Searcharxiv⌕ Search

arXiv subjects

Stephan Schiller

Publications and source records attributed to Stephan Schiller.

At least 19 recordsLinked to original sources
arXiv2026

On the potential for high-accuracy spectroscopy of $\mathrm{H}_2^+$ and $\overline{\mathrm{H}}_2^-$ in Penning traps for a test of CPT invariance

The comparison of vibrational transition frequencies of $\mathrm{H}_2^+$ and $\overline{\mathrm{H}}_2^-$ offers a new opportunity to test CPT invariance. Myers [Phys. Rev. A 98, 010101(R) (2018)] proposed performing laser spectroscopy in a Penning trap (PT) with non-destructive read-out. Here, we provide an extensive analysis of this proposal, introduce novel aspects, and discuss its implementation in PTs that incorporate either the continuous Stern-Gerlach effect or quantum-logic spectroscopy. We derive estimates for the achievable accuracy of the test. We find that a comparison of the vibrational frequencies at a fractional level of $1\times10^{-17}$ is a realistic prospect, using technology that is mostly already available. We also analyze complementary CPT invariance tests, namely those of the g-factor of the bound electron/positron via electron-spin-resonance spectroscopy and of the magnetic moment of the proton/antiproton via radiofrequency spectroscopy.

quant-ph↗
arXiv2026

High-precision Penning-trap spectroscopy of the ground-state spin structure of HD+

We present high-precision spectroscopy of the ground-state hyperfine structure of HD$^+$ at 4~T. We determine the bound-electron $g$ factor, $g_{e,\mathrm{bound}} = -2.002\,278\,540\,96(40)$, to a relative uncertainty of $2\times$10$^{-10}$, the most precise determination of a bound-electron $g$ factor of a molecular ion to date. The experimental value agrees with recently developed ab initio theory that now includes quantum-electrodynamical effects up to order $α^5$ and has reduced the theoretical uncertainty by three orders of magnitude [O. Kullie \textit{et al.}, Phys. Rev. A 112 052813 (2025)]. In addition, we extract the scalar spin-spin interaction coefficients $E_4$~=~925\,395.758(41)$\,$kHz (electron-proton) and $E_5$~=~142\,287.821(22)$\,$kHz (electron-deuteron), which show a moderate tension with another state-of-the-art theoretical prediction [M. Haidar \textit{et al.}, Phys. Rev. A 106 042815 (2022)].

physics.atom-ph↗
arXiv2025

The QTF-Backbone: Proposal for a Nationwide Optical Fibre Backbone in Germany for Quantum Technology and Time and Frequency Metrology

The recent breakthroughs in the distribution of quantum information and high-precision time and frequency (T&F) signals over long-haul optical fibre networks have transformative potential for physically secure communications, resilience of timing infrastructure (such as that supporting Global Navigation Satellite Systems (GNSS)) and fundamental physics. To date, these capabilities remain confined to isolated testbeds, with quantum and T&F signals accessible, for example in Germany, to only a few institutions. In this white paper we propose the QTF Backbone: a dedicated national fibre-optic infrastructure in Germany for the networked distribution of Quantum and T&F signals using dark fibres and specialised hardware. The QTF Backbone is planned as a four-phase deployment over ten years to ensure scalable, sustainable access for research institutions and industry. The concept builds on successful demonstrations of time and frequency distribution at high Technology Readiness Levels (TRLs) across Europe, including PTB-MPQ links in Germany, REFIMEVE in France, and the Italian LIFT network. The QTF Backbone will enable transformative Research and Development (R&D), support a nationwide QTF ecosystem, and ensure the transition from innovation to deployment. As a national and European hub, it will position Germany and Europe at the forefront of quantum networking, as well as T&F transfer.

physics.ins-det↗
arXiv2025

Prospects for the determination of fundamental constants with beyond-state-of-the-art uncertainty using molecular hydrogen ion spectroscopy

The proton, deuteron and triton masses can be determined relative to the electron mass via rovibrational spectroscopy of molecular hydrogen ions. This has to occur via comparison of the experimentally measured transition frequencies and the ab initio calculated frequencies, whose dependence on the mass ratios can be calculated precisely. In precision experiments to date (on HD$^+$ and H$_2^+$), the transitions have involved the ground vibrational level $v=0$ and excited vibrational levels with quantum numbers up to $v'=9$. For these transitions, the sensitivity of the ab initio frequency on the high-order-QED contributions is correlated with that on the mass ratios. This prevents an efficient simultaneous determination of these quantities from experimental data, so that the accuracy of the mass ratios is essentially limited by the theoretical uncertainty. Here we analyze how the accuracy of mass ratios may be improved by providing experimental transition frequencies between levels with larger quantum numbers, whose sensitivity on the mass ratio is positive rather than negative, or close to zero. This allows the unknown QED contributions and involved fundamental constants to be much more efficiently determined from a joint analysis of several measurements. We also consider scenarios where transitions of D$_2^+$ are included. We find these to be powerful approaches, allowing in principle to reach uncertainties for the mass ratios approximately three orders smaller than CODATA 2018. Improvements by a factor of 3.5 for the Rydberg constant, and 11 (14) for the proton (deuteron) charge radius, are also projected.

