arXiv subjects

Susana F. Huelga

Publications and source records attributed to Susana F. Huelga.

At least 19 recordsLinked to original sources

arXiv2026

Discriminating Lindbladian Dynamics

The fundamental task of quantum hypothesis testing, which consists in discriminating quantum objects, has been extensively studied for quantum states and channels. Here, we investigate the fundamental limits of discriminating an arbitrary pair of quantum Markovian dynamics generated by Lindbladians, focusing on the roles of total exposure time and temporal resolution. We allow adaptive choices of evolution durations and arbitrary instantaneous controls between them. We characterise the optimal type-II error exponent (Stein exponent) as the largest instantaneous increase of quantum relative entropy, and give an algebraic criterion for its finiteness in terms of the Lindbladians. Remarkably, an infinite exponent is equivalent to a vanishing type-II error probability at sufficiently large finite total time, for every positive type-I tolerance. While some dynamics admit a finite protocol with zero type-II error, others require increasingly fine temporal control. For the latter, the error vanishes as the minimum allowed evolution duration, or resolution time, tends to zero at fixed sufficiently large total time, but remains bounded away from zero at every fixed positive resolution time. We achieve this using quantum Zeno protocols, establishing temporal resolution as a resource for discrimination. When the null hypothesis is the identity semigroup, an infinite asymptotic error exponent has a stronger consequence: at a fixed finite total exposure time, the type-II error can be made arbitrarily small while keeping the type-I error exactly zero. This is impossible in the corresponding classical setting. Discriminating the identity semigroup from generalised amplitude damping on a qubit provides examples of all three regimes: a finite asymptotic error exponent, zero type-II error attainable at positive resolution time, and vanishing type-II error requiring the resolution time to tend to zero.

quant-ph↗

arXiv2026

Zeno-Assisted Quantum Heat Engines

Finite-time quantum heat engines (QHEs) typically extract less work than their quasistatic counterparts because fast driving generates coherences and non-adiabatic transitions during the work strokes, a phenomenon commonly referred to as quantum friction. Quantum lubrication denotes a broad class of strategies that use auxiliary systems or controls to mitigate this loss. In this work, we introduce a lubrication protocol based on the quantum Zeno dynamics (QZD). By coupling the working medium to an auxiliary lubricant system and frequently monitoring the lubricant, we confine the joint evolution to a Zeno subspace and obtain an effective shortcut to adiabaticity during the work strokes of a QHE running an Otto cycle. In the ideal Zeno limit, the protocol reproduces the transitionless dynamics required to preserve populations in the instantaneous energy basis and recover the Otto efficiency at finite stroke duration. We also analyze several implementation-dependent thermodynamic costs, including switching, driving, monitoring, and imperfect thermalization, in order to assess how these costs constrain the practical gains in efficiency and power. Our results identify QZD as a conceptually distinct route to quantum lubrication and highlight quantum heat engines as a useful setting in which to study the interplay between strong coupling, measurement, and quantum thermodynamic control.

quant-ph↗

arXiv2026

Bridging steady-state and time-domain descriptions of molecular electron transport

Electron transmission from an input electrode, through a molecular system, to an output electrode has been widely studied using the steady-state non-equilibrium Green's function (NEGF) method. Recently, the wave packet method, which provides access to the transient dynamics of electrons as well as internal molecular degrees of freedom, has been employed to investigate enantiospecific electron transport through chiral molecules. In this work, we derive the quantitative relation between the transmission of a finite-size wave packet and the energy-resolved NEGF transmission, showing that the former corresponds to a spectral average of the latter weighted by the wave packet energy distribution. Exploiting this correspondence, we construct non-Gaussian auxiliary wave packets whose spectral weight encodes the Landauer energy-window, allowing current-voltage characteristics to be obtained directly from time propagation. We further show that the correspondence extends to spin-resolved transport in a spin-phonon model of chirality-induced spin selectivity.

cond-mat.mes-hall↗

arXiv2026

Approaching Resource-Theoretic Optimal Performance with Structured Environments

Resource-theoretic approaches to thermodynamics provide powerful, model-independent bounds on the efficiency of physical processes, because they do not rely on microscopic details of the environment. Whether such bounds can be approached by realistic dynamics generated by explicit system-environment interactions remains an open question. Photoisomerization, a fundamental molecular photoreaction, offers a concrete setting to examine this issue. We introduce a tunable microscopic model of a molecular photoswitch coupled to a structured vibrational environment, which interpolates continuously between Markovian and non-Markovian regimes. Resource-theoretic analysis predicts in particular that Markovian Thermal Operations achieve strictly lower yields than general Thermal Operations. We show that environmental memory lifts dynamical restrictions associated with Markovian thermal evolutions, thereby enlarging the set of transformations accessible to the microscopic dynamics. Approaching the thermal operation bound, however, depends on the microscopic coupling structure that generates this memory and directs the resulting dynamics towards the target transformation.

