arXiv subjects

Stephen McVitie

Publications and source records attributed to Stephen McVitie.

18 recordsLinked to original sources

arXiv2026

Compositional and Magnetic Characterisation of Oblique Co and Fe Nanowire Structures Fabricated Using Focused Electron Beam Induced Deposition

Focused electron beam induced deposition (FEBID) is an additive manufacturing technique uniquely suited for fabricating nanoscale 3D prototypes for a range of applications, including spintronic devices. However, the variation of growth dynamics associated with electron beam translation and sample interaction volumes results in structures with non-uniform composition when fabricating intricate 3D geometries. Herein, we measure changes in atomic composition and corresponding changes in magnetic induction in 3D ferromagnetic nanostructures with overhanging elements, e.g. bridges or arches. To investigate the effects of electron beam translation, we fabricated 41 Co and Fe nanowire (NW) structures with growth angle relative to the optic axis varying from 0° to 90°. The (scanning) transmission electron microscopy techniques of electron energy loss spectroscopy and off-axis electron holography were performed to map the NW elemental composition and magnetic induction as a function of NW growth angle. Comparison of the results reveals a reduction in metal content with increased oblique growth angle in FEBID NWs. The magnitude of metal content reduction can be tuned by controlling electron beam parameters, and ferromagnetic NWs with approximately equal metal content at growth angles from 0° to 60° were fabricated by using the lowest viable electron beam voltage and the highest viable beam current to reduce the interaction volume and increase the metal content, respectively.

cond-mat.mes-hall↗

arXiv2026

Beyond conventional skyrmions in synthetic antiferromagnets

Magnetic skyrmions are topologically protected spin textures that can act as reconfigurable nanoscale information carriers. In synthetic antiferromagnets (SAFs), interlayer exchange coupling offers an additional control parameter beyond the interfacial Dzyaloshinskii-Moriya interaction (DMI) and magnetic anisotropy. Here, we engineer a SAF composed of two chemically distinct ferromagnets (CoB and CoFeB), in which the external magnetic field and interlayer exchange act asymmetrically on the sublattices. The competition of these effects, acting as a resultant effective-field, gives rise to two distinct skyrmion families in different field regimes. In large fields, conventional-polarity skyrmions nucleate, with core antiparallel to the external field, whereas in smaller fields an inverse-polarity skyrmion state emerges as the effective-field reverses sign and almost saturates the CoFeB layers. Return-point memory measurements confirm independent nucleation pathways for the two families. Using element-resolved x-ray magnetometry, correlative magnetic force and Lorentz transmission electron microscopies, and parameter-matched micromagnetic modelling, we show that all textures reside only in the CoFeB layers, which experience a Ruderman-Kittel-Kasuya-Yosida (RKKY) exchange field originating from the CoB layers. This effective-field method provides a robust route to programmable three-dimensional spin textures with controlled polarity in selected layers of a multilayer with potential for applications in skyrmion-based computing and spin-logic architectures.

cond-mat.mes-hall↗

arXiv2026

Structural and magnetic properties of co-sputtered epitaxial Fe-Sn kagome thin films

In recent years the intermetallic alloys of Fe and Sn have gained significant interest due to a rich variety of magnetic properties present in these materials. The crystal Fe3Sn2 is a frustrated ferromagnet, while the crystallographically similar FeSn, which differs only by the stacking sequence of its Fe-containining kagome and stanene layers, is an antiferromagnet. Thin-film growth techniques such as magnetron sputtering allow for these different stoichiometric compositions to be grown through adjustments of the rate of deposition of the individual Fe and Sn sources, while all other conditions remain constant. Here, we report the production of high quality epitaxial thin films of Fe$_3$Sn$_2$ and FeSn on sapphire with a Pt seed layer, as well as a mixed phase containing intergrowths of both crystals, all of which we have characterized using both X-ray and four-dimensional scanning transmission electron microscopy (4D-STEM) methods. The resulting crystallographic phase content is compared to the results of magnetization measurements, with correspondence between the predicted ferromagnetic phase content and the resulting magnetization. Further magnetic properties of these films can then also be compared, leading to the discovery of a unique behavior in the temperature dependent coercivity within highly mixed phase alloys, a feature that is absent in either pure Fe3Sn2 and FeSn.

cond-mat.mtrl-sci↗

arXiv2025

Model-Based Iterative Reconstruction of Three-Dimensional Magnetisation in a Nanowire Structure Using Electron Holographic Vector Field Tomography

