arXiv subjects

Shunsuke Yoshizawa

Publications and source records attributed to Shunsuke Yoshizawa.

16 recordsLinked to original sources

arXiv2026

Anisotropic transport of Josephson vortices in atomic-layer superconductors on vicinal surfaces

Atomic steps have strong influences on surface two-dimensional superconductors. Josephson vortices formed at the atomic steps under magnetic fields may dominate transport phenomena at low temperatures, but its experimental verification is still lacking. Here, we report the vortex transport properties of atomic-layer superconductor Si(111)-$(\sqrt{7}\times\sqrt{3})$-In with vicinal surfaces, for which Josephson vortices are directly observed by scanning tunneling microscopy. A sharp drop in resistance with decreasing temperature $T$, detected under out-of-plane magnetic field $B$, reveals a distinctive anisotropy with respect to the atomic step direction. The anisotropy of sheet resistance, proportional to that of vortex mobility, amounts to the order of $10^3$ at intermediate magnetic fields. In the high-$T$ and low-$B$ region, Josephson vortices exhibit thermally excited creep motions with anisotropic activation energy $U_\mathrm{act}$. A further increase in $B$ suppresses $U_\mathrm{act}$ toward zero anisotropically, resulting in one-dimensional pinning-free vortex flow at $0.10 \lesssim B \lesssim 0.20$ T. At the lowest temperatures, the vortex motion is governed by quantum tunneling. A $B$-$T$ phase diagram constructed based on these measurements reveals multiple regions characterized by directionally dependent vortex-transport mechanisms.

cond-mat.supr-con↗

arXiv2025

Topological delocalization against Anderson localization observed in Bi-doped PbSb2Te4 disordered topological insulator

We experimentally investigate the tendency of localization in the bulk and the topological surface states in topological insulators Pb(Bi1-xSbx)2Te4 (x=0.793-0.818) through detailed transport measurements. The bulk electronic states in the range 0.793<=x<0.818 are situated on the insulator side of the Anderson transition, as indicated by k_Fl values (where k_F is the Fermi wavenumber and l is the mean free path) falling below the Ioffe-Regel criterion (i.e., k_F l<1). In contrast, the topological surface states retain high mobility and even exhibit quantum oscillations, demonstrating their resilient nature against strong disorder. These findings highlight the delocalized nature of the topological surface states despite Anderson localization of the bulk electronic states.

cond-mat.mtrl-sci↗

arXiv2024

Visualization of alternating triangular domains of charge density waves in 2H-NbSe$_2$ by scanning tunneling microscopy

The charge density wave (CDW) state of 2H-NbSe$_2$ features commensurate domains separated by domain boundaries accompanied by phase slips known as discommensurations. We have unambiguously visualized the structure of CDW domains using a displacement-field measurement algorithm on a scanning tunneling microscopy image. Each CDW domain is delimited by three vertices and three edges of discommensurations and is designated by a triplet of integers whose sum identifies the types of commensurate structure. The observed structure is consistent with the alternating triangular tiling pattern predicted by a phenomenological Landau theory. The domain shape is affected by crystal defects and also by topological defects in the CDW phase factor. Our results provide a foundation for a complete understanding of the CDW state and its relation to the superconducting state.

cond-mat.str-el↗

arXiv2023

Topological surface states hybridized with bulk states of Bi-doped PbSb2Te4 revealed in quasiparticle interference

Topological surface states of Bi-doped PbSb2Te4 [Pb(Bi0.20Sb0.80)2Te4] are investigated through analyses of quasiparticle interference (QPI) patterns observed by scanning tunneling microscopy. Interpretation of the experimental QPI patterns in the reciprocal space is achieved by numerical QPI simulations using two types of surface density of states produced by density functional theory calculations or a kp surface state model. We found that the Dirac point (DP) of the surface state appears in the bulk band gap of this material and, with the energy being away from the DP, the isoenergy contour of the surface state is substantially deformed or separated into segments due to hybridization with bulk electronic states. These findings provide a more accurate picture of topological surface states, especially at energies away from the DP, providing valuable insight into the electronic properties of topological insulators.

