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Suriyaprasanth Shanmugasundaram

Publications and source records attributed to Suriyaprasanth Shanmugasundaram.

2 recordsLinked to original sources

Partial ionization cross sections of isobutanol

The electron and positron impact partial ionization cross sections (PICS) for isobutanol were calculated using variants of the binary encounter Bethe model (BEB). The modified BEB (mBEB) model and the mass spectrum dependent (MSD) method are used to calculate the PICS of cationic fragments of isobutanol. Also for calculating the positron impact ionization and dissociative ionization cross sections, we have used the BEB-0 model and the BEB-W model which are scaled Wannier threshold laws along with the BEB-A and BEB-B models which obey Jansen's threshold law. The study also compares the PICS calculated from other isomers of butanol presented in the literature. We also presented the synthetic electron impact mass spectrum of isobutanol which is compared with the experimental measurements.

physics.chem-ph↗

Electron impact partial ionization cross sections: R-carvone, 2-butanol, imidazole, and 2-nitroimidazole

We theoretically calculate the electron impact partial and total ionization cross sections of R-carvone $(\mathrm{C_{10}H_{14}O})$, 2-butanol $(\mathrm{C_{4}H_{10}O})$, imidazole $(\mathrm{C_3H_4N_2})$ and 2-nitroimidazole $(\mathrm{C_3H_3N_3O_2})$. We have used the Binary Encounter Bethe (BEB) model to obtain the total electron impact ionization cross sections (TICS). The modified BEB method in combination with mass spectrum data of the molecules is used to calculate the partial ionization cross sections (PICS) of the cationic fragments dissociating from the parent molecule. Our PICS data for R-carvone and 2-butanol are in good agreement with the experimental data for all the cation fragments along with the TICS data. For imidazole and 2-nitroimidazole, the estimates of the PICS are reported for the first time in the present study. We have found that both the modified BEB method and the mass spectrum dependence method work effectively to estimate PICS if we have information about the appearance energies and relative abundance data of the target under investigation.

physics.atm-clus↗