arXiv subjects

Silvia Pandolfi

Publications and source records attributed to Silvia Pandolfi.

11 recordsLinked to original sources

arXiv2026

Spin crossover in FeO under shock compression

FeO (w\"ustite), which exhibits complex electronic and structural properties with increasing pressure and temperature, is a key mineralogical phase for understanding deep planetary interiors. However, direct measurements of its spin state at high-pressure and temperature remain challenging in static compression experiments. Here, we employ laser-driven shock compression to extend the FeO principal Hugoniot up to $\sim$900 GPa and perform in situ X-ray diffraction and X-ray emission spectroscopy up to 250 GPa, probing FeO's crystal structure and spin state. We demonstrate a continuous spin crossover of iron in FeO over a broad pressure range, with the high-spin state persisting beyond Earth's core-mantle boundary (CMB) conditions. These observations provide new experimental constraints on iron spin state at extreme conditions essential for geophysical models of (exo)planetary interiors.

cond-mat.mtrl-sci↗

arXiv2024

Radiation and Heat Transport in Divergent Shock-Bubble Interactions

Shock-bubble interactions (SBI) are important across a wide range of physical systems. In inertial confinement fusion, interactions between laser-driven shocks and micro-voids in both ablators and foam targets generate instabilities that are a major obstacle in achieving ignition. Experiments imaging the collapse of such voids at high energy densities (HED) are constrained by spatial and temporal resolution, making simulations a vital tool in understanding these systems. In this study, we benchmark several radiation and thermal transport models in the xRAGE hydrodynamic code against experimental images of a collapsing mesoscale void during the passage of a 300 GPa shock. We also quantitatively examine the role of transport physics in the evolution of the SBI. This allows us to understand the dynamics of the interaction at timescales shorter than experimental imaging framerates. We find that all radiation models examined reproduce empirical shock velocities within experimental error. Radiation transport is found to reduce shock pressures by providing an additional energy pathway in the ablation region, but this effect is small ($\sim$1\% of total shock pressure). Employing a flux-limited Spitzer model for heat conduction, we find that flux limiters between 0.03 and 0.10 produce agreement with experimental velocities, suggesting that the system is well-within the Spitzer regime. Higher heat conduction is found to lower temperatures in the ablated plasma and to prevent secondary shocks at the ablation front, resulting in weaker primary shocks. Finally, we confirm that the SBI-driven instabilities observed in the HED regime are baroclinically driven, as in the low energy case.

physics.plasm-ph↗

arXiv2024

X-ray Microscopy and Talbot Imaging with the Matter in Extreme Conditions X-ray Imager at LCLS

The last decade has shown the great potential that X-ray Free Electron Lasers (FEL) have to study High Energy Density (HED) physics. Experiments at FELs have made significant breakthroughs in Shock Physics and Dynamic Diffraction, Dense Plasma Physics and Warm Dense Matter Science, using techniques such as isochoric heating, inelastic scattering, small angle scattering and X-ray diffraction. In addition, and complementary to these techniques, the coherent properties of the FEL beam can be used to image HED samples with high fidelity. We present new imaging diagnostics and techniques developed at the Matter in Extreme Conditions (MEC) instrument at Linac Coherent Light Source (LCLS) over the last few years. We show results in Phase Contrast Imaging geometry, where the X-ray beam propagates from the target to a camera revealing its phase, as well as in Direct Imaging geometry, where a real image of the sample plane is produced in the camera with a spatial resolution down to 200 nm. Last, we show an implementation of the Talbot Imaging method allowing both X-ray phase and intensity measurements change introduced by a target with sub-micron resolution.

physics.ins-det↗

arXiv2024

Phase transition kinetics revealed by in situ X-ray diffraction in laser-heated dynamic diamond anvil cells

We report on a novel approach to dynamic compression of materials that bridges the gap between previous static- and dynamic- compression techniques, allowing to explore a wide range of pathways in the pressure-temperature space. By combining a dynamic-diamond anvil cell setup with double-sided laser-heating and in situ X-ray diffraction, we are able to perform dynamic compression at high temperature and characterize structural transitions with unprecedented time resolution. Using this method, we investigate the $γ-ε$ phase transition of iron under dynamic compression for the first time, reaching compression rates of hundreds of GPa/s and temperatures of 2000 K. Our results demonstrate a distinct response of the $γ-ε$ and $α-ε$ transitions to the high compression rates achieved. These findings open up new avenues to study tailored dynamic compression pathways in the pressure-temperature space and highlight the potential of this platform to capture kinetic effects in a diamond anvil cell.

cond-mat.mtrl-sci↗

arXiv2021

Multi-scale characterization of hexagonal Si-4H: a hierarchical nanostructured material

In this work we present a detailed structural characterization of Si-4H, a newly discovered bulk form of hexagonal silicon (Si) with potential optoelectronic applications. Using multi-scale imaging, we reveal a hierarchical structure in the morphology of Si-4H obtained from high-pressure synthesis. We demonstrate discrete structural units, platelets, at an intermediate length-scale between the bulk pellets synthesized at high pressures and the flake-like crystallites inferred in previous studies. Direct observation of the platelets reveals their 2D structure, with planar faces spanning hundreds of nanometers to a few micrometers and thicknesses of only tens of nanometers. We separated and dispersed small packets of quasi-single platelets, which enabled us to analyze the crystalline domains within each grain. With this view, we demonstrate that Si-4H platelets represent the smallest crystalline structural units, which can bend at the single-domain level. Our characterization of the quasi-2D, flexible platelets of hexagonal Si-4H and proof of concept that the platelets can be dispersed and manipulated quite simply demonstrate opportunities to design novel optoelectronic and solar devices.

