arXiv subjects

Stefan Wurster

Publications and source records attributed to Stefan Wurster.

At least 19 recordsLinked to original sources

arXiv2025

Core-Shell Confinement Blocks Hydride Formation: The Impact of Surface Oxides on Hydrogen Sorption in Nanoporous FeTi

Metal hydrides remain an intriguing alternative to conventional gaseous and liquid hydrogen storage methods, offering high volumetric storage density and enhanced hydrogen storage safety at ambient conditions. In this regard, the intermetallic compound FeTi is one of the most promising storage materials. However, its widespread industrial application remains challenging due to the need for activation, slow initial kinetics, large hysteresis, and high material costs. In this study, we aim to overcome these limitations by devising an alternative synthesis pathway to prepare nanoporous and ultra-fine porous FeTi with controlled grain and ligament sizes, allowing us to study the obtained well-defined microstructures in detail. In particular, we observe the confinement of the FeTi phase by surface oxides, which can be correlated with the hydrogen sorption properties of the respective material. These experimental results are further supported by an analytical model allowing the calculation of the absorption pressure as a function of microstructure-dependent elastic stresses. Additionally, we show that such stresses also influence the absorption-desorption hysteresis. This study lays the groundwork for the controlled and systematic study of the processing-structure-properties relations in metal hydrides and FeTi in particular, thereby paving the way to cost-effective and efficient hydrogen storage solutions based on metal hydrides.

cond-mat.mtrl-sci↗

arXiv2024

Stabilization of mechanical strength in a nanocrystalline CoCrNi concentrated alloy by nitrogen alloying

The mechanical performance and microstructures of a CoCrNi medium-entropy alloy (MEA) and NCoCrNi, alloyed with 0.5at% N, after high pressure torsion (HPT) and subsequent annealing treatments in a temperature range of 150-1000 °C were investigated. The introduction of N results in a reduction of grain size by 40% and ~10-15% increased hardness and bending strength after HPT. Both materials showed strain hardening and plasticity after HPT even at these strength levels over 1500 MPa which is induced by the saturated nanocrystalline state. Annealing at intermediate temperatures of 300-500 °C resulted in an additional increase of hardness and strength by ~20-40%, compared to the HPT deformed state. This effect was ~10 % more pronounced in the nitrogen alloyed CoCrNi that also showed better thermal stability. However, the increase in strength after 500 °C annealing was accompanied by a drastic loss of ductility in both materials.

cond-mat.mtrl-sci↗

arXiv2023

Synthesis of hard magnetic α-MnBi phase by high pressure torsion and field assisted annealing

Bulk composites using powder blends of Mn and Bi with equal atomic ratios are consolidated and severely deformed by high-pressure torsion (HPT). Subsequent annealing treatments lead to the formation of the ferromagnetic and rare-earth free hard magnetic α-MnBi phase. The initial phase formation is studied by in-situ high-energy XRD annealing experiments showing a beneficial influence of HPT-deformation on the amount of α-MnBi. The nucleation sites are strongly increased, thus the volumetric α-MnBi phase content exceeds 50 vol.%. A lower HPT-pressure of 2 GPa is found to be preferred over 5 GPa to obtain high α-MnBi contents. Annealing is done with or without applying an external magnetic field. Additionally, influences of the HPT-induced shear deformation are discussed and correlated with preferred diffusion path ways fostering the formation of anisotropic α-MnBi phase.

cond-mat.mtrl-sci↗

arXiv2023

Germany's nationwide travel experiment in 2022: public transport for 9 Euro per month -- First findings of an empirical study

