arXiv subjects

Shreyas Vissapragada

Publications and source records attributed to Shreyas Vissapragada.

54 records · Page 3Linked to original sources

arXiv2022

The Upper Edge of the Neptune Desert Is Stable Against Photoevaporation

Transit surveys indicate that there is a deficit of Neptune-sized planets on close-in orbits. If this ``Neptune desert' is entirely cleared out by atmospheric mass loss, then planets at its upper edge should only be marginally stable against photoevaporation, exhibiting strong outflow signatures in tracers like the metastable helium triplet. We test this hypothesis by carrying out a 12-night photometric survey of the metastable helium feature with Palomar/WIRC, targeting seven gas-giant planets orbiting K-type host stars. Eight nights of data are analyzed here for the first time along with reanalyses of four previously-published datasets. We strongly detect helium absorption signals for WASP-69b, HAT-P-18b, and HAT-P-26b; tentatively detect signals for WASP-52b and NGTS-5b; and do not detect signals for WASP-177b and WASP-80b. We interpret these measured excess absorption signals using grids of Parker wind models to derive mass-loss rates, which are in good agreement with predictions from the hydrodynamical outflow code ATES for all planets except WASP-52b and WASP-80b, where our data suggest that the outflows are much smaller than predicted. Excluding these two planets, the outflows for the rest of the sample are consistent with a mean energy-limited outflow efficiency of $\varepsilon = 0.41^{+0.16}_{-0.13}$. Even when we make the relatively conservative assumption that gas-giant planets experience energy-limited outflows at this efficiency for their entire lives, photoevaporation would still be too inefficient to carve the upper boundary of the Neptune desert. We conclude that this feature of the exoplanet population is a pristine tracer of giant planet formation and migration mechanisms.

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arXiv2022

Non-detection of He I in the atmosphere of GJ1214b with Keck/NIRSPEC, at a time of minimal telluric contamination

Observations of helium in exoplanet atmospheres may reveal the presence of large gaseous envelopes, and indicate ongoing atmospheric escape. Orell-Miquel et al. (2022) used CARMENES to measure a tentative detection of helium for the sub-Neptune GJ 1214b, with a peak excess absorption reaching over 2% in transit depth at 10830 Angstroms. However, several non-detections of helium had previously been reported for GJ 1214b. One explanation for the discrepancy was contamination of the planetary signal by overlapping telluric absorption- and emission lines. We used Keck/NIRSPEC to observe another transit of GJ 1214b at 10830 Angstroms, at a time of minimal contamination by telluric lines, and did not observe planetary helium absorption. Accounting for correlated noise in our measurement, we place an upper limit on the excess absorption size of 1.22% (95% confidence). We find that the discrepancy between the CARMENES and NIRSPEC observations is unlikely to be caused by using different instruments or stellar activity. It is currently unclear whether the difference is due to correlated noise in the observations, or variability in the planetary atmosphere.

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arXiv2022

Constraining the Densities of the Three Kepler-289 Planets with Transit Timing Variations

Kepler-289 is a three-planet system containing two sub-Neptunes and one cool giant planet orbiting a young, Sun-like star. All three planets exhibit transit timing variations (TTVs), with both adjacent planet pairs having orbital periods close to the 2:1 orbital resonance. We observe two transits of Kepler-289c with the Wide-field InfraRed Camera (WIRC) on the 200" Hale Telescope at Palomar Observatory, using diffuser-assisted photometry to achieve space-like photometric precision from the ground. These new transit observations extend the original four-year Kepler TTV baseline by an additional 7.5 years. We re-reduce the archival Kepler data with an improved stellar activity correction and carry out a joint fit with the Palomar data to constrain the transit shapes and derive updated transit times. We then model the TTVs to determine the masses of the three planets and constrain their densities and bulk compositions. Our new analysis improves on previous mass and density constraints by a factor of two or more for all three planets, with the innermost planet showing the largest improvement. Our updated atmospheric mass fractions for the inner two planets indicate that they likely have hydrogen-rich envelopes, consistent with their location on the upper side of the radius valley. We also constrain the heavy element composition of the outer saturn-mass planet, Kepler-289c, for the first time, finding that it contains 30.5 $\pm$ 6.9 $M_{\oplus}$ of metals. We use dust evolution models to show that Kepler-289c must have formed beyond 1~au, and likely beyond 3~au, and then migrated inward.

