arXiv subjects

Susana F. Huelga

Publications and source records attributed to Susana F. Huelga.

At least 55 records · Page 3Linked to original sources

arXiv2020

Efficient construction of tensor-network representations of many-body Gaussian states

We present a procedure to construct tensor-network representations of many-body Gaussian states efficiently and with a controllable error. These states include the ground and thermal states of bosonic and fermionic quadratic Hamiltonians, which are essential in the study of quantum many-body systems. The procedure improves computational time requirements for constructing many-body Gaussian states by up to five orders of magnitude for reasonable parameter values, thus allowing simulations beyond the range of what was hitherto feasible. Our procedure combines ideas from the theory of Gaussian quantum information with tensor-network based numerical methods thereby opening the possibility of exploiting the rich tool-kit of Gaussian methods in tensor-network simulations.

quant-ph↗

arXiv2020

When is a non-Markovian quantum process classical?

More than a century after the inception of quantum theory, the question of which traits and phenomena are fundamentally quantum remains under debate. Here we give an answer to this question for temporal processes which are probed sequentially by means of projective measurements of the same observable. Defining classical processes as those that can---in principle---be simulated by means of classical resources only, we fully characterize the set of such processes. Based on this characterization, we show that for non-Markovian processes (i.e., processes with memory), the absence of coherence does not guarantee the classicality of observed phenomena and furthermore derive an experimentally and computationally accessible measure for non-classicality in the presence of memory. We then provide a direct connection between classicality and the vanishing of quantum discord between the evolving system and its environment. Finally, we demonstrate that---in contrast to the memoryless setting---in the non-Markovian case, there exist processes that are genuinely quantum, i.e., they display non-classical statistics independent of the measurement scheme that is employed to probe them.

quant-ph↗

arXiv2020

Experimental Control of the Degree of Non-Classicality via Quantum Coherence

The origin of non-classicality in physical systems and its connection to distinctly quantum features such as entanglement and coherence is a central question in quantum physics. This work analyses this question theoretically and experimentally, linking quantitatively non-classicality with quantum coherence. On the theoretical front, we show when the coherence of an observable is linearly related to the degree of violation of the Kolmogorov condition, which quantifies the deviation from any classical (non-invasive) explanation of the multi-time statistics. Experimentally, we probe this connection between coherence and non-classicality in a time-multiplexed optical quantum walk. We demonstrate exquisite control of quantum coherence of the walker by varying the degree of coherent superposition effected by the coin, and we show a concomitant variation in the degree of non-classicality of the walker statistics, which can be accessed directly by virtue of the unprecedented control on the measurement-induced effects obtained via fast programmable electro-optic modulators.

quant-ph↗

arXiv2020

A cyanine dye rotaxane porphyrin nanoring complex as a model light harvesting system

A nanoring-rotaxane supramolecular assembly, with a Cy7 cyanine dye (hexamethylindotricarbocyanine) threaded along the axis of the nanoring, has been synthesized as a model for the energy transfer between the light harvesting complex LH1 and the reaction center in purple bacteria photosynthesis. The complex displays efficient energy transfer from the central cyanine dye to the surrounding zinc porphyrin nanoring. We present a theoretical model that reproduces the absorption spectrum of the nanoring and quantifies the excitonic coupling between the nanoring and the central dye, explaining the efficient energy transfer and elucidating the similarity with structurally related natural light harvesting systems.

physics.chem-ph↗

arXiv2020

Universal anti-Kibble-Zurek scaling in fully-connected systems

We investigate the quench dynamics of an open quantum system involving a quantum phase transition. In the isolated case, the quench dynamics involving the phase transition exhibits a number of scaling relations with the quench rate as predicted by the celebrated Kibble-Zurek mechanism. In contact with an environment however, these scaling laws breakdown and one may observe an anti-Kibble-Zurek behavior: slower ramps lead to less adiabatic dynamics, increasing thus non-adiabatic effects with the quench time. In contrast to previous works, we show here that such anti-Kibble-Zurek scaling can acquire a universal form in the sense that it is determined by the equilibrium critical exponents of the phase transition, provided the excited states of the system exhibit singular behavior, as observed in fully-connected models. This demonstrates novel universal scaling laws granted by a system-environment interaction in a critical system. We illustrate these findings in two fully-connected models, namely, the quantum Rabi and the Lipkin-Meshkov-Glick models. In addition, we discuss the impact of non-linear ramps and finite-size systems.