In spring 2022, the German federal government agreed on a set of policy measures that aimed at reducing households' financial burden resulting from a recent price increase, especially in energy and mobility. These included among others, a nationwide public transport ticket for 9~Euro per month for three months in June, July, and August 2022. In transport policy research this is an almost unprecedented behavioral experiment. It allows us to study not only behavioral responses in mode choice and induced demand but also to assess the effectiveness of these instruments. We observe this natural experiment with a three-wave survey and a smartphone-based travel diary with passive tracking on an initial sample of 2,261 participants with a focus on the Munich metropolitan region. This area is chosen as it offers a variety of mode options with a dense and far-reaching public transport network that even provides good access to many leisure destinations. The app has been providing data from 756 participants until the end of September, the three-wave survey by 1,402, and the app and the three waves by 637 participants. In this paper, we report on the study design, the recruitment and study participation as well as the impacts of the policy measures on the self-reported and app-observed travel behavior; we present results on consumer choices for a successor ticket to the 9-Euro-Ticket that started in May 2023. We find a substantial shift in the modal share towards public transport from the car in our sample during the 9-Euro-Ticket period in travel distance (around 5 %) and in trip frequency (around 7 %). The mobility outcomes of the 9-Euro-Ticket however provide evidence that cheap public transport as a policy instrument does not suffice to incentive sustainable travel behavior choices and that other policy instruments are required in addition.

econ.GN↗

arXiv2023

Exchange Bias Demonstrated in Bulk Nanocomposites Processed by High Pressure Torsion

Ferromagnetic (Fe or Fe20Ni80) and antiferromagnetic (NiO) phases were deformed by high pressure torsion, a severe plastic deformation technique, to manufacture bulk sized nanocomposites and demonstrate an exchange bias, which has been reported predominantly for bilayer thin films. High pressure torsion deformation at elevated temperatures proved to be the key to obtain homogeneous bulk nanocomposites. X-ray diffraction investigations detected nanocrystallinity of the ferromagnetic and antiferromagnetic phases. Furthermore, an additional phase was identified by X-ray diffraction, which formed during deformation at elevated temperatures through the reduction of NiO by Fe. Depending on the initial powder composition of Fe50NiO50 or Fe10Ni40NiO50 the new phase was magnetite or maghemite, respectively. Magnetometry measurements demonstrated an exchange bias in the high pressure torsion processed bulk nanocomposites. Additionally, a tailoring of magnetic parameters was demonstrated by the application of different strains or post-process annealing. A correlation between the amount of applied strain and exchange bias was found. The increase of exchange bias through applied strain was related to the microstructural refinement of the nanocomposite. The nanocrystalline maghemite was considered to have a crucial impact on the observed changes of exchange bias through applied strain.

cond-mat.mtrl-sci↗

arXiv2022

A nation-wide experiment: fuel tax cuts and almost free public transport for three months in Germany -- Report 4 Third wave results

In spring 2022, the German federal government agreed on a set of measures that aimed at reducing households' financial burden resulting from a recent price increase, especially in energy and mobility. These measures included among others, a nation-wide public transport ticket for 9EUR per month and a fuel tax cut that reduced fuel prices by more than 15%. In transportation policy and travel behavior research this is an almost unprecedented behavioral experiment. It allows to study not only behavioral responses in mode choice and induced demand but also to assess the effectiveness of transport policy instruments. We observe this natural experiment with a three-wave survey and an app-based travel diary on a sample 2'263 individuals; for the Munich Study, 919 participants in the survey-and-app group and 425 in the survey-only group have been successfully recruited, while 919 participants have been recruited through a professional panel provider to obtain a representative nation-wide reference group for the three-wave survey. In this fourth report we present the results of the third wave. At the end of the study, all three surveys have been completed by 1'484 participants and 642 participants completed all three surveys and used the travel diary throughout the entire study. Based on our results we conclude that when offering a 49EUR-Ticket as a successor to the 9~EUR-Ticket and a local travel pass for 30EUR/month more than 60% of all 9~EUR-Ticket owners would buy one of the two new travel passes. In other words, a substantial increase in travel pass ownership in Germany can be expected, with our modest estimate being around 20%. With the announcement of the introduction of a successor ticket in 2023 as well as with the prevailing high inflation, this study will continue into the year 2023 to monitor the impact on mobility and daily activities.

econ.GN↗

arXiv2022

A nation-wide experiment: fuel tax cuts and almost free public transport for three months in Germany -- Report 3 Second wave results

econ.GN↗

arXiv2022

Magnetron Sputtered Non-Toxic and Precious Element-Free Ti-Zr-Ge Metallic Glass Nanofilms with Enhanced Biocorrosion Resistance

