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Shivani Sharma

Publications and source records attributed to Shivani Sharma.

At least 19 recordsLinked to original sources

Late-Time Cosmic Acceleration in Ho\v{r}ava-Lifshitz Gravity: Observational Evidence from Cosmic Chronometers and Pantheon+SHOES Datasets

We investigate the cosmological implications of Horava-Lifshitz (HL) gravity using a redshift-dependent deceleration parameter of the form $q(z) = q_0 + \frac{q_1 \ln(1+z)}{1 + n\ln(1+z)}$, from which the Hubble parameter $H(z)$ is derived analytically. This parametrization captures the transition from early deceleration to late-time acceleration, with a logarithmic correction governed by $n$ that distinguishes it from standard kinematic models. Model parameters $H_0$, $q_0$, $q_1$, and $n$ are constrained via MCMC using cosmic chronometer (CC) and Pantheon+SHOES datasets, individually and in combination. Across all dataset combinations, $q_0 < 0$, confirming ongoing accelerated expansion. The reconstructed $H(z)$ is consistent with $\Lambda$CDM at low redshifts, with mild deviations at higher redshifts. The $\{r, s\}$ statefinder parameters indicate that the model evolves smoothly, beginning with Chaplygin gas-type behaviour, crossing the $\Lambda$CDM fixed point, and settling into a quintessence-like phase at late times. The $Om(z)$ diagnostic reveals negative slopes throughout, indicating quintessence-like dark energy ($w > -1$). Present-day cosmic age estimates from the individual and combined datasets yield $t_0 \approx 13.7$ Gyr, in agreement with Planck 2018 constraints.

gr-qc

CORDEX-ML-Bench: A Benchmark for Data-Driven Regional Climate Downscaling -Experiment Design and Overview

Machine learning (ML) has emerged as a cost-effective approach to complement dynamical downscaling for producing high-resolution regional climate projections. However, the absence of standardised training and evaluation protocols, applied consistently across multiple domains, continues to hinder meaningful model intercomparison. We introduce CORDEX-ML-Bench, a benchmark aligned with CORDEX, which constitutes the first phase of a community initiative to advance data-driven downscaling toward operational readiness, and complement future dynamical downscaling efforts under CMIP7. The framework targets downscaled daily maximum temperature and precipitation to ~10 km resolution (20x increase) across three pilot regions; European Alps, New Zealand, and Southern Africa. Using a perfect-model experimental design, we evaluate 40 ML configurations developed independently, spanning traditional ML, convolutional U-Nets, vision transformers, graph neural networks, and generative models based on diffusion, flow matching, and generative adversarial networks. Models are trained under two experimental periods, an empirical-statistical downscaling pseudo-reality (historical period only) and Emulator (historical and future periods) -and are evaluated against a core set of metrics developed specifically for assessing downscaling skill. Generative models consistently outperform deterministic approaches for precipitation, better capturing fine-scale variability and extremes. For temperature, the generative advantage narrows and deterministic architectures remain competitive. Models trained solely on the historical period systematically underestimate future climate-change signals while those additionally trained on a future period perform better. These findings raise concerns about historically trained models widely used in an operational setting, underscoring the need for rigorous extrapolation testing.

physics.ao-ph

Magnetic structure evolution and magnetoelastic coupling across the spin reorientation transition in TmCrO3

We present a comprehensive study of the magnetic structure evolution across the spin reorientation transition in orthorhombic (Pnma) TmCrO3. Magnetic susceptibility reveals canted antiferromagnetic (CAFM) ordering at T_N = 125 K, two compensation points (T_comp1 and T_comp2), followed by magnetization reversal with a magnetic susceptibility minimum between T_comp1 and T_comp2. Heat capacity shows a sharp lambda-type transition at T_N, associated with the long-range antiferromagnetic ordering of Cr, followed by a broad feature near 9 K. Neutron powder diffraction (NPD) establishes the Pn'm'a (Gamma2) magnetic structure below T_N. A gradual change in magnetic structure occurs during the spin-reorientation (SRO) transition below 30 K, where the magnetic symmetry transforms from Pn'm'a (Gamma2) to Pn'ma' (Gamma4) phase. However, below the SRO, neither Gamma2 nor Gamma4 alone adequately fit the intensity of magnetic reflections. A satisfactory refinement is achieved using the monoclinic subgroup P21'/c', derived from a combination of Gamma2 and Gamma4. The gradual SRO of Tm and Cr moments across the compensation regime is consistent with the magnetic symmetry P21'/c'. Furthermore, the ordered moments of Cr and Tm in TmCrO3 exhibit a complex, non-monotonic temperature dependence, with the Tm sublattice driving the spin-reorientation transition near the compensation point. Anomalies in the lattice parameters reveal strong magnetoelastic coupling, linking structural distortions to the SRO.