cond-mat.mtrl-sci↗

arXiv2023

Experimental verification of band convergence in Sr and Na codoped PbTe

Scanning tunneling microscopy and transport measurements have been performed to investigate the electronic structure and its temperature dependence in heavily Sr and Na codoped PbTe, which is recognized as one of the most promising thermoelectric materials. Our main findings are as follows: (i) Below T=4.5 K, all carriers are distributed in the first valence band at the L point (L band), which forms tube-shaped Fermi surfaces with concave curvature. With Sr and Na doping, the dispersion of the L band changes, and the band gap increases from 200 meV to 300 meV. (ii) At T=4.5 K, the Fermi energy is located ~100 meV below the edge of the L band for the Sr/Na codoped PbTe. The second valence band at the Sigma point (Sigma band) is lower than the L band by 150 meV, which is significantly smaller than that of pristine PbTe (200 meV). The decrease in the band offset, leading to band convergence, provides a desirable condition for thermoelectric materials.(iii) With increasing temperature, the carrier distribution to the Sigma band starts at T=100 K and we estimate that about 50 percent of the total carriers are redistributed in the Sigma band at T=300 K.Our work demonstrates that scanning tunneling microscopy and angular dependent magnetoresistance measurements are particularly powerful tools to determine the electronic structure and carrier distribution. We believe that they will provide a bird's eye view of the doping strategy towards realizing high-efficiency thermoelectric materials.

cond-mat.mtrl-sci↗

arXiv2023

Field resilient superconductivity in atomic layer crystalline materials

A recent study [S. Yoshizawa {\it et al}., Nature Communications {\bf 12}, 1462 (2021)] reported the occurrence of field-resilient superconductivity, that is, enhancement of the in-plane critical magnetic field $H^{||}_{\rm c2}$ beyond the paramagnetic limiting field, in atomic-layer crystalline ($\sqrt{7}\times\sqrt{3}$)-In on a Si(111) substrate. The present article elucidates the origin of the observed field-resilient noncentrosymmetric superconductivity in this highly crystalline two-dimensional material. We develop the quasiclassical theory of superconductivity by incorporating the Fermi surface anisotropy together with an anisotropic spin splitting and texture specific to atomic-layer crystalline systems. In Si(111)-($\sqrt{7}\times\sqrt{3}$)-In, a typical material with a large antisymmetric spin-orbit coupling (ASOC), we show an example where the combination of the ASOC and disorder effect suppresses the paramagnetic depairing and can lead to an enhancement of $H^{||}_{\rm c2}$ compared to an isotropic system only when a magnetic field is applied in a particular direction due to an anisotropic spin texture. We also study the parity-mixing effect to demonstrate that the enhancement of $H^{||}_{\rm c2}$ is limited in the moderately clean regime because of the fragile $s$+$p$-wave pairing against nonmagnetic scattering in the case of the dominant odd-parity component of a pair wavefunction. Furthermore, from analysis of the transition line, we identify the field-resilience factor taking account of the scattering and suppression of paramagnetic effects and discuss the origin of the field-resilient superconductivity. Through fitting of the $H^{||}_{\rm c2}$ data, the normal-state electron scattering is discussed with a prime focus on the role of atomic steps on a Si(111) surface.

cond-mat.supr-con↗

arXiv2022

Non-charge-transfer origin of Tc Enhancement in a Surface Superconductor Si(111)-(root7xroot3)-In with Adsorbed Organic Molecules

The effects of adsorption of Zn-phthalocyanine (ZnPc) molecules on the superconductivity of the Si(111)-(root7xroot3)-In surface are studied through transport measurements under ultrahigh vacuum environment. The ZnPc molecules are found to increase the transition temperature Tc by 11% at maximum, which is about 2.7 times the Tc increase previously reported using CuPc. By contrast, angle-resolved photoemission spectroscopy measurements and ab initio calculations show that charge transfer from the In atomic layers to ZnPc is substantially smaller than that to CuPc. This clearly shows that charge transfer should be excluded as the origin of the increase in Tc. The push-back effect induced by physical adsorption of molecules is discussed as a possible mechanism for the Tc enhancement.

cond-mat.supr-con↗

arXiv2021

A Principled Approach to Failure Analysis and Model Repairment: Demonstration in Medical Imaging

