arXiv subjects

Siddharth Gandhi

Publications and source records attributed to Siddharth Gandhi.

At least 37 records · Page 2Linked to original sources

arXiv2024

The ESO SupJup Survey III: Confirmation of 13CO in YSES 1 b and Atmospheric Detection of YSES 1 c with CRIRES+

High-resolution spectroscopic characterization of young super-Jovian planets enables precise constraints on elemental and isotopic abundances of their atmospheres. As part of the ESO SupJup Survey, we present high-resolution spectral observations of two wide-orbit super-Jupiters in YSES 1 (or TYC 8998-760-1) using the upgraded VLT/CRIRES+ (R~100,000) in K-band. We carry out free atmospheric retrieval analyses to constrain chemical and isotopic abundances, temperature structures, rotation velocities, and radial velocities. We confirm the previous detection of 13CO in YSES 1 b at a higher significance of 12.6σ, but point to a higher 12CO/13CO ratio of 88+/-13 (1σ confidence interval), consistent with the primary's isotope ratio 66+/-5. We retrieve a solar-like composition in YSES 1 b with a C/O=0.57+/-0.01, indicating a formation via gravitational instability or core accretion beyond the CO iceline. Additionally, the observations lead to detections of H2O and CO in the outer planet YSES 1 c at 7.3σ and 5.7σ, respectively. We constrain the atmospheric C/O ratio of YSES 1 c to be either solar or subsolar (C/O=0.36+/-0.15), indicating the accretion of oxygen-rich solids. The two companions have distinct vsini, 5.34+/-0.14 km/s for YSES 1 b and 11.3+/-2.1 km/s for YSES 1 c, despite their similar natal environments. This may indicate different spin axis inclinations or effective magnetic braking by the long-lived circumplanetary disk around YSES 1 b. YSES 1 represents an intriguing system for comparative studies of super-Jovian companions and linking present atmospheres to formation histories.

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arXiv2024

Phase-resolving the absorption signatures of water and carbon monoxide in the atmosphere of the ultra-hot Jupiter WASP-121b with GEMINI-S/IGRINS

Ultra-hot Jupiters are among the best targets for atmospheric characterization at high spectral resolution. Resolving their transmission spectra as a function of orbital phase offers a unique window into the 3D nature of these objects. In this work, we present three transits of the ultra-hot Jupiter WASP-121b observed with Gemini-S/IGRINS. For the first time, we measure the phase-dependent absorption signals of CO and H$_{\text{2}}$O in the atmosphere of an exoplanet, and we find that they are different. While the blueshift of CO increases during the transit, the absorption lines of H$_{\text{2}}$O become less blueshifted with phase, and even show a redshift in the second half of the transit. These measurements reveal the distinct spatial distributions of both molecules across the atmospheres of ultra-hot Jupiters. Also, we find that the H$_{\text{2}}$O signal is absent in the first quarter of the transit, potentially hinting at cloud formation on the evening terminator of WASP-121b. To further interpret the absorption trails of CO and H$_{\text{2}}$O, as well as the Doppler shifts of Fe previously measured with VLT/ESPRESSO, we compare the data to simulated transits of WASP-121b. To this end, we post-processes the outputs of global circulation models with a 3D Monte-Carlo radiative transfer code. Our analysis shows that the atmosphere of WASP-121b is subject to atmospheric drag, as previously suggested by small hotspot offsets inferred from phase-curve observations. Our study highlights the importance of phase-resolved spectroscopy in unravelling the complex atmospheric structure of ultra-hot Jupiters and sets the stage for further investigations into their chemistry and dynamics.