cond-mat.str-el

Structural Inhomogeneities and Suppressed Magneto-Structural Coupling in Mn-Substituted GeCo2O4

A comprehensive study of Ge1-xMnxCo2O4 (GMCO) system was conducted using neutron powder diffraction (NPD), x-ray diffraction (XRD), Scanning electron microscopy, magnetometry, and heat capacity measurements. Comparative analysis with GeCo2O4 (GCO) highlights the influence of Mn substitution on the crystal and magnetic structure at low temperature. Surprisingly, phase separation is observed in GMCO with a targeted nominal composition of Ge0.5Mn0.5Co2O4. SEM/EDX analysis reveals that the sample predominantly consists of a Mn-rich primary phase with approximate stoichiometry Mn0.74Ge0.18Co2O4, along with a minor Ge-rich secondary phase of composition Ge0.91Mn0.19Co2O4. Although both GCO and GMCO crystallize in cubic symmetry at room temperature, a substantial difference in low-temperature structural properties has been observed. Magnetic and heat capacity data indicate ferrimagnetic ordering in the Mn-rich phase near TC = 108 K, while the Ge-rich phase exhibits antiferromagnetic order at TN = 22 K in GMCO. Analysis of heat capacity data reveals that the estimated magnetic entropy amounts to only 63% of the theoretical value expected in GMCO. A collinear ferrimagnetic arrangement is observed in the Mn rich phase below the magnetic ordering temperature, characterized by antiparallel spins of the Mn at A site and Co at B site along the c-direction. At 5 K, the refined magnetic moments are 2.31(3) for MnA and 1.82(3) uB for CoB in the Mn rich ferrimagnetic phase. The magnetic structure at 5 K in the Ge rich secondary phase is identical to the antiferromagnetic structure of the parent compound GeCo2O4. The refined value of the CoB moment in this phase at 5 K is 2.53(3) uB.

cond-mat.mtrl-sci

Metastable short-range charge order in superconducting CuxTiSe2

In a vast array of materials, including cuprates, transition metal dichalcogenides (TMDs) and rare earth tritellurides, superconductivity is found in the vicinity of short-range charge density wave (CDW) order. The crossover from long-range to short-range charge order often occurs as quenched disorder is introduced, yet it is unclear how this disorder disrupts the CDW. Here, using x-ray photon correlation spectroscopy (XPCS), we investigate the prototypical TMD superconductor CuxTiSe2 and show that disorder induces substantial CDW dynamics. We observe CDW phase fluctuations on a timescale of minutes to hours above the nominal transition temperature while the order parameter amplitude remains finite. These long timescale fluctuations prevent the system from finding the global free energy minimum upon cooling and ultimately traps it in a short-range ordered metastable state. Our findings demonstrate how correlated disorder can give rise to a distinct mechanism of domain formation that may be advantageous to the emergence of superconductivity.

cond-mat.str-el

Analysis of Generalized Hebbian Learning Algorithm for Neuromorphic Hardware Using Spinnaker

Neuromorphic computing, inspired by biological neural networks, has emerged as a promising approach for solving complex machine learning tasks with greater efficiency and lower power consumption. The integration of biologically plausible learning algorithms, such as the Generalized Hebbian Algorithm (GHA), is key to enhancing the performance of neuromorphic systems. In this paper, we explore the application of GHA in large-scale neuromorphic platforms, specifically SpiNNaker, a hardware designed to simulate large neural networks. Our results demonstrate significant improvements in classification accuracy, showcasing the potential of biologically inspired learning algorithms in advancing the field of neuromorphic computing.

cs.NE

Cosmological Model in $f(R, \mathcal{G})$ Gravity : Stability Analysis and Observational Constraints from DESI DR2