The chemical composition and structural state of advanced alloys are the decisive factors in optimum biomedical performance. This contribution presents unique Ti-Zr-Ge metallic glass thin-film compositions fabricated by magnetron sputter deposition targeted for nanocoatings for biofouling prevention. The amorphous nanofilms with nanoscale roughness exhibit a large relaxation and supercooled liquid regions as revealed by flash differential scanning calorimetry. Ti\textsubscript{68}Zr\textsubscript{8}Ge\textsubscript{24} shows the lowest corrosion (0.17 \textmu A cm\textsuperscript{\textminus2}) and passivation (1.22 \textmu A cm\textsuperscript{\textminus2}) current densities, with the lowest corrosion potential of \textminus0.648 V and long-range stability against pitting, corroborating its excellent performance in phosphate buffer solution at 37 {\textdegree}C. The oxide layer is comprised of TiO\textsubscript{2}, TiO\textsubscript{\emph{x}} and ZrO\textsubscript{\emph{x}}, as determined using X-ray photoelectron spectroscopy by short-term ion-etching of the surface layer. The two orders of magnitude increase in the oxide and interface resistance (from 14 to 1257 {\textOmega} cm\textsuperscript{2}) along with an order of magnitude decrease in the capacitance parameter of the oxide interface (from 1.402 x 10\textsuperscript{\textminus5} to 1.677 x 10\textsuperscript{\textminus6} S s\textsuperscript{n} cm\textsuperscript{\textminus2}) of the same composition is linked to the formation of carbonyl groups and reduction of the native oxide layer during linear sweep voltammetry.

cond-mat.mtrl-sci↗

arXiv2022

Manufacturing of Textured Bulk Fe-SmCo$_{5}$ Magnets by Severe Plastic Deformation

Exchange-coupling between soft- and hard-magnetic phases plays an important role in the engineering of novel magnetic materials. To achieve exchange coupling, a two-phase microstructure is necessary. This interface effect is further enhanced if both phase dimensions are reduced to the nanometer scale. At the same time, it is challenging to obtain large sample dimensions. In this study, powder blends and ball-milled powder blends of Fe-SmCo$_{5}$ are consolidated and are deformed by high-pressure torsion (HPT), as this technique allows us to produce bulk magnetic materials of reasonable sizes. Additionally, the effect of severe deformation by ball-milling and severe plastic deformation by HPT on exchange coupling in Fe-SmCo$_{5}$ composites is investigated. Due to the applied shear deformation, it is possible to obtain a texture in both phases, resulting in an anisotropic magnetic behavior and an improved magnetic performance.

cond-mat.mtrl-sci↗

arXiv2022

Oxide-stabilized microstructure of severe plastically deformed CuCo alloys

Nanocrystalline materials are well known for their beneficial mechanical and physical properties. However, it is of utmost importance to stabilize the microstructure at elevated temperatures to broaden the window of application e.g. by pinning grain boundaries through impurities or oxides. CuCo alloys, severe plastically deformed using high-pressure torsion, were used to investigate the evolution of oxides upon annealing. These investigations were performed using electron microscopy, synchrotron high-energy X-ray scattering and atom probe tomography. Monitoring the evolution of oxides by in-situ small angle scattering investigations indicates the growth of primary oxides as well as the formation of another species of oxide at elevated temperatures. Slightly different coarsening can be observed in heat-treated samples, which can be traced back to the influence of different oxide amounts. The initially supersaturated CuCo matrix changes by the decomposition process as well as Co- and Cu-based oxides formation and growth. It has been found that the major number of oxides which are present after annealing, can already be found in the starting materials.