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arXiv2024

Peering above the clouds of the warm Neptune GJ 436b with CRIRES+

Exoplanets with masses between Earth and Neptune are amongst the most commonly observed, yet their properties are poorly constrained. Their transmission spectra are often featureless, which indicate either high-altitude clouds or a high atmospheric metallicity. The archetypical warm Neptune GJ 436b is such a planet showing a flat transmission spectrum in observations with the Hubble Space Telescope (HST). Ground-based high-resolution spectroscopy (HRS) effectively probes exoplanet atmospheres at higher altitudes and can therefore be more sensitive to absorption coming from above potential cloud decks. In this paper we aim to investigate this for the exoplanet GJ 436b. We present new CRIRES+ HRS transit data of GJ 436b. Three transits were observed, but since two were during bad weather conditions, only one transit was analyzed. The radiative transfer code petitRADTRANS was used to create atmospheric models for cross-correlation and signal-injection purposes, including absorption from H$_2$O, CH$_4$, and CO. No transmission signals were detected, but atmospheric constraints can be derived. Injection of artificial transmission signals indicate that if GJ 436b would have a cloud deck at pressures P>10 mbar and a <300$\times$ solar metallicity, these CRIRES+ observations should have resulted in a detection. We estimate that the constraints presented here from one ground-based HRS transit are slightly better than those obtained with four HST transits. Combining HRS data from multiple transits is an interesting avenue for future studies of exoplanets with high-altitude clouds.

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arXiv2024

Revealing H$_2$O dissociation in WASP-76~b through combined high- and low-resolution transmission spectroscopy

Numerous chemical constraints have been possible for exoplanetary atmospheres thanks to high-resolution spectroscopy (HRS) from ground-based facilities as well as low-resolution spectroscopy (LRS) from space. These two techniques have complementary strengths, and hence combined HRS and LRS analyses have the potential for more accurate abundance constraints and increased sensitivity to trace species. In this work we retrieve the atmosphere of the ultra-hot Jupiter WASP-76~b, using high-resolution CARMENES/CAHA and low-resolution HST WFC3 and Spitzer observations of the primary eclipse. As such hot planets are expected to have a substantial fraction of H$_2$O dissociated, we conduct retrievals including both H$_2$O and OH. We explore two retrieval models, one with self-consistent treatment of H$_2$O dissociation and another where H$_2$O and OH are vertically-homogeneous. Both models constrain H$_2$O and OH, with H$_2$O primarily detected by LRS and OH through HRS, highlighting the strengths of each technique and demonstrating the need for combined retrievals to fully constrain chemical compositions. We see only a slight preference for the H$_2$O-dissociation model given that the photospheric constraints for both are very similar, indicating $\log(\mathrm{OH/H_2O}) = 0.7^{+0.3}_{-0.3}$ at 1.5~mbar, showing that the majority of the H$_2$O in the photosphere is dissociated. However, the bulk O/H and C/O ratios inferred from the models differs significantly, and highlights the challenge of constraining bulk compositions from photospheric abundances with strong vertical chemical gradients. Further observations with JWST and ground-based facilities may help shed more light on these processes.

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arXiv2024

High-resolution atmospheric retrievals of WASP-76b transmission spectroscopy with ESPRESSO: Monitoring limb asymmetries across multiple transits

Direct atmospheric retrievals of exoplanets at high-resolution have recently allowed for a more detailed characterisation of their chemistry and dynamics from the ground. By monitoring the longitudinal distribution of species, as well as the varying vertical temperature structure and dynamics between the limbs of WASP-76b, across multiple transits, we aim to enhance our understanding of the 3D nature and chemical/dynamical evolution of such objects over the timescales of months/years. We present retrievals of three VLT/ESPRESSO observations of the ultra-hot Jupiter WASP-76b, including one not yet reported in the literature, from which we constrain the atmospheric abundances, vertical temperature structure, and atmospheric dynamics for both the leading and trailing limbs of the atmosphere separately, via novel rotational broadening kernels. We confirm the presence of VO recently reported in the atmosphere of WASP-76b. We find a uniform longitudinal distribution of Fe and Mg across the limbs of the atmosphere, for each of our transits, consistent with previous works as well as with stellar values. We constrain substellar Na/Fe and Cr/Fe ratios across each of our transits, consistent with previous studies of WASP-76b. Where constrained, V/Fe and VO/Fe ratios were also found to be broadly consistent between the limbs of the atmosphere for each of the transits, as well as with previous studies. However, for two of the transits, both V and VO were unconstrained in the leading limb, suggesting possible depletion due to recombination and condensation. The consistency of our constraints across multiple high-resolution observations, as well as with previous studies using varying modelling/retrieval frameworks and/or instruments, affirms the efficacy of high-resolution ground-based retrievals of exoplanetary atmospheres.