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arXiv2022

Dust Evolution in the Coma of Distant, Inbound Comet C/2017 K2 (PANSTARRS)

C/2017 K2 (PANSTARRS) is an Oort cloud comet previously observed to be active at heliocentric distances r>20 au on what is likely its first passage through the inner solar system. We observed the comet on 2021 March 19-20 at r=6.82 au pre-perihelion and 8.35 deg phase angle with the Hubble Space Telescope (HST), and obtained high spatial resolution photometry and polarimetry mapping the properties of dust over the coma prior to the onset of water ice sublimation activity on the nucleus. We found clear radial gradients in the color and polarization of the coma: the F475W-F775W (g'-i') reflectance slope increased from ~4.5% per 100 nm within ~10,000 km of the nucleus up to ~7% per 100 nm by ~50,000 km, while the negative polarization in F775W (i') strengthened from about -2% to -3.5% over the same range. The radial intensity profiles moreover strongly deviate from profiles simulated for stable dust grains. Near-infrared imagery obtained with the Palomar Hale Telescope on 2021 May 18 at r=6.34 au revealed a continued absence of micron-sized grains in the tail, but showed no clear spatial gradient in JHKs colors. The observed patterns collectively appear consistent with the inner coma being optically dominated by sublimating, micron-sized water ice grains, unlike the tail of more stable, millimeter-sized grains. Finally, we evaluated these results alongside other Oort cloud comets, and found in a reanalysis of HST observations of C/2012 S1 (ISON) that the near-nucleus polarimetric halo reported for that comet is likely an observational artifact.

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arXiv2022

TESS Revisits WASP-12: Updated Orbital Decay Rate and Constraints on Atmospheric Variability

After observing WASP-12 in the second year of the primary mission, the Transiting Exoplanet Survey Satellite (TESS) revisited the system in late 2021 during its extended mission. In this paper, we incorporate the new TESS photometry into a reanalysis of the transits, secondary eclipses, and phase curve. We also present a new $K_s$-band occultation observation of WASP-12b obtained with the Palomar/Wide-field Infrared Camera instrument. The latest TESS photometry spans three consecutive months, quadrupling the total length of the TESS WASP-12 light curve and extending the overall time baseline by almost two years. Based on the full set of available transit and occultation timings, we find that the orbital period is shrinking at a rate of $-29.81 \pm 0.94$ ms yr$^{-1}$. The additional data also increase the measurement precision of the transit depth, orbital parameters, and phase-curve amplitudes. We obtain a secondary eclipse depth of $466 \pm 35$ ppm, a $2σ$ upper limit on the nightside brightness of 70 ppm, and a marginal $6\overset{\circ}{.}2 \pm 2\overset{\circ}{.}8$ eastward offset between the dayside hotspot and the substellar point. The voluminous TESS dataset allows us to assess the level of atmospheric variability on timescales of days, months, and years. We do not detect any statistically significant modulations in the secondary eclipse depth or day-night brightness contrast. Likewise, our measured $K_s$-band occultation depth of $2810 \pm 390$ ppm is consistent with most $\sim$2.2 $μ$m observations in the literature.

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arXiv2022

The Maximum Mass-Loss Efficiency for a Photoionization-Driven Isothermal Parker Wind

Observations of present-day mass-loss rates for close-in transiting exoplanets provide a crucial check on models of planetary evolution. One common approach is to model the planetary absorption signal during the transit in lines like He I 10830 with an isothermal Parker wind, but this leads to a degeneracy between the assumed outflow temperature $T_0$ and the mass-loss rate $\dot{M}$ that can span orders of magnitude in $\dot{M}$. In this study, we re-examine the isothermal Parker wind model using an energy-limited framework. We show that in cases where photoionization is the only heat source, there is a physical upper limit to the efficiency parameter $\varepsilon$ corresponding to the maximal amount of heating. This allows us to rule out a subset of winds with high temperatures and large mass-loss rates as they do not generate enough heat to remain self-consistent. To demonstrate the utility of this framework, we consider spectrally unresolved metastable helium observations of HAT-P-11b, WASP-69b, and HAT-P-18b. For the former two planets, we find that only relatively weak ($\dot{M}\lesssim 10^{11.5}$ g s$^{-1}$) outflows can match the metastable helium observations while remaining energetically self-consistent, while for HAT-P-18b all of the Parker wind models matching the helium data are self-consistent. Our results are in good agreement with more detailed self-consistent simulations and constraints from high-resolution transit spectra.