cond-mat.mtrl-sci↗

arXiv2022

Soft Magnetic Properties of Ultra-Strong and Nanocrystalline Pearlitic Wires

The paper describes the capability of magnetic softening of a coarse grained bulk material by a severe deformation technique. Connecting the microstructure with magnetic properties, the coercive field decreases dramatically for grains smaller than the magnetic exchange length. This makes the investigation of soft magnetic properties of severely drawn pearlitic wires very interesting. With the help of the starting two phase microstructure, it is possible to substantially refine the material, which allows the investigation of magnetic properties for nanocrystalline bulk material. Compared to the coarse grained initial, pearlitic state, the coercivities of the highly deformed wires decrease while the saturation magnetization values increase, even beyond the value expectable from the individual constituents. The lowest coercivity in the drawn state is found to be 520 A m for a wire of 24 um thickness and an annealing treatment has a further positive effect on it. The decreasing coercivity is discussed in the framework of two opposing models: grain refinement on the one hand and dissolution of cementite on the other hand. Auxiliary measurements give a clear indication for the latter model, delivering a sufficient description of the observed evolution of magnetic properties.

cond-mat.mtrl-sci↗

arXiv2021

Nanocrystalline FeCr alloys synthesised by severe plastic deformation -- a potential material for exchange bias and enhanced magnetostriction

This work gives insights into processing and characterisation of bulk nanocrystalline FeCr materials. The investigated FeCr alloys, consisting of 30, 50 and 70 at.% ferromagnetic Fe and remaining anti-ferromagnetic Cr, are processed by arc melting and subsequent severe plastic deformation by high pressure torsion. The physical similarities between elemental Fe and Cr in combination with the nanocrystalline structure of the as-deformed alloys, necessitates advanced characterisation techniques for the as-deformed state: In-situ annealing synchrotron X-ray diffraction measurements as well as electron microscopy experiments are linked to magnetostrictive measurements and reveal a single phase microstructure. Surprisingly, the nanocrystalline FeCr alloys remain supersaturated solid solutions upon annealing above 500°C, meaning a decomposition in a FeCr nanocomposite is suppressed. For the chosen annealing conditions grain growth is faster than decomposition and enhanced magnetostrictive values are found compared to materials in the as-deformed state.

cond-mat.mtrl-sci↗

arXiv2021

Sampling the Cu-Fe-Co phase diagram by severe plastic deformation for enhanced soft magnetic properties

Initial powder mixtures of Cu, Fe and Co are exposed to severe plastic deformation by high-pressure torsion to prepare solid solutions. A broad range of compositions is investigated, whereas this study aims at the synthesis of soft magnetic materials and therefore at the formation of a homogeneous and nanocrystalline microstructure. For intermediate ferromagnetic contents, high-pressure torsion at room temperature yields single-phase supersaturated solid solutions. For higher ferromagnetic contents, two consecutive steps of high-pressure torsion deformation at different temperatures yield the desired nanocrystalline microstructure. Depending on the Co-to-Fe-ratio, either a single-phase supersaturated solid solution or a nanocomposite forms. The composite exhibits an enhanced magnetic moment, indicating the formation of a (Fe,Co)-alloy upon severe plastic deformation. Soft magnetic properties are verified for large Co-to-Fe-ratios and this microstructure is found to remain stable up to 400 °C.

cond-mat.mtrl-sci↗

arXiv2021

On the magnetic nanostructure of a Co-Cu alloy processed by high-pressure torsion

In this study, a preparation route of Co-Cu alloys with soft magnetic properties by high-pressure torsion deformation is introduced. Nanocrystalline, supersaturated single-phase microstructures are obtained after deformation of Co-Cu alloys, which are prepared from an initial powder mixture with Co-contents above 70 wt.%. Isochronal annealing treatments up to 400°C further reveal a remarkable microstructural stability. Only at 600°C, the supersaturated phase decomposes into two fcc-phases. The coercivity, measured by SQUID as a function of annealing temperature, remains significantly below the value for bulk-Co in all states investigated. In order to understand the measured magnetic properties in detail, a quantitative analysis of the magnetic microstructure is carried out by magnetic force microscopy and correlated to the observed changes in coercivity. Our results show that the rising coercivity can be explained by a magnetic hardening effect occurring in context with spinodal decomposition.

cond-mat.mtrl-sci↗

arXiv2021

Strain Induced Anisotropic Magnetic Behaviour and Exchange Coupling Effect in Fe-SmCo$_{5}$ Permanent Magnets Generated by High Pressure Torsion