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arXiv2024

Constraints on atmospheric water abundance and cloud deck pressure in the warm Neptune GJ 3470 b via CARMENES transmission spectroscopy

Observations of cooler atmospheres of super-Earths and Neptune sized objects often show flat transmission spectra. The most likely cause of this trend is the presence of aerosols (i.e. clouds and hazes) in the atmospheres of such objects. High-resolution spectroscopy provides an opportunity to test this hypothesis by targeting molecular species whose spectral line cores extend above the level of such opaque decks. In this work, we analyse high-resolution infrared observations of the warm Neptune GJ 3470 b taken over two transits using CARMENES (R $\sim$ 80,000) and look for signatures of H$_2$O (previously detected using HST WFC3+Spitzer observations) in these transits with a custom pipeline fully accounting for the effects of data cleaning on any potential exoplanet signal. We find that our data are potentially able to weakly detect ($\sim3σ$) an injected signal equivalent to the best-fit model from previous HST WFC3+Spitzer observations. However, we do not make a significant detection using the actual observations. Using a Bayesian framework to simultaneously constrain the H$_2$O Volume Mixing Ratio (VMR) and the cloud top pressure level, we select a family of models compatible with the non detection. These are either very high VMR, cloud-free models, solar-abundance models with a high cloud deck, or sub-solar abundance models with a moderate cloud deck. This is a broader range compared to published results from low-resolution spectroscopy, but is also compatible with them at a 1$σ$ level.

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arXiv2023

$β$ Pictoris b through the eyes of the upgraded CRIRES+

Context: High-resolution spectrographs fed by adaptive optics (AO) provide a unique opportunity to characterize directly imaged exoplanets. Observations with such instruments allow us to probe the atmospheric composition, spin rotation, and radial velocity of the planet, thereby helping to reveal information on its formation and migration history. The recent upgrade of the Cryogenic High-Resolution Infrared Echelle Spectrograph (CRIRES+) at the VLT makes it a highly suitable instrument for characterizing directly imaged exoplanets. Aims: In this work, we report on observations of $β$ Pictoris b with CRIRES+ and use them to constrain the planets atmospheric properties and update the estimation of its spin rotation. Methods: The data were reduced using the open-source \textit{pycrires} package. We subsequently forward-modeled the stellar, planetary, and systematic contribution to the data to detect molecules in the planet's atmosphere. We also used atmospheric retrievals to provide new constraints on its atmosphere. Results: We confidently detected water and carbon monoxide in the atmosphere of $β$ Pictoris b and retrieved a slightly sub-solar carbon-to-oxygen ratio, which is in agreement with previous results. The interpretation is hampered by our limited knowledge of the C/O ratio of the host star. We also obtained a much improved constraint on its spin rotation of $19.9 \pm 1.0$ km/s, which gives a rotation period of $8.7 \pm 0.8$ hours, assuming no obliquity. We find that there is a degeneracy between the metallicity and clouds, but this has minimal impact on the retrieved C/O, $v\sin{i}$, and radial velocity. Our results show that CRIRES+ is performing well and stands as a highly useful instrument for characterizing directly imaged planets.

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arXiv2023

JWST measurements of $^{13}$C, $^{18}$O and $^{17}$O in the atmosphere of super-Jupiter VHS 1256 b

Isotope ratios have recently been measured in the atmospheres of directly-imaged and transiting exoplanets from ground-based observations. The arrival of JWST allows us to characterise exoplanetary atmospheres in further detail and opens up wavelengths inaccessible from the ground. In this work we constrain the carbon and oxygen isotopes $^{13}$C, $^{18}$O and $^{17}$O from CO in the atmosphere of the directly-imaged companion VHS 1256 b through retrievals of the $\sim$4.1-5.3 $μ$m NIRSpec G395H/F290LP observations from the early release science programme (ERS 1386). We detect and constrain $^{13}$C$^{16}$O, $^{12}$C$^{18}$O and $^{12}$C$^{17}$O at 32, 16 and 10$σ$ confidence respectively, thanks to the very high signal-to-noise observations. We find the ratio of abundances are more precisely constrained than their absolute values, with $\mathrm{^{12}C/^{13}C=62^{+2}_{-2}}$, in between previous measurements for companions ($\sim$30) and isolated brown dwarfs ($\sim$100). The oxygen isotope ratios are $\mathrm{^{16}O/^{18}O =425^{+33}_{-28}}$ and $\mathrm{^{16}O/^{17}O=1010^{+120}_{-100}}$. All of the ratios are lower than the local inter-stellar medium and Solar System, suggesting that abundances of the more minor isotopes are enhanced compared to the primary. This could be driven by isotope fractionation in protoplanetary disks, which can potentially alter the carbon and oxygen ratios through isotope selective photodissociation, gas/ice partitioning and isotopic exchange reactions. In addition to CO, we constrain $^{1}$H$_2$$^{16}$O and $^{12}$C$^{16}$O$_2$ (the primary isotopologues of both species), but find only upper limits on $^{12}$C$^1$H$_4$ and $^{14}$N$^{1}$H$_3$. This work highlights the power of JWST to constrain isotopes in exoplanet atmospheres, with great promise in determining formation histories in the future.

