arXiv subjects

Srikanth Sastry

Publications and source records attributed to Srikanth Sastry.

At least 73 records · Page 4Linked to original sources

arXiv2017

Force networks and jamming in shear deformed sphere packings

The formation of self-organised structures that resist shear deformation have been discussed in the context of shear jamming and thickening[1-3], with frictional forces playing a key role. However, shear induces geometric features necessary for jamming even in frictionless packings[4]. We analyse conditions for jamming in such assemblies by solving force and torque balance conditions for their contact geometry. We demonstrate, and validate with frictional simulations, that the isostatic condition for mean contact number Z = D + 1 (for spatial dimension D = 2, 3) holds at jamming for both finite and infinite friction, above the random loose packing density. We show that the shear jamming threshold satisfies the marginal stability condition recently proposed for jamming in frictionless systems[5]. We perform rigidity percolation analysis[6,7] for D = 2 and find that rigidity percolation precedes shear jamming, which however coincides with the percolation of over-constrained regions, leading to the identification of an intermediate phase analogous to that observed in covalent glasses[8].

cond-mat.soft↗

arXiv2017

Density dependence of relaxation dynamics in glass formers, and the dependence of their fragility on the softness of inter-particle interactions

Fragility, quantifying the rapidity of variation of relaxation times, is analysed for a series of model glass formers, which differ in the softness of their interparticle interactions. In an attempt to rationalize experimental observations in colloidal suspensions that softer interactions lead to stronger (less fragile) glass formers, we study the variation of relaxation dynamics with density, rather than temperature, as a control parameter. We employ density temperature scaling, analyzed in recent studies, to address the question. We find that while employing inverse density in place of temperature leads to the conclusion that softer interactions lead to stronger behaviour, the use of scaled variables involving temperature and density lead to the opposite conclusion, similarly to earlier investigations where temperature variation of relaxation dynamics was analysed for the same systems. We rationalize our results by considering the Adam-Gibbs (AG) fragility, which incorporates the density dependence of the configurational entropy and an activation energy that may arise from other properties of a glass former. Within the framework of the Adam-Gibbs relation, by employing density temperature scaling for the analysis, we find that softer particles make more fragile glasses, as deduced from dynamical quantities, which is found to be consistent with the Adam-Gibbs fragility.

cond-mat.soft↗

arXiv2017

Length scale dependence of the Stokes-Einstein and Adam-Gibbs relations in model glass formers

The Adam-Gibbs (AG) relation connects the dynamics of a glass-forming liquid to its the thermodynamics via. the configurational entropy, and is of fundamental importance in descriptions of glassy behaviour. The breakdown of the Stokes-Einstein (SEB) relation between the diffusion coefficient and the viscosity (or structural relaxation times) in glass formers raises the question as to which dynamical quantity the AG relation describes. By performing molecular dynamics simulations, we show that the AG relation is valid over the widest temperature range for the diffusion coefficient and not for the viscosity or relaxation times. Studying relaxation times defined at a given wavelength, we find that SEB and the deviation from the AG relation occur below a temperature at which the correlation length of dynamical heterogeneity equals the wavelength probed.

cond-mat.stat-mech↗

arXiv2017

Glass Transition in Supercooled Liquids with Medium Range Crystalline Order

The origins of rapid dynamical slow down in glass forming liquids in the growth of static length scales, possibly associated with identifiable structural ordering, is a much debated issue. Growth of medium range crystalline order (MRCO) has been observed in various model systems to be associated with glassy behaviour. Such observations raise the question about the eventual state reached by a glass former, if allowed to relax for sufficiently long times. Is a slowly growing crystalline order responsible for slow dynamics? Are the molecular mechanisms for glass transition in liquids with and without MRCO the same? If yes, glass formers with MRCO provide a paradigm for understanding glassy behaviour generically. If not, systems with MRCO form a new class of glass forming materials whose molecular mechanism for slow dynamics may be easier to understand in terms of growing crystalline order, and should be approached in that manner, even while they will not provide generic insights. In this study we perform extensive molecular dynamics simulations of a number of glass forming liquids in two dimensions and show that the static and dynamic properties of glasses with MRCO are different from other glass forming liquids with no predominant local order. We also resolve an important issue regarding the so-called Point-to-set method for determining static length scales, and demonstrate it to be a robust, order agnostic, method for determining static correlation lengths in glass formers.

