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Shion Yamada

Publications and source records attributed to Shion Yamada.

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Single-crystal structural phase diagram of stoichiometric bilayer nickelate La3Ni2O7 under hydrostatic pressure

The bilayer nickelate La3Ni2O7 has attracted intense interest following the discovery of high-temperature superconductivity under pressure, representing the first nickelate superconductor realized in bulk form. However, the crystal structure of the superconducting phase remains under active discussion, complicating efforts to establish its microscopic origin. Here we resolve these structural controversies by establishing a definitive pressure-temperature phase diagram, including the superconducting region of stoichiometric La3Ni2O7 single crystals under hydrostatic conditions using helium as the pressure-transmitting medium. At ambient pressure, La3Ni2O7 adopts a polar orthorhombic Am2m structure characterized by charge order between inequivalent Ni sites and NiO6 octahedral tilting. Upon compression, the system undergoes a direct transition from the charge-ordered Am2m phase to the tetragonal I4/mmm phase near 10 GPa, coinciding with the onset of bulk superconductivity. These results establish the intrinsic structural evolution of La3Ni2O7 and provide a structural framework for microscopic theories of nickelate superconductivity.

cond-mat.supr-con

Anti-pathogenic property of thermophile-fermented compost as a feed additive and its in vivo external diagnostic imaging in a fish model

Fermentative recycling of organic matter is important for a sustainable society, but the functionality of fermented products needs to be adequately evaluated. Here, we clarify the antipathogenic properties for fish of a compost-type feed additive fermented by thermophilic Bacillaceae using non-edible marine resources as raw materials. After prior administration of the compost extract to seabream as a fish model for 70 days, the mortality rate after 28 days of exposure to the fish pathogen Edwardsiella reached a maximum of 20%, although the rate was 60% without prior administration. Under such conditions, the serum complement activity of seabream increased, and the recovery time after anesthesia treatment was also fasten. Furthermore, the differences in the degree of smoothness and glossiness of the fish body surface depending on the administration were statistically shown by imaging techniques to evaluate the texture and color tone of field photographs. These results suggest that thermophile-fermented compost is effective as a functional feed additive against fish disease infection, and that such conditions can be estimated by body surface analysis. This study provides a new perspective for the natural symbiosis industry, as well as for the utilization of non-invasive diagnosis to efficiently estimate the quality of its production activities

q-bio.QM