arXiv subjects

Simone Fratini

Publications and source records attributed to Simone Fratini.

23 records · Page 2Linked to original sources

arXiv2014

Phenomenological model for charge dynamics and optical response of disordered systems: application to organic semiconductors

We provide a phenomenological formula which describes the low-frequency optical absorption of charge carriers in disordered systems with localization. This allows to extract, from experimental data on the optical conductivity, the relevant microscopic parameters determining the transport properties, such as the carrier localization length and the elastic and inelastic scattering times. This general formula is tested and applied here to organic semiconductors, where dynamical molecular disorder is known to play a key role in the transport properties. The present treatment captures the basic ideas underlying the recently proposed transient localization scenario for charge transport, extending it from the d.c. mobility to the frequency domain. When applied to existing optical measurements in rubrene FETs, our analysis provides quantitative evidence for the transient localization phenomenon. Possible applications to other disordered electronic systems are briefly discussed.

cond-mat.mtrl-sci↗

arXiv2013

Emergent Heavy Fermion Behavior at the Wigner-Mott Transition

We study charge ordering driven by Coulomb interactions on triangular lattices relevant to the Wigner-Mott transition in two dimensions. Dynamical mean-field theory reveals the pinball liquid phase, a charge ordered metallic phase containing quasi-localized (pins) coexisting with itinerant (balls) electrons. Based on an effective periodic Anderson model for this phase, we find an antiferromagnetic Kondo coupling between pins and balls and strong quasiparticle renormalization. Non-Fermi liquid behavior can occur in such charge ordered systems due to spin-flip scattering of itinerant electrons off the pins in analogy with heavy fermion compounds.

cond-mat.str-el↗

arXiv2013

Tailoring the molecular structure to suppress extrinsic disorder in organic transistors

In organic field-effect transistors, the structure of the constituent molecules can be tailored to minimize the disorder experienced by charge carriers. Experiments on two perylene derivatives show that disorder can be suppressed by attaching longer core substituents - thereby reducing potential fluctuations in the transistor channel and increasing the mobility at low temperature - without altering the intrinsic transport properties.

cond-mat.mtrl-sci↗

arXiv2012

Charge order at the frontier between the molecular and solid states in Ba3NaRu2O9

We show that the valence electrons of Ba3NaRu2O9, which has a quasi-molecular structure, completely crystallize below 210 K. Using an extended Hubbard model, we show that the charge ordering instability results from long-range Coulomb interactions. However, orbital ordering, metal-metal bonding and formation of a partial spin gap enforce the magnitude of the charge separation. The striped charge order and frustrated hcp lattice of Ru2O9 dimers lead to competition with a quasi-degenerate charge-melted phase under photo-excitation at low temperature. Our results establish a broad class of simple metal oxides as models for emergent phenomena at the border between the molecular and solid states.

cond-mat.str-el↗

arXiv2010

Quantum critical behavior of electrons at the edge of charge order

We consider quantum critical points (QCP) in which quantum fluctuations associated with charge rather than magnetic order induce unconventional metallic properties. Based on finite-T calculations on a two-dimensional extended Hubbard model we show how the coherence scale T* characteristic of Fermi liquid behavior of the homogeneous metal vanishes at the onset of charge order. A strong effective mass enhancement reminiscent of heavy fermion behavior indicates the possible destruction of quasiparticles at the QCP. Experimental probes on quarter-filled layered organic materials are proposed for unveiling the behavior of electrons across the quantum critical region.

cond-mat.str-el↗