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Shun-Cai Zhao

Publications and source records attributed to Shun-Cai Zhao.

At least 19 recordsLinked to original sources

Catalytic Stabilization of Ergotropy and Backflow Suppression in Open Many-Body Quantum Batteries

Coherent energy backflow and non-Markovian oscillations limit energy retention and degrade extractable work (ergotropy) in open many-body quantum batteries. Here, we present a catalyst-mediated charging protocol for a collective spin-array quantum battery coupled to a laser-driven charger. Using the open-system Lindblad master equation, we examine the energy transfer dynamics when both charger and battery are symmetrically coupled to an off-resonant auxiliary catalytic mode. Numerical simulations reveal that while unassisted bipartite setups exhibit pronounced backflow oscillations and poor energy retention, catalytic mediation quenches transient oscillations and accelerates energy injection. The auxiliary system operates as an energy-invariant conduit, maintaining a constant energy expectation value $\langle H_C(t)\rangle \approx \langle H_C(0)\rangle$ and negligible transient population throughout the evolution. Microscopically, virtual excitations of the catalyst generate an effective complex inter-subsystem coupling $J_{\text{eff}}$, which induces an underdamped-to-overdamped dynamical crossover and introduces selective coherence damping. This mechanism prevents population depletion in the battery, stabilizing the population inversion and significantly increasing the asymptotic steady-state ergotropy with increasing battery size $N_B$. These findings clarify the dissipative dynamics of catalyst-mediated energy transfer and provide a practical scheme for improving storage stability in modern quantum hardware platforms.

quant-ph

Lamb-shift-mediated energy transfer in open quantum batteries

Open quantum batteries (QBs) operate under unavoidable system--environment interactions, where both dissipation and coherent frequency renormalization can affect their dynamics. While dissipative effects have been extensively studied, the role of environment-induced frequency shifts, such as the Lamb shift, remains less explored. Here, we investigate a driven open QB consisting of two coherently coupled quantum harmonic oscillators representing the charger and the battery. By incorporating dissipation and Lamb-shift corrections within a Lindblad master equation, we show that the Lamb shift renormalizes the system eigenfrequencies and modifies the resonance condition with the external drive. We further demonstrate that the resulting frequency renormalization leads to a mode-selective energy-transfer process, producing a redistribution of energy between the charger and the battery. This behavior is characterized through a supermode decomposition of the coupled system, which reveals how the environment-induced frequency shift alters the dominant energy-transfer channel. Our results clarify the role of coherent environmental effects in open quantum batteries and provide a physical framework for understanding work-extraction dynamics beyond purely dissipative descriptions.

quant-ph

Transient energy backflow enhanced ergotropy in an open qubit quantum battery assisted by an auxiliary oscillator

Decoherence and dissipation in open quantum systems generally drive quantum batteries toward passive states, thereby reducing their extractable work (ergotropy). Here, we study a driven qubit quantum battery coherently coupled to an auxiliary harmonic oscillator in the presence of dephasing and dissipation. Using the differential formulation of the first law of open quantum thermodynamics, we analyze the local energy-flow dynamics during the charging process. We find that the auxiliary oscillator induces a transient negative local energy current into the qubit subsystem, corresponding to a temporary inward energy backflow. This transient energy redistribution is accompanied by an enhancement of the qubit ergotropy and a partial suppression of decoherence-induced passivation. Moreover, the parameter regime exhibiting a more pronounced negative-current interval is consistently correlated with larger ergotropy enhancement. Our results suggest that transient inward energy flow provides a useful thermodynamic signature associated with enhanced energy storage in open quantum batteries.

quant-ph

Coherent catalyst induced stabilization of ergotropy in open quantum batteries

Environmental dissipation and thermal fluctuations fundamentally constrain the extractable work and long-time stability of open quantum batteries. To mitigate dissipation-induced energy degradation without external driving protocols, we propose a cavity-mediated hybrid quantum battery coupled to an auxiliary coherent qubit. Using the Lindblad master equation and ergotropy analysis, we show that coherent interference between different interaction channels generates a decoherence-free-like invariant subspace that suppresses relaxation-induced energy leakage and stabilizes the steady-state ergotropy. The resulting protection mechanism remains effective under strong dissipation and finite-temperature conditions, indicating that interference-assisted coherent control may provide a feasible strategy for robust quantum energy storage in nonequilibrium open systems.

