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Sougata Halder

Publications and source records attributed to Sougata Halder.

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Vector detection of AC magnetic fields by Nitrogen-Vacancy centers of single orientation in diamond

Nitrogen-Vacancy (NV) centers in diamond have useful properties for detecting both AC and DC magnetic fields with high sensitivity at nano-scale resolution. Vector detection of AC magnetic fields can be achieved by using NV centers having three different orientations. Here, we propose a method to achieve this by using NV centers of single orientation. In this method, a static magnetic field is applied perpendicular to the NV axis, leading to strong mixing of the $m_{s}=-1$ and $1$ electron spin states. As a result, all three electron spin transitions of the triplet ground state have non-zero dipole moments, with each transition coupling to a single component of the magnetic field. This can be used to measure both strength and orientation of the applied AC field. To validate the technique, we perform a proof of principle experiment using a subset of ensemble NV centers in diamond, all having the same orientation.

quant-ph

Insights into the Structure and Ion Transport of Pectin-[BMIM][PF$_6$] Electrolytes

We investigate the effect of pectin on the structure and ion transport properties of the room-temperature ionic liquid electrolyte 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) using molecular dynamics simulations. We find that pectin induces intriguing structural changes in the electrolyte that disrupt large ionic aggregates and promote the formation of smaller ionic clusters, which is a promising finding for ionic conductivity. Due to pectin in [BMIM][PF6] electrolytes, the diffusion coefficient of cations and anions is observed to decrease by a factor of four for a loading of 25 wt. % of pectin in [BMIM][PF6] electrolyte. A strong correlation between the ionic diffusivities (D) and ion-pair relaxation timescales ($\tau_C$) is observed such that D~$\tau_C^{-0.75}$ for cations and D~$\tau_C^{-0.82}$ for anions. The relaxation timescale exponents indicate that the ion transport mechanisms in pectin-[BMIM][PF6] electrolytes are slightly distinct from those found in neat [BMIM][PF6] electrolytes (D~$\tau_C^{-1}$). Since pectin marginally affects ionic diffusivities at the gain of smaller ionic aggregates and viscosity, our results suggest that pectin-IL electrolytes offer improved properties for battery applications, including ionic conductivity, mechanical stability, and biodegradability.

cond-mat.soft