physics.atom-ph↗
arXiv2025

Guidelines for designs for ultrastable laser with $\mathbf{10^{-17}}$ fractional frequency instability

Lasers with long coherence time and narrow linewidth are an essential tool for quantum sensors and clocks. Ultrastable cavities and laser systems are now commercially available with fractional frequency instabilities in the mid $10^{-16}$ range. This document aims to provide technical guidance for researchers starting in the field of ultrastable lasers and to give an outlook toward the next generation of improved ultrastable lasers. These guidelines have arisen from the scope of the EMPIR project ``Next generation ultrastable lasers'' ( https://www.ptb.de/empir2021/nextlasers ) with contributions from the European project partners.

physics.optics↗
arXiv2025

Search for oscillating fundamental constants using a paired detector and vibrational spectroscopy

Ultralight dark matter (UDM) may manifest itself through oscillating fundamental constants of normal matter. These can be experimentally searched for by implementing two dissimilar oscillators producing a beat between their frequencies and analyzing the beat-frequency time series for the presence of any temporal oscillations. Typically, the time series of such a detector contains contributions from nonstationary noise. In order to reduce the influence of such noise we propose and demonstrate paired detectors: two nominally identical detectors whose signals are synchronously recorded. The cross-spectrum of the two individual beat time series is then analyzed for UDM signatures. This approach permits us to suppress spurious signals appearing in uncorrelated fashion in either detector. We furthermore demonstrate detectors that are based on a vibrational molecular transition, which are advantageous due to their larger sensitivity to oscillations of the nuclear masses. The analysis of 274 hours of data yielded improved bounds for the coupling constants of UDM to nuclear mass and to electron mass in the frequency ranges 10-500 Hz and 10-122 kHz, with improvement factors between 6 and 10. These bounds are currently the strongest. Similar bounds are obtained for the fine-structure constant. The present approach may be generalized to large ensembles of detectors.

hep-ph↗
arXiv2022

Search for ultralight dark matter with spectroscopy of radio-frequency atomic transitions

The effects of scalar and pseudoscalar ultralight bosonic dark matter (UBDM) were searched for by comparing the frequency of a quartz oscillator to that of a hyperfine-structure transition in $^{87}$Rb, and an electronic transition in $^{164}$Dy. We constrain linear interactions between a scalar UBDM field and Standard-Model (SM) fields for an underlying UBDM particle mass in the range $1\times10^{-17}-8.3\times10^{-13} $ eV and quadratic interactions between a pseudoscalar UBDM field and SM fields in the range $5\times10^{-18}- 4.1\times10^{-13} $ eV. Within regions of the respective ranges, our constraints on linear interactions significantly improve on results from previous, direct searches for oscillations in atomic parameters, while constraints on quadratic interactions surpass limits imposed by such direct searches as well as by astrophysical observations.

physics.atom-ph↗
arXiv2021

Probing fast oscillating scalar dark matter with atoms and molecules

Light scalar Dark Matter with scalar couplings to matter is expected within several scenarios to induce variations in the fundamental constants of nature. Such variations can be searched for, among other ways, via atomic spectroscopy. Sensitive atomic observables arise primarily due to possible changes in the fine-structure constant or the electron mass. Most of the searches to date have focused on slow variations of the constants (i.e. modulation frequencies $<$ 1 Hz). In a recent experiment \mbox{[Phys. Rev. Lett. 123, 141102 (2019)]} called WReSL (Weekend Relaxion-Search Laboratory), we reported on a direct search for rapid variations in the radio-frequency band. Such a search is particularly motivated within a class of relaxion Dark Matter models. We discuss the WReSL experiment, report on progress towards improved measurements of rapid fundamental constant variations, and discuss the planned extension of the work to molecules, in which rapid variations of the nuclear mass can be sensitively searched for.

physics.atom-ph↗
arXiv2020

A simplified cryogenic optical resonator apparatus providing ultra-low frequency drift

