arXiv subjects

Sy-Hwang Liou

Publications and source records attributed to Sy-Hwang Liou.

13 recordsLinked to original sources

arXiv2025

Spin Dynamics in the van der Waals Ferromagnet CrTe2 Engineered by Niobium Doping

Understanding and controlling spin dynamics in two-dimensional (2D) van der Waals (vdW) ferromagnets is essential for their application in magnonics and hybrid quantum platforms. Here, we investigate the spin dynamics of the vdW ferromagnet 1T-CrTe_{2} and demonstrate their systematic tunability via niobium (Nb) substitution in Cr_{1-x}Nb_{x}Te_{2}(x=0-0.2). Ferromagnetic resonance (FMR) spectroscopy reveals that Nb doping enables wide-band tuning of the resonance frequency from 40 GHz down to the few-GHz regime, accompanied by a moderate increase in the Gilbert damping constant from ~0.066 to ~0.14, while preserving robust room-temperature ferromagnetism. Complementary magnetometry shows a concurrent reduction of the Curie temperature and saturation magnetization with increasing Nb content. Density functional theory calculations attribute the observed spin-dynamic trends to Nb-induced modifications of magnetic anisotropy and magnetic exchange interactions. Furthermore, CrTe_{2} flakes (~80 nm thick) exhibit lower resonance frequencies and damping than bulk crystals, consistent with thickness, surface/interface, and shape-dependent magnetic anisotropy. These results establish Nb-doped CrTe_{2} as a tunable vdW ferromagnet with controllable spin dynamics, extending its functionality from spintronics to broadband magnonics and quantum magnonics.

cond-mat.mtrl-sci↗

arXiv2025

Nitrogen-Vacancy Magnetometry of Edge Magnetism in WS2 Flakes

Two-dimensional (2D) magnets are of significant interest both as a platform for exploring novel fundamental physics and for their potential in spintronic and optoelectronic devices. Recent bulk magnetometry studies have indicated a weak ferromagnetic response in WS2, and theoretical predictions suggest edge-localized magnetization in flakes with partial hydrogenation. Here, we use room-temperature wide-field quantum diamond magnetometry to image pristine and Fe-implanted WS2 flakes of varying thicknesses (45-160 nm), exfoliated from bulk crystals and transferred to NV-doped diamond substrates. We observe direct evidence of edge-localized stray magnetic fields, which scale linearly with applied external magnetic field (4.4-220 mT), reaching up to 4.7 uT. The edge signal shows a limited dependence on the flake thickness, consistent with dipolar field decay and sensing geometry. Magnetic simulations using five alternative models favor the presence of edge magnetization aligned along an axis slightly tilted from the normal to the WS2 flake plane, consistent with spin canting in antiferromagnetically coupled edge states. Our findings establish WS2 as a promising platform for edge-controlled 2D spintronics.

cond-mat.mes-hall↗

arXiv2025

Effect of Magnetic Anisotropy and Gradient-Induced Dzyaloshinskii-Moriya Interaction on the Formation of Magnetic Skyrmions

Topological spin textures (e.g. skyrmions) can be stabilized by interfacial Dzyaloshinskii-Moriya interaction (DMI) in the magnetic multilayer, which has been intensively studied. Recently, Bloch-type magnetic skyrmions stabilized by composition gradient-induced DMI (g-DMI) have been observed in 10-nm thick CoPt single layer. However, magnetic anisotropy in gradient-composition engineered CoPt (g-CoPt) films is highly sensitive to both the relative Co/Pt composition and the film thickness, leading to a complex interplay with g-DMI. The stability of skyrmions under the combined influence of magnetic anisotropy and g-DMI is crucial yet remains poorly understood. Here, we conduct a systematic study on the characteristics of magnetic skyrmions as a function of gradient polarity and effective gradient (defined as gradient/thickness) in g-CoPt single layers (thickness of 10-30 nm) using magnetic force microscopy (MFM), bulk magnetometry, and topological Hall effect measurements. Brillouin light scattering spectroscopy confirms that both the sign and magnitude of g-DMI depend on the polarity and amplitude of the composition gradient in g-CoPt films. MFM reveals that skyrmion size and density vary with g-CoPt film thickness, gradient polarity, and applied magnetic field. An increased skyrmion density is observed in samples exhibiting higher magnetic anisotropy, in agreement with micromagnetic simulations and energy barrier calculations.

