arXiv subjects

Stephanie Simmons

Publications and source records attributed to Stephanie Simmons.

At least 19 recordsLinked to original sources

arXiv2026

Optically Resolved Excited State Hyperfine Structure of a Silicon Colour Centre in the Telecom Bands

Nuclear spin qubits in silicon offer exceptionally coherent quantum memory, and optically-interfaced spins are a promising platform for both quantum networking and distributed quantum computing. It has been proposed that emitters with diamagnetic ground states may permit an optical interface to nuclear spin memories via metastable, hyperfine-coupled excited states while suppressing key sources of decoherence. Until now, direct optical observation of suitable transitions in silicon colour centres has remained elusive. Here we characterize the singly-ionized interstitial aluminum donor (Al$_\mathrm{i}^+$) in isotopically purified $^{28}$Si and find several novel features of this little-studied defect. We measure bright emission and strong optical transitions and, in contrast to previous studies of this centre, attribute its emission to an exchange-split spin triplet and singlet level of the lowest-energy 1s:T$_2$ excited state. We measure the excited-state lifetimes and, as a consequence of its narrow emission linewidth, observe the fine and hyperfine structure of the long-lived triplet state. This constitutes the first measurement of an optically-resolved hyperfine structure in the excited state of a telecommunications-band silicon colour centre.

quant-ph↗

arXiv2026

Spectral tuning of single T centres by the Stark effect

Among the many solid-state emitters being explored for scalable quantum technologies, the silicon T centre is a leading candidate offering long-lived spin qubits, a telecommunications-band spin-photon interface, and integration with on-chip photonic circuits. However, nanophotonic integration broadens both the inhomogeneous spectral distribution and individual emitter linewidths. Here, we integrate single T centres into silicon nanophotonic cavities with p-i-n diodes for local electronic control. These devices enable Stark tuning up to 30 GHz, sufficient to bring 55(2)% of on-chip T centres into mutual resonance, and demonstrate tunable lifetime reduction across the cavity resonance. A model of the joint excitation probability shows an orders-of-magnitude increase in entanglement rate by tuning distinct emitters into mutual resonance. Luminescence modulation at high reverse biases reveals a transition to a dark charge state. Finally, bias-induced modulation of the optical transition splitting uncovers a potential mechanism for electrically driven excited-state spin mixing via spin-orbit coupling. Localized and individual spectral tuning increases the yield of performant silicon spin-photon interfaces and the number of devices per chip available for large-scale entanglement and quantum information technologies.

quant-ph↗

arXiv2025

Silicon T centre hyperfine structure and memory protection schemes

Combining the long-coherence of spin qubits and the capability to transmit information and entanglement through photons, spin-photon interfaces (SPIs) are a promising platform for networked quantum computation and long-distance quantum communication. SPIs that possess local `memory' qubits in addition to the optically coupled `communication' qubit can improve remote entanglement fidelities through brokered entanglement schemes and entanglement purification. In these schemes, it is critical to protect the memory qubit from decoherence during entanglement operations on the communications qubit. Silicon, a platform with mature microelectronic and nanophotonic fabrication, is host to the T centre, an SPI with emission in the telecommunications O-band that directly integrates with silicon nanophotonics. Cavity-coupled T centres are a platform for brokered entanglement distribution in silicon photonic circuits and over long-distance optical fibre links. The T centre's electron and nuclear spin qubits are an intrinsic register of communication and memory qubits respectively, with anisotropic hyperfine coupling. In this work we determine the T centre's hydrogen hyperfine coupling tensor. We also introduce schemes to protect against dephasing or eliminate relaxation of the T centre's hydrogen memory qubit during optical excitation. These results address a key challenge for practical T centre quantum networks.

quant-ph↗

arXiv2025

Giant Isotope Effect on the Excited-State Lifetime and Emission Efficiency of the Silicon T Centre

Efficient single-photon emitters are desirable for quantum technologies including quantum networks and photonic quantum computers. We investigate the T centre, a telecommunications-band emitter in silicon, and find a strong isotope dependence of its excited-state lifetime. In particular, the lifetime of the deuterium T centre is over five times longer than the common protium variant. Through explicit first-principles calculations, we demonstrate that this dramatic difference is due to a reduction in the carbon-hydrogen local vibrational mode energy, which suppresses non-radiative decay. Our results imply that the deuterium T centre approaches unit quantum efficiency, enabling more efficient single-photon sources, quantum memories, and entanglement generation.