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arXiv2021

p-winds: an open-source Python code to model planetary outflows and upper atmospheres

Atmospheric escape is considered to be one of the main channels for evolution in sub-Jovian planets, particularly in their early lives. While there are several hypotheses proposed to explain escape in exoplanets, testing them with atmospheric observations remains a challenge. In this context, high-resolution transmission spectroscopy of transiting exoplanets for the metastable helium triplet (He 2$^3$S) at $1\,083$ nm has emerged as a reliable technique to observe and measure escape. To aid in the prediction and interpretation of metastable He transmission spectroscopy observations, we developed the code p-winds. This is an open-source, fully documented, scalable Python implementation of the one-dimensional, purely H+He Parker wind model for upper atmospheres coupled with ionization balance, ray-tracing, and radiative transfer routines. We demonstrate an atmospheric retrieval by fitting p-winds models to the observed metastable He transmission spectrum of the warm Neptune HAT-P-11 b, and take into account the variation of the in-transit absorption caused by transit geometry. For this planet, our best fit yields a total atmospheric escape rate of approximately $2.5 \times 10^{10}$ g s$^{-1}$ and wind temperature of $7200$ K. The range of retrieved mass loss rates increases significantly when we let the H atom fraction be a free parameter, but the posterior distribution of the latter remains unconstrained by He observations alone. The stellar host limb darkening does not have a significant impact in the retrieved escape rate or outflow temperature for HAT-P-11 b. Based on the non-detection of escaping He for GJ 436 b, we are able to rule out total escape rates higher than $3.4 \times 10^{10}$ g s$^{-1}$ at 99.7% (3$σ$) confidence.

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arXiv2021

TOI-2109b: An Ultrahot Gas Giant on a 16 hr Orbit

We report the discovery of an ultrahot Jupiter with an extremely short orbital period of $0.67247414\,\pm\,0.00000028$ days ($\sim$16 hr). The $1.347 \pm 0.047$ $R_{\rm Jup}$ planet, initially identified by the Transiting Exoplanet Survey Satellite (TESS) mission, orbits TOI-2109 (TIC 392476080): a $T_{\rm eff} \sim 6500$ K F-type star with a mass of $1.447 \pm 0.077$ $M_{\rm Sun}$, a radius of $1.698 \pm 0.060$ $R_{\rm Sun}$, and a rotational velocity of $v\sin i_* = 81.9 \pm 1.7$ km s$^{-1}$. The planetary nature of TOI-2109b was confirmed through radial velocity measurements, which yielded a planet mass of $5.02 \pm 0.75$ $M_{\rm Jup}$. Analysis of the Doppler shadow in spectroscopic transit observations indicates a well-aligned system, with a sky-projected obliquity of $λ= 1\overset{\circ}{.}7 \pm 1\overset{\circ}{.}7$. From the TESS full-orbit light curve, we measured a secondary eclipse depth of $731 \pm 46$ ppm, as well as phase-curve variations from the planet's longitudinal brightness modulation and ellipsoidal distortion of the host star. Combining the TESS-band occultation measurement with a $K_s$-band secondary eclipse depth ($2012 \pm 80$ ppm) derived from ground-based observations, we find that the dayside emission of TOI-2109b is consistent with a brightness temperature of $3631 \pm 69$ K, making it the second hottest exoplanet hitherto discovered. By virtue of its extreme irradiation and strong planet-star gravitational interaction, TOI-2109b is an exceptionally promising target for intensive follow-up studies using current and near-future telescope facilities to probe for orbital decay, detect tidally driven atmospheric escape, and assess the impacts of H$_2$ dissociation and recombination on the global heat transport.

