arXiv subjects

Silvia Protopapa

Publications and source records attributed to Silvia Protopapa.

At least 19 recordsLinked to original sources

arXiv2026

Constraints on the Atmospheric Composition of 2002 XV$_{93}$ from JWST Spectroscopy

The recent detection of an atmosphere surrounding the trans-Neptunian object (TNO) 2002 XV$_{93}$ from stellar occultation measurements has challenged the longstanding view that only the largest TNOs can sustain an atmosphere. Atmospheric refraction modeling of the occultation light curves indicated a surface pressure of 100$-$200 nbar, despite 2002 XV$_{93}$'s relatively small size (~510 km in diameter) and weak surface gravity. Together with the detection of methane fluorescence on Makemake, this result suggests that tenuous atmospheres may be more common among TNOs than previously thought. We report JWST/NIRSpec observations acquired before and after the 2024 stellar occultation measurements, obtained with the PRISM and medium-resolution gratings at resolving powers of ~100 and ~1000, respectively. We detect no statistically significant emission features attributed to methane or carbon monoxide gas. By comparing the higher spectral resolution data with synthetic fluorescence models, we report upper limits for the methane and carbon monoxide surface partial pressures of $(3-10)\times10^{-6}$ and $(50-300)\times10^{-6}$ nbar, respectively, substantially below the atmospheric pressure inferred from the occultation measurements. Additionally, we report no evidence of an extended source of either methane gas or refractory material. Our results indicate that the atmospheric interpretation of the occultation measurements may require either a composition dominated by volatile species other than methane and carbon monoxide, with nitrogen and argon as possible candidates, or a methane-dominated atmosphere confined near the surface with a steeply decreasing vertical density profile.

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arXiv2026

JWST reveals anomalously enhanced methane outgassing from below Chiron's water ice and carbon dioxide bearing surface

Centaurs are inward-scattered Kuiper belt objects, with some exhibiting comet-like activity. The physical mechanisms powering this activity remain poorly understood, with carbon monoxide (CO) sublimation or the crystallization of amorphous water ice commonly invoked as the dominant drivers. Here we present high-resolution JWST spectroscopy of 2060 Chiron, one of the largest known Centaurs, revealing methane and carbon dioxide gas emission with distinct coma spatial morphologies and production rates of $Q_{\rm CH_4}=(1.55\pm0.04)\times10^{27}$ molecules s$^{-1}$ and $Q_{\rm CO_2}=(1.01\pm0.06)\times10^{26}$ molecules s$^{-1}$. The surface spectrum displays spectral signatures attributed to water ice, carbon dioxide, CO, and refractory organic-rich material, while lacking detectable methane ice absorption bands. These findings suggest that carbon dioxide production is sustained by direct surface sublimation, whereas methane originates from the subsurface. The absence of measurable CO emission despite the presence of solid-state CO implies that any surviving primordial CO reservoir remains thermally inaccessible at greater depth below the methane, while irradiation-produced near-surface CO may be inefficiently released from the surface matrix. This inferred volatile stratification may result from long-term thermal evolution or potentially partial differentiation. Chiron differs markedly from other active small bodies, where CO production typically dominates over methane, indicating that Centaur activity may be driven by a broader range of volatile and thermophysical processes than predicted by canonical models.

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arXiv2025

JWST/NIRSpec Observations of Salacia-Actaea and Máni: Exploring Population-level Trends among Water-ice-rich Kuiper Belt Objects

We present observations of the midsized Kuiper Belt objects (KBOs) Salacia$-$Actaea and Máni, obtained with the Near-Infrared Spectrograph on JWST. The satellite Actaea was fully blended with Salacia at the spatial resolution of the integral field unit, and we extracted the combined spectrum. The 0.7$-$5.1 $μ$m reflectance spectra of Salacia$-$Actaea and Máni display prominent water-ice absorption bands at 1.5, 2, 3, and 4$-$5 $μ$m. The $ν_{3}$ fundamental vibrational band of carbon dioxide ice at 4.25 $μ$m is present in both spectra. From a quantitative band-depth analysis of the entire current JWST spectroscopic sample of water-ice-rich KBOs, we find strong evidence for a positive covariance between relative water-ice abundance and size, which may indicate the emergent impacts of internal differentiation and cryovolcanic production of surface water ice on midsized KBOs. A detailed look at the distribution of 2 and 3 $μ$m band depths suggests additional sources of variability, such as different water-ice grain sizes. In addition, we report an apparent transition in the carbon dioxide band depth at object diameters of roughly 300$-$500 km, with larger objects showing systematically weaker absorptions, although selection effects within the sample do not allow us to confidently distinguish between a size-dependent phenomenon and a correlation with dynamical class.