cond-mat.mtrl-sci↗

arXiv2025

Giant Topological Hall Effect Across Wide Temperature in Pt/NiCo2O4 Heterostructure

Topological Hall effect (THE), a quantum phenomenon arising from emergent magnetic field generated by topological spin texture, is a key method for detecting non-coplanar spin structures like skyrmions in magnetic materials. Here, we investigate a bilayer structure of Pt and conducting ferrimagnet NiCo2O4 (NCO) of perpendicular magnetic anisotropy and demonstrate giant THE across a temperature range 2 - 350 K. The absence of THE in single-layer Pt and NCO, as well as in Pt/Cu/NCO, suggests its interfacial origin. The maximum THE occurring just before the NCO coercive field indicates its connection to magnetic nucleation centers, which are topologically equivalent to skyrmions. The large normalized THE, based on the emergent-field model, points to a high population density of small nucleation centers. This aligns with the unresolvable domain structures during magnetization reversal, even though clear domain structures are detected after zero-field cooling. These results establish heavy metal/NCO as a promising system for exploring topological spin structures.

cond-mat.mtrl-sci↗

arXiv2024

Effect of Substrate on Spin-Wave Propagation Properties in Ferrimagnetic Thulium Iron Garnet Thin Films

Rare-earth iron garnets have distinctive spin-wave (SW) properties such as low magnetic damping and long SW coherence length making them ideal candidates for magnonics. Among them, thulium iron garnet (TmIG) is a ferrimagnetic insulator with unique magnetic properties including perpendicular magnetic anisotropy (PMA) and topological hall effect at room temperature when grown down to a few nanometers, extending its application to magnon spintronics. Here, the SW propagation properties of TmIG films (thickness of 7-34 nm) grown on GGG and sGGG substrates are studied at room temperature. Magnetic measurements show in-plane magnetic anisotropy for TmIG films grown on GGG and out-of-plane magnetic anisotropy for films grown on sGGG substrates with PMA. SW electrical transmission spectroscopy measurements on TmIG/GGG films unveil magnetostatic surface spin waves (MSSWs) propagating up to 80 um with a SW group velocity of 2-8 km s^-1. Intriguingly, these MSSWs exhibit nonreciprocal propagation, opening new applications in SW functional devices. TmIG films grown on sGGG substrates exhibit forward volume spin waves with a reciprocal propagation behavior up to 32 um.

cond-mat.mtrl-sci↗

arXiv2024

Plasmonic Nanocavity to Boost Single Photon Emission from Defects in Thin Hexagonal Boron Nitride

Efficient and compact single photon emission platforms operating at room temperature with ultrafast speed and high brightness will be fundamental components of the emerging quantum communications and computing fields. However, so far, it is very challenging to design practical deterministic single photon emitters based on nanoscale solid-state materials that meet the fast emission rate and strong brightness demands. Here, a solution is provided to this longstanding problem by using metallic nanocavities integrated with hexagonal boron nitride (hBN) flakes with defects acting as nanoscale single photon emitters (SPEs) at room temperature. The presented hybrid nanophotonic structure creates a rapid speedup and large enhancement in single photon emission at room temperature. Hence, the nonclassical light emission performance is substantially improved compared to plain hBN flakes and hBN on gold-layered structures without nanocavity. Extensive theoretical calculations are also performed to accurately model the new hybrid nanophotonic system and prove that the incorporation of plasmonic nanocavity is key to efficient SPE performance. The proposed quantum nanocavity single photon source is expected to be an element of paramount importance to the envisioned room-temperature integrated quantum photonic networks.

physics.optics↗

arXiv2024

Room Temperature Magnetic Skyrmions in Gradient-Composition Engineered CoPt Single Layers