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arXiv2021

A Search for Planetary Metastable Helium Absorption in the V1298 Tau System

Early in their lives, planets endure extreme amounts of ionizing radiation from their host stars. For planets with primordial hydrogen and helium-rich envelopes, this can lead to substantial mass loss. Direct observations of atmospheric escape in young planetary systems can help elucidate this critical stage of planetary evolution. In this work, we search for metastable helium absorption---a tracer of tenuous gas in escaping atmospheres---during transits of three planets orbiting the young solar analogue V1298 Tau. We characterize the stellar helium line using HET/HPF, and find that it evolves substantially on timescales of days to months. The line is stable on hour-long timescales except for one set of spectra taken during the decay phase of a stellar flare, where absoprtion increased with time. Utilizing a beam-shaping diffuser and a narrowband filter centered on the helium feature, we observe four transits with Palomar/WIRC: two partial transits of planet d ($P = 12.4$ days), one partial transit of planet b ($P = 24.1$ days), and one full transit of planet c ($P = 8.2$ days). We do not detect the transit of planet c, and we find no evidence of excess absorption for planet b, with $ΔR_\mathrm{b}/R_\star<0.019$ in our bandpass. We find a tentative absorption signal for planet d with $ΔR_\mathrm{d}/R_\star = 0.0205\pm0.054$, but the best-fit model requires a substantial (-100$\pm$14 min) transit-timing offset on a two-month timescale. Nevertheless, our data suggest that V1298 Tau d may have a high present-day mass-loss rate, making it a priority target for follow-up observations.

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arXiv2021

Preview of Comet C/2021 A1 (Leonard) and Its Encounter with Venus

Long period comet C/2021 A1 (Leonard) will approach Venus to within 0.029 au on 2021 December 18 and may subsequently graze the planet with its dust trail less than two days later. We observed C/2021 A1 with the Lowell Discovery Telescope on 2021 January 13 and March 3, as well as with the Palomar Hale Telescope on 2021 March 20, while the comet was inbound at heliocentric distances of r=4.97 au, 4.46 au, and 4.28 au, respectively. Tail morphology suggests that the dust is optically dominated by ~0.1-1 mm radius grains produced in the prior year. Neither narrowband imaging photometry nor spectrophotometry reveal any definitive gas emission, placing 3-sigma upper bounds on CN production of <1e23 molec/s at both of the latter two epochs. Trajectory analysis indicates that large (>1 mm) grains ejected at extremely large heliocentric distances (r>30 au) are most strongly favored to reach Venus. The flux of such meteors on Venus, and thus their potential direct or indirect observability, is highly uncertain as the comet's dust production history is poorly constrained at these distances, but will likely fall well below the meteor flux from comet C/2013 A1 (Siding Spring)'s closer encounter to Mars in 2014, and thus poses negligible risk to any spacecraft in orbit around Venus. Dust produced in previous apparitions will not likely contribute substantially to the meteor flux, nor will dust from any future activity apart from an unlikely high speed (>0.5 km/s) dust outburst prior to the comet reaching r~2 au in 2021 September.

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arXiv2021

Metastable Helium Reveals an Extended Atmosphere for the Gas Giant HAT-P-18b

The metastable helium line at 1083 nm can be used to probe the extended upper atmospheres of close-in exoplanets and thus provide insight into their atmospheric mass loss, which is likely to be significant in sculpting their population. We used an ultranarrowband filter centered on this line to observe two transits of the low-density gas giant HAT-P-18b, using the 200" Hale Telescope at Palomar Observatory, and report the detection of its extended upper atmosphere. We constrain the excess absorption to be $0.46\pm0.12\%$ in our 0.635 nm bandpass, exceeding the transit depth from the Transiting Exoplanet Survey Satellite (TESS) by $3.9σ$. If we fit this signal with a 1D Parker wind model, we find that it corresponds to an atmospheric mass loss rate between $8.3^{+2.8}_{-1.9} \times 10^{-5}$ $M_\mathrm{J}$/Gyr and $2.63^{+0.46}_{-0.64} \times 10^{-3}$ $M_\mathrm{J}$/Gyr for thermosphere temperatures ranging from 4000 K to 13000 K, respectively. With a J magnitude of 10.8, this is the faintest system for which such a measurement has been made to date, demonstrating the effectiveness of this approach for surveying mass loss on a diverse sample of close-in gas giant planets.

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arXiv2020

Constraints on Metastable Helium in the Atmospheres of WASP-69b and WASP-52b with Ultra-Narrowband Photometry

