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Subhasis Ghosh

Publications and source records attributed to Subhasis Ghosh.

At least 19 recordsLinked to original sources

Contrasting anisotropic electron-phonon-spin coupling in Fe$_{3}$GeTe$_{2}$ and Fe$_{5}$GeTe$_{2}$: A helicity-resolved Raman study

Two-dimensional van der Waals ferromagnets Fe$_3$GeTe$ _2$ (F3GT) and Fe$_5$GeTe$_2$ (F5GT) exhibit pronounced magneto-optical responses, which open promising platforms for investigating the interplay among lattice, electronic, and magnetic degrees of freedom. Here, we present a comparative study of optical resonance-induced anisotropic electron-phonon coupling and its association with magnetic ordering in these systems using wavelength- and temperature-dependent helicity-resolved Raman spectroscopy. By resolving the doubly degenerate E modes under left- and right-circularly polarized excitations, we demonstrate that the temperature evolution of the chiral mode splitting ($\Delta f$) does not track the magnetization behavior, indicating that the helicity-dependent Raman response arises not solely from time-reversal symmetry breaking due to magnetic order, but also from spin-orbit-coupled electronic interactions. Notably, in F3GT, the out-of-plane magnetization indirectly governs the in-plane anisotropic electron-phonon coupling under optical resonance, whereas F5GT exhibits static anisotropic interactions. The Fano asymmetry parameter $1/q$ reveals mode- and temperature-dependent coupling strengths between phonons and the electronic continuum, with pronounced angular anisotropy in F3GT but isotropic behavior in F5GT--- a consequence of its multiple Fe sites and enhanced interlayer hybridization in the latter. Our results demonstrate the role of crystal structure and magnetic anisotropy in shaping the anisotropically coupled electron-phonon-spin dynamics in these layered metallic ferromagnets, and highlight Fe$_x$GeTe$_2$ as a versatile platform for microscopic insight into chiral light-matter interactions in layered metallic ferromagnets.

cond-mat.str-el

Demystifying the trend of the healthcare index: Is historical price a key driver?

Healthcare sector indices consolidate the economic health of pharmaceutical, biotechnology, and healthcare service firms. The short-term movements in these indices are closely intertwined with capital allocation decisions affecting research and development investment, drug availability, and long-term health outcomes. This research investigates whether historical open-high-low-close (OHLC) index data contain sufficient information for predicting the directional movement of the opening index on the subsequent trading day. The problem is formulated as a supervised classification task involving a one-step-ahead rolling window. A diverse feature set is constructed, comprising original prices, volatility-based technical indicators, and a novel class of nowcasting features derived from mutual OHLC ratios. The framework is evaluated on data from healthcare indices in the U.S. and Indian markets over a five-year period spanning multiple economic phases, including the COVID-19 pandemic. The results demonstrate robust predictive performance, with accuracy exceeding 0.8 and Matthews correlation coefficients above 0.6. Notably, the proposed nowcasting features have emerged as a key determinant of the market movement. We have employed the Shapley-based explainability paradigm to further elucidate the contribution of the features: outcomes reveal the dominant role of the nowcasting features, followed by a more moderate contribution of original prices. This research offers a societal utility: the proposed features and model for short-term forecasting of healthcare indices can reduce information asymmetry and support a more stable and equitable health economy.

q-fin.ST

Anisotropic electron-phonon coupling and chiral phonons in van der Waals room temperature ferromagnet Fe$_{5}$GeTe$_{2}$

The layered van der Waals Fe$_5$GeTe$_2$ (F5GT) compound exhibits room-temperature ferromagnetism, making it a promising candidate for technological applications. In our study, combined temperature, wavelength, and polarization-dependent Raman measurements, along with {\it ab initio} calculations reveal important aspects of lattice dynamics and electron-phonon interactions. The angle-resolved Raman intensity under linear polarization configurations exhibits a strong tilt in the laboratory coordinate system, indicating the existence of anisotropic electron-phonon coupling. The temperature evolution of this anisotropy is discussed by extracting the phase factor of the Raman tensor elements from the angle-resolved intensity measured at different temperatures, also uncovering a spin-orbit coupling-mediated electron-phonon response in F5GT. The thermal evolution of electron-phonon coupling is also examined by measuring the temperature dependence of the Fano parameter of the asymmetric peak in the Raman spectra, while wavelength-dependent measurements establish the role of optical resonance in enhancing the anisotropic interaction. Finally, the threefold rotational symmetry guarantees the existence of chiral phonons. We present direct spectroscopic evidence for these chiral vibrational modes through cross-circularly polarized Raman measurements, complemented by theoretical calculations of phonon circular polarization. Together, these results identify F5GT as an ideal platform for investigating emergent couplings among lattice, electronic, and magnetic degrees of freedom and for advancing the understanding of chiral phonons in magnetic van der Waals materials.