quant-ph

Negative refraction with low absorption using EIT in a four-level left-handed atomic system

We suggest a scheme for obtaining negative refraction with low absorption in a left-handed atomic system.Under the the appropriate conditions,the atomic system displays negative refraction with negative permittivity and permeability(Left-handedness)in a common frequency range,simultaneously.And the imaginary parts of permittivity and permeability show transparently propagate in the same frequency range.Finally,the negative refraction show low absorption due to the EIT effect,and the figure of merit demonstrated this in this resonant atomic system.

quant-ph

Negative refraction with absorption suppressed by electromagneticly induced transparency in a left-handed atomic system

This paper intends to realize negative refraction with absorption suppressed by the electromagneticly induced transparency(EIT) in a dense four-level atomic system. Without the two equal transition frequencies responding to the probe field, the atomic system displays a negative refraction with the simultaneously negative permittivity and negative permeability(Left-handedness). The response of the probe field is amplified and propagates transparency in some frequency extents. Therefore, our aim for searching the low-loss negative refraction can be achieved in the scheme, given the main applied limitation of the negative refractive materials is the large amount of dissipation and absorption. However, an excessive signal field intensity would increase the absorption near the resonance in our scheme.

quant-ph

Different roles of quantum interference in a quantum dot photocell with two intermediate bands

It is generally believed that quantum interference can improve the transport of photo-generated carriers in a photocell, thereby improve the photoelectric conversion efficiency. In this work, we explicitly explore different roles of quantum interferences in the photoelectric conversion efficiency in a quantum dot (QD) photocell with two intermediate bands. The increasing transition rates from different charge transport channels bring out first increasing, then decreasing, and then monotonically decreasing photoelectric conversion efficiencies. And the photoelectric conversions increase with quantum coherence generated by the upper transition rates owing to their robust quantum interference. However, the conversion efficiency decrease with the quantum interference induced by two lower-transition rates due to the shortened population lifetime in the intermediate bands. These results provide insight into different roles of quantum interferences in photoelectric conversion efficiency, and may provide some artificial strategies to achieve efficient photoelectric conversion via the adjusted quantum interferences in a QD photocell with multi-intermediate bands.

physics.app-ph

Charging Dynamics in a Distance-Modulated Planar Quantum-Battery Architecture

While the spatial arrangement of individual units is essential for the physical implementation of quantum batteries, geometry-dependent interactions are rarely explicitly incorporated into existing theoretical models. To address this, we propose a planar many-body quantum-battery architecture consisting of coupled resonators. By introducing a distance-dependent function to modulate both the inter-battery coupling and tunneling, we investigate the open-system charging dynamics in the strong-coupling regime using a Redfield master-equation approach. Using ergotropy as the primary figure of merit, we demonstrate that the charging performance is highly sensitive to the inter-battery distance, nearest-neighbor coupling strength, and environmental conditions. Specifically, decreasing the inter-battery distance within an optimal window suppresses charging fluctuations and accelerates the system's approach to a steady charged state. However, an excessively short distance amplifies environmental dissipation, thereby degrading the overall performance. Furthermore, while overly strong inter-battery coupling induces post-charging instability, moderate coupling achieves a favorable balance between maximum stored energy and stability. We also establish that the system-bath coupling and bath cutoff frequency predominantly govern the charging timescale, and that the planar architecture maintains its robustness against thermal fluctuations over a broad temperature range. These results highlight the critical role of geometry-controlled interactions in many-body quantum batteries, providing a theoretical foundation for the design and optimization of two-dimensional quantum energy-storage devices.

quant-ph

Energy-Invariant Catalysis of Stable Ergotropy in Strongly Coupled Spin-Chain Quantum Batteries