Infrared observations of metastable 2$^3$S helium absorption with ground- and space-based spectroscopy are rapidly maturing, as this species is a unique probe of exoplanet atmospheres. Specifically, the transit depth in the triplet feature (with vacuum wavelengths near 1083.3 nm) can be used to constrain the temperature and mass loss rate of an exoplanet's upper atmosphere. Here, we present a new photometric technique to measure metastable 2$^3$S helium absorption using an ultra-narrowband filter (full-width at half-maximum of 0.635 nm) coupled to a beam-shaping diffuser installed in the Wide-field Infrared Camera (WIRC) on the 200-inch Hale Telescope at Palomar Observatory. We use telluric OH lines and a helium arc lamp to characterize refractive effects through the filter and to confirm our understanding of the filter transmission profile. We benchmark our new technique by observing a transit of WASP-69b and detect an excess absorption of $0.498\pm0.045$% (11.1$σ$), consistent with previous measurements after considering our bandpass. Then, we use this method to study the inflated gas giant WASP-52b and place a 95th-percentile upper limit on excess absorption in our helium bandpass of 0.47%. Using an atmospheric escape model, we constrain the mass loss rate for WASP-69b to be $5.25^{+0.65}_{-0.46}\times10^{-4}~M_\mathrm{J}/\mathrm{Gyr}$ ($3.32^{+0.67}_{-0.56}\times10^{-3}~M_\mathrm{J}/\mathrm{Gyr}$) at 7,000 K (12,000 K). Additionally, we set an upper limit on the mass loss rate of WASP-52b at these temperatures of $2.1\times10^{-4}~M_\mathrm{J}/\mathrm{Gyr}$ ($2.1\times10^{-3}~M_\mathrm{J}/\mathrm{Gyr}$). These results show that ultra-narrowband photometry can reliably quantify absorption in the metastable helium feature.

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arXiv2020

Exploring Whether Super-Puffs Can Be Explained as Ringed Exoplanets

An intriguing, growing class of planets are the "super-puffs," objects with exceptionally large radii for their masses and thus correspondingly low densities ($\lesssim0.3\rm\,g\,cm^{-3}$). Here we consider whether they could have large inferred radii because they are in fact ringed. This would naturally explain why super-puffs have thus far only shown featureless transit spectra. We find that this hypothesis can work in some cases but not all. The close proximity of the super-puffs to their parent stars necessitates rings with a rocky rather than icy composition. This limits the radius of the rings, and makes it challenging to explain the large size of Kepler 51b, 51c, 51d, and 79d unless the rings are composed of porous material. Furthermore, the short tidal locking timescales for Kepler 18d, 223d, and 223e mean that these planets may be spinning too slowly, resulting in a small oblateness and rings that are warped by their parent star. Kepler 87c and 177c have the best chance of being explained by rings. Using transit simulations, we show that testing this hypothesis requires photometry with a precision of somewhere between ~10 ppm and ~50 ppm, which roughly scales with the ratio of the planet and star's radii. We conclude with a note about the recently discovered super-puff HIP 41378f.

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arXiv2020

Diffuser-Assisted Infrared Transit Photometry for Four Dynamically Interacting \textit{Kepler} Systems

We present ground-based infrared transit observations for four dynamically interacting \textit{Kepler} planets, including Kepler-29b, Kepler-36c, KOI-1783.01, and Kepler-177c, obtained using the Wide-field Infrared Camera on the Hale 200" telescope at Palomar Observatory. By utilizing an engineered diffuser and custom guiding software, we mitigate time-correlated telluric and instrumental noise sources in these observations. We achieve an infrared photometric precision comparable to or better than that of space-based observatories such as the \textit{Spitzer Space Telescope}, and detect transits with greater than 3$σ$ significance for all planets. For Kepler-177c ($J=13.9$) our measurement uncertainties are only $1.2\times$ the photon noise limit and 1.9 times better than the predicted photometric precision for \textit{Spitzer} IRAC photometry of this same target. We find that a single transit observation obtained $4-5$ years after the end of the original \textit{Kepler} mission can reduce dynamical mass uncertainties by as much as a factor of three for these systems. Additionally, we combine our new observations of KOI-1783.01 with information from the literature to confirm the planetary nature of this system. We discuss the implications of our new mass and radius constraints in the context of known exoplanets with low incident fluxes, and we note that Kepler-177c may be a more massive analog to the currently known super-puffs given its core mass (3.8$\pm0.9M_\Earth$) and large gas-to-core ratio (2.8$\pm0.7$). Our demonstrated infrared photometric performance opens up new avenues for ground-based observations of transiting exoplanets previously thought to be restricted to space-based investigation.