A system providing an optical frequency with an instability comparable to that of a hydrogen maser is presented. It consists of a $5$ $\mathrm{cm}$ long, vertically oriented silicon optical resonator operated at temperatures between $1.5$ $\mathrm{K}$ and $3.6$ $\mathrm{K}$ in a closed-cycle cryostat with low-temperature Joule-Thomson stage. We show that with a standard cryostat, a simple cryogenic optomechanical setup, no active or passive vibration isolation, a minimum frequency instability of $2.5\times10^{-15}$ at $τ=1500$ $\mathrm{s}$ integration time can be reached. The influence of pulse-tube vibrations was minimized by using a resonator designed for low acceleration sensitivity. With reduced optical laser power and interrogation duty cycle an ultra-low fractional frequency drift of $-2.6\times10^{-19}$/$\mathrm{s}$ is reached. At $3.5$ $\mathrm{K}$ the resonator frequency exhibits a vanishing thermal sensitivity and an ultra-small temperature derivative $8.5\times10^{-12}/\mathrm{K}^{2}$. These are favorable properties that should lead to high performance also in simpler cryostats not equipped with a Joule-Thomson stage.

physics.ins-det↗
arXiv2018

Characteristics of long-lived persistent spectral holes in $Eu^{3+}:Y_{2}SiO_{5}$ at $1.2~K$

Properties of persistent spectral holes (SHs) relevant for frequency metrology have been investigated in the system $Eu^{3+}:Y_{2}SiO_{5}$ (0.5%) at crystallographic site 1 and a temperature of $1.2$ Kelvin. Hole linewidths as small as $0.6~kHz$ have been reliably achieved. The theoretically predicted $T^4$-dependence of the frequency shift with temperature has been confirmed with high precision. The thermal hysteresis of the SH frequency between $1.15~K$ and $4.1~K$ was measured to be less than $6\cdot10^{-3}$ fractionally. After initially burning a large ensemble of SHs, their properties were studied on long time scales by probing different subsets at different times. SHs could still be observed 49 days after burning if not interrogated in the meantime. During this time, the SH linewidth increased from $4$ to $5.5~kHz$, and the absorption contrast decreased from 35% to 15%. During a 14-day interval the absolute optical frequencies of previously unperturbed spectral holes were measured with respect to a GPS-monitored active H-maser, using a femtosecond frequency comb. The fractional frequency drift rate exhibited an upper limit of $2.3\cdot10^{-19} s^{-1}$, 65 times smaller than the most stringent previous limit.

physics.atom-ph↗
arXiv2018

Simulation of force-insensitive optical cavities in cubic spacers

We analyze the properties of optical cavities contained in spacers with approximate octahedral symmetry and made of different materials,following the design of Webster and Gill (S. Webster, P. Gill, Optics Letters 36(18), 3572 (2011)). We show that for isotropic materials with Young's modulus less than 200 GPa, the Poisson's ratio $ν$ must lie in a "magic" range 0.13<$ν$<0.23 in order to null the influence of the forces supporting the spacer. This restriction can be overcome with the use of anisotropic materials such as silicon. A detailed study aiming at identification of all suitable crystal orientations of silicon with respect to the resonator body is performed and the relation to the Poisson's ratio and the Young's modulus along these orientations is discussed. We also perform an analysis of the sensitivity of the cavity performance to errors in spacer manufacturing. We find that the orientation of the [110] or [100] crystallographic directions oriented along one of the three optical axes of the resonator provides low sensitivities to imprecise manufacturing and interesting options for fundamental physics experiments.

physics.ins-det↗
arXiv2018

Characterization of the long-term dimensional stability of a NEXCERA block using the optical resonator technique

NEXCERA is a machinable and highly polishable ceramic with attractive properties for use in precision instruments, in particular because its coefficient of thermal expansion exhibits a zero crossing at room temperature. We performed an accurate measurement of the long-term drift of the length of a 12~cm long NEXCERA block by using it as a spacer of a high-finesse optical cavity. At room temperature, we found a fractional length drift rate $L^{-1}dΔL/dt=-1.74\times10^{-8}~\mathrm{yr}^{-1}$.

physics.ins-det↗
arXiv2018

A high-performance optical lattice clock based on bosonic atoms

Optical lattice clocks with uncertainty and instability in the $10^{-17}$-range and below have so far been demonstrated exclusively using fermions. Here, we demonstrate a bosonic optical lattice clock with $3\times 10^{-18}$ instability and $2.0\times 10^{-17}$ accuracy, both values improving on previous work by a factor 30. This was enabled by probing the clock transition with an ultra-long interrogation time of 4 s, using the long coherence time provided by a cryogenic silicon resonator, by careful stabilization of relevant operating parameters, and by operating at low atom density. This work demonstrates that bosonic clocks, in combination with highly coherent interrogation lasers, are suitable for high-accuracy applications with particular requirements, such as high reliability, transportability, operation in space, or suitability for particular fundamental physics topics. As an example, we determine the $^{88}\textrm{Sr} - ^{87}$Sr isotope shift with 12 mHz uncertainty.