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arXiv2025

Rotational Dynamics in Pulsational Pair-Instability Supernovae: Implications for Mass-Loss and Transient Events

Pulsational pair-instability supernovae (PPISNe) are transient events occurring in progenitor stars with helium cores of approximately 32-65 solar masses, where rapid electron-positron pair production induces pressure loss, collapse, and pulsations driving episodic mass loss. The number, strength, and duration of these pulses can lead to shell collisions that produce shock-powered transients, potentially explaining some of the most luminous events, such as superluminous supernovae, and other rare transients. Rapid progenitor rotation lowers the PPISN mass threshold and influences the dynamics, energetics, and chemical composition of PPISN-driven pulses. In this study, we computed 1D evolutionary models of massive, rotating PPISN progenitor stars with zero-age main-sequence masses of 85-140 solar masses and solar metallicity and 10% solar metallicity. Our analysis reveals strong correlations between PPISN ejected mass and total energy as well as between ejected mass and peak ejected shell velocity. Additionally, moderate correlations indicate that higher initial PPISN progenitor mass leads to greater mass ejection and energy release, while negative correlations show that rapid rotation appears to reduce mass ejection and kinetic energy of the shells. Subsequent pulses lead to hydrogen-poor, carbon- and oxygen-enriched ejected shells, indicating the effect of rotationally-induced chemical mixing in PPISN-driven episodic mass loss with implications for their transients. We model the light curve and synthetic spectra that arise from the collision of two H-poor shells for one of our models using the radiation transport code SuperLite. We find that shock-heated H-poor PPISN shell collisions from rapidly rotating progenitors can lead to moderately luminous H-poor transients that share some similarities with observed SLSN-I events.

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arXiv2025

Optical and Near-Infrared Spectroscopy of the Outbursting Comet 12P/Pons-Brooks

We present optical and near-infrared (NIR) observations of the outbursting, Halley-type comet 12P/Pons-Brooks. Three NIR spectra were obtained during two outbursts in October and November 2023, with the 3-meter Infrared Telescope Facility and the Palomar 200-inch Telescope, respectively. The NIR spectra exhibited absorption features at 1.5 and 2.0 $μ$m, consistent with the diagnostic absorption bands of water ice, superimposed on a red dust-scattering continuum. We find that the absorption bands and the red continuum can be well explained by micrometer-sized crystalline ice at 140--170 K, along with sub-micrometer-sized refractory grains (e.g., amorphous carbon). In addition, an optical spectrum was obtained with the Lijiang 2.4-meter Telescope during the November 2023 outburst, which exhibited the emission bands of gaseous CN, C$_3$, C$_2$ and NH$_2$. The C$_3$/CN and C$_2$/CN ratios suggest that 12P/Pons-Brooks was ''typical'' in C$_3$ abundance but somewhat depleted in C$_2$. The specific kinetic energy of the 2023 November outburst is estimated to be $\sim8\times10^3$ J kg$^{-1}$, suggesting a likely triggering mechanism similar to 332P/Ikeya--Murakami and 17P/Holmes, i.e., the crystallization of amorphous water ice. A refractory-to-ice ratio of $\sim$1.7--3.2 is derived from the total mass loss of dust and gas, aligning with the lower-end estimates for 67P/Churyumov-Gerasimenko and 1P/Halley. This suggests either a less evolved nucleus or an outburst region enriched in icy materials relative to the bulk nucleus.