In this article, we examine the dynamical system of the Decoupled Power-law $f(R,\mathcal{G})$ gravity model. This $f(R,G)$ model framework is composed of interactions between dark matter and scalar field through the linear coupling term. The key objective of the present study is to describe the cosmological viability of the modified gravity theory formulated with gravity $ f(R, \mathcal{G}) $. We transform the cosmological equations into an autonomous system of ordinary differential equations by suitable transformation of variables. The decoupled power-law $ f(R,\mathcal{G})$ model governed by $ f(R, \mathcal{G}) = \alpha R^m + \beta \mathcal{G}^n $ has been investigated in detail to characterize the stability properties of the critical points of the autonomous system. The model may explain the late-time accelerating universe expansion corresponding to the attractor in the model. Depending on the effective equation of state parameter values corresponding to the critical points, we study the observational viability of the model using low-redshift observational data, such as observational Hubble data. Furthermore, we investigate the effects of parameters using the effective equation of the state parameter and the statefinder diagnostics. We further investigate the observational viability of the model by constraining its parameters through Markov Chain Monte Carlo (MCMC) analysis of the combined cosmic chronometer, Pantheon+SH0ES, CMB, and DESI DR2 BAO data. The constrained model predicts $H_0 = 69.71 \pm 0.61~\mathrm{km\,s^{-1}\,Mpc^{-1}}$, $q_0=-0.530$ with a transition redshift $z_t=0.646$, and a quintessence-like effective equation of state. The cosmographic parameters and cosmic age are also consistent with $\Lambda$CDM expectations.

gr-qc

Structural and Magnetic properties of Ge0.5Mn0.5Co2O4 using neutron diffraction

The structural and magnetic properties of Ge0.5Mn0.5Co2O4 (GMCO) have been investigated in detail utilizing neutron powder diffraction (NPD), x-ray diffraction (XRD), DC magnetometry, and heat capacity analysis and compared with GeCo2O4. Despite both compounds exhibiting a cubic structure at room temperature, a substantial difference on low temperature structural properties have been observed for GMCO, indicating the effect of Mn substitution on crystal structure. The magnetic and heat capacity data reveal a ferrimagnetic ordering around 108 K in GMCO. A minor secondary phase is confirmed which undergoes long range AFM ordering at further lower temperatures. This secondary phase remains undetected in XRD due to identical lattice parameters. Furthermore, the analysis of heat capacity data indicates a broadening of the high-temperature transition, attributing to the short-range correlation persisting up to higher temperatures. The estimated magnetic entropy amounts is 63% of the value expected for GMCO. The missing entropy is likely linked with the short-range magnetic correlations persisting well above the transition temperature. Cation distribution at the A and B sites has been estimated in GMCO using NPD. Magnetic structures are also confirmed in the main phase as well as in the secondary phase using NPD analysis. The high-temperature transition corresponds to the ferrimagnetic ordering of A and B site cations in the main phase. A collinear ferrimagnetic arrangement of A and B site spins aligned parallel to c axis is observed. The average values of A and B site moments in the ferrimagnetic phase at 5 K are 2.31(3) and 1.82(3)mB, respectively, with the temperature dependence of moments following the expected power law behavior. The low-temperature ordering is attributed to the antiferromagnetic ordering of B site ions associated with the secondary phase, something similar to GeCo2O4.

cond-mat.str-el

SuperdropNet: a Stable and Accurate Machine Learning Proxy for Droplet-based Cloud Microphysics

Cloud microphysics has important consequences for climate and weather phenomena, and inaccurate representations can limit forecast accuracy. While atmospheric models increasingly resolve storms and clouds, the accuracy of the underlying microphysics remains limited by computationally expedient bulk moment schemes based on simplifying assumptions. Droplet-based Lagrangian schemes are more accurate but are underutilized due to their large computational overhead. Machine learning (ML) based schemes can bridge this gap by learning from vast droplet-based simulation datasets, but have so far struggled to match the accuracy and stability of bulk moment schemes. To address this challenge, we developed SuperdropNet, an ML-based emulator of the Lagrangian superdroplet simulations. To improve accuracy and stability, we employ multi-step autoregressive prediction during training, impose physical constraints, and carefully control stochasticity in the training data. Superdropnet predicted hydrometeor states and cloud-to-rain transition times more accurately than previous ML emulators, and matched or outperformed bulk moment schemes in many cases. We further carried out detailed analyses to reveal how multistep autoregressive training improves performance, and how the performance of SuperdropNet and other microphysical schemes hydrometeors' mass, number and size distribution. Together our results suggest that ML models can effectively emulate cloud microphysics, in a manner consistent with droplet-based simulations.

physics.ao-ph

Quantum Griffiths singularity in the stoichiometric heavy-fermion system CeRh$_4$Al$_{15}$

