arXiv subjects

Sreeram Rajesh

Publications and source records attributed to Sreeram Rajesh.

6 recordsLinked to original sources

arXiv2026

Impact of viscoelastic polymer solution droplets on a granular bed

The impact of polymer solution droplets on granular beds is relevant to powder processing, binder jetting additive manufacturing, and environmental applications involving erosion control or spray deposition, yet most controlled studies of drop--grain interactions have focused on Newtonian liquids. In this study, we experimentally investigate the impact of viscoelastic polyethylene oxide (PEO) droplets on a dry granular bed and compare the resulting cratering dynamics with those of Newtonian liquids over a wide range of impact energies and Ohnesorge numbers. Crater morphology changes with impact energy, and this evolution occurs at lower energies for drops of polymer solution, consistent with their distinct liquid--grain interactions during impact. The crater diameter exhibits two distinct regimes: a low-energy plateau and a power-law growth at higher impact energies. We identify the transition between these regimes and show that, although the plateau size and the power law remain nearly unchanged, viscoelastic droplets reach the transition at lower impact energy than Newtonian droplets. This suggests that viscoelasticity modifies how the impact energy is partitioned between droplet deformation and dissipation in the granular bed.

cond-mat.soft↗

arXiv2026

Axial forces in capillary liquid bridges of polymer solutions

Liquid bridges form between particles during wet mixing with binders or by condensation due to ambient humidity. The consequences of capillary bridges can be quite drastic, creating macroscopic cohesion, as seen in sandcastles and in the formation of particulate agglomerates. Bulk effects in cohesive particles arise from forces generated by capillary bridges, so particle-scale measurements are needed to develop predictive models. Most existing studies at the particle scale assume Newtonian liquids. Yet many binders in industry and in the environment can exhibit viscoelastic behavior. In this study, we measure the axial force generated by liquid bridges of viscoelastic polymer solutions between two spherical beads during controlled uniaxial separation. We vary the polymer concentration, separation velocity, and particle size, and track the force as the bridge thins and ruptures. At quasi-static rates, the axial force remains dominated by capillarity and is not significantly affected by polymer rheology. However, increasing the stretching rate increases the peak force through viscous dissipation and promotes the formation of a viscoelastic filament, thereby delaying rupture. The peak axial forces collapse when rescaled by a capillary number and particle size, while the effective rupture distance collapses with a Weissenberg number. These results provide a simple first-order particle-scale force law for polymeric binders.

cond-mat.soft↗

arXiv2025

Impact and spreading dynamics of a drop of fiber suspension on a solid substrate

The presence of non-Brownian spherical particles dispersed in a liquid modifies the impact and spreading dynamics of a drop on a hydrophilic substrate. This difference in spreading dynamics is attributed to the increase in the suspension's viscosity caused by the particles. Similarly, anisotropic non-Brownian particles, such as fibers, also increase the bulk viscosity. In addition to the fiber diameter, D, the length, L, which determines the aspect ratio A = L/D, is crucial in controlling the fiber suspension viscosity. Therefore, we hypothesize that the drop impact of fiber suspensions with different volume fractions will result in a similar modification of the spreading dynamics. To investigate the impact and spreading dynamics, we prepared suspensions of fibers with an aspect ratio A = 12 at different volume fractions, spanning the dilute, semi-dilute, and dense concentration regimes. Additionally, we conducted a subset of experiments with aspect ratios A = 4 and A = 20. Furthermore, we characterized the thickness of the resulting droplet film (the coating) and the orientation of fibers after the spreading dynamics reached a steady state. The presence of fibers results in a decrease in the final droplet size, as an increase in volume fraction leads to an increase in the suspension viscosity. To rationalize these results, we used a modified equation, originally developed for spherical particles, which incorporates the suspension viscosity. Furthermore, we observed that volume fraction plays only a weak role in controlling splashing. However, it is crucial in determining the final thickness and resulting fiber coating. We also used a novel approach to quantify the final fiber orientation and showed that the resulting distribution is anisotropic within the quantified range.

cond-mat.soft↗

arXiv2022

Pinch-off of bubbles in a polymer solution

The formation of gas bubbles in a liquid occurs in various engineering processes, such as during foam generation or agitation and mixing in bubbly flows. A challenge in describing the initial formation of a gas bubble is due to the singular behavior at pinch-off. Past experiments in Newtonian fluids have shown that the minimum neck radius follows a power-law evolution shortly before the break-up. The exponent of the power-law depends on the viscosity of the surrounding Newtonian liquid, and ranges from 0.5 for low viscosity to 1 for large viscosity. However, bubble formation in a viscoelastic polymer solution remains unclear, and in particular, if the evolution is still captured by a power-law and how the exponent varies with the polymer concentration. In this study, we use high-speed imaging to analyze the bubble pinch-off in solutions of polymers. We characterize the time evolution of the neck radius when varying the concentration and thus the characteristic relaxation time and describe the influence of viscoelasticity on the bubble pinch-off. Our results reveal that the presence of polymers does not influence the thinning until the latter stages, when their presence in sufficient concentration delays the pinch-off.

cond-mat.soft↗

arXiv2022

Transition to the viscoelastic regime in the thinning of polymer solutions

In this study, we investigate the transition between the Newtonian and the viscoelastic regimes during the pinch-off of droplets of dilute polymer solutions and discuss its link to the coil-stretch transition. The detachment of a drop from a nozzle is associated with the formation of a liquid neck that causes the divergence of the local stress in a vanishingly small region. If the liquid is a polymer solution, this increasing stress progressively unwinds the polymer chains, up to a point where the resulting increase in the viscosity slows down drastically the thinning. This threshold to a viscoelastic behavior corresponds to a macroscopic strain rate $\dot{\varepsilon}_{\rm c}$. In the present study, we characterize the variations of $\dot{\varepsilon}_{\rm c}$ with respect to the polymer concentration and molar weight, to the solvent viscosity, and to the nozzle size, i.e., the weight of the drop. We provide empirical scaling laws for these variations. We also analyze the thinning dynamics at the transition and show that it follows a self-similar dynamics controlled by the time scale ${\dot{\varepsilon}_{\rm c}}^{-1}$. This characteristic time is different and always shorter than the relaxation time of the polymer.

cond-mat.soft↗

arXiv2021

Droplet detachment and pinch-off of bidisperse particulate suspensions

When a droplet is generated, the ligament connecting the drop to the nozzle thins down and eventually pinches off. Adding solid particles to the liquid phase leads to a more complex dynamic, notably by increasing the shear viscosity. Moreover, it introduces an additional length scale to the system, the diameter of the particles, which eventually becomes comparable to the diameter of the ligament. In this paper, we experimentally investigate the thinning and pinch-off of drops of suspensions with two different sizes of particles. We characterize the thinning for different particle size ratios and different proportions of small particles. Long before the pinch-off, the thinning rate is that of an equivalent liquid whose viscosity is that of the suspension. Later, when the ligament thickness approaches the size of the large particles, the thinning accelerates and leads to an early pinch-off. We explain how the bidisperse particle size distribution lowers the viscosity by making the packing more efficient, which speeds up the thinning. This result can be used to predict the dynamics of droplet formation with bidisperse suspensions.

cond-mat.soft↗