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arXiv2023

Retrieval survey of metals in six ultra-hot Jupiters: Trends in chemistry, rain-out, ionisation and atmospheric dynamics

Ground-based high-resolution spectroscopy (HRS) has detected numerous chemical species and atmospheric dynamics in exoplanets, most notably ultra-hot Jupiters (UHJs). However, quantitative estimates on abundances have been challenging but are essential for accurate comparative characterisation and to determine formation scenarios. In this work we retrieve the atmospheres of six UHJs (WASP-76~b, MASCARA-4~b, MASCARA-2~b, WASP-121~b, HAT-P-70~b and WASP-189~b) with ESPRESSO and HARPS-N/HARPS observations, exploring trends in eleven neutral species and dynamics. While Fe abundances agree well with stellar values, Mg, Ni, Cr, Mn and V show more variation, highlighting the difficulty in using a single species as a proxy for metallicity. We find that Ca, Na, Ti and TiO are under-abundant, potentially due to ionisation and/or night-side rain-out. Our retrievals also show that relative abundances between species are more robust, consistent with previous works. We perform spatially- and phase-resolved retrievals for WASP-76~b and WASP-121~b given their high signal-to-noise observations, and find the chemical abundances in each of the terminator regions are broadly consistent. We additionally constrain dynamics for our sample through Doppler shifts and broadening of the planetary signals during the primary eclipse, with median blue shifts between $\sim$0.9-9.0~km/s due to day-night winds. Furthermore, we constrain spectroscopic masses for MASCARA-2~b and HAT-P-70~b consistent with their known upper limits, but we note that these may be biased due to degeneracies. This work highlights the importance of future HRS studies to further probe differences and trends between exoplanets.

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arXiv2023

Early Insights for Atmospheric Retrievals of Exoplanets using JWST Transit Spectroscopy

We have entered the era of the James Webb Space Telescope (JWST). We use the first JWST transmission spectrum of the hot Saturn-mass exoplanet, WASP-39 b, obtained with the NIRSpec instrument in the 3-5 $μ$m range to investigate (a) what atmospheric constraints are possible with JWST-quality data in this spectral range, (b) requirements for atmospheric models used in retrievals, (c) effect of differences between data reduction pipelines on retrieved atmospheric properties, and (d) complementarity between JWST data in the 3-5 $μ$m range and HST observations at shorter wavelengths. JWST spectra in the 3-5 $μ$m range provide a promising avenue for chemical detections while encompassing a window in cloud opacity for several prominent aerosols. We confirm recent inferences of CO$_2$, SO$_2$, H$_2$O, and CO in WASP-39 b, report tentative evidence for H$_2$S, and retrieve elemental abundances consistent with Saturn's metallicity. We retrieve molecular abundances with $\sim$0.3-0.6 dex precision with this relatively limited spectral range. When considering the 3-5 $μ$m data alone, reported differences in spectra with different reduction pipelines can affect abundance estimates by up to $\sim$1 dex and the detectability of less prominent species. Complementing with data at shorter wavelengths, e.g. with other JWST instruments or HST WFC3 ($\sim$0.8-1.7 $μ$m), can significantly improve the accuracy and precision of the abundance estimates. The high data quality enables constraints on aerosol properties, including their composition, modal size and extent, motivating their consideration in retrievals. Our results highlight the promise of JWST exoplanet spectroscopy, while underscoring the importance of robust data reduction and atmospheric retrieval approaches in the JWST era.