High-pressure torsion (HPT), a technique of severe plastic deformation (SPD), is shown as a promising processing method for exchange-spring magnetic materials in bulk form. Powder mixtures of Fe and SmCo$_{5}$ are consolidated and deformed by HPT exhibiting sample dimensions of several millimetres, being essential for bulky magnetic applications. The structural evolution during HPT deformation of Fe-SmCo$_{5}$ compounds at room- and elevated- temperatures of chemical compositions consisting of 87, 47, 24 and 10 wt.% Fe is studied and microstructurally analysed. Electron microscopy and synchrotron X-ray diffraction reveal a dual-phase nanostructured composite for the as-deformed samples with grain refinement after HPT deformation. SQUID magnetometry measurements show hysteresis curves of an exchange coupled nanocomposite at room temperature, while for low temperatures a decoupling of Fe and SmCo$_{5}$ is observed. Furthermore, exchange interactions between the hard- and soft-magnetic phase can explain a shift of the hysteresis curve. Strong emphasis is devoted to the correlation between the magnetic properties and the evolving nano-structure during HPT deformation, which is conducted for a 1:1 composition ratio of Fe to SmCo$_{5}$. SQUID magnetometry measurements show an increasing saturation magnetisation for increasing strain $γ$ and a maximum of the coercive field strength at a shear strain of $γ$ = 75.

cond-mat.mtrl-sci↗

arXiv2021

In situ AC-hysteresis measurements of SPD-processed Cu20(Fe15Co85)80

The changes of magnetic properties upon heat treatment of a metastable supersaturated solid solution processed by severe plastic deformation are investigated by in-situ AC-hysteresis measurements. Data are analyzed in the framework of dynamic loss theory, with correlative investigations of the microstructural properties. The evolution of hysteresis upon annealing points out that the single-phase supersaturated solid solution remains stable up to 400°C, then hindering of domain wall motion sets in at this temperature. At 600°C, a multi phase microstructure is present, causing a significant increase in coercivity.

cond-mat.mtrl-sci↗

arXiv2021

Processing of nanostructured bulk Fe-Cr alloys by severe plastic deformation

The processing of binary alloys consisting of ferromagnetic Fe and antiferromagnetic Cr by severe plastic deformation (SPD) with different chemical compositions has been investigated. Although the phase diagram exhibits a large gap in the thermodynamical equilibrium at lower temperatures, it is shown that techniques based on SPD help to overcome common processing limits. Different processing routes including initial ball milling (BM) and arc melting (AM) and a concatenation with annealing treatments prior to high-pressure torsion (HPT) deformation are compared in this work. Investigation of the deformed microstructures by electron microscopy and synchrotron X-ray diffraction reveal homogeneous, nanocrystalline microstructures for HPT deformed AM alloys. HPT deformation of powder blends and BM powders leads to an exorbitant increase in hardness or an unusual fast formation of a $σ$-phase and therefore impede successful processing.

cond-mat.mtrl-sci↗

arXiv2020

Intermixing of Fe and Cu on the atomic scale by high-pressure torsion as revealed by DC- and AC-SQUID susceptometry and atom probe tomography

The capability of high-pressure torsion on the preparation of supersaturated solid solutions, consisting of Cu-14Fe (wt.%), is studied. From microstructural investigations a steady state is obtained with nanocrystalline grains. The as-deformed state is analyzed with atom probe tomography, revealing an enhanced solubility and the presence of Fe-rich particles. The DC-hysteresis loop shows suppressed long range interactions in the as-deformed state and evolves towards a typical bulk hysteresis loop when annealed at 500°C. AC-susceptometry measurements of the as-deformed state reveal the presence of a superparamagnetic blocking peak, as well as a magnetic frustrated phase, whereas the transition of the latter follows the Almeida-Thouless line, coinciding with the microstructural investigations by atom probe tomography. AC-susceptometry shows that the frustrated state vanishes for annealing at 250°C.

cond-mat.mtrl-sci↗