Machine learning models commonly exhibit unexpected failures post-deployment due to either data shifts or uncommon situations in the training environment. Domain experts typically go through the tedious process of inspecting the failure cases manually, identifying failure modes and then attempting to fix the model. In this work, we aim to standardise and bring principles to this process through answering two critical questions: (i) how do we know that we have identified meaningful and distinct failure types?; (ii) how can we validate that a model has, indeed, been repaired? We suggest that the quality of the identified failure types can be validated through measuring the intra- and inter-type generalisation after fine-tuning and introduce metrics to compare different subtyping methods. Furthermore, we argue that a model can be considered repaired if it achieves high accuracy on the failure types while retaining performance on the previously correct data. We combine these two ideas into a principled framework for evaluating the quality of both the identified failure subtypes and model repairment. We evaluate its utility on a classification and an object detection tasks. Our code is available at https://github.com/Rokken-lab6/Failure-Analysis-and-Model-Repairment

cs.LG↗

arXiv2021

Atomic-layer Rashba-type superconductor protected by dynamic spin-momentum locking

Spin-momentum locking is essential to the spin-split Fermi surfaces of inversion-symmetry broken materials, which are caused by either Rashba-type or Zeeman-type spin-orbit coupling (SOC). While the effect of Zeeman-type SOC on superconductivity has experimentally been shown recently, that of Rashba-type SOC remains elusive. Here we report on convincing evidence for the critical role of the spin-momentum locking on crystalline atomic-layer superconductors on surfaces, for which the presence of the Rashba-type SOC is demonstrated. In-situ electron transport measurements reveal that in-plane upper critical magnetic field is anomalously enhanced, reaching approximately three times the Pauli limit at $T = 0$. Our quantitative analysis clarifies that dynamic spin-momentum locking, a mechanism where spin is forced to flip at every elastic electron scattering, suppresses the Cooper pair-breaking parameter by orders of magnitude and thereby protects superconductivity. The present result provides a new insight into how superconductivity can survive the detrimental effects of strong magnetic fields and exchange interactions.

cond-mat.supr-con↗

arXiv2017

Vibrational Energy Transfer from Photo-Excited Carbon Nanotubes to Proteins Observed by Coherent Phonon Spectroscopy

Vibrational energy transfer from photo-excited single-wall carbon nanotubes (SWCNTs) to coupled proteins is a key to engineer thermally induced biological reactions such as photothermal therapy. Here, we explored vibrational energy transfer from the photo-excited SWCNTs to different adsorbed biological materials by means of a femtosecond pump-probe technique. We show that the vibrational relaxation time of the radial breathing modes (RBMs) in SWCNTs significantly depends on the structure of coupled materials, i.e. proteins or biopolymers, indicating the vibrational energy transfer is governed by overlap of phonon density of states between the SWCNTs and coupled materials.

cond-mat.mtrl-sci↗

arXiv2016

Two-dimensional atomic layer-molecule hybrid superconductors with controllable exchange coupling

The coexistence and competition of superconductivity and magnetism can lead to a variety of rich physics and technological applications. Recent discovery of atomic-layer superconductors and self-assembly of magnetic molecules on solid surfaces should allow one to create a new two-dimensional (2D) hybrid superconducting system, but its possibility has never been fully investigated so far. Here we report the fabrication of highly ordered 2D hybrid superconductors based on indium atomic layers on silicon surfaces and magnetic metal-phthalocyanines (MPc) and clarify their detailed structural, superconducting and magnetic properties. Our primary findings include a substantial controllability of the superconducting transition temperatures (Tc) through substitution of central metal ions (M = Cu, Fe, Mn) of the molecules. This is attributed to charge transfers between the magnetic molecules and the superconducting layers and to different degrees of exchange coupling between them, which originates from anisotropic distributions of the relevant d-orbitals. The present study opens a route for designing and creating exotic 2D superconductors with an atomic-scale precision.

cond-mat.supr-con↗

arXiv2015

Disorder-induced suppression of superconductivity in the Si(111)-($\sqrt{7}\times\sqrt{3}$)-In surface: Scanning tunneling microscopy study