quant-ph↗

arXiv2020

Optimized auxiliary oscillators for the simulation of general open quantum systems

A method for the systematic construction of few-body damped harmonic oscillator networks accurately reproducing the effect of general bosonic environments in open quantum systems is presented. Under the sole assumptions of a Gaussian environment and regardless of the system coupled to it, an algorithm to determine the parameters of an equivalent set of interacting damped oscillators obeying a Markovian quantum master equation is introduced. By choosing a suitable coupling to the system and minimizing an appropriate distance between the two-time correlation function of this effective bath and that of the target environment, the error induced in the reduced dynamics of the system is brought under rigorous control. The interactions among the effective modes provide remarkable flexibility in replicating non-Markovian effects on the system even with a small number of oscillators, and the resulting Lindblad equation may therefore be integrated at a very reasonable computational cost using standard methods for Markovian problems, even in strongly non-perturbative coupling regimes and at arbitrary temperatures including zero. We apply the method to an exactly solvable problem in order to demonstrate its accuracy, and present a study based on current research in the context of coherent transport in biological aggregates as a more realistic example of its use; performance and versatility are highlighted, and theoretical and numerical advantages over existing methods, as well as possible future improvements, are discussed.

quant-ph↗

arXiv2020

Efficient simulation of open quantum systems coupled to a fermionic bath

We present and analyze the fermionic time evolving density matrix using orthogonal polynomials algorithm (fTEDOPA), which enables the numerically exact simulation of open quantum systems coupled to a fermionic environment. The method allows for simulating the time evolution of open quantum systems with arbitrary spectral densities at zero or finite temperatures with controllable and certified error. We demonstrate the efficacy of the method towards the simulation of quintessential fermionic open quantum systems including the resonant level model and quantum dot coupled to an impurity and towards simulating hitherto intractable problems in quantum transport. Furthermore, we demonstrate significant efficiency gains in the computational costs by performing simulations in the Heisenberg picture. Finally, we compare different approaches for simulating finite-temperature situations and provide guidelines for choosing between these approaches.

quant-ph↗

arXiv2020

Limited-control metrology approaching the Heisenberg limit without entanglement preparation

Current metrological bounds typically assume full control over all particles that are involved in the protocol. Relaxing this assumption we study metrological performance when only limited control is available. As an example, we measure a static magnetic field when a fully controlled quantum sensor is supplemented by particles over which only global control is possible. We show that even for a noisy quantum sensor, a protocol that maps the magnetic field to a precession frequency can achieve transient super-Heisenberg scaling in measurement time and Heisenberg scaling in the particle number. This leads to an estimation uncertainty that approaches that achievable under full control to within a factor independent of the particle number for a given total time. Applications to hybrid sensing devices and the crucial role of the quantum character of the sensor are discussed.

quant-ph↗

arXiv2020

Accessible coherence in open quantum system dynamics

Quantum coherence generated in a physical process can only be cast as a potentially useful resource if its effects can be detected at a later time. Recently, the notion of non-coherence-generating-and-detecting (NCGD) dynamics has been introduced and related to the classicality of the statistics associated with sequential measurements at different times. However, in order for a dynamics to be NCGD, its propagators need to satisfy a given set of conditions for all triples of consecutive times. We reduce this to a finite set of $d(d-1)$ conditions, where $d$ is the dimension of the quantum system, provided that the generator is time-independent. Further conditions are derived for the more general time-dependent case. The application of this result to the case of a qubit dynamics allows us to elucidate which kind of noise gives rise to non-coherence-generation-and-detection.