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arXiv2019

The Orbit of WASP-12b is Decaying

WASP-12b is a transiting hot Jupiter on a 1.09-day orbit around a late-F star. Since the planet's discovery in 2008, the time interval between transits has been decreasing by $29\pm 2$ msec year$^{-1}$. This is a possible sign of orbital decay, although the previously available data left open the possibility that the planet's orbit is slightly eccentric and is undergoing apsidal precession. Here, we present new transit and occultation observations that provide more decisive evidence for orbital decay, which is favored over apsidal precession by a $Δ\mathrm{BIC}$ of 22.3 or Bayes factor of 70,000. We also present new radial-velocity data that rule out the Rømer effect as the cause of the period change. This makes WASP-12 the first planetary system for which we can be confident that the orbit is decaying. The decay timescale for the orbit is $P/\dot{P} = 3.25\pm 0.23$ Myr. Interpreting the decay as the result of tidal dissipation, the modified stellar tidal quality factor is $Q'_\star = 1.8 \times10^{5}$.

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arXiv2019

WIRC+Pol: a low-resolution near-infrared spectropolarimeter

WIRC+Pol is a newly commissioned low-resolution (R~100), near-infrared (J and H band) spectropolarimetry mode of the Wide-field InfraRed Camera (WIRC) on the 200-inch Hale Telescope at Palomar Observatory. The instrument utilizes a novel polarimeter design based on a quarter-wave plate and a polarization grating (PG), which provides full linear polarization measurements (Stokes I, Q, and U) in one exposure. The PG also has high transmission across the J and H bands. The instrument is situated at the prime focus of an equatorially mounted telescope. As a result, the system only has one reflection in the light path, providing minimal telescope induced polarization. A data reduction pipeline has been developed for WIRC+Pol to produce linear polarization measurements from observations. WIRC+Pol has been on-sky since February 2017. Results from the first year commissioning data show that the instrument has a high dispersion efficiency as expected from the polarization grating. We demonstrate the polarimetric stability of the instrument with RMS variation at 0.2% level over 30 minutes for a bright standard star (J = 8.7). While the spectral extraction is photon noise limited, polarization calibration between sources remain limited by systematics, likely related to gravity dependent pointing effects. We discuss instrumental systematics we have uncovered in the data, their potential causes, along with calibrations that are necessary to eliminate them. We describe a modulator upgrade that will eliminate the slowly varying systematics and provide polarimetric accuracy better than 0.1%.

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arXiv2017

Methanol formation in TW Hya and future prospects for detecting larger complex molecules in disks with ALMA

Gas-phase methanol was recently detected in a protoplanetary disk for the first time with ALMA. The peak abundance and distribution of methanol observed in TW Hya differed from that predicted by chemical models. Here, the chemistry of methanol gas and ice is calculated using a physical model tailored for TW Hya with the aim to contrast the results with the recent detection in this source. New pathways for the formation of larger complex molecules (e.g., ethylene glycol) are included in an updated chemical model, as well as the fragmentation of methanol ice upon photodesorption. It is found that including fragmentation upon photodesorption improves the agreement between the peak abundance reached in the chemical models with that observed in TW Hya ($\sim 10^{-11}$ with respect to \ce{H2}); however, the model predicts that the peak in emission resides a factor of $2-3$ farther out in the disk than the ALMA images. Reasons for the persistent differences in the gas-phase methanol distribution between models and the observations of TW Hya are discussed. These include the location of the ice reservoir which may coincide with the compact mm-dust disk ($\lesssim 60$~au) and sources of gas-phase methanol which have not yet been considered in models. The possibility of detecting larger molecules with ALMA is also explored. Calculations of the rotational spectra of complex molecules other than methanol using a parametric model constrained by the TW Hya observations suggest that the detection of individual emission lines of complex molecules with ALMA remains challenging. However, the signal-to-noise ratio can be enhanced via stacking of multiple transitions which have similar upper energy levels.

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arXiv2017

On the Energetics of the HCO$^+$ + C $\to$ CH$^+$ + CO Reaction and Some Astrochemical Implications

We explore the energetics of the titular reaction, which current astrochemical databases consider open at typical dense molecular (i.e., dark) cloud conditions. As is common for reactions involving the transfer of light particles, we assume that there are no intersystem crossings of the potential energy surfaces involved. In the absence of any such crossings, we find that this reaction is endoergic and will be suppressed at dark cloud temperatures. Updating accordingly a generic astrochemical model for dark clouds changes the predicted gas-phase abundances of 224 species by greater than a factor of 2. Of these species, 43 have been observed in the interstellar medium. Our findings demonstrate the astrochemical importance of determining the role of intersystem crossings, if any, in the titular reaction.

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