physics.atom-ph↗
arXiv2018

Rotational spectroscopy of cold, trapped molecular ions in the Lamb-Dicke regime

Sympathetic cooling of trapped ions has been established as a powerful technique for manipulation of non-laser-coolable ions (Raizen1992,Waki1992,Bowe1999,Barrett2003). For molecular ions, it promises vastly enhanced spectroscopic resolution and accuracy. However, this potential remains untapped so far, with the best resolution achieved being not better than $5\times10^{-8}$ fractionally, due to residual Doppler broadening being present in ion clusters even at the lowest achievable translational temperatures (Bressel2012). Here we introduce a general and accessible approach that enables Doppler-free rotational spectroscopy. It makes use of the strong radial spatial confinement of molecular ions when trapped and crystallized in a linear quadrupole trap, providing the Lamb-Dicke regime for rotational transitions. We achieve a line width of $1\times10^{-9}$ fractionally and $1.3~\textrm{kHz}$ absolute, an improvement by $50$ and nearly $3\times10^{3}$, respectively, over other methods. The systematic uncertainty is $2.5\times10^{-10}$. As an application, we demonstrate the most precise test of $\textit{ab initio}$ molecular theory and the most precise ($1.3~\textrm{PPB}$) spectroscopic determination of the proton mass. The results represent the long overdue extension of Doppler-free microwave spectroscopy of laser-cooled atomic ion clusters (Berkeland1998) to higher spectroscopy frequencies and to molecules. This approach enables a vast range of high-precision measurements on molecules, both on rotational and, as we project, vibrational transitions.

quant-ph↗
arXiv2018

Laser-stimulated electric quadrupole transitions in the molecular hydrogen ion H2+

Molecular hydrogen ions are of metrological relevance due to the possibility of precise theoretical evaluation of their spectrum and of external-field-induced shifts. We report the results of the calculations of the rate of laser-induced electric quadrupole transitions between a large set of ro-vibrational states of ${\rm H_2^+}$. The hyperfine and Zeeman structure of the E2 transition spectrum and the effects of the laser polarization are treated in detail. We also present the nuclear spin-electron spin coupling constants, computed with a precision 10 times higher than previously.

physics.atom-ph↗
arXiv2015

A quantum cascade laser-based mid-IR frequency metrology system with ultra-narrow linewidth and $1\times 10^{-13}$-level frequency instability

We demonstrate a powerful tool for high-resolution mid-IR spectroscopy and frequency metrology with quantum cascade lasers (QCLs). We have implemented frequency stabilization of a QCL to an ultra-low expansion (ULE) reference cavity, via upconversion to the near-IR spectral range, at a level of $1\times10^{-13}$. The absolute frequency of the QCL is measured relative to a hydrogen maser, with instability $<1\times10^{-13}$ and inaccuracy $5\times10^{-13}$, using a frequency comb phase-stabilized to an independent ultrastable laser. The QCL linewidth is determined to be 60 Hz, dominated by fiber noise. Active suppression of fiber noise could result in sub-10 Hz linewidth.

physics.optics↗
arXiv2014

A compact, robust, and transportable ultra-stable laser with a fractional frequency instability of $1\times10^{-15}$

We present a compact and robust transportable ultra-stable laser system with minimum fractional frequency instability of $1\times10^{-15}$ at integration times between 1 to 10 s. The system was conceived as a prototype of a subsystem of a microwave-optical local oscillator to be used on the satellite mission STE-QUEST (Space-Time Explorer and QUantum Equivalence Principle Space Test, http://sci.esa.int/ste-quest/). It was therefore designed to be compact, to sustain accelerations occurring during rocket launch, to exhibit low vibration sensitivity, and to reach a low frequency instability. Overall dimensions of the optical system are $40\textrm{ cm}\times20\textrm{ cm}\times30\textrm{ cm}$. The acceleration sensitivities of the optical frequency in the three directions were measured to be $1.7\times10^{-11}/g$, $8.0\times10^{-11}/g$, and $3.9\times10^{-10}/g$, and the absolute frequency instability was determined via a three-cornered hat measurement. The design is also appropriate and useful for terrestrial applications.

physics.optics↗