Methods for characterisation of 3D magnetic spin structures are necessary to advance the performance of 3D magnetic nanoscale technologies. However, as the component dimensions approach the nanometre range, it becomes more challenging to analyse 3D magnetic configurations with the appropriate spatial resolution. In this paper, we present a method based on Lorentz transmission electron microscopy in which model-based iterative reconstruction (MBIR) is used to reconstruct the most probable magnetisation in an exemplar nanostructure. This method is based on relating electron phase measurements to the magnetic configuration of the nanostructure, and therefore, the method is subject to certain limitations. In this proof-of-concept experiment, MBIR was tested on an L-shaped ferromagnetic cobalt nanowire, fabricated using focused electron beam induced deposition. Off-axis electron holography was used to acquire a tomographic tilt series of electron holograms, which were analysed to measure magnetic electron phase shift over two tilt arcs with up to $ \pm 60$ degree tilt range. Then, a 3D magnetisation vector field consistent with the tomographic phase measurements was reconstructed, revealing multiple magnetic domains within the nanowire. The reconstructed magnetisation is accurate for magnetic domains larger than 50 nm, and higher resolution can be achieved by the continued development of tomographic reconstruction algorithms.

cond-mat.mes-hall↗

arXiv2024

Strain-induced dynamic control over the population of quantum emitters in two-dimensional materials

The discovery of quantum emitters (QEs) in two-dimensional materials (2D) has triggered a surge of research to assess their suitability for quantum photonics. While their microscopic origin is still the subject of intense studies, position-controlled QEs are routinely fabricated using static strain gradients, which are used to drive excitons towards localized regions of the crystal where quantum light emission takes place. However, the use of strain in a dynamic fashion to control the brightness of single-photon sources in 2D materials has not been explored so far. In this work, we address this challenge by introducing a novel hybrid semiconductorpiezoelectric device in which WSe2 monolayers are integrated onto piezoelectric pillars that provide both static and dynamic strains. The static strains are first used to induce the formation of QEs, whose emission shows photon anti-bunching. Their energy and brightness are then controlled via the application of voltages to the piezoelectric pillars. Numerical simulations combined with drift-diffusion equations show that these effects are due to a strain-induced modification of the confining-potential landscape, which in turn leads to a net redistribution of excitons among the different QEs. Our work provides a method to dynamically control the brightness of single photon sources based on 2D materials.

cond-mat.mtrl-sci↗

arXiv2024

Phase Coexistence and Transitions between Antiferromagnetic and Ferromagnetic States in a Synthetic Antiferromagnet

In synthetic antiferromagnets (SAFs) the combination of antiferromagnetic order and synthesis using conventional sputtering techniques is combined to produce systems that are advantageous for spintronics applications. Here we present the preparation and study of SAF multilayers possessing both perpendicular magnetic anisotropy and the Dzyaloshinskii-Moriya interaction. The multilayers have an antiferromagnetically (AF) aligned ground state but can be forced into a full ferromagnetic (FM) alignment by applying an out-of-plane field $\sim 100$~mT. We study the spin textures in these multilayers in their ground state as well as around the transition point between the AF and FM states, at fields $\sim 40$~mT, by imaging the spin textures using complementary methods: photo-emission electron, magnetic force, and Lorentz transmission electron microscopies. The transformation into a FM state by field proceeds by a nucleation and growth process, where first skyrmionic nuclei form, which broaden into regions containing a FM-aligned labyrinth pattern that eventually occupies the whole film. This process remarkably occurs without any significant change in the net magnetic moment of the multilayer. The mix of AF- and FM-aligned regions on the micron scale in the middle of this transition is reminiscent of a first-order phase transition that exhibits phase coexistence. These results are important for guiding the design of spintronic devices using chiral magnetic textures made from SAFs.

cond-mat.mes-hall↗

arXiv2021

Strong magnon-photon coupling with chip-integrated YIG in the zero-temperature limit

