arXiv subjects

Sijia Zhang

Publications and source records attributed to Sijia Zhang.

12 recordsLinked to original sources

arXiv2026

Superconducting Hydride Mg2RhH6 Experimentally Achieved at Lower Pressure

Although tremendous progress has been made in recent years in the field of polyhydride superconductors, the realization of high critical temperature superconductivity still relies on formidable high pressures. Searching for superconducting hydrides at lower pressures is of particular importance. Here we report the first experimental synthesis of the Mg2RhH6, which achieves superconductivity under a significantly reduced pressure of 30 GPa. The synthesis of Mg2RhH6 proceeds via a two step process (1) preparation of the Mg2RhH5 precursor containing hydrogen atoms stabilized by covalent bonds, followed by (2) hydrogen supplementation resulting in the filling of electrons into anti bonding orbitals above 30 GPa, which was accompanied by the structural transition from RhH5 square pyramid to RhH6 octahedron. Superconductivity is achieved at 30 GPa with a Tc of 24 K, which is further enhanced to 29 K at 53 GPa, evidenced by a sharp drop of resistivity to zero and characteristic suppression of Tc under applied magnetic fields. Our experiments prove the Mg2RhH6 superconductor to be thermodynamically stable above 30 GPa, making it the first case exhibiting a Tc of approximately 30 K at a readily accessible pressure. This study pioneers a highly promising pathway for the rational design and discovery of high temperature superconductors within phonon mediated BCS framework.

cond-mat.supr-con↗

arXiv2026

Superconductivity of Tellurium Polyhydride with Tc above 90K

We report experimental diacovery of superconductivity (SC) in tellurium (Te) polyhydride. The compound was synthesized at high pressure and high temperature conditions using a diamond anvil cell combined with a laser heating system. Subsequent in situ transport measurements at high pressures, performed as a function of temperature and applied magnetic field, revealed a superconducting transition with a critical temperature Tc about 91 K at 263 GPa. The superconducting phase is assigned to TeH4 with characterized face shared TeH12 cage forming quasi molecular H2 units based on synchrotron x-ray diffraction experiments. Analysis of the SC behavior at magnetic fields yielded a Ginzburg Landau (GL) coherence length of approximately 54 angstroms. Tellurium polyhydride thus becomes another chalcogen polyhydride superconductor in addition to the landmark discovery of the first polyhydride high Tc SC SH3.

cond-mat.supr-con↗

arXiv2026

Outstanding TC Enhancement in 5d-3d Y2NiIrO6 by Compression

Understanding and predicting the properties of 5d compounds critically depend on the identification of the superexchange interactions from which their magnetism emerges. The study of pressure effects on double perovskite Y2NiIrO6 (YNIO) provides deep insight toward this goal. At ambient pressure, YNIO is a ferrimagnetic insulator with the Ir4+-5d Jeff = 1/2 Mott-insulating state. Under physical pressure up to 17 GPa, the compound exhibits concurrent compression on Ni/Ir-O bond lengths and Ni-O-Ir bond angles, leading to an increase of the Curie temperature from 192 to 243 K. On the contrary, external pressure increases distanced Ir-Ir interaction and in turn induces magnetic frustration in Sr2IrO4/Sr3Ir2O7 due to the extended 5d orbitals. In YNIO, the rock-salt ordered Ni-Ir naturally blocks extended superexchange beyond the nearest neighbor, and in turn suppresses such magnetic frustration. Moreover, the orthogonal Ni eg-Ir t2g pathway in YNIO is robust under lattice distortion, while the superexchange is weakened by bond bending in La2NiMnO6 with a similar half-filed eg-t2g configuration. Our findings establish a framework for elucidating the mechanism of 5d-3d superexchange and guide bond-engineered magnetism in iridate-related systems.

cond-mat.str-el↗

arXiv2025

Scalable Mixed-Integer Optimization with Neural Constraints via Dual Decomposition

Embedding deep neural networks (NNs) into mixed-integer programs (MIPs) is attractive for decision making with learned constraints, yet state-of-the-art monolithic linearisations blow up in size and quickly become intractable. In this paper, we introduce a novel dual-decomposition framework that relaxes the single coupling equality u=x with an augmented Lagrange multiplier and splits the problem into a vanilla MIP and a constrained NN block. Each part is tackled by the solver that suits it best-branch and cut for the MIP subproblem, first-order optimisation for the NN subproblem-so the model remains modular, the number of integer variables never grows with network depth, and the per-iteration cost scales only linearly with the NN size. On the public \textsc{SurrogateLIB} benchmark, our method proves \textbf{scalable}, \textbf{modular}, and \textbf{adaptable}: it runs $120\times$ faster than an exact Big-M formulation on the largest test case; the NN sub-solver can be swapped from a log-barrier interior step to a projected-gradient routine with no code changes and identical objective value; and swapping the MLP for an LSTM backbone still completes the full optimisation in 47s without any bespoke adaptation.