The critical effect of disorder on the two-dimensional (2D) surface superconductor Si(111)-($\sqrt{7}\times\sqrt{3}$)-In is clarified by comparing two regions with different degrees of disorder. Low-temperature scanning tunneling microscopy measurements reveal that superconductivity is retained in the less disordered region, judging from the characteristic differential conductance ($dI/dV$) spectra and from the formation of vortices under magnetic fields. In striking contrast, the absence of those features in the highly disordered region shows that superconductivity is strongly suppressed there. Analysis of observed zero-bias anomalies in $dI/dV$ spectra allows us to estimate the reduction in the transition temperature $T_{\rm c}$, which explains the fate of superconductivity in each region.

cond-mat.mes-hall↗

arXiv2014

Imaging Josephson Vortices on the Surface Superconductor Si(111)-(root7xroot3)-In using a Scanning Tunneling Microscope

We have studied the superconducting Si(111)-(root7xroot3)-In surface using a 3He-based low-temperature scanning tunneling microscope (STM). Zero-bias conductance (ZBC) images taken over a large surface area reveal that vortices are trapped at atomic steps after magnetic fields are applied. The crossover behavior from Pearl to Josephson vortices is clearly identified from their elongated shapes along the steps and significant recovery of superconductivity within the cores. Our numerical calculations combined with experiments clarify that these characteristic features are determined by the relative strength of the interterrace Josephson coupling at the atomic step.

cond-mat.mes-hall↗

arXiv2013

Unexpectedly robust protection from backscattering in the topological insulator Bi$_{1.5}$Sb$_{0.5}$Te$_{1.7}$Se$_{1.3}$

Electron scattering in the topological surface state (TSS) of the bulk-insulating topological insulator Bi$_{1.5}$Sb$_{0.5}$Te$_{1.7}$Se$_{1.3}$ was studied using quasiparticle interference observed by scanning tunneling microscopy. It was found that not only the 180$^{\circ}$ backscattering but also a wide range of backscattering angles of 100$^{\circ}$--180$^{\circ}$ is effectively prohibited in the TSS. This conclusion was obtained by comparing the observed scattering vectors with the diameters of the constant-energy contours of the TSS, which were measured for both occupied and unoccupied states using time- and angle-resolved photoemission spectroscopy. The unexpectedly robust protection from backscattering in the TSS is a good news for applications, but it poses a challenge to the theoretical understanding of the transport in the TSS.

cond-mat.mes-hall↗

arXiv2013

High-Resolution Scanning Tunneling Spectroscopy of Vortex Cores in Inhomogeneous Electronic States of Bi2Sr2CaCu2Ox

We studied electronic states in vortex cores of slightly overdoped Bi2Sr2CaCu2Ox by scanning tunneling spectroscopy. We have found that they have stripe structures with a 4a0 width extending along the Cu-O bond directions. Vortex core states are observed as two peaks at particle-hole symmetric positions in the energy gap. Along a stripe, the peak positions of vortex core states are constant and not influenced by the spatial variation of the energy gap Δ. Outer stripes have a larger energy than inner stripes. A mazelike pattern in the electronic states at E = +-Δhas been observed all over the surface both inside and outside the vortex core. The orientation of stripes of vortex core states was found to be related to the mazelike pattern in the vortex core region. A short-range order of the mazelike pattern spatially coexists with the superconductivity and locally breaks the symmetry of the two Cu-O bond directions. We propose that the vortex core bound states are formed by Bogoliubov quasiparticles owing to the depairing of Cooper pairs and have a local C2 symmetry influenced by the short-range order of the mazelike pattern.

cond-mat.supr-con↗

arXiv2007

Anti-phase Modulation of Electron- and Hole-like States in Vortex Core of Bi2Sr2CaCu2Ox Probed by Scanning Tunneling Spectroscopy

In the vortex core of slightly overdoped Bi2Sr2CaCu2Ox, the electron-like and hole-like states have been found to exhibit spatial modulations in anti-phase with each other along the Cu-O bonding direction. Some kind of one-dimensionality has been observed in the vortex core, and it is more clearly seen in differential conductance maps at lower biases below +-9 mV.

cond-mat.supr-con↗