The cross-integration of spin-wave and superconducting technologies is a promising method for creating novel hybrid devices for future information processing technologies to store, manipulate, or convert data in both classical and quantum regimes. Hybrid magnon-polariton systems have been widely studied using bulk Yttrium Iron Garnet (Y$_{3}$Fe$_{5}$O$_{12}$, YIG) and three-dimensional microwave photon cavities. However, limitations in YIG growth have thus far prevented its incorporation into CMOS compatible technology such as high quality factor superconducting quantum technology. To overcome this impediment, we have used Plasma Focused Ion Beam (PFIB) technology -- taking advantage of precision placement down to the micron-scale -- to integrate YIG with superconducting microwave devices. Ferromagnetic resonance has been measured at millikelvin temperatures on PFIB-processed YIG samples using planar microwave circuits. Furthermore, we demonstrate strong coupling between superconducting resonator and YIG ferromagnetic resonance modes by maintaining reasonably low loss while reducing the system down to the micron scale. This achievement of strong coupling on-chip is a crucial step toward fabrication of functional hybrid quantum devices that advantage from spin-wave and superconducting components.

cond-mat.mes-hall↗

arXiv2020

Phase domain boundary motion and memristance in gradient-doped FeRh nanopillars induced by spin injection

The B2-ordered alloy FeRh shows a metamagnetic phase transition, transforming from antiferromagnetic (AF) to ferromagnetic (FM) order at a temperature $T_\mathrm{t} \sim 380 $~K in bulk. As well as temperature, the phase transition can be triggered by many means such as strain, chemical doping, or magnetic or electric fields. Its first-order nature means that phase coexistence is possible. Here we show that a phase boundary in a 300~nm diameter nanopillar, controlled by a doping gradient during film growth, is moved by an electrical current in the direction of electron flow. We attribute this to spin injection from one magnetically ordered phase region into the other driving the phase transition in a region just next to the phase boundary. The associated change in resistance of the nanopillar shows memristive properties, suggesting potential applications as memory cells or artificial synapses in neuromorphic computing schemes.

cond-mat.mtrl-sci↗

arXiv2020

Asymmetric Magnetic Relaxation behavior of Domains and Domain Walls Observed Through the FeRh First-Order Metamagnetic Phase Transition

The phase coexistence present through a first-order phase transition means there will be finite regions between the two phases where the structure of the system will vary from one phase to the other, known as a phase boundary wall. This region is said to play an important but unknown role in the dynamics of the first-order phase transitions. Here, by using both x-ray photon correlation spectroscopy and magnetometry techniques to measure the temporal isothermal development at various points through the thermally activated first-order metamagnetic phase transition present in the near-equiatomic FeRh alloy, we are able to isolate the dynamic behavior of the domain walls in this system. These investigations reveal that relaxation behavior of the domain walls changes when phase coexistence is introduced into the system and that the domain wall dynamics is different to the macroscale behavior. We attribute this to the effect of the exchange coupling between regions of either magnetic phase changing the dynamic properties of domain walls relative to bulk regions of either phase. We also believe this behavior comes from the influence of the phase boundary wall on other magnetic objects in the system.

cond-mat.mes-hall↗

arXiv2020

Fast Pixelated Detectors in Scanning Transmission Electron Microscopy. Part I: Data Acquisition, Live Processing and Storage

The use of fast pixelated detectors and direct electron detection technology is revolutionising many aspects of scanning transmission electron microscopy (STEM). The widespread adoption of these new technologies is impeded by the technical challenges associated with them. These include issues related to hardware control, and the acquisition, real-time processing and visualisation, and storage of data from such detectors. We discuss these problems and present software solutions for them, with a view to making the benefits of new detectors in the context of STEM more accessible. Throughout, we provide examples of the application of the technologies presented, using data from a Medipix3 direct electron detector. Most of our software is available under an open source licence, permitting transparency of the implemented algorithms, and allowing the community to freely use and further improve upon them.

physics.ins-det↗

arXiv2020

Artificial double-helix for geometrical control of magnetic chirality

Chirality plays a major role in nature, from particle physics to DNA, and its control is much sought-after due to the scientific and technological opportunities it unlocks. For magnetic materials, chiral interactions between spins promote the formation of sophisticated swirling magnetic states such as skyrmions, with rich topological properties and great potential for future technologies. Currently, chiral magnetism requires either a restricted group of natural materials or synthetic thin-film systems that exploit interfacial effects. Here, using state-of-the-art nanofabrication and magnetic X-ray microscopy, we demonstrate the imprinting of complex chiral spin states via three-dimensional geometric effects at the nanoscale. By balancing dipolar and exchange interactions in an artificial ferromagnetic double-helix nanostructure, we create magnetic domains and domain walls with a well-defined spin chirality, determined solely by the chiral geometry. We further demonstrate the ability to create confined 3D spin textures and topological defects by locally interfacing geometries of opposite chirality. The ability to create chiral spin textures via 3D nano-patterning alone enables exquisite control over the properties and location of complex topological magnetic states, of great importance for the development of future metamaterials and devices in which chirality provides enhanced functionality.

