arXiv subjects

Shotaro Sakai

Publications and source records attributed to Shotaro Sakai.

4 recordsLinked to original sources

arXiv2026

Oxygen isotope fractionation in the Martian atmosphere induced by CO$_2$ photolysis and O$_3$ formation

The enrichment of heavy isotopes of volatile elements in the Martian atmosphere indicates that Mars lost a large portion of its atmosphere through escape to space. Recent atmospheric measurements by ExoMars Trace Gas Orbiter (TGO) have suggested that the vertical profiles of oxygen isotopic compositions are influenced by chemical reactions involving isotopic fractionation. However, their quantitative impacts have not yet been fully evaluated. In this study, we develop a 1D photochemical model that incorporates oxygen isotopic fractionation associated with CO$_2$ photolysis and O$_3$ formation to investigate the vertical profiles of oxygen isotopic compositions. Our calculations show that CO is depleted in heavy oxygen isotopes relative to CO$_2$, reaching $δ^{18}$O $\sim -25$ per mil and $δ^{17}$O $\sim -15$ per mil, primarily due to isotopic fractionation during CO$_2$ photolysis. The vertical profiles of oxygen and carbon isotopic compositions are in good agreement between our model and the TGO measurements. O$_3$ is strongly enriched in $^{18}$O and $^{17}$O, reaching $δ^{18}$O $\sim 100$ per mil and $δ^{17}$O $\sim 50$ per mil as a consequence of the isotopic fractionation during its formation, whereas atomic oxygen is highly depleted in the heavy oxygen isotopes with $δ^{18}$O $\lesssim -100$ per mil and $δ^{17}$O $\lesssim -50$ per mil so as to compensate for their enrichment in O$_3$. These chemical fractionation processes can deplete the heavy oxygen isotopes in species that escape from the upper atmosphere, and thereby enhance the isotopic fractionation associated with oxygen escape to space. Such fractionated isotopic compositions of escaping oxygen may be detectable by the Martian Moons eXploration (MMX) mission.

astro-ph.EP↗

arXiv2026

Atmospheric Escape Rates from Mars - If it Orbited an Old M-Dwarf Star

Atmospheric escape is an important process that influences the evolution of planetary atmospheres. A variety of physical mechanisms can contribute to escape from an atmosphere, including thermal escape, ion escape, photochemical escape, and sputtering. Here we estimate escape rates via each of these processes for a hypothetical Mars-like exoplanet orbiting Barnard's star (an old, inactive M dwarf star). We place the planet at an orbital distance that receives the same total stellar flux as it does in our solar system. We use the measured stellar extreme ultraviolet (EUV) spectrum and assumptions on the star's magnetic field to determine both the high-energy radiation and the stellar wind environment around the planet. This information is used to model the response of the planet's thermosphere, exosphere and magnetosphere using a variety of models that have been validated against solar system observations. We find overall escape rates that are dominated by thermal processes and elevated by 2-5 orders of magnitude relative to present-day Mars, suggesting that a Mars-like planet orbiting Barnard's star would not retain a significant atmosphere for more than 10's of millions of years. Recently reported planets around Barnard's star should also not have retained significant atmospheres. By extension, Mars-like planets orbiting any M dwarf near the 'Habitable Zone' should not retain atmospheres for extended periods of time.

astro-ph.EP↗

arXiv2023

Strong depletion of $^{13}$C in CO induced by photolysis of CO$_{2}$ in the Martian atmosphere calculated by a photochemical model

The isotopic signature of atmospheric carbon offers a unique tracer for the history of the Martian atmosphere and the origin of organic matter on Mars. Photolysis of CO$_{2}$ is known to induce strong isotopic fractionation of carbon between CO$_{2}$ and CO. However, its effect on the carbon isotopic compositions in the Martian atmosphere remains uncertain. Here we develop a 1-D photochemical model considering isotopic fractionation via photolysis of CO$_{2}$ to estimate the vertical profiles of the carbon isotopic compositions of CO and CO$_{2}$ in the Martian atmosphere. We find that CO is depleted in $^{13}$C compared with CO$_{2}$ at each altitude due to the fractionation via CO$_{2}$ photolysis: the minimum value of $δ^{13}$C in CO is about $-170$ per mil under the standard eddy diffusion setting. This result supports the hypothesis that fractionated atmospheric CO is responsible for the production of the $^{13}$C-depleted organic carbon in Martian sediments detected by Curiosity Rover through the conversion of CO into organic materials and their deposition on the surface. The photolysis and transport-induced fractionation of CO we report here leads to a $\sim 15$ % decrease in the amount of inferred atmospheric loss when combined with the present-day fractionation of the atmosphere and previous studies of carbon escape to space. The fractionated isotopic composition of CO in the Martian atmosphere may be observed by ExoMars Trace Gas Orbiter (TGO) and ground-based telescopes, and escaping ion species produced by the fractionated carbon-bearing species may be detected by Martian Moons eXploration (MMX) in the future.

astro-ph.EP↗

arXiv2023

Photochemical and RadiatiOn Transport model for Extensive USe (PROTEUS)

We introduce a new flexible one-dimensional photochemical model named Photochemical and RadiatiOn Transport model for Extensive USe (PROTEUS), which consists of a Python graphical user interface (GUI) program and Fortran 90 modules. PROTEUS is designed for adaptability to many planetary atmospheres, for flexibility to deal with thousands of or more chemical reactions with high efficiency, and for intuitive operation with GUI. Chemical reactions can be easily implemented into the Python GUI program in a simple string format, and users can intuitively select a planet and chemical reactions on GUI. Chemical reactions selected on GUI are automatically analyzed by string parsing functions in the Python GUI program, then applied to the Fortran 90 modules to simulate with the selected chemical reactions on a selected planet. PROTEUS can significantly save the time for those who need to develop a new photochemical model; users just need to write chemical reactions in the Python GUI program and just select them on GUI to run a new photochemical model.

astro-ph.IM↗