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arXiv2025

A Large Outburst, Coma Asymmetries, and the Color of Comet 243P/NEAT

Water ice is a fundamental building material of comets and other bodies in the outer solar system. Yet, the properties of cometary water ice are challenging to study, due to its volatility and the typical distances at which comets are observed. Cometary outbursts, impulsive mass-loss events that can liberate large amounts of material, offer opportunities to directly observe and characterize cometary water ice. We present a study of comet 243P/NEAT, instigated by a $-3$ mag outburst that occurred in December 2018. Optical images and a 251-day lightcurve were examined to characterize the outburst and the comet's quiescent activity. Variations in the quiescent lightcurve appear to be dominated by coma asymmetries, rather than changing activity levels as the comet approached and receded from the Sun. Furthermore, the lightcurve shows evidence for 1 to 2 additional small outbursts ($-0.3$ mag) occurring in September 2018. The large December 2018 outburst likely ejected water ice grains, yet no signatures of ice were found in color photometry, a color map, nor a near-infrared spectrum. We discuss possible dynamical and thermal reasons for this non-detection. In this context, we examined the comae of comets 103P/Hartley 2 and C/2013 US$_{10}$ (Catalina), and show that a one-to-one mapping between continuum color and the presence of water ice cannot be supported. We also discuss possible causes for the large outburst, and find that there is an apparent grouping in the kinetic energy per mass estimates for the outbursts of 5 comets.

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arXiv2025

Laboratory Investigation of CO2-Driven Enhancement of Radiolytic H2O2 on Europa and Other Icy Moons

Observations of Europa's leading hemisphere reveal elevated H2O2 in the warmer, low latitude chaos terrains compared to the colder, polar regions. This distribution disagrees with prior laboratory radiolysis studies of pure water ice, which show higher H2O2 yields at colder temperatures. The regions with higher peroxide abundance, Tara and Powys Regiones, also present increased amounts of CO2, possibly sourced from Europa's interior. To investigate whether CO2 influences radiolysis of water ice to boost H2O2 production, we irradiated water ice doped with varying amounts of CO2 with 10 keV electrons at 70 and 100 K. Our results indicate that CO2, even in trace amounts (< 3%), significantly enhances H2O2 yields at temperatures relevant to Europa. We discuss the mechanisms by which CO2 boosts peroxide synthesis and quantify H2O2 creation and destruction cross sections and G-values across different CO2 concentrations. These findings provide a plausible explanation for the perplexing H2O2 distribution on Europa and has implications for understanding peroxide on other icy bodies such as Ganymede and Charon, where it has been detected alongside CO2.

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arXiv2025

JWST Reveals Spectral Tracers of Recent Surface Modification on Europa

Europa has been modified by a variety of geologic processes, exposing internally-derived materials that are heavily irradiated by charged particles trapped in Jupiter's magnetosphere. Prior spectral analysis of H2O ice on Europa relied on low signal-to-noise data at wavelengths >2.5 microns, limiting assessment of a 3.1 micron Fresnel peak that is diagnostic of exposed crystalline ice. We report new measurements of H2O ice spectral features using high signal-to-noise data collected by the NIRSpec spectrograph (1.48 - 5.35 microns) on the James Webb Space Telescope. These data reveal a narrow 3.1 micron crystalline H2O ice Fresnel peak, which is primarily located at southern latitudes in Tara and Powys Regiones. Our analysis indicates that crystalline ice exposed in these low-latitude regiones is likely sustained by ongoing thermal (re)crystallization outpacing charged particle amorphization of the top 10 microns of Europa's regolith over short timescales (<15 days). We also measured H2O ice features centered near 1.5 microns, 1.65 microns, and 2.0 microns, and a broad 3.6 micron H2O continuum peak, which are all stronger at northern latitudes, in contrast to the 3.1 micron Fresnel peak identified at southern latitudes. These results support the hypothesis that H2O ice in Europa's regolith is vertically stratified, with amorphous ice grains dominating its exposed surface, except in Tara and Powys Regiones. We also find that a previously detected 4.38 micron 13O2 feature is present almost exclusively at southern latitudes in Tara and Powys Regiones, likely derived from an internal source of carbon-bearing material.

