arXiv subjects

Shilpam Sharma

Publications and source records attributed to Shilpam Sharma.

29 records · Page 2Linked to original sources

arXiv2015

Magnetic behavior of the metal organic framework solid: [(CH3)2NH2][Co(HCOO)3]

In this study we examine the phase transitions in single crystals of [(CH3)2NH2]Co(HCOO)3], using magnetization and specific heat measurements as a function of temperature and magnetic field. Magnetisation measurements indicate a transition at 15 K that is associated with an antiferromagnetic transition. The results of the isothermal magnetization versus magnetic field curves demonstrate the presence of a single-ion magnet phase, coexisting with antiferromagnetism. A peak in specific heat is seen at 15 K, corresponding to the magnetic transition. The enthalpy of the transition evaluated from the area under the specific heat peak decreases with the application of magnetic field of upto8 T. This is suggestive of long range antiferromagnetic magnetic order, giving way to single-ion magnetic behavior under external field. In experiments at high temperatures, corresponding to the well-known structural transition in this system, the specific heat measurements, shows a peak at ~155K, that is insensitive to applied magnetic field. The magnetisation in this temperature range, while it exhibits a paramagnetic behavior, shows a distinct jump that has been attributed to a spin-state transition of Co2+ associated with the structural transition.

cond-mat.mtrl-sci↗

arXiv2014

Role of Se vacancies on Shubnikov de Haas oscillations in Bi2Se3: a combined magneto-resistance and positron annihilation study

Magneto resistance measurements coupled with positron lifetime measurements, to characterize the vacancy type defects, have been carried out on the topological insulator (TI) system Bi2Se3, of varying Se/Bi ratio. Pronounced Shubnikov de Haas (SdH) oscillations are seen in nominal Bi2Se3.1 crystals for measurements performed in magnetic fields up to 15 T in the 4 K to 10 K temperature range, with field applied perpendicular to the (001) plane of the crystal. The quantum oscillations, characteristic of 2D electronic structure, are seen only in the crystals that have a lower concentration of Se vacancies, as inferred from positron annihilation spectroscopy.

cond-mat.mtrl-sci↗

arXiv2014

Structural investigations in BaFe2-xRuxAs2 as a function of Ru and temperature

We present Synchrotron XRD measurements on powdered single crystal samples of BaFe2-xRuxAs2 samples, as a function of Ru content at room temperature. The Rietveld refinements reveal that the a-axis increases with Ru substitution, while the c-axis decreases. The variation of positional co-ordinates of As (zAs), the Fe-As bond length and the As-Fe-As bond angles have been determined from the Rietveld refinements. In the sample with x=0.1, temperature dependent XRD measurements were carried out. The results indicate that while the orthorhombicity shows the characteristic increase with decrease in temperature, the As-Fe-As bond angles, Fe-As bond length and positional co-ordinate of the As show definite anomalies close to the structural transition. First principle ab-initio simulations are performed in order to understand the experimentally observed anomalies in structural parameters. The experimental observations are discussed in the context of the simulation results.

cond-mat.supr-con↗

arXiv2014

Unification of the Pressure and Composition Dependence of Superconductivity in Ru substituted BaFe2As2

Temperature dependent high pressure electrical resistivity studies has been carried out on Ba(Fe_{1-x}Ru_{x})_{2}As_{2} single crystals with x = 0.12, 0.26 and 0.35, which correspond to under doped, optimally doped and over doped composition regimes respectively. The evolution of structural/magnetic (T_{S-M}) and superconducting transition (T_(c)) temperatures, with pressure for various compositions have been obtained. The normal state resistivity has been analyzed in terms of a model that incorporates both spin fluctuations and the opening of the gap in the spin density wave (SDW)phase. It is shown that Tc scales with the strength of the spin fluctuation, B, and T_{S-M} scales with the SDW gap parameter, Δ. This provides a prescription for the unification of the composition and pressure induced superconductivity in BaFe2As2.

cond-mat.supr-con↗

arXiv2012

Critical current density and magnetic phase diagram of BaFe1.29Ru0.71As2 Single Crystals

The critical current density has been measured on single crystals of Ru substituted BaFe2As2 superconductor at several temperatures and in fields up to 16 T. The magnetisation versus field isotherms reveal the occurrence of a clear second magnetisation peak (SMP) also known as fish-tail effect for both H parallel and perpendicular to c-axis of the crystal. The in-field resistance and magnetisation data are used to put forth a vortex phase diagram. The nature of the vortices have been determined from scaling behaviour of the pinning force density extracted from the Jc-H isotherms. The scaled JC versus reduced temperature behaviour seems to fit to a power law that indicates unambiguously that pinning in this system arises due to the spatial variation in the mean free path, viz. delta-l pinning.