quant-ph↗

arXiv2025

Laser-induced spectral diffusion and excited-state mixing of silicon T centres

To find practical application as photon sources for entangled optical resource states or as spin-photon interfaces in entangled networks, semiconductor emitters must produce indistinguishable photons with high efficiency and spectral stability. Nanophotonic cavity integration increases efficiency and bandwidth, but it also introduces environmental charge instability and spectral diffusion. Among various candidates, silicon colour centres have emerged as compelling platforms for integrated-emitter quantum technologies. Here we investigate the dynamics of spectral wandering in nanophotonics-coupled, individual silicon T centres using spectral correlation measurements. We observe that spectral fluctuations are driven predominantly by the near-infrared excitation laser, consistent with a power-dependent Ornstein-Uhlenbeck process, and show that the spectrum is stable for up to 1.5 ms in the dark. We demonstrate a 35x narrowing of the emitter linewidth to 110 MHz using a resonance-check scheme and discuss the advantage for pairwise entanglement rates and optical resource state generators. Finally, we report laser-induced spin-mixing in the excited state and discuss potential mechanisms common to both phenomena. These effects must be considered in calibrating T centre devices for high-performance entanglement generation.

quant-ph↗

arXiv2025

Computing Efficiently in QLDPC Codes

It is the prevailing belief that quantum error correcting techniques will be required to build a utility-scale quantum computer able to perform computations that are out of reach of classical computers. The QECCs that have been most extensively studied and therefore highly optimized, surface codes, are extremely resource intensive in terms of the number of physical qubits needed. A promising alternative, QLDPC codes, has been proposed more recently. These codes are much less resource intensive, requiring significantly fewer physical qubits per logical qubit than practical surface code implementations. A successful application of QLDPC codes would therefore drastically reduce the timeline to reaching quantum computers that can run algorithms with proven exponential speedups like Shor's algorithm and QPE. However to date QLDPC codes have been predominantly studied in the context of quantum memories; there has been no known method for implementing arbitrary logical Clifford operators in a QLDPC code proven efficient in terms of circuit depth. In combination with known methods for implementing T gates, an efficient implementation of the Clifford group unlocks resource-efficient universal quantum computation. In this paper, we introduce a new family of QLDPC codes that enable efficient compilation of the full Clifford group via transversal operations. Our construction executes any m-qubit Clifford operation in at most O(m) syndrome extraction rounds, significantly surpassing state-of-the-art lattice surgery methods. We run circuit-level simulations of depth-126 logical circuits to show that logical operations in our QLDPC codes attains near-memory performance. These results demonstrate that QLDPC codes are a viable means to reduce the resources required to implement all logical quantum algorithms, thereby unlocking a reduced timeline to commercially valuable quantum computing.

quant-ph↗

arXiv2025

Electrically-triggered spin-photon devices in silicon

Quantum networking and computing technologies demand scalable hardware with high-speed control for large systems of quantum devices. Solid-state platforms have emerged as promising candidates, offering scalable fabrication for a wide range of qubits. Architectures based on spin-photon interfaces allow for highly-connected quantum networks over photonic links, enabling entanglement distribution for quantum networking and distributed quantum computing protocols. With the potential to address these demands, optically-active spin defects in silicon are one proposed platform for building quantum technologies. Here, we electrically excite the silicon T centre in integrated optoelectronic devices that combine nanophotonic waveguides and cavities with p-i-n diodes. We observe single-photon electroluminescence from a cavity-coupled T centre with $g^{(2)}(0)=0.05(2)$. Further, we use the electrically-triggered emission to herald the electron spin state, initializing it with $92(8)\%$ fidelity. This shows, for the first time, electrically-injected single-photon emission from a silicon colour centre and a new method of electrically-triggered spin initialization. These findings present a new telecommunications band light source for silicon and a highly parallel control method for T centre quantum processors, advancing the T centre as a versatile defect for scalable quantum technologies.

