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Simon Weis

Publications and source records attributed to Simon Weis.

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Skinny emulsions take on granular matter

Our understanding of the structural features of foams and emulsions has advanced significantly over the last 20 years. However, with a search for "super-stable" liquid dispersions, foam and emulsion science employs increasingly complex formulations which create solid-like visco-elastic layers at the bubble/drop surfaces. These lead to elastic, adhesive and frictional forces between bubbles/drops, impacting strongly how they pack and deform against each other, asking for an adaptation of the currently available structural description. The possibility to modify systematically the interfacial properties makes these dispersions ideal systems for the exploration of soft granular materials with complex interactions. We present here a first systematic analysis of the structural features of such a system using a model silicone emulsion containing millimetre-sized polyethylene glycol drops (PEG). Solid-like drop surfaces are obtained by polymeric cross-linking reactions at the PEG-silicone interface. Using a novel droplet-micromanipulator, we highlight the presence of elastic, adhesive and frictional interactions between two drops. We then provide for the first time a full tomographic analysis of the structural features of these emulsions. An in-depth analysis of the angle of repose, local volume fraction distributions, pair correlation functions and the drop deformations for different skin formulations allow us to put in evidence the striking difference with "ordinary" emulsions having fluid-like drop surfaces. While strong analogies with frictional hard-sphere systems can be drawn, these systems display a set of unique features due to the high deformability of the drops which await systematic exploration.

cond-mat.soft

Structural similarity between dry and wet sphere packings

The mechanical properties of granular materials change significantly in the presence of a wetting liquid which creates capillary bridges between the particles. Here we demonstrate, using X-ray tomographies of dry and wet sphere packings, that this change in mechanical properties is not accompanied by structural differences between the packings. We characterize the latter by the average numbers of contacts of each sphere $\langle Z\rangle$ and the shape isotropy $\langle \beta_0^{2,0} \rangle$ of the Voronoi cells of the particles. Additionally, we show that the number of liquid bridges per sphere $\langle B\rangle$ is approximately equal to $\langle Z\rangle + 2$, independent of the volume fraction of the packing. These findings will be helpful in guiding the development of both particle-based models and continuum mechanical descriptions of wet granular matter.

cond-mat.soft

Charging changes contact composition in binary sphere packings

Equal volume mixtures of small and large polytetrafluorethylene (PTFE) spheres are shaken in an atmosphere of controlled humidity which allows to also control their tribo-charging. We find that the contact numbers are charge-dependent: as the charge density of the beads increases, the number of same-type contacts decreases and the number of opposite-type contacts increases. This change is not caused by a global segregation of the sample. Hence, tribo-charging can be a way to tune the local composition of a granular material.

cond-mat.soft

Pomelo, a tool for computing Generic Set Voronoi Diagrams of Aspherical Particles of Arbitrary Shape

We describe the development of a new software tool, called "Pomelo", for the calculation of Set Voronoi diagrams. Voronoi diagrams are a spatial partition of the space around the particles into separate Voronoi cells, e.g. applicable to granular materials. A generalization of the conventional Voronoi diagram for points or monodisperse spheres is the Set Voronoi diagram, also known as navigational map or tessellation by zone of influence. In this construction, a Set Voronoi cell contains the volume that is closer to the surface of one particle than to the surface of any other particle. This is required for aspherical or polydisperse systems. Pomelo is designed to be easy to use and as generic as possible. It directly supports common particle shapes and offers a generic mode, which allows to deal with any type of particles that can be described mathematically. Pomelo can create output in different standard formats, which allows direct visualization and further processing. Finally, we describe three applications of the Set Voronoi code in granular and soft matter physics, namely the problem of packings of ellipsoidal particles with varying degrees of particle-particle friction, mechanical stable packings of tetrahedra and a model for liquid crystal systems of particles with shapes reminiscent of pears

physics.data-an

Analyzing X-Ray tomographies of granular packings

Starting from three-dimensional volume data of a granular packing, as e.g. obtained by X-ray Computed Tomography, we discuss methods to first detect the individual particles in the sample and then analyze their properties. This analysis includes the pair correlation function, the volume and shape of the Voronoi cells and the number and type of contacts formed between individual particles. We mainly focus on packings of monodisperse spheres, but we will also comment on other monoschematic particles such as ellipsoids and tetrahedra. This paper is accompanied by a package of free software containing all programs (including source code) and an example three-dimensional dataset which allows the reader to reproduce and modify all examples given.

physics.data-an

Local analysis of the history dependence in tetrahedra packings

The mechanical properties of a granular sample depend frequently on the way the packing was prepared. However, is not well understood which properties of the packing store this information. Here we present an X-ray tomography study of three pairs of tetrahedra packings prepared with three different tapping protocols. The packings in each pair differs in the number of mechanical constraints $C$ imposed on the particles by their contacts, while their bulk volume fraction $\phi_{global}$ is approximately the same. We decompose $C$ into the contributions of the three different contact types possible between tetrahedra -- face-to-face (F2F), edge-to-face (E2F), and point contacts -- which each fix a different amount of constraints. We then perform a local analysis of the contact distribution by grouping the particles together according to their individual volume fraction $\phi_{local}$ computed from a Voronoi tessellation. We find that in samples which have been tapped sufficiently long the number of F2F contacts becomes an universal function of $\phi_{local}$. In contrast the number of E2F and point contacts varies with the applied tapping protocol. Moreover, we find that the anisotropy of the shape of the Voronoi cells depends on the tapping protocol. This behavior differs from spheres and ellipsoids and posses a significant constraint for any mean-field approach to tetrahedra packings.

cond-mat.soft