quant-ph↗

arXiv2026

Tensor network methods for non-perturbative dynamics of open quantum systems

The description of open quantum system dynamics beyond the perturbative treatment (usually associated with Markovian master equations) is a computationally challenging task due to the unfavorable exponential scaling of memory kernels. Developed over recent decades in the context of quantum information and condensed matter, tensor networks provide both a new formalism and a toolbox for overcoming previous computational bottlenecks. This framework enables the formulation of non-perturbative, numerically exact methods for describing the dynamics of open quantum systems to controllable numerical accuracy. In this review, we present these methods and discuss their commonalities and differences to paint a comprehensive view of the field.

quant-ph↗

arXiv2026

Robustness of spin state superpositions for noisy quantum metrology

Quantum metrology faces major challenges in noisy environments, where decoherence rapidly degrades useful quantum resources. We investigate the dynamics of the precision limits given by the quantum Fisher information (QFI) for phase estimation under spatially correlated dephasing. We characterize the dynamics of the QFI by the sensitivity and degradation indicators that can be obtained as analytical expressions derived using perturbative theory treatment. These short-time and weak-noise formulas yield analytic insight into how collective-spin moments govern both (i) the noiseless sensitivity and (ii) the leading noise-induced degradation of metrological usefulness. We identify a trade-off that is intrinsic to our commuting encoding-noise structure. We analyze the QFI dynamics for the Gaussian spin state (GSS) superpositions, encompassing spin coherent state (SCS), Dicke state superpositions, spin-squeezed states, and GHZ-like states. Predictions from indicators of the QFI dynamics are compared to both the quantum Cramér--Rao bound and the measurement-specific sensitivity bounds for an optimal parameter and interrogation time under a finite total time resource. When possible, we analytically derive the measurement-specific sensitivity bounds for spin-projection and parity-based measurements.

quant-ph↗

arXiv2026

DAMPyF: a Python implementation of the DAMPF method for the simulation of open-system dynamics

DAMPyF is an open-source Python implementation of the dissipation-assisted matrix product factorization (DAMPF) method, a tensor-network-based approach for the numerically exact simulation of finite-dimensional quantum systems coupled to bosonic environments. The method relies on a pseudomode representation of structured reservoirs and a matrix-product-state representation of the density matrix of the extended system, comprising the system and the pseudomodes. DAMPyF currently provides two workflows. First, it supports excitation energy-transfer dynamics within the single-system-excitation manifold, in which a system excitation is propagated in time. Second, it provides a high-level workflow tailored to molecular spectroscopy, in which the system levels represent electronic states and optical coherences are propagated for the subsequent computation of linear spectra, including absorption and circular dichroism. This paper describes the physical model, the DAMPF algorithm, the user-facing code structure, installation and execution, input and output formats, and minimal examples.

quant-ph↗

arXiv2026

Thermalization of open quantum systems with pseudomodes

Pseudomode approaches allow for an exact and unapproximated description of a quantum system interacting arbitrarily strongly with a bath. In general, a system coupled to pseudomodes will not thermalize to the system's Gibbs state: This is to be expected when the system-bath coupling is non-perturbative, but conflicts with common thermodynamic intuition when the system-bath coupling is asymptotically weak. We explore under which circumstances pseudomode models satisfy detailed balance (and subsequently thermalize to the system Gibbs state) and how specific choices of parameters can force "weak" detailed balance that is restricted to a limited frequency range. A combination of Hermitian and non-Hermitian pseudomodes that yields a flat effective-temperature profile is also considered. The results and criteria established here are relevant for the construction of pseudomode models in contexts where thermodynamic consistency is required.

quant-ph↗

arXiv2026

Relativistic Gravity-Induced Entanglement via Frame Dragging

Gravity-induced entanglement has been proposed as a method for testing the non-classical nature of gravity via tabletop experiments. While most existing proposals are restricted to the Newtonian limit, the frame dragging effect offers access to genuinely post-Newtonian features of the gravitational interaction and remains comparatively less explored. Here, we study gravity-induced entanglement generated by frame dragging in an interferometric setting and compute the entanglement phase between the rotational degrees of freedom of a source mass and the paths of a particle in two complementary ways: (i) via Schrödinger evolution with a quantized Lense-Thirring Hamiltonian in the large angular momentum limit, and (ii) via the on-shell action of linearized quantum gravity within the stationary phase approximation. Both approaches yield the same entanglement phase, consistent with the proper time difference between the interferometer arms. The path integral derivation further reveals how gravitational retardation modifies the entanglement phase, thereby making the local, relativistically causal linearized-gravity description explicit. Under the standard locality/mediator assumptions used in existing arguments, the resulting entanglement would witness non-classicality of the gravitational interaction.