We present a detailed investigation of the stoichiometric CeRh$_4$Al$_{15}$ single crystal compound using the temperature dependence of the heat capacity [$C_{\text{P}}$($T$)], electrical resistivity [$ρ$($T$)], magnetic susceptibility [$χ$($T$)], and magnetization [$M$($H$)] measurements for a magnetic field ($H$) applied in the basal plane and along the $c$-axis. The low temperature power-law behavior of $C$/$T$ $\propto$ $χ$ $\propto$ $T^{-1+α}$, the isotherm magnetization, $M \sim H^α$ with the exponent $α$ = 0.45 - 0.55, and the $T$-linear resistivity $Δρ$ $\sim$ $T^ε$ with $ε\sim$ 1 are found to be consistent with the formation of quantum Griffiths singularities in the non-Fermi-liquid (NFL) regime. We further investigated the spin dynamics of a polycrystalline sample of CeRh$_4$Al$_{15}$, using zero-field (ZF) and longitudinal-field (LF) muon spin relaxation ($μ$SR) measurements. ZF-$μ$SR measurements do not reveal any sign of long-range magnetic ordering down to 70~mK. The electronic relaxation rate ($λ$) below 0.5~K increases rapidly and shows a thermal activation-like characteristic [$T$log($λ$)$\sim$ $T$] over the entire measured temperature range between 70~mK to 4~K, indicating the presence of low energy spin fluctuations in CeRh$_4$Al$_{15}$. LF-$μ$SR measurements show a time-field ($t/H^η$) scaling of the $μ$SR asymmetry indicating a quantum critical behavior of this compound. Furthermore, inelastic neutron scattering study on the polycrystalline sample reveals two crystal field excitations near 19 and 33~meV. These features collectively provide strong evidence of NFL behavior in CeRh$_4$Al$_{15}$ due to the formation of Griffiths phase close to a $T$ $\rightarrow$ 0~K quantum critical point.

cond-mat.str-el

Four Factor Authentication with emerging cybersecurity for Mobile Transactions

Cybersecurity is very essential for Mobile Transactions to complete seamlessly. Mobile Commerce (Mcom.) is the very basic transaction type, which is very commonly used (2 in 5 people uses mobile as transaction medium), To secure this there are various technologies used by this research. The four factors formally known as Multi-Factor-Authentication are: two of them are Traditional methods (User Login-password and One Time Password (aka OTP)) with addition of Geolocation and Facial Recognition. All the data is converted to a text file, which is hidden in an image (using Babushka algorithm). The end-point then decrypts the image using same algorithm.

cs.CR

Testing spatial curvature and anisotropic expansion on top of the $Λ$CDM model

We explore the possible advantages of extending the $Λ$CDM model by more realistic backgrounds compared to its spatially flat RW spacetime assumption, while preserving the underpinning physics; in particular, by simultaneously allowing non-zero spatial curvature and anisotropic expansion on top of it, viz., the An-$oΛ$CDM model. This is to test whether the latest data support spatial flatness and/or isotropic expansion, and, if not, to explore the roles of spatial curvature and expansion anisotropy (due to its stiff fluid-like behavior) in addressing some of the cosmological tensions. We first present the theoretical background and explicit mathematical construction of An-$oΛ$CDM; combining the simplest anisotropic generalizations of the RW spacetime, viz., the Bianchi type I, V, and IX spacetimes. Then we constrain this model and its particular cases, viz., An-$Λ$CDM, $oΛ$CDM, and $Λ$CDM, by using the data sets from different probes, viz., Planck CMB(+Lens), BAO, SnIa Pantheon, and CC data, and discuss the results. Ultimately, we conclude that, within the setup under consideration, (i) the data confirm the spatial flatness and isotropic expansion, though a very small amount of present-day expansion anisotropy cannot be excluded, e.g., $Ω_{\sigma0}\lesssim10^{-18}$ (95\% C.L.) for An-$Λ$CDM from CMB+Lens, (ii) the introduction of spatial curvature or anisotropic expansion, or both, on top $Λ$CDM does not offer a possible relaxation to the $H_0$ tension, and (iii) the introduction of anisotropic expansion neither affects the closed space prediction from CMB(+Lens) nor does it improve the drastically reduced value of $H_0$ led by the closed space. We discuss why it is important and indispensable to maintain the geometric generalization work program, especially in models that offer solutions to cosmological tensions. [abridged]

astro-ph.CO

Quantum critical spin-liquid-like behavior in S = 1/2 quasikagome lattice CeRh1-xPdxSn investigated using muon spin relaxation and neutron scattering