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arXiv2022

The Roasting Marshmallows Program with IGRINS on Gemini South I: Composition and Climate of the Ultra Hot Jupiter WASP-18 b

We present high-resolution dayside thermal emission observations of the exoplanet WASP-18b using IGRINS on Gemini South. We remove stellar and telluric signatures using standard algorithms, and we extract the planet signal via cross correlation with model spectra. We detect the atmosphere of WASP-18b at a signal-to-noise ratio (SNR) of 5.9 using a full chemistry model, measure H2O (SNR=3.3), CO (SNR=4.0), and OH (SNR=4.8) individually, and confirm previous claims of a thermal inversion layer. The three species are confidently detected (>4$σ$) with a Bayesian inference framework, which we also use to retrieve abundance, temperature, and velocity information. For this ultra-hot Jupiter (UHJ), thermal dissociation processes likely play an important role. Retrieving abundances constant with altitude and allowing the temperature-pressure profile to freely adjust results in a moderately super-stellar carbon to oxygen ratio (C/O=0.75^{+0.14}_{-0.17}) and metallicity ([M/H]=1.03^{+0.65}_{-1.01}). Accounting for undetectable oxygen produced by thermal dissociation leads to C/O=0.45^{+0.08}_{-0.10} and [M/H]=1.17^{+0.66}_{-1.01}. A retrieval that assumes radiative-convective-thermochemical-equilibrium and naturally accounts for thermal dissociation constrains C/O<0.34 (2$σ$) and [M/H]=0.48^{+0.33}_{-0.29}, in line with the chemistry of the parent star. Looking at the velocity information, we see a tantalising signature of different Doppler shifts at the level of a few km/s for different molecules, which might probe dynamics as a function of altitude and location on the planet disk. Our results demonstrate that ground-based, high-resolution spectroscopy at infrared wavelengths can provide meaningful constraints on the compositions and climate of highly irradiated planets. This work also elucidates potential pitfalls with commonly employed retrieval assumptions when applied to UHJ spectra.

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arXiv2022

The GAPS Programme at TNG XXXIX -- Multiple molecular species in the atmosphere of the warm giant planet WASP-80 b unveiled at high resolution with GIANO-B

Detections of molecules in the atmosphere of gas giant exoplanets allow us to investigate the physico-chemical properties of the atmospheres. Their inferred chemical composition is used as tracer of planet formation and evolution mechanisms. Currently, an increasing number of detections is showing a possible rich chemistry of the hotter gaseous planets, but whether this extends to cooler giants is still unknown. We observed four transits of WASP-80 b, a warm transiting giant planet orbiting a late-K dwarf star with the near-infrared GIANO-B spectrograph installed at the Telescopio Nazionale Galileo and performed high resolution transmission spectroscopy analysis. We report the detection of several molecular species in its atmosphere. Combining the four nights and comparing our transmission spectrum to planetary atmosphere models containing the signature of individual molecules within the cross-correlation framework, we find the presence of H2O, CH4, NH3 and HCN with high significance, tentative detection of CO2, and inconclusive results for C2H2 and CO. A qualitative interpretation of these results, using physically motivated models, suggests an atmosphere consistent with solar composition and the presence of disequilibrium chemistry and we therefore recommend the inclusion of the latter in future modelling of sub-1000K planets.

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arXiv2022

Spatially-resolving the terminator: Variation of Fe, temperature and winds in WASP-76 b across planetary limbs and orbital phase