cond-mat.soft↗

arXiv2016

The yielding transition in amorphous solids under oscillatory shear deformation

Amorphous solids are ubiquitous among natural and man-made materials. Often used as structural materials for their attractive mechanical properties, their utility depends critically on their response to applied stresses. Processes underlying such mechanical response, and in particular the yielding behaviour of amorphous solids, are not satisfactorily understood. Although studied extensively[1-14], observed yielding behaviour can be gradual and depend significantly on conditions of study, making it difficult to convincingly validate existing theoretical descriptions of a sharp yielding transition[4, 6, 8, 13, 15]. Here, we employ oscillatory deformation as a reliable probe of the yielding transition. Through extensive computer simulations for a wide range of system sizes, we demonstrate that cyclically deformed model glasses exhibit a sharply defined yielding transition with characteristics that are independent of preparation history. In contrast to prevailing expectations[4, 8, 12], the statistics of avalanches reveals no signature of the impending transition, but exhibit dramatic, qualitative, changes in character across the transition.

cond-mat.dis-nn↗

arXiv2016

Effect of total and pair configurational entropy in determining dynamics of supercooled liquids over a range of densities

In this paper, we present a study of supercooled liquids interacting with the Lennard Jones (LJ) potential and the corresponding purely repulsive (Weeks-Chandler-Andersen or WCA) potential, over a range of densities and temperatures, in order to understand the origin of their different dynamics in spite of their structures being similar. Using the configurational entropy as the thermodynamic marker via the Adam Gibbs (AG) relation, we show that the difference in the dynamics of these two systems at low temperatures can be explained from thermodynamics. At higher densities both the thermodynamical and dynamical difference between these model systems decrease, which is quantitatively demonstrated in this paper by calculating different parameters. The study also reveals the origin of the difference in pair entropy despite the similarity in the structure. Although the maximum difference in structure is obtained in the partial radial distribution function (rdf) of the B type of particles, the rdf of AA pairs and AB pairs give rise to the differences in the entropy and dynamics. This work supports the observation made in an earlier study (Phys. Rev. Lett.,\textbf {113}, 225701, 2014) and shows that they are generic in nature, independent of density.

cond-mat.soft↗

arXiv2015

Disentangling the role of structure and friction in shear jamming

Amorphous packings of spheres have been intensely investigated in order to understand the mechanical and flow behaviour of dense granular matter, and to explore universal aspects of the transition from fluid to structurally arrested or jammed states. Considerable attention has recently been focussed on anisotropic packings of frictional grains generated by shear deformation leading to shear jamming, which occurs below the jamming density for isotropic packings of frictionless grains. With the aim of disentangling the role of shear deformation induced structures and friction in generating shear jamming, we study sheared assemblies of frictionless spheres computationally, over a wide range of densities, extending far below the isotropic jamming point. We demonstrate the emergence of a variety of geometric features characteristic of jammed packings with the increase of shear strain. The average contact number and the distributions of contact forces suggest the presence of a threshold density, well below the isotropic jamming point, above which a qualitative change occurs in the jamming behaviour of sheared configurations. We show that above this threshold density, friction stabilizes the sheared configurations we generate. Our results thus reveal the emergence of geometric features characteristic of jammed states as a result of shear deformation alone, while friction is instrumental in stabilising packings over a range of densities below the isotropic jamming point.

cond-mat.soft↗

arXiv2015

Stochastic Approach to Plasticity and Yield in Amorphous Solids

We focus on the probability distribution function (pdf) $P(Δγ; γ)$ where $Δγ$ are the {\em measured} strain intervals between plastic events in an athermal strained amorphous solids, and $γ$ measures the accumulated strain. The tail of this distribution as $Δγ\to 0$ (in the thermodynamic limit) scales like $Δγ^η$. The exponent $η$ is related via scaling relations to the tail of the pdf of the eigenvalues of the {\em plastic modes} of the Hessian matrix $P(λ)$ which scales like $λ^θ$, $η=(θ-1)/2$. The numerical values of $η$ or $θ$ can be determined easily in the unstrained material and in the yielded state of plastic flow. Special care is called for in the determination of these exponents between these states as $γ$ increases. Determining the $γ$ dependence of the pdf $P(Δγ; γ)$ can shed important light on plasticity and yield. We conclude that the pdf's of both $Δγ$ and $λ$ are not continuous functions of $γ$. In slowly quenched amorphous solids they undergo two discontinuous transitions, first at $γ=0^+$ and then at the yield point $γ=γ_{_{\rm Y}}$ to plastic flow. In quickly quenched amorphous solids the second transition is smeared out due to the non existing stress peak before yield. The nature of these transitions and scaling relations with the system size dependence of $\langle Δγ\rangle$ are discussed.