We present the results of muon spin relaxation ($μ$SR) and neutron scattering on the Ce-based quasikagome lattice CeRh$_{1-x}$Pd$_{x}$Sn ($x=0.1$ to 0.75). Our ZF-$μ$SR results reveal the absence of static long-range magnetic order down to 0.05~K in $x = 0.1$ single crystals. The weak temperature-dependent plateaus of the dynamic spin fluctuations below 0.2~K in ZF-$μ$SR together with its longitudinal-field (LF) dependence between 0 and 3~kG indicate the presence of dynamic spin fluctuations persisting even at $T$ = 0.05~K without static magnetic order. On the other hand, $C_{\text{4f}}$/$T$ increases as --log $T$ on cooling below 0.9~K, passes through a broad maximum at 0.13~K and slightly decreases on further cooling. The ac-susceptibility also exhibits a frequency independent broad peak at 0.16~K, which is prominent with an applied field $H$ along $c$-direction. We, therefore, argue that such a behavior for $x=0.1$ (namely, a plateau in spin relaxation rate ($λ$) below 0.2~K and a linear $T$ dependence in $C_{\text{4f}}$ below 0.13~K) can be attributed to a metallic spin-liquid (SL) ground state near the quantum critical point in the frustrated Kondo lattice. The LF-$μ$SR study suggests that the out of kagome plane spin fluctuations are responsible for the SL behavior. Low energy inelastic neutron scattering (INS) of $x$ = 0.1 reveals gapless magnetic excitations, which are also supported by the behavior of $C_{\text{4f}}$ proportional to $T^{1.1}$ down to 0.06~K.

cond-mat.str-el

Crystal Electic Field and Possible Coupling with Phonon in Kondo lattice CeCuGa3

We investigate the magnetic and crystal electric field (CEF) states of the Kondo lattice system CeCuGa3 by muon spin relaxation (muSR), neutron diffraction, and inelastic neutron scattering (INS) measurements. A noncentrosymmetric BaNiSn3-type tetragonal crystal structure (space group I4mm) is inferred from x-ray as well as from neutron powder diffraction. The low-temperature magnetic susceptibility and heat capacity data show an anomaly near 2.3 - 2.5~K associated with long range magnetic ordering, which is further confirmed by muSR and neutron diffraction data. The neutron powder diffraction collected at 1.7 K shows the presence of magnetic Bragg peaks indexed by an incommensurate magnetic propagation vector k = (0.148, 0.148, 0) and the magnetic structure is best described by a longitudinal spin density wave with ordered moments lying in ab-plane. An analysis of the INS data based on a CEF model reveals the presence of two magnetic excitations near 4.5 meV and 6.9 meV. The magnetic heat capacity data suggest an overall CEF splitting of 20.7 meV, however the excitation between 20 and 30 meV is very broad and weak in our INS data, but could provide an evidence of CEF level in this energy range in agreement with the magnetic entropy. Our analysis of INS data based on the CEF-phonon model indicates that the two excitations at 4.5 meV and 6.9 meV have their origin in CEF-phonon coupling (i.e. splitting of one CEF peak into two peaks, called vibron), with an overall splitting of 28.16 meV, similar to the case of CeCuAl3 and CeAuAl3.

cond-mat.str-el

Rastall gravity extension of the standard $Λ$CDM model: theoretical features and observational constraints

We present a detailed investigation of the Rastall gravity extension of the standard $Λ$CDM model. We review the model for two simultaneous modifications of different nature in the Friedmann equation due to the Rastall gravity: the new contributions of the material (actual) sources (considered as effective source) and the altered evolution of the material sources. We discuss the role/behavior of these modifications with regard to some low redshift tensions, including the so-called $H_0$ tension, prevailing within the standard $Λ$CDM. We constrain the model at the level of linear perturbations, and obtain the first constraints through a robust and accurate analysis using the latest full Planck CMB data, with and without including BAO data. We find that the Rastall parameter $ε$ (null for general relativity) is consistent with zero at 68\% CL (with a tendency towards positive values, $-0.0001 < ε< 0.0007$ (CMB+BAO) at 68\% CL), which in turn implies no significant statistical evidence for deviation from general relativity, and also a precision of $\mathcal{O}(10^{-4})$ for the coefficient $-1/2$ of the term $g_{μν}R$ in the Einstein field equations of general relativity (guaranteeing the local energy-momentum conservation). We explore the consequences led by the Rastall gravity on the cosmological parameters in the light of the observational analyses. It turns out that the effective source dynamically screens the usual vacuum energy at high redshifts, but this mechanism barely works due to the opposition by the altered evolution of CDM. Consequently, two simultaneous modifications of different nature in the Friedmann equation act against each other, and do not help to considerably relax the so-called low redshift tensions. Our results may offer a guide for the research community that studies the Rastall gravity in various aspects of gravitation and cosmology.