quant-ph↗

arXiv2024

Distributed Quantum Computing in Silicon

Commercially impactful quantum algorithms such as quantum chemistry and Shor's algorithm require a number of qubits and gates far beyond the capacity of any existing quantum processor. Distributed architectures, which scale horizontally by networking modules, provide a route to commercial utility and will eventually surpass the capability of any single quantum computing module. Such processors consume remote entanglement distributed between modules to realize distributed quantum logic. Networked quantum computers will therefore require the capability to rapidly distribute high fidelity entanglement between modules. Here we present preliminary demonstrations of some key distributed quantum computing protocols on silicon T centres in isotopically-enriched silicon. We demonstrate the distribution of entanglement between modules and consume it to apply a teleported gate sequence, establishing a proof-of-concept for T centres as a distributed quantum computing and networking platform.

quant-ph↗

arXiv2024

Optical transition parameters of the silicon T centre

The silicon T centre's narrow, telecommunications-band optical emission, long spin coherence, and direct photonic integration have spurred interest in this emitter as a spin-photon interface for distributed quantum computing and networking. However, key parameters of the T centre's spin-selective optical transitions remain undetermined or ambiguous in literature. In this paper we present a Hamiltonian of the T centre TX state and determine key parameters of the optical transition from T$_0$ to TX$_0$ from a combined analysis of published results, density functional theory, and new spectroscopy. We resolve ambiguous values of the internal defect potential in the literature, and we present the first measurements of electrically tuned T centre emission. As a result, we provide a model of the T centre's optical and spin properties under strain, electric, and magnetic fields that can be utilized for realizing quantum technologies.

quant-ph↗

arXiv2023

Scalable Fault-Tolerant Quantum Technologies with Silicon Colour Centres

The scaling barriers currently faced by both quantum networking and quantum computing technologies ultimately amount to the same core challenge of distributing high-quality entanglement at scale. In this Perspective, a novel quantum information processing architecture based on optically active spins in silicon is proposed that offers a combined single technological platform for scalable fault-tolerant quantum computing and networking. The architecture is optimized for overall entanglement distribution and leverages colour centre spins in silicon (T centres) for their manufacturability, photonic interface, and high fidelity information processing properties. Silicon nanophotonic optical circuits allow for photonic links between T centres, which are networked via telecom-band optical photons in a highly-connected graph. This high connectivity unlocks the use of low-overhead quantum error correction codes, significantly accelerating the timeline for modular, scalable fault-tolerant quantum repeaters and quantum processors.

quant-ph↗

arXiv2023

Co-audit: tools to help humans double-check AI-generated content

Users are increasingly being warned to check AI-generated content for correctness. Still, as LLMs (and other generative models) generate more complex output, such as summaries, tables, or code, it becomes harder for the user to audit or evaluate the output for quality or correctness. Hence, we are seeing the emergence of tool-assisted experiences to help the user double-check a piece of AI-generated content. We refer to these as co-audit tools. Co-audit tools complement prompt engineering techniques: one helps the user construct the input prompt, while the other helps them check the output response. As a specific example, this paper describes recent research on co-audit tools for spreadsheet computations powered by generative models. We explain why co-audit experiences are essential for any application of generative AI where quality is important and errors are consequential (as is common in spreadsheet computations). We propose a preliminary list of principles for co-audit, and outline research challenges.

cs.HC↗

arXiv2023

High-efficiency single photon emission from a silicon T-center in a nanobeam

Color centers in Si could serve as both efficient quantum emitters and quantum memories with long coherence times in an all-silicon platform. Of the various known color centers, the T center holds particular promise because it possesses a spin ground state that has long coherence times. But this color center exhibits a long excited state lifetime which results in a low photon emission rate, requiring methods to extract photon emission with high efficiency. We demonstrate high-efficiency single photon emission from a single T center using a nanobeam. The nanobeam efficiently radiates light in a mode that is well-matched to a lensed fiber, enabling us to collect over 70% of the T center emission directly into a single mode fiber. This efficiency enables us to directly demonstrate single photon emission from the zero phonon line, which represents the coherent emission from the T center. Our results represent an important step towards silicon-integrated spin-photon interfaces for quantum computing and quantum networks.

quant-ph↗

arXiv2023

Room temperature quantum bit storage exceeding 39 minutes using ionized donors in 28-silicon

