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Siegfried Dietrich

Publications and source records attributed to Siegfried Dietrich.

26 records · Page 2Linked to original sources
arXiv2011

Trapping colloids near chemical stripes via critical Casimir forces

We study theoretically and experimentally the solvent-mediated critical Casimir force acting on colloidal particles immersed in a binary liquid mixture of water and 2,6-lutidine and close to substrates which are chemically patterned with periodically alternating stripes of antagonistic adsorption preferences. These patterns are experimentally realized via microcontact printing. Upon approaching the critical demixing point of the solvent, normal and lateral critical Casimir forces generate laterally confining effective potentials for the colloids. We analyze in detail the rich behavior of the spherical colloids close to such substrates. For all patterned substrates we investigated, our measurements of these effective potentials agree with the corresponding theoretical predictions. Since both the directions and the strengths of the critical Casimir forces can be tuned by minute temperature changes, this provides a new mechanism for controlling colloids as model systems, opening encouraging perspectives for applications.

cond-mat.soft↗
arXiv2010

Critical Casimir forces and adsorption profiles in the presence of a chemically structured substrate

Motivated by recent experiments with confined binary liquid mixtures near demixing, we study the universal critical properties of a system, which belongs to the Ising universality class, in the film geometry. We employ periodic boundary conditions in the two lateral directions and fixed boundary conditions on the two confining surfaces, such that one of them has a spatially homogeneous adsorption preference while the other one exhibits a laterally alternating adsorption preference, resembling locally a single chemical step. By means of Monte Carlo simulations of an improved Hamiltonian, so that the leading scaling corrections are suppressed, numerical integration, and finite-size scaling analysis we determine the critical Casimir force and its universal scaling function for various values of the aspect ratio of the film. In the limit of a vanishing aspect ratio the critical Casimir force of this system reduces to the mean value of the critical Casimir force for laterally homogeneous ++ and +- boundary conditions, corresponding to the surface spins on the two surfaces being fixed to equal and opposite values, respectively. We show that the universal scaling function of the critical Casimir force for small but finite aspect ratios displays a linear dependence on the aspect ratio which is solely due to the presence of the lateral inhomogeneity. We also analyze the order-parameter profiles at criticality and their universal scaling function which allows us to probe theoretical predictions and to compare with experimental data.

cond-mat.stat-mech↗
arXiv2008

Force balance of particles trapped at fluid interfaces

We study the effective forces acting between colloidal particles trapped at a fluid interface which itself is exposed to a pressure field. To this end we apply what we call the ``force approach'', which relies solely on the condition of mechanical equilibrium and turns to be in a certain sense less restrictive than the more frequently used ``energy approach'', which is based on the minimization of a free energy functional. The main goal is to elucidate the advantages and disadvantages of the force approach as compared to the energy approach. First, we derive a general stress-tensor formulation of the forces at the interface and work out a useful analogy with 2D electrostatics in the particular case of small deformations of the interface relative to its flat configuration. We apply this analogy to compute the asymptotic decay of the effective force between particles trapped at a fluid interface, extending the validity of previous results. Second, we address the case of deformations of a non-flat interface. We compute the deformation of a spherical droplet due to the electric field of a charged particle trapped at its surface and conclude that the interparticle capillary force is unlikely to explain certain recent experimental observations. Finally we discuss the application to a generally curved interface and show as an illustrative example that a nonspherical particle deposited on an interface forming a minimal surface is pulled to regions of larger curvature.

cond-mat.soft↗
arXiv2008

Theory of capillary-induced interactions beyond the superposition approximation

Within a general theoretical framework we study the effective, deformation-induced interaction between two colloidal particles trapped at a fluid interface in the regime of small deformations. In many studies, this interaction has been computed with the ansatz that the actual interface configuration for the pair is given by the linear superposition of the interface deformations around the single particles. Here we assess the validity of this approach and compute the leading term of the effective interaction for large interparticle separation beyond this so-called superposition approximation. As an application, we consider the experimentally relevant case of interface deformations owing to the electrostatic field emanating from charged colloidal particles. In mechanical isolation, i.e., if the net force acting on the total system consisting of the particles plus the interface vanishes, the superposition approximation is actually invalid. The effective capillary interaction is governed by contributions beyond this approximation and turns out to be attractive. For sufficiently small surface charges on the colloids, such that linearization is strictly valid, and at asymptotically large separations, the effective interaction does not overcome the direct electrostatic repulsion between the colloidal particles.

cond-mat.soft↗
arXiv2005

Capillary-induced interactions between colloids at an interface

Within a general framework we study the effective, deformation-induced interaction between two colloids trapped at a fluid interface. As an application, we consider the interface deformation owing to the electrostatic field of charged colloids. The effective interaction is attractive and overcomes the direct electrostatic repulsion at large separations if the system is not mechanically isolated. Otherwise, a net attraction seems possible only for large enough colloidal charges.

cond-mat.soft↗
arXiv2005

Local orientations of fluctuating fluid interfaces

Thermal fluctuations cause the local normal vectors of fluid interfaces to deviate from the vertical direction defined by the flat mean interface position. This leads to a nonzero mean value of the corresponding polar tilt angle which renders a characterization of the thermal state of an interface. Based on the concept of an effective interface Hamiltonian we determine the variances of the local interface position and of its lateral derivatives. This leads to the probability distribution functions for the metric of the interface and for the tilt angle which allows us to calculate its mean value and its mean square deviation. We compare the temperature dependences of these quantities as predicted by the simple capillary wave model, by an improved phenomenological model, and by the microscopic effective interface Hamiltonian derived from density functional theory. The mean tilt angle discriminates clearly between these theoretical approaches and emphasizes the importance of the variation of the surface tension at small wave lengths. Also the tilt angle two-point correlation function is determined which renders an additional structural characterization of interfacial fluctuations. Various experimental accesses to measure the local orientational fluctuations are discussed.

cond-mat.soft↗
arXiv2003

Wall adsorption of a colloidal particle moving in a quiescent partially wetting fluid

In thermal equilibrium, a colloidal particle between two parallel plates immersed in a fluid which partially wets both the particle and the plates, is attracted by the walls. However, if the particle moves parallel to the plates, a hydrodynamic lift force away from the plates arises in the limit of low Reynolds number. We study theoretically the competition of these two effects and identify the range of velocity in which the velocity may serve as a parameter controlling the adsorption in microflows.

cond-mat.soft↗