Exoplanet atmospheres are inherently three-dimensional systems in which thermal/chemical variation and winds can strongly influence spectra. Recently, the ultra-hot Jupiter WASP-76 b has shown evidence for condensation and asymmetric Fe absorption with time. However, it is currently unclear whether these asymmetries are driven by chemical or thermal differences between the two limbs, as precise constraints on variation in these have remained elusive due to the challenges of modelling these dynamics in a Bayesian framework. To address this we develop a new model, HyDRA-2D, capable of simultaneously retrieving morning and evening terminators with day-night winds. We explore variations in Fe, temperature profile, winds and opacity deck with limb and orbital phase using VLT/ESPRESSO observations of WASP-76 b. We find Fe is more prominent on the evening for the last quarter of the transit, with $\log(X_\mathrm{Fe}) = {-4.03}^{+0.28}_{-0.31}$, but the morning shows a lower abundance with a wider uncertainty, $\log(X_\mathrm{Fe}) = {-4.59}^{+0.85}_{-1.0}$, driven by degeneracy with the opacity deck and the stronger evening signal. We constrain 0.1 mbar temperatures ranging from $2950^{+111}_{-156}$ K to $2615^{+266}_{-275}$ K, with a trend of higher temperatures for the more irradiated atmospheric regions. We also constrain a day-night wind speed of $9.8^{+1.2}_{-1.1}$ km/s for the last quarter, higher than $5.9^{+1.5}_{-1.1}$ km/s for the first, in line with general circulation models. We find our new spatially- and phase-resolved treatment is statistically favoured by 4.9$σ$ over traditional 1D-retrievals, and thus demonstrate the power of such modelling for robust constraints with current and future facilities.

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arXiv2022

Water observed in the atmosphere of τ Bootis Ab with CARMENES/CAHA

Characterising the atmospheres of hot Jupiters is important in understanding the formation and migration of these exotic planets. However, there are still many open questions about the chemical and physical properties of these atmospheres. Here, we confirm the detection of water vapour in thermal emission from the non-transiting hot Jupiter τ Bootis Ab with the high resolution NIR CARMENES spectrograph. Combining over 17 h of observations (560 spectra) and using a Bayesian cross-correlation to log-likelihood approach, we measure a systemic velocity of $V_{sys} = -11.51^{+0.59}_{-0.60}$ km/s and a radial velocity semi-amplitude of $K_{P} = 106.21^{+1.76}_{-1.71}$ km/s for the planet, which results in an absolute mass of $M_{P} = 6.24^{+0.17}_{-0.18} M_{J}$ and an orbital inclination of $41.6^{+1.0}_{-0.9}$ degrees. Our retrieved $V_{sys}$ shows a significant shift (+5 km/s) from the literature value, which could be caused by an inaccurate time of periastron. Within the explored model grid, we measure a preference for solar water abundance (VMR = $10^{-3}$) and no evidence for additional minor species in the atmosphere. Given the extensive orbital coverage of the data, we searched for a phase dependency in the water signal but found no strong evidence of variation with orbital phase. This detection is at odds with recent observations from SPIRou/CFHT and their tight upper limit on water abundance. We recommend further observations of the atmosphere τ Bootis Ab to try and resolve these discrepancies.

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arXiv2021

A solar C/O and sub-solar metallicity in a hot Jupiter atmosphere

Measurements of the atmospheric carbon (C) and oxygen (O) relative to hydrogen (H) in hot Jupiters (relative to their host stars) provide insight into their formation location and subsequent orbital migration. Hot Jupiters that form beyond the major volatile (H2O/CO/CO2) ice lines and subsequently migrate post disk-dissipation are predicted have atmospheric carbon-to-oxygen ratios (C/O) near 1 and subsolar metallicities, whereas planets that migrate through the disk before dissipation are predicted to be heavily polluted by infalling O-rich icy planetesimals, resulting in C/O < 0.5 and super-solar metallicities. Previous observations of hot Jupiters have been able to provide bounded constraints on either H2O or CO, but not both for the same planet, leaving uncertain the true elemental C and O inventory and subsequent C/O and metallicity determinations. Here we report spectroscopic observations of a typical transiting hot Jupiter, WASP-77Ab. From these, we determine the atmospheric gas volume mixing ratio constraints on both H2O and CO (9.5$\times 10^{-5}$ - 1.5$\times 10^{-4}$ and 1.2$\times 10^{-4}$ - 2.6$\times 10^{-4}$, respectively). From these bounded constraints, we are able to derive the atmospheric C/H (0.35$^{+0.17}_{-0.10}$ $\times$ Solar) and O/H (0.32 $^{+0.12}_{-0.08}$ $\times$ Solar) abundances and the corresponding atmospheric carbon-to-oxygen ratio (C/O=0.59$\pm$0.08; the solar value is 0.55). The sub-solar (C+O)/H (0.33$^{+0.13}_{-0.09}$ $\times$ Solar) is suggestive of a metal-depleted atmosphere relative to what is expected for Jovian-like planets while the near solar value of C/O rules out the disk-free migration/C-rich atmosphere scenario.