Quantum memories capable of storing and retrieving coherent information for extended times at room temperature would enable a host of new technologies. Electron and nuclear spin qubits using shallow neutral donors in semiconductors have been studied extensively but are limited to low temperatures ($\le$10 K); however, the nuclear spins of ionized donors have potential for high temperature operation. We use optical methods and dynamical decoupling to realize this potential for an ensemble of 31P donors in isotopically purified 28Si and observe a room temperature coherence time of over 39 minutes. We further show that a coherent spin superposition can be cycled from 4.2 K to room temperature and back, and report a cryogenic coherence time of 3 hours in the same system.

quant-ph↗

arXiv2022

Memory and transduction prospects for silicon T centre devices

The T centre, a silicon-native spin-photon interface with telecommunications-band optical transitions and long-lived microwave qubits, offers an appealing new platform for both optical quantum memory and microwave to optical telecommunications band transduction. A wide range of quantum memory and transduction schemes could be implemented on such a platform, with advantages and disadvantages that depend sensitively on the ensemble properties. In this work we characterize T centre spin ensembles to inform device design. We perform the first T ensemble optical depth measurement and calculate the improvement in centre density or resonant optical enhancement required for efficient optical quantum memory. We further demonstrate a coherent microwave interface by coherent population trapping (CPT) and Autler-Townes splitting (ATS). We then determine the most promising microwave and optical quantum memory protocol for such ensembles. By estimating the memory efficiency both in free-space and in the presence of a cavity, we show that efficient optical memory is possible with forecast densities. Finally, we formulate a transduction proposal and discuss the achievable efficiency and fidelity.

quant-ph↗

arXiv2022

The emerging commercial landscape of quantum computing

Quantum computing technologies are advancing, and the class of addressable problems is expanding. Together with the emergence of new ventures and government-sponsored partnerships, these trends will help lower the barrier for new technology adoption and provide stability in an uncertain market. Until then, quantum computing presents an exciting testbed for different strategies in an emerging market.

physics.soc-ph↗

arXiv2020

Thermal activation of valley-orbit states of neutral magnesium in silicon

Interstitial magnesium acts as a moderately deep double donor in silicon, and is relatively easily introduced by diffusion. Unlike the case of the chalcogen double donors, the binding energies of the even-parity valley-orbit excited states 1sT$_2$ and 1sE have remained elusive. Here we report on temperature dependence absorption measurements focusing on the neutral charge species. Our results demonstrate thermal activation from the ground state 1sA to the valley-orbit states, as observed by transitions from the thermally populated levels to the odd-parity states 2p$_0$ and 2p$_{\pm}$

physics.app-ph↗

arXiv2018

A Mg-pair isoelectronic bound exciton identified by its isotopic fingerprint in $^{28}$Si

We use the greatly improved optical linewidths provided by highly enriched $^{28}$Si to study a photoluminescence line near 1017 meV previously observed in the luminescence spectrum of natural Si diffused with Mg, and suggested to result from the recombination of an isoelectronic bound exciton localized at a Mg-pair center. In $^{28}$Si this no-phonon line is found to be comprised of five components whose relative intensities closely match the relative abundances of Mg-pairs formed by random combinations of the three stable isotopes of Mg, thus confirming the Mg-pair hypothesis. We further present the results of temperature dependence studies of this center that reveal unusual and as yet unexplained behaviour.

cond-mat.mtrl-sci↗

arXiv2018

Characterization of the Si:Se+ spin-photon interface

Silicon is the most developed electronic and photonic technological platform and hosts some of the highest-performance spin and photonic qubits developed to date. A hybrid quantum technology harnessing an efficient spin-photon interface in silicon would unlock considerable potential by enabling ultra-long-lived photonic memories, distributed quantum networks, microwave to optical photon converters, and spin-based quantum processors, all linked using integrated silicon photonics. However, the indirect bandgap of silicon makes identification of efficient spin-photon interfaces nontrivial. Here we build upon the recent identification of chalcogen donors as a promising spin-photon interface in silicon. We determined that the spin-dependent optical degree of freedom has a transition dipole moment stronger than previously thought (here 1.96(8) Debye), and the T1 spin lifetime in low magnetic fields is longer than previously thought (> 4.6(1.5) hours). We furthermore determined the optical excited state lifetime (7.7(4) ns), and therefore the natural radiative efficiency (0.80(9) %), and by measuring the phonon sideband, determined the zero-phonon emission fraction (16(1) %). Taken together, these parameters indicate that an integrated quantum optoelectronic platform based upon chalcogen donor qubits in silicon is well within reach of current capabilities.

quant-ph↗