quant-ph↗

arXiv2026

Quantum Cramer-Rao Precision Limit of Noisy Continuous Sensing

Quantum sensors hold considerable promise for precision measurement, yet their capabilities are inherently constrained by environmental noise. A fundamental task in quantum sensing is determining the precision limit of noisy sensor devices. For continuously monitored quantum sensors, characterizing the optimal precision in the presence of environments other than the measurement channel is an outstanding open theoretical challenge, due to the infinite-dimensional nature of the sensor output field and the complex temporal correlation of the photons therein. Here, we establish a numerically efficient method to determine the quantum Cramer-Rao bound for continuously monitored quantum sensors subject to general environmental noise -- Markovian or non-Markovian, and showcase its application with paradigmatic models of continuously monitored quantum sensors. Applicable to both constant-parameter and waveform estimation, our method provides a rigorous and practical framework for assessing and enhancing the sensor performance in realistic settings, with broad applications across experimental quantum physics.

quant-ph↗

arXiv2026

Angular Momentum Entanglement Mediated By General Relativistic Frame Dragging

Current proposals to probe the quantum nature of gravity in the low-energy regime predominantly focus on the Newtonian interaction term. In this work, we present a theoretical exploration of gravitationally mediated entanglement arising from a genuinely general relativistic effect: frame dragging. This interaction gives rise to an effective dipolar coupling between the angular momenta of two rotating, spherically symmetric masses, allowing entanglement generation between angular momentum degrees of freedom. We represent the quantum states by angular momentum eigenstates and show that, while the maximal entangling rate is achieved for highly delocalized initial states, non-negligible quantum correlations can still emerge even when the initial states are not prepared in superposition. We then analyze the robustness of the resulting entanglement in the presence of common noise sources, explicitly acknowledging the challenges associated with a potential implementation. We also note that, for spherically symmetric masses, angular momentum degrees of freedom are intrinsically insensitive to Casimir and Coulomb interactions, thereby mitigating key decoherence channels present in existing proposals. Finally, we discuss possible state preparation and detection strategies while framing our results within the broader landscape of gravitationally mediated entanglement schemes, emphasizing the role of this framework as a conceptual avenue for exploring genuinely relativistic quantum gravitational effects.

quant-ph↗

arXiv2025

Asymptotic relaxation in quantum Markovian dynamics

We investigate the long-time behavior of quantum Markovian dynamics generated by time-dependent Gorini-Kossakowski-Lindblad-Sudarshan (GKLS) master equations. We introduce a notion of weak relaxation and derive sufficient conditions guaranteeing asymptotic independence from the initial state. Our results provide a quantitative extension of the Spohn-Frigerio theorem to time-dependent generators, yielding explicit contraction bounds in terms of the instantaneous steady state and time-integrated dissipation rates. For a class of microscopically derived master equations, we further obtain a graph-theoretic characterization of the aforementioned conditions that directly links the structure of the jump operators to the relaxation properties. The general theory is illustrated by applications to driven finite-level systems, including a detailed three-level example, and is extended to a non-Markovian setting by means of time-local master equations that become of GKLS form at long times. These findings pave the way for the development of a more general theory of relaxation beyond the Markovian case.

quant-ph↗

arXiv2025

Correlated dynamics as a resource in molecular switches

Photoisomerization, a photochemical process underlying many biological mechanisms, has been modeled recently within the quantum resource theory of thermodynamics. This approach has emerged as a promising tool for studying fundamental limitations to nanoscale processes independently of the microscopic details governing their dynamics. On the other hand, correlations between physical systems have been shown to play a crucial role in quantum thermodynamics by lowering the work cost of certain operations. Here, we explore quantitatively how correlations between multiple photoswitches can enhance the efficiency of photoisomerization beyond that attainable for single molecules. Furthermore, our analysis provides insights into the interplay between quantum and classical correlations in these transformations.