math.OC↗

arXiv2025

CLCR: Contrastive Learning-based Constraint Reordering for Efficient MILP Solving

Constraint ordering plays a critical role in the efficiency of Mixed-Integer Linear Programming (MILP) solvers, particularly for large-scale problems where poorly ordered constraints trigger increased LP iterations and suboptimal search trajectories. This paper introduces CLCR (Contrastive Learning-based Constraint Reordering), a novel framework that systematically optimizes constraint ordering to accelerate MILP solving. CLCR first clusters constraints based on their structural patterns and then employs contrastive learning with a pointer network to optimize their sequence, preserving problem equivalence while improving solver efficiency. Experiments on benchmarks show CLCR reduces solving time by 30% and LP iterations by 25% on average, without sacrificing solution accuracy. This work demonstrates the potential of data-driven constraint ordering to enhance optimization models, offering a new paradigm for bridging mathematical programming with machine learning.

cs.LG↗

arXiv2025

Beyond Local Selection: Global Cut Selection for Enhanced Mixed-Integer Programming

In mixed-integer programming (MIP) solvers, cutting planes are essential for Branch-and-Cut (B&C) algorithms as they reduce the search space and accelerate the solving process. Traditional methods rely on hard-coded heuristics for cut plane selection but fail to leverage problem-specific structural features. Recent machine learning approaches use neural networks for cut selection but focus narrowly on the efficiency of single-node within the B&C algorithm, without considering the broader contextual information. To address this, we propose Global Cut Selection (GCS), which uses a bipartite graph to represent the search tree and combines graph neural networks with reinforcement learning to develop cut selection strategies. Unlike prior methods, GCS applies cutting planes across all nodes, incorporating richer contextual information. Experiments show GCS significantly improves solving efficiency for synthetic and large-scale real-world MIPs compared to traditional and learning-based methods.

cs.AI↗

arXiv2023

Superconductivity above 30 K achieved in dense scandium

Superconductivity is one of most intriguing quantum phenomena, and the quest for elemental superconductors with high critical temperature (Tc) is of great scientific significance due to their relatively simple material composition and the underlying mechanism. Here we report the experimental discovery of densely compressed scandium (Sc) becoming the first elemental superconductor with Tc breaking into 30 K range, which is comparable to the Tc values of the classic La-Ba-Cu-O or LaFeAsO superconductors. Our results show that Tconset of Sc increases from ~3 K at around 43 GPa to ~32 K at about 283 GPa (Tczero ~ 31 K), which is well above liquid neon temperature. Interestingly measured Tc shows no sign of saturation up to the maximum pressure achieved in our experiments, indicating that Tc might be even higher upon further compression.

cond-mat.supr-con↗

arXiv2023

Superconductivity above 70 K observed in lutetium polyhydrides

The binary polyhydrides of heavy rare earth lutetium that shares a similar valence electron configuration to lanthanum have been experimentally discovered to be superconductive. The lutetium polyhydrides were successfully synthesized at high pressure and high temperature conditions using a diamond anvil cell in combinations with the in-situ high pressure laser heating technique. The resistance measurements as a function of temperature were performed at the same pressure of synthesis in order to study the transitions of superconductivity (SC). The superconducting transition with a maximum onset temperature (Tc) 71 K was observed at pressure of 218 GPa in the experiments. The Tc decreased to 65 K when pressure was at 181 GPa. From the evolution of SC at applied magnetic fields, the upper critical field at zero temperature μ0Hc2(0) was obtained to be ~36 Tesla. The in-situ high pressure X-ray diffraction experiments imply that the high Tc SC should arise from the Lu4H23 phase with Pm-3n symmetry that forms a new type of hydrogen cage framework different from those reported for previous light rare earth polyhydride superconductors.