cond-mat.mtrl-sci

Graphene Straintronics by Molecular Trapping

Here, we report on controlling strain in graphene by trapping molecules at the graphene-substrate interface, leveraging molecular dipole moments. Spectroscopic and transport measurements show that strain correlates with the dipole moments of trapped molecules, with a dipole range of 1.5 D to 4.9 D resulting in a 50-fold increase in strain and a substantial rise in the residual carrier density. This has been possible by charge transfer between graphene and trapped molecules, altering the C=C bond length, and causing biaxial strain. First-principles density functional theory calculations confirm a consistent dependence of bending height on molecular dipole moments.

cond-mat.mes-hall

NDUI+: A fused DMSP-VIIRS based global normalized difference urban index dataset

Urbanization is advancing rapidly, covering less than 2% of Earth's surface yet profoundly influencing global environments and experiencing disproportionate impacts from extreme weather events. Effective urban management and planning require high-resolution, temporally consistent datasets that capture the complexity of urban growth and dynamics. This study presents NDUI+, a novel global urban dataset addressing critical gaps in urban data continuity and quality. NDUI+ integrates data from the Defense Meteorological Satellite Program's Operational Linescan System (DMSP-OLS), VIIRS Nighttime Light, and Landsat 7 NDVI using advanced remote sensing and deep learning techniques. The dataset resolves sensor discontinuity challenges, offering a seamless 30-meter spatial and annual temporal resolution time series from 1999 to the present. NDUI+ demonstrates high precision and granularity, aligning closely with high-resolution satellite data and capturing urban dynamics effectively. The dataset provides valuable insights for urban climate studies, IPCC assessments, and urbanization research, complementing resources like UT-GLOBUS for urban modeling.

physics.soc-ph

Origin of magnetic anisotropy in $La_{(1\-x)}Sr_{x}MnO_{3}$

Here, we report the origin of magnetic anisotropy in Sr-doped infinite layer manganites $La_{(1\-x)}Sr_{x}MnO_{3}$ (0.125 \leq x \leq 0.400). Magnetic anisotropy is responsible for the large difference in the temperature dependence of field-cooled and zero-field-cooled magnetization. Translational symmetry breaking in the context of spins around the boundary between the ferromagnetic (FM) antiferromagnetic (AFM) region leads to FM-AFM interaction and results in magnetic anisotropy (exchange anisotropy). Here, we propose that FM-AFM interaction around the boundary between FM clusters or domains in the AFM background or between AFM clusters or domains in the ferromagnetic background is responsible for doping-dependent nonmonotonic behavior and the origin of magnetic anisotropy.

cond-mat.str-el

Magnetism in quasi-two-dimensional tri-layer La$_{2.1}$Sr$_{1.9}$Mn$_3$O$_{10}$ manganite

The tri-layer La$_{3-3x}$Sr$_{1+3x}$Mn$_{3}$O$_{10}$ manganites of Ruddlesden-Popper (RP) series are naturally arranged layered structure with alternate stacking of m-MnO$_2$ (m = 3) planes and rock-salt type block layers (La, Sr)$_2$O$_2$ along c-axis. The dimensionality of the RP series manganites depends on the number of perovskite layers and significantly affects the magnetic and transport properties of the system. The tri-layer La$_{2.1}$Sr$_{1.9}$Mn$_{3}$O$_{10}$ shows second-order magnetic phase transition. The critical behavior of phase transition has been studied around the transition temperature (T$_C$) to understand the low dimensional magnetism in tri-layer La$_{2.1}$Sr$_{1.9}$Mn$_{3}$O$_{10}$ of the Ruddlesden-Popper series manganites. We have determined the critical exponents for tri-layer La$_{2.1}$Sr$_{1.9}$Mn$_{3}$O$_{10}$, which belong to the short-range two-dimensional (2D)-Ising universality class. The low dimensional magnetism in tri-layer La$_{2.1}$Sr$_{1.9}$Mn$_{3}$O$_{10}$ manganite is also explained with the help of renormalization group theoretical approach for short-range 2D-Ising systems. It has been shown that the layered structure of tri-layer La$_{2.1}$Sr$_{1.9}$Mn$_{3}$O$_{10}$ results in three different type of interactions intra-planer ($ J_{ab} $), intra-tri-layer ($ J_{c} $) and inter-tri-layer ($ J' $) such that $ J_{ab} $ $ > $ $ J_{c} $ $ >> $$ J' $ and competition among these give rise to the canted antiferromagnetic spin structure above T$ _{C} $. Based on the similar magnetic interaction in bi-layer manganite, we propose that the tri-layer La$_{2.1}$Sr$_{1.9}$Mn$_{3}$O$_{10}$ should be able to host the skyrmion below T$ _{C} $ due to its strong anisotropy and layered structure.