Quantum batteries (QBs) provide a platform for exploring quantum-scale energy storage, yet most existing analyses rely on weak-coupling and Markovian approximations. In realistic implementations operating in strongly coupled non-Markovian regimes, environmental memory effects induce pronounced oscillations of the maximum extractable work (ergotropy), hindering stable energy output. Here, we investigate the stabilization of ergotropy in a spin-chain QB assisted by an energy-invariant catalyst, namely an auxiliary subsystem whose average energy remains unchanged during the evolution. The dynamics are described by a Nakajima-Zwanzig master equation with a Gaussian memory kernel, enabling a systematic characterization of non-Markovian effects. Our results show that the memory-kernel parameters, the spin number, and the characteristic frequencies of both the cavity field and the local excitations jointly regulate the ergotropy dynamics. Compared with the uncatalyzed case, the catalyst effectively reshapes the system energy spectrum, markedly suppresses non-Markovian oscillations, and promotes a quasi-stationary regime of extractable work. These findings provide a practical strategy for stabilizing energy flows in strongly coupled open quantum systems, offering theoretical guidance for the development of robust quantum energy devices and contributing to ongoing research in quantum thermodynamics.

quant-ph

Multi-timescale time encoding for CNN prediction of Fenna-Matthews-Olson energy-transfer dynamics

Machine learning simulations of open quantum dynamics often rely on recursive predictors that accumulate error. We develop a non-recursive convolutional neural networks (CNNs) that maps system parameters and a redundant time encoding directly to excitation-energy-transfer populations in the Fenna-Matthews-Olson complex. The encoding-modified logistic plus $\tanh$ functions-normalizes time and resolves fast, transitional, and quasi-steady regimes, while physics-informed labels enforce population conservation and inter-site consistency. Trained only on $0\sim 7 ps$ reference trajectories generated with a Lindblad model in QuTiP, the network accurately predicts $0\sim100 ps$ dynamics across a range of reorganization energies, bath rates, and temperatures. Beyond $20 ps$, the absolute relative error remains below 0.05, demonstrating stable long-time extrapolation. By avoiding step-by-step recursion, the method suppresses error accumulation and generalizes across timescales. These results show that redundant time encoding enables data-efficient inference of long-time quantum dissipative dynamics in realistic pigment-protein complexes, and may aid the data-driven design of light-harvesting materials.

physics.chem-ph

Rapid and Stable Collective Charging and Discharge Suppression in Strongly Coupled Many-Body Quantum Batteries

Achieving rapid and stable energy storage in quantum batteries (QBs) remains a key challenge, particularly under strong system-environment coupling where non-Markovian effects become prominent. While most previous studies focus on weak coupling regimes, we propose a many-body QB model exhibiting collective charging and discharge suppression in a non-perturbative regime. The model adopts a $Λ$-type configuration where multiple battery units share a common excited state and have individual ground states, forming an effective collective structure. To accurately capture the dynamics under strong coupling, the system's time evolution is governed by a Redfield-type master equation tincorporating memory effects via a Debye spectral density. We quantify the stored energy using ergotropy and analyze the impact of tunneling, driving strength, spectral width, and environmental temperature on charging performance. Numerical simulations reveal that optimized driving and reservoir engineering can simultaneously achieve rapid and stable charging while suppressing energy leakage. These results provide theoretical insight into strong-coupling thermodynamics and guide the design of robust QB platforms using solid-state or atomic systems.

quant-ph

Non-Markovian N-spin chain quantum battery in thermal charging process

Ergotropy serves as a key indicator for assessing the performance of quantum batteries(QBs). Using the Redfield master equation, we investigate ergotropy dynamics in a non-Markovian QB composed of an N-spin chain embedded in a microcavity. Distinct from Markovian charging process, the thermal charging process exhibits a distinct oscillatory behavior in the extracted ergotropy. We show these oscillations are suppressible via synergistic control of coherent driving, cavity parameters, and spin-spin couplings. In addition, we analyze the influence of various system and environmental parameters on the time evolution of ergotropy, revealing rich dynamical features. Our results offer new insights into the control of energy extraction in QBs and may inform future designs of practical battery architectures.

