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Shuohan Liu

Publications and source records attributed to Shuohan Liu.

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Generalized causality constraint based on duality symmetry reveals untapped potential of sound absorption

Causality constraints are known to bind sound absorption to a limit that can only be achieved by optimizing the system bandwidth for a specific material thickness. This limit is defined on the assumption of a one-port system, generally causing duality symmetry to be overlooked. Here, we define a generalized causality constraint of sound absorption by investigating reflection and transmission of a two-port hybrid monopole-dipole resonator. With our theory, we show that the absorption limit is approached by relying on the well-established critical coupling as well as by matching effective compressibility and density. We experimentally show that the designed resonator absorbance follows the duality symmetry condition embodied in the large bandwidth reported. A comparison with a traditional foam liner and other competitive works further validates our findings, confirming an intrinsic connection between duality symmetry and scattering causality. Our results untap unexplored absorption potential in broadband acoustic metamaterials.

physics.app-ph

Water-stable MOFs and Hydrophobically Encapsulated MOFs for CO2 Capture from Ambient Air and Wet Flue Gas

The extra CO2 that has already been released into the atmosphere has to be removed in order to create a world that is carbon neutral. Technologies have been created to remove carbon dioxide from wet flue gas or even directly from ambient air, however these technologies are not widely deployed yet. New generations of creative CO2 capture sorbents have been produced as a consequence of recent improvements in material assembly and surface chemistry. We summarize recent progress on water-stable and encapsulated metal-organic frameworks (MOFs) for CO2 capture under a wide range of environmental and operating conditions. In particular, newly developed water-stable MOFs and hydrophobic coating technologies are discussed with insights into their materials discovery and the synergistic effects between different components of these hybrid sorbent systems. The future perspectives and directions of water-stable and encapsulated MOFs are also given for Direct Air Capture of CO2 and CO2 capture from wet flue gas.

cond-mat.mtrl-sci