cond-mat.soft↗

arXiv2015

Unraveling the success and failure of mode coupling theory from consideration of entropy

We analyze the dynamics of model supercooled liquids in a temperature regime where predictions of mode coupling theory (MCT) are known to be valid qualitatively. In this regime, the Adam-Gibbs (AG) relation, based on an activation picture of dynamics also describes the dynamics satisfactorily, and we explore the mutual consistency and interrelation of these descriptions. Although entropy and dynamics are related via phenomenological theories, the connection between MCT and entropy has not been argued for. In this work we explore this connection and provide a microscopic derivation of the phenomenological Rosenfeld theory. At low temperatures the overlap between MCT power law regime and AG relation implies that the AG relation predicts an avoided divergence at $T_c$, the origin of which is traced back to the vanishing of pair configurational entropy, which we find occurs at the same temperature. We also show that the residual multiparticle entropy plays an important role in describing the relaxation time

cond-mat.soft↗

arXiv2015

Short-time $β$-relaxation in glass-forming liquids is cooperative in nature

Temporal relaxation of density fluctuations in supercooled liquids near the glass transition occurs in multiple steps. The short-time $β$-relaxation is generally attributed to spatially local processes involving the rattling motion of a particle in the transient cage formed by its neighbors. Using molecular dynamics simulations for three model glass-forming liquids, we show that the $β$-relaxation is actually cooperative in nature. Using finite-size scaling analysis, we extract a growing length-scale associated with $β$-relaxation from the observed dependence of the $β$-relaxation time on the system size. Remarkably, the temperature dependence of this length scale is found to be the same as that of the length scale that describes the spatial heterogeneity of local dynamics in the long-time $α$-relaxation regime. These results show that the conventional interpretation of $β$-relaxation as a local process is too simplified and provide a clear connection between short-time dynamics and long-time structural relaxation in glass-forming liquids.

cond-mat.stat-mech↗

arXiv2015

Free volume under shear

Using an athermal quasistatic simulation protocol, we study the distribution of free volumes in sheared hard-particle packings close to, but below, the random-close packing threshold. We show that under shear, and independent of volume fraction, the free volumes develop features similar to close-packed systems -- particles self-organize in a manner as to mimick the isotropically jammed state. We compare athermally sheared packings with thermalized packings and show that thermalization leads to an erasure of these structural features. The temporal evolution, in particular the opening-up and the closing of free-volume patches is associated with the single-particle dynamics, showing a crossover from ballistic to diffusive behavior.

cond-mat.soft↗

arXiv2015

Memory Effects in Schematic Models of Glasses Subjected to Oscillatory Deformation

We consider two schematic models of glasses subjected to oscillatory shear deformation, motivated by the observations, in computer simulations of a model glass, of a nonequilibrium transition from a localized to a diffusive regime as the shear amplitude is increased, and of persistent memory effects in the localized regime. The first of these schematic models is the NK model, a spin model with disordered multi-spin interactions previously studied as a model for sheared amorphous solids. The second model, a transition matrix model, is an abstract formulation of the manner in which occupancy of local energy minima evolves under oscillatory deformation cycles. In both of these models, we find a behavior similar to that of an atomic model glass studied earlier. We discuss possible further extensions of the approaches outlined.

cond-mat.stat-mech↗

arXiv2015

Consensus using Asynchronous Failure Detectors

The FLP result shows that crash-tolerant consensus is impossible to solve in asynchronous systems, and several solutions have been proposed for crash-tolerant consensus under alternative (stronger) models. One popular approach is to augment the asynchronous system with appropriate failure detectors, which provide (potentially unreliable) information about process crashes in the system, to circumvent the FLP impossibility. In this paper, we demonstrate the exact mechanism by which (sufficiently powerful) asynchronous failure detectors enable solving crash-tolerant consensus. Our approach, which borrows arguments from the FLP impossibility proof and the famous result from CHT, which shows that $Ω$ is a weakest failure detector to solve consensus, also yields a natural proof to $Ω$ as a weakest asynchronous failure detector to solve consensus. The use of I/O automata theory in our approach enables us to model execution in a more detailed fashion than CHT and also addresses the latent assumptions and assertions in the original result in CHT.