cond-mat.mtrl-sci↗

arXiv2021

Maximum likelihood estimation of hidden Markov models for continuous longitudinal data with missing responses and dropout

We propose an inferential approach for maximum likelihood estimation of the hidden Markov models for continuous responses. We extend to the case of longitudinal observations the finite mixture model of multivariate Gaussian distributions with Missing At Random (MAR) outcomes, also accounting for possible dropout. The resulting hidden Markov model accounts for different types of missing pattern: (i) partially missing outcomes at a given time occasion; (ii) completely missing outcomes at a given time occasion (intermittent pattern); (iii) dropout before the end of the period of observation (monotone pattern). The MAR assumption is formulated to deal with the first two types of missingness, while to account for informative dropout we assume an extra absorbing state. Maximum likelihood estimation of the model parameters is based on an extended Expectation-Maximization algorithm relying on suitable recursions. The proposal is illustrated by a Monte Carlo simulation study and an application based on historical data on primary biliary cholangitis.

stat.ME↗

arXiv2015

LMest: an R package for latent Markov models for categorical longitudinal data

Latent Markov (LM) models represent an important class of models for the analysis of longitudinal data (Bartolucci et. al., 2013), especially when response variables are categorical. These models have a great potential of application for the analysis of social, medical, and behavioral data as well as in other disciplines. We propose the R package LMest, which is tailored to deal with these types of model. In particular, we consider a general framework for extended LM models by including individual covariates and by formulating a mixed approach to take into account additional dependence structures in the data. Such extensions lead to a very flexible class of models, which allows us to fit different types of longitudinal data. Model parameters are estimated through the expectation-maximization algorithm, based on the forward-backward recursions, which is implemented in the main functions of the package. The package also allows us to perform local and global decoding and to obtain standard errors for the parameter estimates. We illustrate its use and the most important features on the basis of examples involving applications in health and criminology.

stat.CO↗

arXiv2014

Item selection by Latent Class-based methods

The evaluation of nursing homes is usually based on the administration of questionnaires made of a large number of polytomous items. In such a context, the Latent Class (LC) model represents a useful tool for clustering subjects in homogenous groups corresponding to different degrees of impairment of the health conditions. It is known that the performance of model-based clustering and the accuracy of the choice of the number of latent classes may be affected by the presence of irrelevant or noise variables. In this paper, we show the application of an item selection algorithm to real data collected within a project, named ULISSE, on the quality-of-life of elderly patients hosted in italian nursing homes. This algorithm, which is closely related to that proposed by Dean and Raftery in 2010, is aimed at finding the subset of items which provides the best clustering according to the Bayesian Information Criterion. At the same time, it allows us to select the optimal number of latent classes. Given the complexity of the ULISSE study, we perform a validation of the results by means of a sensitivity analysis to different specifications of the initial subset of items and of a resampling procedure.

stat.AP↗

arXiv2014

Three-step estimation of latent Markov models with covariates

We propose a modified version of the three-step estimation method for the latent class model with covariates, which may be used to estimate latent Markov models for longitudinal data. The three-step estimation approach we propose is based on a preliminary clustering of sample units on the basis of the time specific responses only. This approach represents an useful estimation tool when a large number of response variables are observed at each time occasion. In such a context, full maximum likelihood estimation, which is typically based on the Expectation-Maximization algorithm, may have some drawbacks, essentially due to the presence of many local maxima of the model likelihood. Moreover, the EM algorithm may be particularly slow to converge, and may become unstable with complex LM models. We prove the consistency of the proposed three-step estimator when the number of response variables tends to infinity. We also show the results of a simulation study aimed at evaluating the performance of the proposed alternative approach with respect to the full likelihood method. We finally illustrate an application to a real dataset on the health status of elderly people hosted in Italian nursing homes.

stat.ME↗

arXiv2012

A comparison of some criteria for states selection in the latent Markov model for longitudinal data

We compare different selection criteria to choose the number of latent states of a multivariate latent Markov model for longitudinal data. This model is based on an underlying Markov chain to represent the evolution of a latent characteristic of a group of individuals over time. Then, the response variables observed at the different occasions are assumed to be conditionally independent given this chain. Maximum likelihood of the model is carried out through an Expectation-Maximization algorithm based on forward-backward recursions which are well known in the hidden Markov literature for time series. The selection criteria we consider in our comparison are based on penalized versions of the maximum log-likelihood or on the posterior probabilities of belonging to each latent state, that is the conditional probability of the latent state given the observed data. A Monte Carlo simulation study shows that the indices referred to the log-likelihood based information criteria perform in general better with respect to those referred to the classification based criteria. This is due to the fact that the latter tend to underestimate the true number of latent states, especially in the univariate case.

stat.ME↗

arXiv2011

Bayesian inference for a class of latent Markov models for categorical longitudinal data

We propose a Bayesian inference approach for a class of latent Markov models. These models are widely used for the analysis of longitudinal categorical data, when the interest is in studying the evolution of an individual unobservable characteristic. We consider, in particular, the basic latent Markov, which does not account for individual covariates, and its version that includes such covariates in the measurement model. The proposed inferential approach is based on a system of priors formulated on a transformation of the initial and transition probabilities of the latent Markov chain. This system of priors is equivalent to one based on Dirichlet distributions. In order to draw samples from the joint posterior distribution of the parameters and the number of latent states, we implement a reversible jump algorithm which alternates moves of Metropolis-Hastings type with moves of split/combine and birth/death types. The proposed approach is illustrated through two applications based on longitudinal datasets.

stat.ME↗