quant-ph↗

arXiv2020

Temporal correlations of sunlight may assist photoprotection in bacterial Photosynthesis

Photosynthetic systems utilize adaptability to respond efficiently to fluctuations in their light environment. As a result, large photosynthetic yields can be achieved in conditions of low light intensity, while photoprotection mechanisms are activated in conditions of elevated light intensity. In sharp contrast with these observations, current theoretical models predict bacterial cell death for physiologically high light intensities. To resolve this discrepancy, we consider a unified framework to describe three stages of photosynthesis in natural conditions, namely light absorption, exciton transfer and charge separation dynamics, to investigate the relationship between the statistical features of thermal light and the Quinol production in bacterial photosynthesis. This approach allows us to identify a mechanism of photoprotection that relies on charge recombination facilitated by the photon bunching statistics characteristic of thermal sunlight. Our results suggest that the flexible design underpinning natural photosynthesis may therefore rely on exploiting the temporal correlations of thermal light, manifested in photo-bunching patterns, which are preserved for excitations reaching the reaction center.

physics.bio-ph↗

arXiv2019

Efficient simulation of finite-temperature open quantum systems

Chain-mapping techniques in combination with the time-dependent density matrix renormalization group are a powerful tool for the simulation of open-system quantum dynamics. For finite-temperature environments, however, this approach suffers from an unfavorable algorithmic scaling with increasing temperature. We prove that the system dynamics under thermal environments can be non-perturbatively described by temperature-dependent system-environmental couplings with the initial environment state being in its pure vacuum state, instead of a mixed thermal state. As a consequence, as long as the initial system state is pure, the global system-environment state remains pure at all times. The resulting speedup and relaxed memory requirements of this approach enable the efficient simulation of open quantum systems interacting with highly structured environments in any temperature range, with applications extending from quantum thermodynamics to quantum effects in mesoscopic systems.

quant-ph↗

arXiv2019

Universality in the Decay and Revival of Loschmidt Echoes

A critically enhanced decay of the Loschmidt echo is characteristic of sudden quench dynamics near a quantum phase transition. Here, we demonstrate that the decay and revival of the Loschmidt echo follows power-law scaling in the system size and the distance from a critical point with equilibrium critical exponents. We reveal such dynamical scaling laws by analyzing relevant perturbations to the Loschmidt echo cast in a scaling invariant form. We confirm the validity and the generality of the predicted dynamical scaling laws with a diverse range of critical models such as Ising spin models with a short and long range interaction, a finite-component system phase transition, and a topological phase transition. Moreover, using the integrability of systems in the thermodynamic limit, we derive such scaling laws analytically from a microscopic analysis. Our finding promotes the Loschmidt echo to a quantitative non-equilibrium probe of criticality and allows for quantitative predictions on the role of criticality on various physical scenarios where the Loschmidt echo is central to describing non-equilibrium dynamics.

quant-ph↗

arXiv2019

Dissipation-assisted matrix product factorization

Charge and energy transfer in biological and synthetic organic materials are strongly influenced by the coupling of electronic states to high-frequency underdamped vibrations under dephasing noise. Non-perturbative simulations of these systems require a substantial computational effort and current methods can only be applied to large systems with severely coarse-grained environmental structures. In this letter, we introduce a dissipation-assisted matrix product factorization (DAMPF) method based on a memory-efficient matrix product operator (MPO) representation of the vibronic state at finite temperature. In this approach, the correlations between environmental vibrational modes can be controlled by the MPO bond dimension, allowing for systematic interpolation between approximate and numerically exact dynamics. Crucially, by subjecting the vibrational modes to damping, we show that one can significantly reduce the bond dimension required to achieve a desired accuracy, and also consider a continuous, highly structured spectral density in a non-perturbative manner. We demonstrate that our method can simulate large vibronic systems consisting of 10-50 sites coupled with 100-1000 underdamped modes in total and for a wide range of parameter regimes. An analytical error bound is provided which allows one to monitor the accuracy of the numerical results. This formalism will facilitate the investigation of spatially extended systems with applications to quantum biology, organic photovoltaics and quantum thermodynamics.