quant-ph

Quantum dynamics evolution predicted by the long short-term memory network in the photosystem II reaction center

Predicting future physical behavior from limited theoretical simulation data is an emerging research paradigm driven by the integration of artificial intelligence and quantum physics. In this work, charge transport (CT) behavior was predicted over extended time scales using a deep learning model-the long short-term memory (LSTM) network with an error-threshold training method-in the photosystem II reaction center (PSII-RC). Theoretical simulation data within 8 fs were used to train the modified LSTM network, yielding distinct predictions with differences on the order of $10^{-4}$ over prolonged periods compared to the training set collection time. The results highlight the potential of LSTM to uncover the underlying physics governing CT beyond conventional quantum physical methods. These findings warrant further investigation to fully explore the scope and efficacy of LSTM in advancing our understanding of photosynthesis at the molecular scale.

physics.chem-ph

Influence of the coupled-dipoles on photosynthetic performance in a photosynthetic quantum heat engine

Recent evidence suggests that the multi charge-separation pathways can contribute to the photosynthetic performance. In this work, the influence of coupled-dipoles on the photosynthetic performance was investigated in a two-charge separation pathways quantum heat engine (QHE) model. And the population dynamics of the two coupled sites, j-V characteristics and power involving this photosynthetic QHE model were evaluated for the photosynthetic performance. The results illustrate that the photosynthetic performance can be greatly enhanced but quantum interference was deactivated by the coupled-dipoles between the two-charge separation pathways. However, the photosynthetic performance can also be promoted by the deactivated quantum interference owing to the coupled-dipoles. It is a novel role of the coupled-dipoles in the energy transport process of biological photosynthetic and some artificial strategies may be motivated by this photosynthetic QHE model in the future.

physics.chem-ph

Charge-transport enhanced by the quantum entanglement in the Photosystem II reaction center

Revealing the role of quantum entanglement in charge-transport in the Photosystem II reaction center (PSII RC) is of great significance. In this work, we theoretically demonstrate that the robust quantum entanglement provides regulatory benefits to the charge-transport via a quantum heat engine (QHE) model with two absorbed photon channels. The calculation results manifest that the dynamic charge-transport and the steady-state photosynthetic properties of the PSII RC were enhanced by the intensity of quantum entanglement. Insight into the role of quantum entanglement in photosynthesis could motivate new experimental strategies for biomimetic photosynthetic devices in the future.

physics.chem-ph

Left-handedness without absorption in the four-level Y-type atomic medium

In this paper,three external fields interacting with the four-level Y-type atomic system described by the density-matrix approach is investigated .The results show that the left-handedness with zero absorption are achieved.And the zero absorption property displays the possibility of manipulation with varying the phase and the intensity of the coupling field. The zero absorption property may be used to amplify the evanescent waves that have been lost in the imaging by traditional lenses.Our scheme proposes an approach to obtain negative refractive medium with zero absorption and the possibility to enhance the imaging resolution in realizing "superlenses".

quant-ph

Electromagnetic chirality-induced negative refraction with the same amplitude and anti-phase of the two chirality coefficients

We suggest a scheme of electromagnetic chirality-induced negative refraction utilizing magneto-electric cross coupling in a four-level atomic system. The negative refraction can be achieved with the two chirality coefficients having the same amplitude but the opposite phase,and without requiring the simultaneous presence of an electric-dipole and a magnetic-dipole transition near the same transition frequency. The simultaneously negative electric permittivity and magnetic permeability does not require, either.

quant-ph

2D isotropic negative permeability in a Λ-type three-level atomic system

A approach for two-dimensional(2D) negative permeability in a $Λ$-type three-level atomic system interacting with a probe magnetic and the superposition of two orthogonal standing-wave fields is proposed. Through the theoretical analysis and numerical simulation, two equally and tunable peak maxima of negative magnetic responses are observed in the x-y plane, and around the peak maxima region the negative permeability is isotropic. A new avenue to 2D isotropic negative

quant-ph