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Shinichiro Yano

Publications and source records attributed to Shinichiro Yano.

3 recordsLinked to original sources

A double-spiral spin ordering in the helimagnet YBaCuFeO$_{5}$

Materials with a spiral spin ordering always show a rich phase diagram and can be a playground for studying the exotic physical properties associated with spiral magnetism. Using neutron elastic and resonant x-ray scattering on a high-quality single crystal YBaCuFeO$_{5}$, we demonstrate YBaCuFeO$_{5}$ to be a helimagnet consisting of a double-spiral spin ordering. YBaCuFeO$_{5}$ undergoes a commensurate to incommensurate magnetic phase transition at $T_{N2}$$\sim$ 175 K, and the incommensurate phase consists of two spin-ordered components. Both components have different periodicities but with the same propagating direction along the {\it c}-axis below $T_{N2}$. Using resonant x-ray scattering at the Fe and Cu \textit{K}-edges, we further demonstrate that both spiral spin orderings result from the Fe$^{3+}$ and Cu$^{2+}$, respectively, forming a double-spiral spin ordering structure. This can be understood to be caused by the coupling between both sublattices of Fe$^{3+}$ and Cu$^{2+}$ with the atomic lattice.

cond-mat.str-el

Structure and magnetic properties of a La$_{0.75}$Sr$_{0.25}$Cr$_{0.90}$O$_{3-δ}$ single crystal

We have successfully grown large and good-quality single crystals of the La$_{0.75}$Sr$_{0.25}$Cr$_{0.90}$O$_{3-δ}$ compound using the floating-zone method with laser diodes. We investigated the crystal quality, crystallography, chemical composition, magnetic properties and the oxidation state of Cr in the grown single crystals by employing a combination of techniques, including X-ray Laue and powder diffraction, scanning electron microscopy, magnetization measurements, X-ray photoelectron spectroscopy and light absorption. The La$_{0.75}$Sr$_{0.25}$Cr$_{0.90}$O$_{3-δ}$ single crystal exhibits a single-phase composition, crystallizing in a trigonal structure with the space group $R\bar{3}c$ at room temperature. The chemical composition was determined as La$_{0.75}$Sr$_{0.25}$Cr$_{0.90}$O$_{3-δ}$, indicating a significant chromium deficiency. Upon warming, we observed five distinctive characteristic temperatures, namely $T_1 =$ 21.50(1) K, $T_2 =$ 34.98(1) K, $T_3 =$ 117.94(1) K, $T_4 =$ 155.01(1) K, and $T_{\textrm{N}} =$ 271.80(1) K, revealing five distinct magnetic anomalies. Our magnetization study allows us to explore the nature of these anomalies. Remarkably, the oxidation state of chromium in the single-crystal La$_{0.75}$Sr$_{0.25}$Cr$_{0.90}$O$_{3-δ}$, characterized by a band gap of 1.630(8) eV, is exclusively attributed to Cr$^{3+}$ ions, making a departure from the findings of previous studies on polycrystalline materials.

cond-mat.mtrl-sci

Colossal barocaloric effects in plastic crystals

Solid-state refrigeration technology based on caloric effects are promising to replace the currently used vapor compression cycles. However, their application is restricted due to limited performances of caloric materials. Here, we have identified colossal barocaloric effects (CBCEs) in a class of disordered solids called plastic crystals. The obtained entropy changes are about 380 J kg-1 K-1 in the representative neopentylglycol around room temperature. Inelastic neutron scattering reveals that the CBCEs in plastic crystals are attributed to the combination of the vast molecular orientational disorder, giant compressibility, and high anharmonic lattice dynamics. Our study establishes the microscopic scenario for CBCEs in plastic crystals and paves a new route to the next-generation solid-state refrigeration technology.

cond-mat.mtrl-sci