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arXiv2024

Observations of Uranus at High Phase Angle as Seen by New Horizons

We present flux measurements of Uranus observed at phase angles of 43.9°, 44.0°, and 52.4° by the Multispectral Visible Imaging Camera (MVIC) on the New Horizons spacecraft during 2023, 2010, and 2019, respectively. New Horizons imaged Uranus at a distance of about 24-70 AU (2023) in four color filters, with bandpasses of 400-550 nm, 540-700 nm, 780-975 nm, and 860-910 nm. High-phase-angle observations are of interest for studying the energy balance of Uranus, constraining the atmospheric scattering behavior, and understanding the planet as an analog for ice giant exoplanets. The new observations from New Horizons provide access to a wider wavelength range and different season compared to previous observations from both Voyager spacecraft. We performed aperture photometry on the New Horizons observations of Uranus to obtain its brightness in each photometric band. The photometry suggests that Uranus may be darker than predicted by a Lambertian phase curve in the Blue and Red filters. Comparison to simultaneous low-phase Hubble WFC3 and ground-based community-led observations indicates a lack of large-scale features at full-phase that would introduce variation in the rotational light curve. The New Horizons reflectance in the Blue (492 nm) and Red (624 nm) filters does not exhibit statistically significant variation and is consistent with the expected error bars. These results place new constraints on the atmospheric model of Uranus and its reflectivity. The observations are analogous to those from future exoplanet direct-imaging missions, which will capture unresolved images of exoplanets at partial phases. These results will serve as a "ground-truth" with which to interpret exo-ice giant data.

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arXiv2024

Prominent mid-infrared excess of the dwarf planet (136472) Makemake discovered by JWST/MIRI indicates ongoing activity

We report on the discovery of a very prominent mid-infrared (18-25 μm) excess associated with the trans-Neptunian dwarf planet (136472) Makemake. The excess, detected by the MIRI instrument of the James Webb Space Telescope, along with previous measurements from the Spitzer and Herschel space telescopes, indicates the occurrence of temperatures of about 150 K, much higher than what solid surfaces at Makemake's heliocentric distance could reach by solar irradiation. We identify two potential explanations: a continuously visible, currently active region, powered by subsurface upwelling and possibly cryovolcanic activity, covering <1% of Makemake's surface, or an as yet undetected ring containing very small carbonaceous dust grains, which have not been seen before in trans-Neptunian or Centaur rings. Both scenarios point to unprecedented phenomena among trans-Neptunian objects and could greatly impact our understanding of these distant worlds.

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arXiv2024

Moderate D/H Ratios in Methane Ice on Eris and Makemake as Evidence of Hydrothermal or Metamorphic Processes in Their Interiors: Geochemical Analysis

Dwarf planets Eris and Makemake have surfaces bearing methane ice of unknown origin. D/H ratios were recently determined from James Webb Space Telescope (JWST) observations of Eris and Makemake, giving us new clues to decipher the origin of methane. Here, we develop geochemical models to test if the origin of methane could be primordial, derived from CO$_2$ or CO ("abiotic"), or sourced by organics ("thermogenic"). We find that primordial methane is inconsistent with the observational data, whereas both abiotic and thermogenic methane can have D/H ratios that overlap the observed ranges. This suggests that Eris and Makemake either never acquired a significant amount of methane during their formation, or their original inventories were removed and then replaced by a source of internally produced methane. Because producing abiotic or thermogenic methane likely requires temperatures above ~150°C, we infer that Eris and Makemake have rocky cores that underwent substantial radiogenic heating. Their cores may still be warm/hot enough to make methane. This heating could have driven hydrothermal circulation at the bottom of an ice-covered ocean to generate abiotic methane, and/or metamorphic reactions involving accreted organic matter could have occurred in response to heating in the deeper interior, generating thermogenic methane. Additional analyses of relevant thermal evolution model results and theoretical predictions of the D/H ratio of methane in the solar nebula support our findings of elevated subsurface temperatures and an apparent lack of primordial methane on Eris and Makemake. It remains an open question whether their D/H ratios may have evolved subsequent to methane outgassing. Recommendations are given for future activities to further test proposed scenarios of abiotic and thermogenic methane production on Eris and Makemake, and to explore these worlds up close.