cond-mat.supr-con↗

arXiv2011

75As NMR probe of antiferromagnetic fluctuations in Ba(Fe1-xRux)2As2

The evolution of 75As NMR parameters with composition and temperature was probed in the Ba(Fe1-xRux)2As2 system where Fe is replaced by isovalent Ru. While the Ru-end member was found to be a conventional Fermi liquid, the composition (x=0.5) corresponding to the highest Tc (20K) in this system shows an upturn in 75As 1/T1T below about 80 K evidencing the presence of antiferromagnetic (AFM) fluctuations. These results are similar to those obtained in another system with isovalent substitution BaFe2(As1-xPx)2 [Y. Nakai, T. Iye, S. Kitagawa, K. Ishida, H. Ikeda, S. Kasahara, H. Shishido, T. Shibauchi, Y. Matsuda, and T. Terashima, Phys. Rev. Lett. 105, 107003 (2010)] and point to the possible role of AFM fluctuations in driving superconductivity.

cond-mat.supr-con↗

arXiv2011

High intrinsic flux pinning strength of BaFe2-xCoxAs2 superconductor

The field dependence of flux pinning potential, U0, for under-doped, optimally doped and over-doped Ba(Fe,Co)2As2 single crystals has been investigated. U0 is determined using the Thermally Activated Flux Flow (TAFF) model, for both H || ab and H || c configurations. The observed power law dependencies of U0 versus H suggest that for fields upto 12 T for H || ab and 7 T for H || c, individual flux pinning, and for fields beyond 7 T for H || c, collective pinning becomes operative. A comparison of U0 for the Ba(Fe,Co)2As2 system with some other superconductors is presented

cond-mat.supr-con↗

arXiv2011

Superconducting and critical properties of PrOFe0.9Co0.1As: effect of P doping

PrOFe0.9Co0.1As is known to be a superconductor with a TC of ~14 K. In an attempt to induce charge transfer and also induce chemical pressure between the FeAs and PrO layers we have synthesized for the first time oxypnictides of the type PrOFe0.9Co0.1As1-xPx (P doping at As sites). All the compounds crystallize in the tetragonal ZrCuSiAs type structure (space group = P4/nmm). The lattice parameters (a and c) decrease as expected on substitution of smaller phosphorous at the arsenic site in PrOFe0.9Co0.1As and a decrease in TC was observed on substitution of P ions at a low rate of 0.13K/at. % of P for x > 0.1. The irreversibility field (Hirr) and critical current density (JC), obtained using the AC susceptibility measurements was found to decrease monotonically with increasing 'P' concentration. 'Hirr' is observed to be much smaller than HC2, pointing to a very low pinning energy. The pinning potential obtained using both in-field transport and AC susceptibility measurements indicate a low value of ~40 meV and show no significant variation with P substitution.

cond-mat.supr-con↗

arXiv2011

Upper critical field anisotropy in BaFe2-xCoxAs2 single crystals synthesized without flux

The upper critical field was measured upto 12 T for three BaFe2-xCoxAs2 single crystals with estimated Co concentrations of x = 0.082, x = 0.117 and x = 0.143. HC2 versus temperature was measured from temperature dependent resistivity, for various applied magnetic fields, H || ab and H || c. The [dHC2/dT]T=Tc, normalized with the corresponding TC, decreases with increasing Co content, for both directions. The anisotropy γ defined as HC2 || ab / HC2 || c shows a distinct increase with Co content, and its temperature dependence shows a peak close to the TC. Magneto transport measurements, in the spin density wave regions, showed significant negative MR for H || ab and positive MR of H || c in the x = 0.082 sample. The implications of these results are discussed.

cond-mat.supr-con↗

arXiv2010

Superconductivity in Ru substituted BaFe2-xRuxAs2

The occurrence of bulk superconductivity at ~22 K is reported in polycrystalline samples of BaFe2-xRuxAs2 for nominal Ru content in the range of x=0.75 to 1.125. A systematic suppression of the spin density wave transition temperature (TSDW) precedes the appearance of superconductivity in the system. A phase diagram is proposed based on the measured TSDW and superconducting transition temperature (TC) variations as a function of Ru composition. Band structure calculations, indicate introduction of electron carriers in the system upon Ru substitutiom. The calculated magnetic moment on Fe shows a minimum at x=1.0, suggesting that the suppression of the magnetic moment is associated with the emergence of superconductivity. Results of low temperature and high field Mossbauer measurements are presented. These indicate weakening of magnetic interaction with Ru substitution

cond-mat.supr-con↗

arXiv2009

Critical properties of superconducting Ba1-xKxFe2As2

Magnetisation and magnetoresistance measurements have been carried out on superconducting Ba1-xKxFe2As2 samples with x=0.40 and 0.50. From low field magnetization data carried out at different temperatures below TC, HC1 has been extracted. The plot of HC1 versus temperature shows an anomalous increase at low temperatures. From high field magnetization hysterisis measurements carried out in fields up to 16 T at 4.2 K and 20 K, the critical current density has been evaluated using the Bean critical state model. The JC determined from the high field data is >104A/cm2 at 4.2 K and 5 T. The superconducting transitions were also measured resistively in increasing applied magnetic fields up to 12 Tesla. From the variation of the TC onset with applied field, dHC2/dT at TC was obtained to be -7.708 T/K and -5.57 T/K in the samples with x=0.40 and 0.50.

cond-mat.supr-con↗