cond-mat.str-el

Multiple phases with tricritical point and Lifshitz point in skyrmion host Cu$_2$OSeO$_3$

Magnetic skyrmions, a topologically stable spin swirling object, have attracted a great interest due to their potential applications in future spintronics and ultra high dense magnetic memory devices. Cu$_2$OSeO$_3$ is only known insulating chiral helimagnet with multiple phases including skyrmion phase. Existence of skyrmion phase as well as first and second order phase transitions make Cu$_2$OSeO$_3$ a promissing candidate for investigating complex magnetic phenomena. Here, we report that both first and second order magnetic phase transitions are responsible in determining the phase diagram with atleast two multicritical point in Cu$_2$OSeO$_3$. Fluctuation-induced first order transition is realized as a precursor for skyrmion phase over a small window of temperature of magnetic field. The evolution of field dependent entropy at the phase transition provides the evidence for tricritical point. Furthermore, existence of commensurate and incommensurate phases, alongwith co-existence of three second order phase transitions provide evidence for the existence of Lifshitz point.

cond-mat.str-el

Relativistic nature of carriers: Origin of electron-hole conduction asymmetry in m o n o l a ye r gr a p h e n e

We report electron-hole conduction asymmetry in monolayer graphene. Previously, it has been claimed that electron-hole conduction asymmetry is due to imbalanced carrier injection from metallic electrodes. Here, we show that metallic contacts have negligible impact on asymmetric conduction and may be either sample or device-dependent phenomena. Electrical measurements show that monolayer graphene based devices exhibit suppressed electron conduction compared to hole conduction due to the presence of donor impurities which scatter electrons more efficiently. This can be explained by the relativistic nature of charge carriers in a graphene monolayer and can be reconciled with the fact that in a relativistic quantum system transport cross section does depend on the sign of scattering potential in contrast to a nonrelativistic quantum system.

cond-mat.mes-hall

Photoinduced Suppression of Superconductivity in Bi$_2$Sr$_2$Ca$_2$Cu$_3$O$_{10+δ}$

Superconductivity in high temperature superconductors is achieved by introducing charge carriers into cuprate insulators containing CuO$_2$ planes. Perturbation in these CuO$_2$ planes suppresses superconductivity by strongly affecting the electronic environment. Here we have use photoinduced electronic modification of Cu ion in CuO$_2$ plane to investigate the effect of local perturbation in Bi$_2$Sr$_2$Ca$_2$Cu$_3$O$_{10+δ}$. This method has been used to suppress superconducting transition temperature T$_c$. We show that our results on photoinduced suppression of superconductivity are consistent with a scenario based on pinning of fluctuating stripes in Bi$_2$Sr$_2$Ca$_2$Cu$_3$O$_{10+δ}$.

cond-mat.supr-con

Mechanism of Electric Field Induced Conductance Transition in Molecular Organic Semiconductor Based Thin Films

We have studied the electrical field induced conductance transition in thin film of Perylenetetracarboxylic dianhydride sandwiched between two metal electrodes, from an insulating state to conducting state with a high ON-OFF ratio in those devices, where one of electrodes is either Al or Cu. Temperature dependence of resistivity shows semiconducting behavior in OFF-state, but it shows metallic behavior in the ON-state. Devices with a thin intermediate layer of LiF between metal electrode and organic layer, or devices fabricated in planar configuration do not show switching behavior. All these suggest that conducting pathways are responsible for the electric field induced conductance transition.