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arXiv2024

Revealing Callisto's carbon-rich surface and CO2 atmosphere with JWST

We analyzed spectral cubes of Callisto's leading and trailing hemispheres, collected with the NIRSpec Integrated Field Unit (G395H) on the James Webb Space Telescope. These spatially resolved data show strong 4.25-micron absorption bands resulting from solid-state 12CO2, with the strongest spectral features at low latitudes near the center of its trailing hemisphere, consistent with radiolytic production spurred by magnetospheric plasma interacting with native H2O mixed with carbonaceous compounds. We detected CO2 rovibrational emission lines between 4.2 and 4.3 microns over both hemispheres, confirming the global presence of CO2 gas in Callisto's tenuous atmosphere. These results represent the first detection of CO2 gas over Callisto's trailing side. The distribution of CO2 gas is offset from the subsolar region on either hemisphere, suggesting that sputtering, radiolysis, and geologic processes help sustain Callisto's atmosphere. We detected a 4.38-micron absorption band that likely results from solid-state 13CO2. A prominent 4.57-micron absorption band that might result from CN-bearing organics is present and significantly stronger on Callisto's leading hemisphere, unlike 12CO2, suggesting these two spectral features are spatially anti-associated. The distribution of the 4.57-micron band is more consistent with a native origin and/or accumulation of dust from Jupiter's irregular satellites. Other, more subtle absorption features could result from CH-bearing organics, CO, carbonyl sulfide (OCS), and Na-bearing minerals. These results highlight the need for preparatory laboratory work and improved surface-atmosphere interaction models to better understand carbon chemistry on the icy Galilean moons before the arrival of NASA's Europa Clipper and ESA's JUICE spacecraft.

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arXiv2022

Large-scale cryovolcanic resurfacing on Pluto

The New Horizons spacecraft returned images and compositional data showing that terrains on Pluto span a variety of ages, ranging from relatively ancient, heavily cratered areas to very young surfaces with few-to-no impact craters. One of the regions with very few impact craters is dominated by enormous rises with hummocky flanks. Similar features do not exist anywhere else in the imaged solar system. Here we analyze the geomorphology and composition of the features and conclude this region was resurfaced by cryovolcanic processes, of a type and scale so far unique to Pluto. Creation of this terrain requires multiple eruption sites and a large volume of material (>104 km^3) to form what we propose are multiple, several-km-high domes, some of which merge to form more complex planforms. The existence of these massive features suggests Pluto's interior structure and evolution allows for either enhanced retention of heat or more heat overall than was anticipated before New Horizons, which permitted mobilization of water-ice-rich materials late in Pluto's history.

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arXiv2022

A LOOK at Outbursts of Comet C/2014 UN$_{271}$ (Bernardinelli-Bernstein) Near 20 au

Cometary activity may be driven by ices with very low sublimation temperatures, such as carbon monoxide ice, which can sublimate at distances well beyond 20 au. This point is emphasized by the discovery of Oort cloud comet C/2014 UN$_{271}$ (Bernardinelli-Bernstein), and its observed activity out to $\sim$26 au. Through observations of this comet's optical brightness and behavior, we can potentially discern the drivers of activity in the outer solar system. We present a study of the activity of comet Bernardinelli-Bernstein with broad-band optical photometry taken at 19-20 au from the Sun (2021 June to 2022 February) as part of the LCO Outbursting Objects Key (LOOK) Project. Our analysis shows that the comet's optical brightness during this period was initially dominated by cometary outbursts, stochastic events that ejected $\sim10^7$ to $\sim10^8$ kg of material on short (< 1 day) timescales. We present evidence for three such outbursts occurring in 2021 June and September. The nominal nuclear volumes excavated by these events are similar to the 10-100 m pit-shaped voids on the surfaces of short-period comet nuclei, as imaged by spacecraft. Two out of three Oort cloud comets observed at large pre-perihelion distances exhibit outburst behavior near 20 au, suggesting such events may be common in this population. In addition, quiescent CO-driven activity may account for the brightness of the comet in 2022 January to February, but that variations in the cometary active area (i.e., the amount of sublimating ice) with heliocentric distance are also possible.

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arXiv2022

The LCO Outbursting Objects Key Project: Overview and Year 1 Status

The LCO Outbursting Objects Key (LOOK) Project uses the telescopes of the Las Cumbres Observatory (LCO) Network to: (1) to systematically monitor a sample of Dynamically New Comets over the whole sky, and (2) use alerts from existing sky surveys to rapidly respond to and characterize detected outburst activity in all small bodies. The data gathered on outbursts helps to characterize each outburst's evolution with time, assess the frequency and magnitude distribution of outbursts in general, and contributes to the understanding of outburst processes and volatile distribution in the Solar System. The LOOK Project exploits the synergy between current and future wide-field surveys such as ZTF, PanSTARRS, and LSST as well as rapid-response telescope networks such as LCO, and serves as an excellent testbed for what will be needed the much larger number of objects coming from Rubin Observatory. We will describe the LOOK Project goals, the planning and target selection (including the use of NEOexchange as a Target and Observation Manager or "TOM"), and results from the first phase of observations, including the detection of activity and outbursts on the giant comet C/2014 UN271 (Bernardinelli-Bernstein) and the discovery and follow-up of outbursts on comets. Within these outburst discoveries, we present a high cadence of 7P/Pons-Winnecke with days, a large outburst on 57P/duToit-Neujmin-Delporte, and evidence that comet P/2020 X1 (ATLAS) was in outburst when discovered.

