm{As}_{1-x}\mathrm{P}_{x}\mathrm{)_{2}}$ ($x$ = 0.25, $y$ = 0.08) by means of angle-resolved photoemission spectroscopy. From the comparison with the results of $\mathrm{BaFe_{2}}(\mathrm{As}_{1-x}\mathrm{P}_{x}\mathrm{)_{2}}$, the effects of smaller structural anisotropy ($c/a$) on the Fermi surfaces (FSs) and the gap structures are discussed. The observed FSs have three dimensional shapes. One of the hole FSs is strongly warped between the $Γ$ and $Z$ points, and the innermost FS observed at the $Z$ point disappears at the $Γ$ point, which is similar to the FS features of $\mathrm{SrFe_{2}}(\mathrm{As}_{1-x}\mathrm{P}_{x}\mathrm{)_{2}}$ ($x$ = 0.35). In the superconducting state, the node like gap-minimum is present for the $d_{xy}$ electron FS near the $X$ point, while the gaps around the other high symmetry points are isotropic. Several theoretical models based on the spin and/or the orbital fluctuation are examined to explain all these experimental results.

cond-mat.supr-con↗

arXiv2019

Multilayer Effects in Bi2Sr2Ca2Cu3O10+z Superconductors

We discuss the characteristic features of triple Cu-O2 layer cuprates superconductors, by comparing those of single and double layer cuprates superconductors. After a brief introduction to multilayer cuprates and their characteristic properties such as the doping imbalance between the inner and outer Cu-O2 planes (IP and OP, respectively) revealed by nuclear magnetic resonance, we present the experimental results of angle resolved photoemission and Raman scattering spectroscopy for the triple layer Bi2Sr2Ca2Cu3O10+z which showed two different superconducting gaps opening on the IP and OP. The doping dependence of the double peak structure in Raman spectra was found to be qualitatively consistent with that of single and double layer cuprates, if each layer doping for the IP and OP is taken into account. The fact that the IP and OP share the same electronic phase diagram and the same transition temperature (Tc) hints to a coupling between the IP and OP. Moreover, the energies of IP and OP Raman peaks were found to be very large, not scaling with Tc, which can be attributed to the strong influence of the pseudogap of the underdoped IP in triple layer cuprates. These findings suggest that the high Tc and the large gap ratio of triple layer cuprates are realized through a combination of the interlayer coupling between the OP and IP and the interaction between superconductivity and the pseudogap.

cond-mat.supr-con↗

arXiv2019

Quantitative Comparison between Electronic Raman Scattering and Angle-Resolved Photoemission Spectra in Bi$_2$Sr$_2$CaCu$_2$O$_{8+δ}$ Superconductors: Doping Dependence of Nodal and Antinodal Superconducting Gaps

Both electronic Raman scattering (ERS) and angle-resolved photoemission spectra (ARPES) revealed two energy scales for the gap in different momentum spaces in the cuprates. However, the interpretations were different, and the gap values were also different in two experiments. In order to clarify the origin of these discrepancies, we directly compared ERS and ARPES by calculating ERS from the experimental data of ARPES through the Kubo formula. The calculated ERS spectra were in good agreement with the experimental results except for the B$_{1g}$ peak energies. The doping-dependent B$_{2g}$ peak energy was well reproduced from a doping-independent d-wave gap deduced from ARPES, by assuming a particular spectral weight distribution along the Fermi surface. The B$_{1g}$ peak energies could not be reproduced by the ARPES data. The difference between B$_{1g}$ ERS and antinodal ARPES became larger with underdoping, which implies that the effect of the pseudogap is different in these two techniques.

cond-mat.supr-con↗

arXiv2016

Investigation of Precursor Superconducting State in YBa$_2$Cu$_3$O$_{7-δ}$ through In-plane Optical Spectroscopy

A precursor of superconductivity has been searched in the in-plane optical spectra of underdoped YBa$_2$Cu$_3$O$_y$, in which the previous $c$-axis optical spectra showed the presence of superconducting carriers at a temperature far above $T_c$ [Uykur $et al$., Phys. Rev. Lett. 112, 127003 (2014)][Dubroka $et al$., Phys. Rev. Lett. 106, 047006 (2011)]. By carefully subtracting the normal component from the imaginary part of conductivity $σ_2$($ω$), we found a clear in-plane response of superconducting condensate at the temperature consistent with the $c$-axis optical data. This confirms that the precursory superconductivity developing with reducing a doping level is an intrinsic phenomenon in the cuprates.

cond-mat.supr-con↗

arXiv2016

Effects of $c/a$ Anisotropy and Local Crystal Structure on Superconductivity in $A\mathrm{Fe_{2}}(\mathrm{As}_{1-x}\mathrm{P}_{x}\mathrm{)_{2}}$ ($A$=Ba$_{1-y}$Sr$_y$, Sr$_{1-y}$Ca$_y$ and Eu)