cond-mat.supr-con↗

arXiv2021

Crystal structure and properties of iron-based spin-chain compound Ba9Fe3Se15

We report the synthesis of a new quasi one-dimensional (1D) iron selenide. Ba9Fe3Se15 was synthesized at high temperature and high pressure of 5.5 GPa and systematically studied via structural, magnetic and transport measurements at ambient and at high-pressures. Ba9Fe3Se15 crystallizes in a monoclinic structure and consists of face-sharing FeSe6 octahedral chains along the c axis. At ambient pressure it exhibits an insulating behavior with a band gap ~460 meV and undergoes a ferrimagnet-like phase transition at 14 K. Under high pressure, a complete metallization occurs at ~29 GPa, which is accompanied by a spin state crossover from high spin (HS) state to low spin (LS) state. The LS appears for pressures P >36 GPa.

cond-mat.supr-con↗

arXiv2020

A New Quasi One-Dimensional Compound Ba3TiTe5 and Superconductivity Induced by Pressure

We report systematical studies of a new quasi-one-dimensional (1D) compound Ba3TiTe5 and the high-pressure induced superconductivity therein. Ba3TiTe5 was synthesized at high pressure and high temperature. It crystallizes into a hexagonal structure (P63/mcm), which consists of infinite face-sharing octahedral TiTe6 chains and Te chains along the c axis, exhibiting a strong 1D characteristic structure. The first-principles calculations demonstrate that Ba3TiTe5 is a well-defined 1D conductor and thus, it can be considered a starting point to explore the exotic physics induced by pressure via enhancing the interchain hopping to move the 1D conductor to a high dimensional metal. For Ba3TiTe5, high-pressure techniques were employed to study the emerging physics dependent on interchain hopping, such as the Umklapp scattering effect, spin/charge density wave (SDW/CDW), superconductivity and non-Fermi Liquid behavior. Finally, a complete phase diagram was plotted. The superconductivity emerges from 8.8 GPa, near which the Umklapp gap is mostly suppressed. Tc is enhanced and reaches the maximum ~6 K at about 36.7 GPa, where the spin/charge density wave (SDW/CDW) is completely suppressed, and a non-Fermi Liquid behavior appears. Our results suggest that the appearance of superconductivity is associated with the fluctuation due to the suppression of Umklapp gap and the enhancement of Tc is related with the fluctuation of the SDW/CDW.

cond-mat.supr-con↗

arXiv2019

Anomalous behavior of the quasi-one-dimensional quantum material Na$_{2}$OsO$_{4}$ at high pressure

Na$_{2}$OsO$_{4}$ is an unusual quantum material that, in contrast to the common 5${d}^{2}$ oxides with spins = 1, owns a magnetically silent ground state with spin = 0 and a band gap at Fermi level attributed to a distortion in the OsO$_{6}$ octahedral sites. In this semiconductor, our low-temperature electrical transport measurements indicate an anomaly at 6.3 K with a power-law behavior inclining through the semiconductor-to-metal transition observed at 23 GPa. Even more peculiarly, we discover that before this transition, the material becomes more insulating instead of merely turning into a metal according to the conventional wisdom. To investigate the underlying mechanisms, we applied experimental and theoretical methods to examine the electronic and crystal structures comprehensively, and conclude that the enhanced insulating state at high pressure originates from the enlarged distortion of the OsO$_{6}$. It is such a distortion that widens the band gap and decreases the electron occupancy in Os's ${t}_{2g}$ orbital through an interplay of the lattice, charge, and orbital in the material, which is responsible for the changes observed in our experiments.

cond-mat.mtrl-sci↗

arXiv2011

Pressure-induced isostructural phase transition and correlation of FeAs coordination with the superconducting properties of 111-type Na1-xFeAs

The effect of pressure on the crystalline structure and superconducting transition temperature (Tc) of the 111-type Na1-xFeAs system using in situ high pressure synchrotron x-ray powder diffraction and diamond anvil cell techniques is studied. A pressure-induced tetragonal to tetragonal isostructural phase transition was found. The systematic evolution of the FeAs4 tetrahedron as a function of pressure based on Rietveld refinements on the powder x-ray diffraction patterns was obtained. The non-monotonic Tc(P) behavior of Na1-xFeAs is found to correlate with the anomalies of the distance between the anion (As) and the iron layer as well as the bond angle between As-Fe-As for the two tetragonal phases. This behavior provides the key structural information in understanding the origin of the pressure dependence of Tc for 111-type iron pnictide superconductors. A pressure-induced structural phase transition is also observed at 20 GPa.

cond-mat.supr-con↗