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Simón Paiva-Ortega

Publications and source records attributed to Simón Paiva-Ortega.

2 recordsLinked to original sources

Bottom-Up Design of Quantum Optical Experiments Using Discrete Generative Models

Designing quantum optical experiments requires searching over discrete circuit topologies and continuous parameters, often with multiple realizations of the same target state. Graph-based methods commonly address this problem by optimizing a dense graph and pruning it toward a single circuit. We introduce \texttt{Grinch}, a bottom-up reward-driven generative framework that learns to sample optical graphs directly from fidelity-based rewards without relying on a pre-existing training dataset. We demonstrate the framework on multipartite entangled states, graph and cluster states, and nonlocal photonic-gate targets, obtaining multiple high-fidelity optical graphs. We identify asymptotic solutions for states that cannot be generated exactly by graphs, as well as nonlocal Toffoli gate constructions requiring two ancillas. Our work presents hardware-constraint objectives, which lead to alternative constructions of CNOT and Toffoli gates when connections between ancilla nodes are restricted. These findings illustrate a reward-driven approach to quantum optical inverse design, exploring alternative circuit topologies while directly incorporating connectivity constraints into the search process.

quant-ph↗

Detection Defines Dephasing in Two-Dimensional Electronic Spectroscopy of Materials: Coherent Field Emission versus Incoherent Population Observables

The homogeneous spectral linewidth associated with light-matter interactions is a fundamental descriptor of the optical properties of materials, governed by the quantum dynamics of the condensed-matter system. We discuss here that the homogeneous linewidth measured by means of two-dimensional electronic spectroscopy depends not only on the intrinsic microscopic dynamics of the material, but also on the observable through which those dynamics are projected onto the measurement. In this Perspective, we develop a unified framework showing that identical microscopic dynamics can yield different experimentally inferred dephasing times because different detection operators project different sectors of the nonequilibrium dynamics. For coherent emitted-field measurements, the observed linewidth largely retains its conventional connection to the optical coherence time $T_2$. By contrast, in population-detected modalities such as photoluminescence, photocurrent, and other action-detected two-dimensional spectroscopies, the apparent linewidth can additionally encode excited-state population redistribution dynamics, leading naturally to an effective coherence time $T_{2,\mathrm{eff}}$. Using a coupled-mode model propagated under a common Liouvillian, we show that identical microscopic dynamics yield distinct apparent dephasing times when projected onto coherent-emission and population-derived observables. The detection observable is therefore not merely part of the experimental implementation, but determines what dynamical information remains experimentally observable and how homogeneous linewidths should be interpreted as materials descriptors.

physics.chem-ph↗