arXiv subjects

Sohrab Khalifeh

Publications and source records attributed to Sohrab Khalifeh.

3 recordsLinked to original sources

arXiv2017

Effect of Anodizing Parameters on Corrosion Resistance of Coated Purified Magnesium

Magnesium and its alloys are being considered for biodegradable biomaterials. However, high and uncontrollable corrosion rates have limited the use of magnesium and its alloys in biological environments. In this research, high purified magnesium (HP-Mg) was coated with stearic acid in order to improve the corrosion resistance of magnesium. Anodization and immersion in stearic acid were used to form a hydrophobic layer on magnesium substrate. Different DC voltages, times, electrolytes, and temperatures were tested. Electrochemical impedance spectroscopy and potentiodynamic polarization were used to measure the corrosion rates of the coated HP-Mg. The results showed that optimum corrosion resistance occurred for specimens anodized at +4 volts for 4 minutes at 70°C in borate benzoate. The corrosion resistance was temporarily enhanced by 1000x.

cond-mat.mtrl-sci↗

arXiv2017

Super-Hydrophobic Stearic Acid Layer Formed on Anodized High Purified Magnesium for Improving Corrosion Resistance of Biodegradable Implants

Magnesium and its alloys are ideal candidates for biodegradable implants. However, they can dissolve too rapidly in the human body for most applications. In this research, high purified magnesium (HP-Mg) was coated with stearic acid in order to slow the corrosion rate of magnesium in simulated body fluid at 37°C. HP-Mg was anodized to form an oxide/hydroxide layer, then it was immersed in a stearic acid solution. Electrochemical impedance spectroscopy and potentiodynamic polarization were used to estimate the corrosion rate of HP-Mg specimens. The results confirm that the hydrophobic coating can temporarily decrease the corrosion rate of HP-Mg by 1000x.

cond-mat.mtrl-sci↗

arXiv2017

Influence of Heat Treatment on the Corrosion Behavior of Purified Magnesium and AZ31 Alloy

Magnesium and its alloys are ideal for biodegradable implants due to their biocompatibility and their low-stress shielding. However, they can corrode too rapidly in the biological environment. The objective of this research was to develop heat treatments to slow the corrosion of high purified magnesium and AZ31 alloy in simulated body fluid at 37°C. Heat treatments were performed at different temperatures and times. Hydrogen evolution, weight loss, PDP, and EIS methods were used to measure the corrosion rates. Results show that heat treating can increase the corrosion resistance of HP-Mg by 2x and AZ31 by 10x.

cond-mat.mtrl-sci↗