arXiv subjects

Silvio R. Salinas

Publications and source records attributed to Silvio R. Salinas.

7 recordsLinked to original sources

arXiv2026

Gibbs variational principles and Boltzmann irreversible theorem

We analyze the Gibbs variational principles associated with the probability distributions of (i) an isolated system and (ii) a system at constant temperature. We give an example of using the Gibbs inequality to obtain the free energy and analyze the phase diagram of an Ising model with competing interactions. We also review the Boltzmann irreversible theorem, and show how it is connected to the Gibbs variational principles. This connection is established by using the Kolmogorov equation for the evolution of the probability distribution, which predicts a monotonic increase of entropy for an isolated system, and a decrease of the free energy for a system in contact with a thermal reservoir.

cond-mat.stat-mech↗

arXiv2023

Hard-needle elastomer in one spatial dimension

We perform exact Statistical Mechanics calculations for a system of elongated objects (hard needles) that are restricted to translate along a line and rotate within a plane, and that interact via both excluded-volume steric repulsion and harmonic elastic forces between neighbors. This system represents a one-dimensional model of a liquid crystal elastomer, and has a zero-tension critical point that we describe using the transfer-matrix method. In the absence of elastic interactions, we build on previous results by Kantor and Kardar, and find that the nematic order parameter $Q$ decays linearly with tension $σ$. In the presence of elastic interactions, the system exhibits a standard universal scaling form, with $Q / |σ|$ being a function of the rescaled elastic energy constant $k / |σ|^Δ$, where $Δ$ is a critical exponent equal to $2$ for this model. At zero tension, simple scaling arguments lead to the asymptotic behavior $Q \sim k^{1/Δ}$, which does not depend on the equilibrium distance of the springs in this model.

cond-mat.stat-mech↗

arXiv2017

Uniaxial and biaxial structures in the elastic Maier-Saupe model

We perform statistical mechanics calculations to analyze the global phase diagram of a fully-connected version of a Maier-Saupe-Zwanzig lattice model with the inclusion of couplings to an elastic strain field. We point out the presence of uniaxial and biaxial nematic structures, depending on temperature $T$ and on the applied stress $σ$. Under uniaxial extensive tension, applied stress favors uniaxial orientation, and we obtain a first-order boundary, along which there is a coexistence of two uniaxial paranematic phases, and which ends at a simple critical point. Under uniaxial compressive tension, stress favors biaxial orientation; for small values of the coupling parameters, the first-order boundary ends at a tricritical point, beyond which there is a continuous transition between a paranematic and a biaxially ordered structure. For some representative choices of the model parameters, we obtain a number of analytic results, including the location of critical and tricritical points and the line of stability of the biaxial phase.

cond-mat.soft↗

arXiv2015

Bethe-lattice calculations for the phase diagram of a two-state Janus gas

We use a simple lattice statistical model to analyze the effects of directional interactions on the phase diagram of a fluid of two-state Janus particles. The problem is formulated in terms of nonlinear recursion relations along the branches of a Cayley tree. Directional interactions are taken into account by the geometry of this graph. Physical solutions on the Bethe lattice (the deep interior of a Cayley tree) come from the analysis of the attractors of the recursion relations. We investigate a number of situations, depending on the concentrations of the types of Janus particles and the parameters of the potential, and make contact with results from recent numerical simulations.

cond-mat.soft↗

arXiv2015

Recovering the equivalence of ensembles

The equivalence of thermodynamic results in the canonical and the microcanonical ensembles has been questioned in some calculations for spin models with long-range interactions. We show that these claims of inequivalence are related to an inadequate definition of the independent (density) variables in the microcanonical ensemble. We illustrate this point with the example of a simple spin-1 ideal paramagnet, and then revisit the original calculations of Barré, Mukamel, and Ruffo, for a mean-field spin-1 Blume-Capel model. If the microcanonical ensemble is defined in terms of adequate density variables, we show that there is no disagreement with the calculations in the usual canonical ensemble (with fixed thermodynamic field variables).

cond-mat.stat-mech↗

arXiv2006

A thermodynamical fiber bundle model for the fracture of disordered materials

We investigate a disordered version of a thermodynamic fiber bundle model proposed by Selinger, Wang, Gelbart, and Ben-Shaul a few years ago. For simple forms of disorder, the model is analytically tractable and displays some new features. At either constant stress or constant strain, there is a non monotonic increase of the fraction of broken fibers as a function of temperature. Moreover, the same values of some macroscopic quantities as stress and strain may correspond to different microscopic cofigurations, which can be essential for determining the thermal activation time of the fracture. We argue that different microscopic states may be characterized by an experimentally accessible analog of the Edwards-Anderson parameter. At zero temperature, we recover the behavior of the irreversible fiber bundle model.

cond-mat.stat-mech↗

arXiv1999

Metamagnets in uniform and random fields

We study a two-sublattice Ising metamagnet with nearest and next-nearest-neighbor interactions, in both uniform and random fields. Using a mean-field approximation, we show that the qualitative features of the phase diagrams are significantly dependent on the distribution of the random fields. In particular, for a Gaussian distribution of random fields, the behavior of the model is qualitatively similar to a dilute Ising metamagnet in a uniform field.

cond-mat.dis-nn↗