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arXiv2021

Evaluation of short-term temporal evolution of Pluto's surface composition from 2014-2017 with APO/TripleSpec

In this work we present the results of a spectral observing campaign of Pluto to search for temporal changes in surface composition on 1- to 3-year timescales. Near-infrared spectra of Pluto were obtained from June 2014 to August 2017 with the TripleSpec cross-dispersed spectrograph at the Apache Point Observatory's 3.5-meter Astrophysical Research Consortium (ARC) telescope. Observations were requested in order to obtain spectra of approximately the same sub-observer hemisphere $\sim$14 months apart, thus removing the effects of viewing geometry and rotation phase. Comparison of the CH$_4$ (methane) band areas and band center shifts between each component of these "matched pairs" revealed a surface in transition. Band areas for the 1.66 and 1.72 $μ$m CH$_4$ absorption features exhibited a $>$5-$σ$ increase between 2014-06-17 and 2015-08-19, corresponding to a sub-observer hemisphere centered at $\sim$280$^{\circ}$E, with the latter date only 1 month after the New Horizons flyby of Pluto. The majority of matched pairs were obtained of the anti-Charon hemisphere, home to the bright, volatile-rich Sputnik Planitia, and did not present statistically significant changes in CH$_4$ band areas. CH$_4$ band center shifts, which provide information on the mixing state of CH$_4$ and N$_2$ in solid solution, were calculated between components of each matched pair, with no significant band shifts detected. The favored explanation for these combined results is the sublimation of more-volatile N$_2$ from the northern latitudes of Pluto in the lead-up to northern hemisphere summer solstice in 2029, leading to an increase in CH$_4$ concentration.

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arXiv2021

New Investigations of Dark Floored Pits in the Volatile Ice of Sputnik Planitia on Pluto

Sputnik Planitia, Pluto's gigantic ice glacier, hosts numerous scientific mysteries, including the presence of thousands of elongated pit structures. We examine various attributes of these pit structures in New Horizons data sets, revealing their length, aspect ratios, and orientation properties; we also study their interior reflectivities, colors, and compositions, and compare these attributes to some other relevant regions on Pluto. We then comment on origin mechanisms of the pits and also the fate of the missing volatiles represented by the pits on Sputnik Planitia.

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arXiv2021

Non-detection of water-ice grains in the coma of comet 46P/Wirtanen and implications for hyperactivity

Hyperactive comets have high water production rates, with inferred sublimation areas of order the surface area of the nucleus. Comets 46P/Wirtanen and 103P/Hartley 2 are two examples of this cometary class. Based on observations of comet Hartley 2 by the Deep Impact spacecraft, hyperactivity appears to be caused by the ejection of water-ice grains and/or water-ice rich chunks of nucleus into the coma. These materials increase the sublimating surface area, and yield high water production rates. The historic close approach of comet Wirtanen to Earth in 2018 afforded an opportunity to test Hartley 2 style hyperactivity in a second Jupiter-family comet. We present high spatial resolution, near-infrared spectroscopy of the inner coma of Wirtanen. No evidence for the 1.5- or 2.0-$μ$m water-ice absorption bands is found in six 0.8-2.5 $μ$m spectra taken around perihelion and closest approach to Earth. In addition, the strong 3.0-$μ$m water-ice absorption band is absent in a 2.0-5.3 $μ$m spectrum taken near perihelion. Using spectroscopic and sublimation lifetime models we set constraints on the physical properties of the ice grains in the coma, assuming they are responsible for the comet's hyperactivity. We rule out pure water-ice grains of any size, given their long lifetime. Instead, the hyperactivity of the nucleus and lack of water-ice absorption features in our spectra can be explained either by icy grains on the order of 1 $μ$m in size with a small amount of low albedo dust (greater than 0.5% by volume), or large chunks containing significant amounts of water ice.

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