cs.DC↗

arXiv2014

Free volume distribution of nearly jammed hard sphere packings

We calculate the free volume distributions of nearly jammed packings of monodisperse and bidisperse hard sphere configurations. These distributions differ qualitatively from those of the fluid, displaying a power law tail at large free volumes, which constitutes a distinct signature of nearly jammed configurations, persisting for moderate degrees of decompression. We reproduce and explain the observed distribution by considering the pair correlation function within the first coordination shell for jammed hard sphere configurations. We analyze features of the equation of state near jamming, and discuss the significance of observed asphericities of the free volumes to the equation of state.

cond-mat.soft↗

arXiv2014

Solvability-Based Comparison of Failure Detectors

Failure detectors are oracles that have been introduced to provide processes in asynchronous systems with information about faults. This information can then be used to solve problems otherwise unsolvable in asynchronous systems. A natural question is on the "minimum amount of information" a failure detector has to provide for a given problem. This question is classically addressed using a relation that states that a failure detector D is stronger (that is, provides "more, or better, information") than a failure detector D' if D can be used to implement D'. It has recently been shown that this classic implementability relation has some drawbacks. To overcome this, different relations have been defined, one of which states that a failure detector D is stronger than D' if D can solve all the time-free problems solvable by D'. In this paper we compare the implementability-based hierarchy of failure detectors to the hierarchy based on solvability. This is done by introducing a new proof technique for establishing the solvability relation. We apply this technique to known failure detectors from the literature and demonstrate significant differences between the hierarchies.

cs.DC↗

arXiv2014

The role of structure and entropy in determining differences in dynamics for glass formers with different interaction potentials

We present a study of two model liquids with different interaction potentials, exhibiting similar structure but significantly different dynamics at low temperatures. By evaluating the configurational entropy, we show that the differences in the dynamics of these systems can be understood in terms of their thermodynamic differences. Analyzing their structure, we demonstrate that differences in pair correlation functions between the two systems, through their contribution to the entropy, dominate the differences in their dynamics, and indeed overestimate the differences. Including the contribution of higher order structural correlations to the entropy leads to smaller estimates for the relaxation times, as well as smaller differences between the two studied systems.

cond-mat.soft↗

arXiv2013

Density-temperature scaling of the fragility in a model glass-former

Dynamical quantities such as the diffusion coefficient and relaxation times for some glass-formers may depend on density and temperature through a specific combination, rather than independently, allowing the representation of data over ranges of density and temperature as a function of a single scaling variable. Such a scaling, referred to as density - temperature (DT) scaling, is exact for liquids with inverse power law (IPL) interactions but has also been found to be approximately valid in many non-IPL liquids. We have analyzed the consequences of DT scaling on the density dependence of the fragility in a model glass-former. We find the density dependence of kinetic fragility to be weak, and show that it can be understood in terms of DT scaling and deviations of DT scaling at low densities. We also show that the Adam-Gibbs relation exhibits DT scaling and the scaling exponent computed from the density dependence of the activation free energy in the Adam-Gibbs relation, is consistent with the exponent values obtained by other means.

cond-mat.stat-mech↗

arXiv2013

Oscillatory athermal quasi-static deformation of a model glass

We report computer simulations of oscillatory athermal quasi-static shear deformation of dense amorphous samples of a three dimensional model glass former. A dynamical transition is observed as the amplitude of the deformation is varied: for large values of the amplitude the system exhibits diffusive behavior and loss of memory of the initial conditions, whereas localization is observed for small amplitudes. Our results suggest that the same kind of transition found in driven colloidal systems is present in the case of amorphous solids (e.g. metallic glasses). The onset of the transition is shown to be related to the onset of energy dissipation. Shear banding is observed for large system sizes, without, however, affecting qualitative aspects of the transition.

cond-mat.dis-nn↗