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arXiv2021

Five carbon- and nitrogen-bearing species in a hot giant planet's atmosphere

The atmospheres of gaseous giant exoplanets orbiting close to their parent stars (hot Jupiters) have been probed for nearly two decades. They allow us to investigate the chemical and physical properties of planetary atmospheres under extreme irradiation conditions. Previous observations of hot Jupiters as they transit in front of their host stars have revealed the frequent presence of water vapour and carbon monoxide in their atmospheres; this has been studied in terms of scaled solar composition under the usual assumption of chemical equilibrium. Both molecules as well as hydrogen cyanide were found in the atmosphere of HD 209458b, a well studied hot Jupiter (with equilibrium temperature around 1,500 kelvin), whereas ammonia was tentatively detected there and subsequently refuted. Here we report observations of HD 209458b that indicate the presence of water (H2O), carbon monoxide (CO), hydrogen cyanide (HCN), methane (CH4), ammonia (NH3) and acetylene (C2H2), with statistical significance of 5.3 to 9.9 standard deviations per molecule. Atmospheric models in radiative and chemical equilibrium that account for the detected species indicate a carbon-rich chemistry with a carbon-to-oxygen ratio close to or greater than 1, higher than the solar value (0.55). According to existing models relating the atmospheric chemistry to planet formation and migration scenarios, this would suggest that HD 209458b formed far from its present location and subsequently migrated inwards. Other hot Jupiters may also show a richer chemistry than has been previously found, which would bring into question the frequently made assumption that they have solar-like and oxygen-rich compositions.

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arXiv2020

Coupled Day-Night Models of Exoplanetary Atmospheres

We provide a new framework to model the day side and night side atmospheres of irradiated exoplanets using 1-D radiative transfer by incorporating a self-consistent heat flux carried by circulation currents (winds) between the two sides. The advantages of our model are its physical motivation and computational efficiency, which allows for an exploration of a wide range of atmospheric parameters. We use this forward model to explore the day and night side atmosphere of WASP-76~b, an ultra-hot Jupiter which shows evidence for a thermal inversion and Fe condensation, and WASP-43~b, comparing our model against high precision phase curves and general circulation models. We are able to closely match the observations as well as prior theoretical predictions for both of these planets with our model. We also model a range of hot Jupiters with equilibrium temperatures between 1000-3000~K and reproduce the observed trend that the day-night temperature contrast increases with equilibrium temperature up to $\sim$2500~K beyond which the dissociation of H$_2$ becomes significant and the relative temperature difference declines.

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arXiv2020

Seeing above the Clouds with High Resolution Spectroscopy

In the last decade ground based high resolution Doppler spectroscopy (HRS) has detected numerous species in transiting and non-transiting hot Jupiters, and is ideally placed for atmospheric characterisation of warm Neptunes and super Earths. Many of these cooler and smaller exoplanets have shown cloudy atmospheres from low resolution near infrared observations, making constraints on chemical species difficult. We investigate how HRS can improve on these given its sensitivity to spectral line cores which probe higher altitudes above the clouds. We model transmission spectra for the warm Neptune GJ~3470~b and determine the detectability of H$_2$O with the CARMENES, GIANO and SPIRou spectrographs. We also model a grid of spectra for another warm Neptune, GJ~436~b, over a range of cloud-top pressure and H$_2$O abundance. We show H$_2$O is detectable for both planets with modest observational time and that the high H$_2$O abundance-high cloud deck degeneracy is broken with HRS. However, meaningful constraints on abundance and cloud-top pressure are only possible in the high metallicity scenario. We also show that detections of CH$_4$ and NH$_3$ are possible from cloudy models of GJ~436~b. Lastly, we show how the presence of the Earth's transmission spectrum hinders the detection of H$_2$O for the most cloudy scenarios given that telluric absorption overlaps with the strongest H$_2$O features. The constraints possible with HRS on the molecular species can be used for compositional analysis and to study the chemical diversity of such planets in the future.

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