quant-ph↗

arXiv2019

Non-monotonic population and coherence evolution in Markovian open-system dynamics

We consider a simple microscopic model where the open-system dynamics of a qubit, despite being Markovian, shows features which are typically associated to the presence of memory effects. Namely, a non monotonic behavior both in the population and in the coherence evolution arises due to the presence of non-secular contributions, which break the phase covariance of the Lindbladian (semigroup) dynamics. We also show by an explicit construction how such a non-monotonic behaviour can be reproduced by a phase covariant evolution, but only at the price of inserting some state-dependent memory effects.

quant-ph↗

arXiv2018

Coherence and non-classicality of quantum Markov processes

Although quantum coherence is a basic trait of quantum mechanics, the presence of coherences in the quantum description of a certain phenomenon does not rule out the possibility to give an alternative description of the same phenomenon in purely classical terms. Here, we give definite criteria to determine when and to what extent quantum coherence is equivalent to non-classicality. We prove that a Markovian multi-time statistics obtained from repeated measurements of a non-degenerate observable cannot be traced back to a classical statistics if and only if the dynamics is able to generate coherences and to subsequently turn them into populations. Furthermore, we show with simple examples that such connection between quantum coherence and non-classicality is generally absent if the statistics is non-Markovian.

quant-ph↗

arXiv2018

Precision Limits in Quantum Metrology with Open Quantum Systems

The laws of quantum mechanics allow to perform measurements whose precision supersedes results predicted by classical parameter estimation theory. That is, the precision bound imposed by the central limit theorem in the estimation of a broad class of parameters, like atomic frequencies in spectroscopy or external magnetic field in magnetometry, can be overcome when using quantum probes. Environmental noise, however, generally alters the ultimate precision that can be achieved in the estimation of an unknown parameter. This tutorial reviews recent theoretical work aimed at obtaining general precision bounds in the presence of an environment. We adopt a complementary approach, where we first analyze the problem within the general framework of describing the quantum systems in terms of quantum dynamical maps and then relate this abstract formalism to a microscopic description of the system's dissipative time evolution. We will show that although some forms of noise do render quantum systems standard quantum limited, precision beyond classical bounds is still possible in the presence of different forms of local environmental fluctuations.

quant-ph↗

arXiv2018

Controllable Non-Markovianity for a Spin Qubit in Diamond

We present a flexible scheme to realize non-artificial non-Markovian dynamics of an electronic spin qubit, using a nitrogen-vacancy center in diamond where the inherent nitrogen spin serves as a regulator of the dynamics. By changing the population of the nitrogen spin, we show that we can smoothly tune the non-Markovianity of the electron spin's dynamic. Furthermore, we examine the decoherence dynamics induced by the spin bath to exclude other sources of non-Markovianity. The amount of collected measurement data is kept at a minimum by employing Bayesian data analysis. This allows for a precise quantification of the parameters involved in the description of the dynamics and a prediction of so far unobserved data points.

quant-ph↗

arXiv2018

Improving the precision of frequency estimation via long-time coherences

In the last years several estimation strategies have been formulated to determine the value of an unknown parameter in the most precise way, taking into account the presence of noise. These strategies typically rely on the use of quantum entanglement between the sensing probes and they have been shown to be optimal in the asymptotic limit in the number of probes, as long as one performs measurements on shorter and shorter time scales. Here, we present a different approach to frequency estimation, which exploits quantum coherence in the state of each sensing particle in the long time limit and is obtained by properly engineering the environment. By means of a commonly used master equation, we show that our strategy can overcome the precision achievable with entanglement-based strategies for a finite number of probes. We discuss a possible implementation of the scheme in a realistic setup that uses trapped ions as quantum sensors.

quant-ph↗