We investigated the effects of $c/a$ anisotropy and local crystal structure on superconductivity (SC) in As/P solid solution systems, $A\mathrm{Fe_{2}}(\mathrm{As}_{1-x}\mathrm{P}_{x}\mathrm{)_{2}}$ ($A$122P) with various $A$ ions. With decreasing $A$ site atomic size from $A$=Ba to Eu, the structural anisotropy decreases, and the rate of decreasing with $x$ also increases. The rapid narrowing of the region of antiferromagnetic composition ($x$) can be considered to be a result of this anisotropy change due mainly to the change in the Fermi surface (FS) nesting condition. By contrast, although the structural anisotropy systematically changes, the maximum $T_{\mathrm{c}}$ values are almost the same in all $A$122P systems except for Eu122P. These results indicate that the modification of the FS topology via the structural anisotropy does not affect SC. However local structural parameters, such as pnictogen height, are crucial for $T_{\mathrm{c}}$.

cond-mat.supr-con↗

arXiv2015

Scanning Tunneling Spectroscopy on SrFe$\mathrm{_2}$(As$\mathrm{_{1-x}}$P$\mathrm{_x}$)$\mathrm{_2}$

We investigated SrFe$\mathrm{_2}$(As$\mathrm{_{1-x}}$P$\mathrm{_x}$)$\mathrm{_2}$ single crystals with four different phosphorus concentrations x in the superconducting phase (x = 0.35, 0.46) and in the magnetic phase (x = 0, 0.2). The superconducting samples display a V-shaped superconducting gap, which suggests nodal superconductivity. Furthermore we determined the superconducting coherence length by measuring the spatially resolved superconducting density of states (DOS). Using inelastic tunneling spectroscopy we investigated excitations in the samples with four different phosphorus concentrations. Inelastic peaks are related to bosonic modes. Phonon and non-phonon mechanism for the origin of these peaks are discussed.

cond-mat.supr-con↗

arXiv2015

Importance of Fermi Surface Topology for In-Plane Resistivity Anisotropy in Hole- and Electron-Doped Ba(Fe$_{1-x}$TM$_{x}$)$_2$As$_2$ (TM=Cr, Mn and Co)

The in-plane anisotropy of resistivity has been investigated for Ba(Fe$_{1-x}$TM$_{x}$)$_2$As$_2$ (TM-Ba122, TM$=$Cr, Mn, and Co) where the substitution sites are the same but the doped carriers are different for different TM elements. The Hall coefficient measurements indicated that hole carriers are effectively doped by Cr substitution but not by Mn substitution. It has been found that the resistivity difference $Δρ=ρ_{\rm b}-ρ_{\rm a}$ in the antiferromagnetic-orthorhombic (AFO) phase of Cr-Ba122 is initially positive but it turns to negative with increasing Cr content, whereas the positive $Δρ$ monotonically increases with Mn substitution in Mn-Ba122. In the paramagnetic-tetragonal phase, $Δρ$ is always positive, but it decreases with substitution in Cr-Ba122, in contrast to the electron-doped case. These results demonstrate that the resistivity anisotropy exhibits electron-hole asymmetry in both AFO and nematic phases and that it depends on the Fermi surface topology whether the carrier scattering results in a positive or negative $Δρ$.

cond-mat.supr-con↗

arXiv2014

Electronic Phase Diagram of SrFe$_2$(As$_{1-x}$P$_x$)$_2$: Effect of Structural Dimensionality

We have investigated the electronic properties of SrFe$_2$(As$_{1-x}$P$_x$)$_2$ ($0\leqq x\leqq1$) single crystals with postannealing treatment and established a phase diagram of this system. The postannealing treatment reduced the residual resistivity in an antiferromagnetic-orthorhombic phase and enhanced the superconducting transition temperature to $T_{c, optimal}$=33\,K in the superconducting phase. The obtained phase diagram and electronic properties are similar to those of BaFe$_2$(As$_{1-x}$P$_x$)$_2$ despite the large difference in lattice constants. This indicates that, for superconductivity, the dimensionality of the Fermi surface determined by the crystal structural anisotropy is less important than the pnictogen height from the Fe plane.

cond-mat.supr-con↗

arXiv2014

Persistence of superconducting condensate far above the critical temperature in YBa$_2$(Cu,Zn)$_3$O$_y$ revealed by $c$-axis optical conductivity measurements for several Zn concentrations and carrier doping levels

The superconductivity precursor phenomena in high temperature cuprate superconductors was studied by direct measurements of superconducting condensate with the use of the $c$-axis optical conductivity of YBa$_{2}$(Cu$_{1-x}$Zn$_{x}$)$_{3}$O$_{y}$ for several doping levels ($p$) as well as for several Zn-concentrations. Both of the real and imaginary part of the optical conductivity clearly showed that the superconducting carriers persist up to the high temperatures $T$$_{p}$ that is higher than the critical temperature $T$$_{c}$ but lower than the pseudogap temperature $T$$^{\ast}$. $T$$_{p}$ increases with reducing doping level like $T$$^{\ast}$, but decreases with Zn-substitution unlike $T$$^{\ast}$.

cond-mat.supr-con↗