cond-mat.mes-hall↗

arXiv2019

Heisenberg pseudo-exchange and emergent anisotropies in field-driven pinwheel artificial spin ice

Rotating all islands in square artificial spin ice (ASI) uniformly about their centres gives rise to the recently reported pinwheel ASI. At angles around 45$^\mathrm{o}$, the antiferromagnetic ordering changes to ferromagnetic and the magnetic configurations of the system exhibit near-degeneracy, making it particularly sensitive to small perturbations. We investigate through micromagnetic modelling the influence of dipolar fields produced by physically extended islands in field-driven magnetisation processes in pinwheel arrays, and compare the results to hysteresis experiments performed in-situ using Lorentz transmission electron microscopy. We find that magnetisation end-states induce a Heisenberg pseudo-exchange interaction that governs both the inter-island coupling and the resultant array reversal process. Symmetry reduction gives rise to anisotropies and array-corner mediated avalanche reversals through a cascade of nearest-neighbour (NN) islands. The symmetries of the anisotropy axes are related to those of the geometrical array but are misaligned to the array axes as a result of the correlated interactions between neighbouring islands. The NN dipolar coupling is reduced by decreasing the island size and, using this property, we track the transition from the strongly coupled regime towards the pure point dipole one and observe modification of the ferromagnetic array reversal process. Our results shed light on important aspects of the interactions in pinwheel ASI, and demonstrate a mechanism by which their properties may be tuned for use in a range of fundamental research and spintronic applications.

cond-mat.mes-hall↗

arXiv2019

Direct visualization of the magnetostructural phase transition in nano-scale FeRh thin films using differential phase contrast imaging

To advance the use of thermally-activated magnetic materials in device applications it is necessary to examine their behaviour on the localised scale in operando conditions. Equi-atomic FeRh undergoes a magnetostructural transition from an antiferromagnetic (AF) to a ferromagnetic (FM) phase above room temperature (~ 75 to 105 °C) and hence is considered a very desirable material for the next generation of novel nanomagnetic or spintronic devices. For this to be realised, we must fully understand the intricate details of AF to FM transition and associated FM domain growth on the scale of their operation. Here we combine in-situ heating with a comprehensive suite of advanced transmission electron microscopy techniques to investigate directly the magnetostructural transition in nano-scale FeRh thin films. Differential phase contrast imaging visualizes the stages of FM domain growth in both cross-sectional and planar FeRh thin films as a function of temperature. Small surface FM signals are also detected due to interfacial strain with the MgO substrate and Fe deficiency after HF etching of the substrate, providing a directional bias for FM domain growth. Our work provides high resolution imaging and quantitative measurements throughout the transition, which were previously inaccessible, and offers new fundamental insight into their potential use in magnetic devices.

cond-mat.mtrl-sci↗

arXiv2019

Ice-rule made manifold: phase transitions, topological defects and manifold restoration in two-dimensional artificial spin systems

Artificial spin ices are arrays of correlated nano-scale magnetic islands that prove an excellent playground in which to study the role of topology in critical phenomena. Here, we investigate a continuum of spin ice geometries, parameterised by rotation of the islands. In doing so, we morph from the classic square ice to the recently studied pinwheel geometry, with the rotation angle acting as a proxy for controlling inter-island interactions. We experimentally observe a change in ground state magnetic order from antiferromagnetic to ferromagnetic across this class of geometries using Lorentz transmission electron microscopy on thermally annealed cobalt arrays. The change in ordering leads to an apparent change in the nature of the defects supported: from one-dimensional strings in the antiferromagnetic phase to two-dimensional vortex-like structures in the ferromagnetic one, consistent with the scaling predicted by the Kibble-Zurek mechanism. Our results show how magnetic order in artificial spin ices can be tuned by changes in geometry so that a truly frustrated ice-rule phase is possible in two-dimensional systems. Furthermore, we demonstrate this system as a testbed to investigate out-of-equilibrium dynamics across phases.