cond-mat.other

Photoluminescence Spectroscopy of Band Gap Shrinkage in GaN

We present an experimental investigation of band-gap shrinkage in n-type GaN using photoluminescence spectroscopy, as a function of electron concentration and temperature. The observed systematic shift of the band-to-band transition energy to lower energies with increasing electron concentration has been interpreted as many-body effects due to exchange and correlation among majority and minority carriers. The band-to-band transition energy also shifts to lower energy with increasing temperature. The parameters that describe the temperature dependence red-shift of the band-edge transition energy are evaluated using different models and we find that the semi-empirical relation based on phonon-dispersion related spectral function leads to excellent fit to the experimental data.

cond-mat.mtrl-sci

Charge Carrier Transport in Metal Phthalocyanine Based Disordered Thin Films

The charge carrier transport in metal phthallocyanine based disordered thin films has been investigated. Charge carrier mobility in these disordered thin films strongly depends on the electric field and temperature due to hopping conduction. The applicability of two different Gaussian disorder models has been compared and evaluated for charge carrier transport using simple experimental results and based on our extensive analysis, it has been found that spatial and energetic correlation is important in explaining the electrical transport in these organic semiconductors.

cond-mat.dis-nn

Pairs of Gold Electrodes with Nanometer Separation Performed over SiO$_2$ Substrates with a Molecular Adhesion Monolayer

Pairs of electrodes with nanometer separation (nano-gap) are achieved through an electromigration-induced break-junction (EIBJ) technique at room temperature. Lithographically defined gold (Au) wires are formed by e-beam evaporation over oxide coated silicon substrates silanized with (3-Mercaptopropyl)trimethoxysilane (MPTMS) and then subjected to electromigration at room temperature to create a nanometer scale gap between the two newly formed Au electrodes. The Si-O-Si covalent bond at the SiO$_2$ surface and the Au-sulphur (Au-S) bond at the top evaporated Au side, makes MPTMS as an efficient adhesive monolayer between SiO$_2$ and Au. Although the Au wires are initially 2$μ$m wide, gaps with length $\sim$1nm and width $\sim$5nm are observed after breaking and imaging through a field effect scanning electron microscope (FESEM). This technique eliminates the presence of any residual metal interlink in the adhesion layer (chromium or titanium for Au deposition over SiO$_2$) after breaking the gold wire and it is much easier to implement than the commonly used low temperature EIBJ technique which needs to be executed at 4.2 K. Metal-molecule-metal structures with symmetrical metal-molecule contacts at both ends of the molecule, are fabricated by forming a self-assembled monolayer of -dithiol molecules between the EIBJ created Au electrodes with nanometer separation. Electrical conduction through single molecules of 1,4-Benzenedimethanethiol (XYL) is tested using the Au/XYL/Au structure with chemisorbed gold-sulfur (Au-S) coupling at both contacts.

cond-mat.mes-hall

Origin of Low-Frequency Negative Transconductance Dispersion in p-HEMT

Measurements of low-frequency transconductance dispersion at different temperatures and conductance deep level transient spectroscopic(CDLTS) studies of an AlGaAs/InGaAs pseudomorphic HEMT were carried out. The experimental results show the presence of defect states at the AlGaAs/InGaAs hetero-interface. A mobility degradation model was developed to explain the low frequency negative transconductance dispersion as well as the apparent hole-like peaks observed in the CDLTS spectra. This model incorporates a time dependent change in 2DEG mobility due to ionised impurity scattering by the remaining charge states at the adjoining AlGaAs/InGaAs hetero-interface.

cond-mat.mes-hall

The Origin of Stokes Shift in Semiconductor Quantum Dots

The mechanism of Stokes shift in semiconductor quantum dots is investigated by calculating the energy of the excitonic states. We have taken into account all possible contributions to the total electronic energy in the dot, i.e, dielectric mismatch between dot and surrounding medium, the effects of finite barrier height and electron-hole exchange interaction. The Stokes shift is calculated as a function of radius of dot and compared with experimental data on two different semiconductor based quantum dots. These results provide evidence for exchange splitting of excitonic states, as the mechanism of Stokes shift in quantum dot

cond-mat.mes-hall

Temperature dependence of the band gap shrinkage due to electron-phonon interaction in undoped n-type GaN

The photoluminescence spectra of band-edge transitions in GaN is studied as a function of temperature. The parameters that describe the temperature dependence red-shift of the band-edge transition energy and the broadening of emission line are evaluated using different models. We find that the semi-empirical relation based on phonon-dispersion related spectral function leads to excellent fit to the experimental data. The exciton-phonon coupling constants are determined from the analysis of linewidth broadening.

cond-mat.mtrl-sci