astro-ph.CO

Investigation of the magnetic ground state of the ordered double perovskite Sr2YbRuO6: a tale of two transitions

Comprehensive muon spin rotation/relaxation (muSR) and neutron powder diffraction (NPD) studies supported via bulk measurements have been performed on the ordered double perovskite Sr2YbRuO6 to investigate the nature of the magnetic ground state. Two sharp transitions at TN1 ~ 42 K and TN2 ~ 36 K have been observed in the static and dynamic magnetization measurements, coinciding with the heat capacity data. In order to confirm the origin of the observed phase transitions and the magnetic ground state, microscopic evidences are presented here. An initial indication of long-range magnetic ordering comes from a sharp drop in the muon initial asymmetry and a peak in the relaxation rate near TN1. NPD confirms that the magnetic ground state of Sr2YbRuO6 consists of an antiferromagnetic (AFM) structure with interpenetrating lattices of parallel Yb3+ and Ru5+ moments lying in the ab-plane and adopting a A-type AFM structure. Intriguingly, a small but remarkable change is observed in the long-range ordering parameters at TN2 confirming the presence of a weak spin reorientation (i.e. change in spin configuration) transition of Ru and Yb moments, as well as a change in the magnetic moment evolution of the Yb3+ spins at TN2. The temperature dependent behaviour of the Yb3+ and Ru5+ moments suggests that the 4d-electrons of Ru5+ play a dominating role in stabilizing the long range ordered magnetic ground state in the double perovskite Sr2YbRuO6 whereas only the Yb3+ moments show an arrest at TN2. The observed magnetic structure and the presence of a ferromagnetic interaction between Ru- and Yb- ions are explained with use of the Goodenough-Kanamori-Anderson (GKA) rules. Possible reasons for the presence of the second magnetic phase transition and of a compensation point in the magnetization data are linked to competing mechanisms of magnetic anisotropy.

cond-mat.str-el

Suppression of long-range ordering and multiferroicity in Sr-substituted Ba3-xSrxMnNb2O9 (x = 1 and 3)

Effects of Sr substitution at A-site in ordered perovskite Ba3-xSrxMnNb2O9 (x = 1 and 3) have been investigated using X-ray diffraction, magnetization, dielectric/magnetodielectric and neutron diffraction measurements. The parent compound Ba3MnNb2O9 having a large spin (S=5/2) is known to exhibit type-II multiferroic properties with quasi 2D triangular lattice antiferromagnetic ground state. A slight perturbation in exchange interaction due to substitution of smaller size isovalent ion at the A-site in Ba3-xSrxMnNb2O9 (x = 1 and 3) has been found to alter the ground states drastically and hence the multiferroicity. The crucial role of various fluctuations (quantum and/or thermal), weak lattice distortion induced by Sr-substitution and slight imbalance between different fluctuations in determining the ground states and the multiferroicity is discussed and compared with the results of smaller spin compounds (S = 1/2 or 1).

cond-mat.str-el

Strain-induced tuning of optical properties of layered Mo$S_2$

The sensitive correlation between optical parameters and strain in Mo$S_2$ results in a totally different approach to tune the optical properties. Usually, an external source of strain is employed to monitor the optical and vibrational properties of a material. It is always challenging to have a precise control over the strain and its consequences on material properties. Here, we report the presence of a compressive strain in Mo$S_2$ crystalline powder and nanosheets obtained via the process of ball-milling and probe sonication. The diffraction peaks in the X-ray diffraction pattern shift to higher 2$θ$ value implying a compressive strain that increases with the processing time. The absorption spectra, photoluminescence and Raman modes are blue-shifted w.r.t the bulk unprocessed sample. The observed blue-shift is attributed to the presence of compressive strain in the samples. Whereas in thin nano-sheets of Mo$S_2$, it is very likely that both quantum confinement as well as strain result in the observed blue-shift. These results indicate that by optimizing the processing conditions and/or time, a strain of desired amount and hence tunable shift in optical properties of material can be achieved.

cond-mat.mes-hall