quant-ph↗

arXiv2025

Physically constrained quantum clock-driven dynamics

Thermal machines are physical systems designed to convert thermal energy into practical work through cyclic state transformations. A key component in such a machine is a clock-equipped control element that dictates which interaction Hamiltonian governs the system-reservoir interactions at specific times, while itself remaining unaffected. However, in the context of quantum dynamics, it is well known that maintaining perfect isolation is practically impossible, except under highly idealized conditions. In this study, we begin with such an idealized model for a clock and systematically relax its main assumptions to develop a more realistic framework. Our approach yields a simplified yet physically consistent description of clock dynamics, enabling the analysis of deviations from ideal time-keeping, which we interpret as clock degradation. We introduce a continuous time operator to derive a lower bound on this degradation, grounded in a generalized time-energy uncertainty relation. These results highlight trade-offs between clock performance and energy uncertainty in physically realizable control schemes.

quant-ph↗

arXiv2025

Quantum Fisher information from tensor network integration of Lyapunov equation

The Quantum Fisher Information (QFI) is a geometric measure of state deformation calculated along the trajectory parameterizing an ensemble of quantum states. It serves as a key concept in quantum metrology, where it is linked to the fundamental limit on the precision of the parameter that we estimate. However, the QFI is notoriously difficult to calculate due to its non-linear mathematical form. For mixed states, standard numerical procedures based on eigendecomposition quickly become impractical with increasing system size. To overcome this limitation, we introduce a novel numerical approach based on Lyapunov integrals that combines the concept of symmetric logarithmic derivative and tensor networks. Importantly, this approach requires only the elementary matrix product states algorithm for time-evolution, opening a perspective for broad usage and application to many-body systems. We discuss the advantages and limitations of our methodology through an illustrative example in quantum metrology, where the thermal state of the transverse-field Ising model is used to measure magnetic field amplitude.

quant-ph↗

arXiv2025

The Thermodynamic Costs of Pure Dephasing in Quantum Heat Engines: Quasistatic Efficiency at Finite Power

Quantum heat engines are commonly believed to achieve their optimal efficiency only when operated quasi-statically. When running at finite power, however, they suffer effective friction due to the generation of coherences and transitions between energy eigenstates. It was noted that it is possible to increase the power of a quantum heat engine using external control schemes or suitable dephasing noise. Here, we investigate the thermodynamic cost associated with dephasing noise schemes using both numerical and analytical methods. Our findings unveil that the observed gain in power is generally not free of thermodynamic costs, as it involves energy costs of the control fields or heat flows between thermal and dephasing baths. These contributions must be duly accounted for when determining the engine's overall efficiency. Interestingly, we identify a particular working regime where these costs become negligible, demonstrating that quantum heat engines can be operated at any power with an efficiency per cycle that approaches arbitrarily closely that under quasistatic operation.

quant-ph↗

arXiv2025

Full Microscopic Simulations Uncover Persistent Quantum Effects in Primary Photosynthesis

The presence of quantum effects in photosynthetic excitation energy transfer has been intensely debated over the past decade. Nonlinear spectroscopy cannot unambiguously distinguish coherent electronic dynamics from underdamped vibrational motion, and rigorous numerical simulations of realistic microscopic models have been intractable. Experimental studies supported by approximate numerical treatments that severely coarse-grain the vibrational environment have claimed the absence of long-lived quantum effects. Here, we report the first non-perturbative, accurate microscopic model simulations of the Fenna-Matthews-Olson photosynthetic complex and demonstrate the presence of long-lived excitonic coherences at 77 K and room temperature, which persist on picosecond time scales, similar to those of excitation energy transfer. Furthermore, we show that full microscopic simulations of nonlinear optical spectra are essential for identifying experimental evidence of quantum effects in photosynthesis, as approximate theoretical methods can misinterpret experimental data and potentially overlook quantum phenomena.

physics.chem-ph↗

arXiv2024

Making Quantum Collision Models Exact

Quantum collision describe open quantum systems through repeated interactions with a coarse-grained environment. However, a complete certification of these models is lacking, as no complete error bounds on the simulation of system observables have been established. Here, we show that Markovian and non-Markovian collision models can be recovered analytically from chain mapping techniques starting from a general microscopic Hamiltonian. This derivation reveals a previously unidentified source of error -- induced by an unfaithful sampling of the environment -- in dynamics obtained with collision models that can become dominant for small but finite time-steps. With the complete characterization of this error, all collision models errors are now identified and quantified, which enables the promotion of collision models to the class of numerically exact methods. To confirm the predictions of our equivalence results, we implemented a non-Markovian collision model of the Spin Boson Model, and identified, as predicted, a regime in which the collision model is fundamentally inaccurate.

quant-ph↗