cond-mat.mes-hall↗

arXiv2019

Order and Disorder in the Magnetisation of the Chiral Crystal CrNb$_3$S$_6$

Competing magnetic anisotropies in chiral crystals with Dzyaloshinskii Moriya exchange interactions can give rise to non-trivial chiral topological magnetisation configurations with new and interesting properties. One such configuration is the magnetic soliton, where the moment continuously rotates about an axis. This magnetic system can be considered to be one dimensional and, because of this, it supports a macroscale coherent magnetisation, giving rise to a tunable chiral soliton lattice (CSL) that is of potential use in a number of applications in nanomagnetism and spintronics. In this work we characterise the transitions between the forced-ferromagnetic (F-FM) phase and the CSL one in CrNb$_3$S$_6$ using differential phase contrast imaging in a scanning transmission electron microscope, conventional Fresnel imaging, ferromagnetic resonance spectroscopy, and mean-field modelling. We find that the formation and movement of dislocations mediate the formation of CSL and F-FM regions and that these strongly influence the highly hysteretic static and dynamic properties of the system. Sample size and morphology can be used to tailor the properties of the system and, with the application of magnetic field, to locate and stabalise normally unstable dislocations and modify their dimensions and magnetic configurations in ways beyond that predicted to occur in uniform films.

cond-mat.mtrl-sci↗

arXiv2018

Superferromagnetism and domain-wall topologies in artificial 'pinwheel' spin ice

For over ten years, arrays of interacting single-domain nanomagnets, referred to as artificial spin ices, have been engineered with the aim to study frustration in model spin systems. Here, we use Fresnel imaging to study the reversal process in 'pinwheel' artificial spin ice, a modified square ASI structure obtained by rotating each island by some angle about its midpoint. Our results demonstrate that a simple 45° rotation changes the magnetic ordering from antiferromagnetic to ferromagnetic, creating a superferromagnet which exhibits mesoscopic domain growth mediated by domain wall nucleation and coherent domain propagation. We observe several domain-wall configurations, most of which are direct analogues to those seen in continuous ferromagnetic films. However, novel charged walls also appear due to the geometric constraints of the system. Changing the orientation of the external magnetic field allows control of the nature of the spin reversal with the emergence of either 1-D or 2-D avalanches. This unique property of pinwheel ASI could be employed to tune devices based on magnetotransport phenomena such as Hall circuits.

cond-mat.dis-nn↗

arXiv2017

Very low critical current density for motion of coupled domain walls in synthetic ferrimagnet nanowires

Domain walls in ferromagnetic nanowires are potential building-blocks of future technologies such as racetrack memories, in which data encoded in the domain walls are transported using spin-polarised currents. However, the development of energy-efficient devices has been hampered by the high current densities needed to initiate domain wall motion. We show here that a remarkable reduction in the critical current density can be achieved for in-plane magnetised coupled domain walls in CoFe/Ru/CoFe synthetic ferrimagnet tracks. The antiferromagnetic exchange coupling between the layers leads to simple Néel wall structures, imaged using photoemission electron and Lorentz transmission electron microscopy, with a width of only $\sim 100$~nm. The measured critical current density to set these walls in motion, detected using magnetotransport measurements, is $1.0 \times 10^{11}$~Am$^{-2}$, almost an order of magnitude lower than in a ferromagnetically coupled control sample. Theoretical modelling indicates that this is due to nonadiabatic driving of anisotropically coupled walls, a mechanism that can be used to design efficient domain-wall devices.

cond-mat.mes-hall↗

arXiv2015

Magnetic microscopy of topologically protected homochiral domain walls in an ultrathin perpendicularly magnetized Co film

Next-generation concepts for solid-state memory devices are based on current-driven domain wall propagation, where the wall velocity governs the device performance. It has been shown that the domain wall velocity and the direction of travel is controlled by the nature of the wall and its chirality. This chirality is attributed to effects emerging from the lack of inversion symmetry at the interface between a ferromagnet and a heavy metal, leading to an interfacial Dzyaloshinskii-Moriya interaction that can control the shape and chirality of the magnetic domain wall. Here we present direct imaging of domain walls in Pt/Co/AlO$_x$ films using Lorentz transmission electron microscopy, demonstrating the presence of homochiral, and thus topologically protected, Néel walls. Such domain walls are good candidates for dense data storage, bringing the bit size down close to the limit of the domain wall width.

cond-mat.mtrl-sci↗