Topologically protected magnetic skyrmions in magnetic materials are stabilized by interfacial or bulk Dzyaloshinskii-Moriya interaction (DMI). Interfacial DMI decays with increase of the magnetic layer thickness in just a few nanometers and bulk DMI typically stabilizes magnetic skyrmions at low temperatures. Consequently, more flexibility in manipulation of DMI is required for utilizing nanoscale skyrmions in energy efficient memory and logic devices at room temperature (RT). Here, we demonstrate the observation of RT skyrmions stabilized by gradient DMI (g-DMI) in composition gradient engineered CoPt single layer films by employing topological Hall effect, magnetic force microscopy, and nitrogen vacancy scanning magnetometry. Skyrmions remain stable at a wide range of applied magnetic fields and are confirmed to be nearly Bloch-type from micromagnetic simulation and analytical magnetization reconstruction. Furthermore, we observe skyrmion pairs which may be explained by skyrmion-antiskyrmion interactions. Our findings expand the family of magnetic materials hosting RT magnetic skyrmions by tuning g-DMI via gradient polarity and choice of magnetic elements.

cond-mat.mes-hall↗

arXiv2024

Magnetic Relaxometry of Methemoglobin by Widefield Nitrogen-Vacancy Microscopy

Hemoglobin (Hb) is a multifaceted protein, classified as a metalloprotein, chromoprotein, and globulin. It incorporates iron, which plays a crucial role in transporting oxygen within red blood cells. Hb functions by carrying oxygen from the respiratory organs to diverse tissues in the body, where it releases oxygen to fuel aerobic respiration, thus supporting the organism's metabolic processes. Hb can exist in several forms, primarily distinguished by the oxidation state of the iron in the heme group, including Methemoglobin (MetHb). Measuring the concentration of MetHb is crucial because it cannot transport oxygen, hence higher concentration of MetHb in the blood causes methemoglobinemia. Here, we use optically detected magnetic relaxometry of paramagnetic iron spins in MetHb drop-casted onto nanostructured diamond doped with shallow high density nitrogen vacancy (NV) spin qubits. We modify the MetHb concentration in the range of 6 x 10^6 - 1.8 x 10^7 adsorbed Fe+3 spins per um^2 and observe an increase of the NV relaxation rate G1 (= 1/T1, T1 is NV spin lattice relaxation time) up to 2 x 10^3 s^-1. NV magnetic relaxometry of MetHb in phosphate-buffered saline solution shows a similar effect with an increase of G1 to 6.7 x 10e3 s^-1 upon increasing the MetHb concentration to 100 uM. The increase of NV G1 is explained by the increased spin noise coming from the Fe+3 spins present in MetHb proteins. This study presents an additional usage of NV quantum sensors to detect paramagnetic centers of biomolecules at volumes below 100 picoliter.

physics.bio-ph↗

arXiv2023

Nitrogen-Vacancy Magnetic Relaxometry of Nanoclustered Cytochrome C Proteins

Nitrogen-vacancy (NV) magnetometry offers an alternative tool to detect paramagnetic centers in cells with a favorable combination of magnetic sensitivity and spatial resolution. Here, we employ NV magnetic relaxometry to detect cytochrome C (Cyt-C) nanoclusters. Cyt-C is a water-soluble protein that plays a vital role in the electron transport chain of mitochondria. Under ambient conditions, the heme group in Cyt-C remains in the Fe3+ state, which is paramagnetic. We vary the concentration of Cyt-C from 6 to 54 uM and observe a reduction of the NV spin-lattice relaxation time (T1) from 1.2 ms to 150 us, which is attributed to the spin noise originating from the Fe3+ spins. NV T1 imaging of Cyt-C drop-casted on a nanostructured diamond chip allows us to detect the relaxation rates from the adsorbed Fe3+ within Cyt-C.

physics.bio-ph↗

arXiv2023

Nitrogen-vacancy magnetometry of individual Fe-triazole spin crossover nanorods

[Fe(Htrz)2(trz)](BF4) (Fe-triazole) spin crossover molecules show thermal, electrical, and optical switching between high spin (HS) and low spin (LS) states, making them promising candidates for molecular spintronics. The LS and HS transitions originate from the electronic configurations of Fe(II), and are considered to be diamagnetic and paramagnetic respectively. The Fe(II) LS state has six paired electrons in the ground states with no interaction with the magnetic field and a diamagnetic behavior is usually observed. While the bulk magnetic properties of Fe-triazole compounds are widely studied by standard magnetometry techniques their properties at the individual level are missing. Here we use nitrogen vacancy (NV) based magnetometry to study the magnetic properties of the Fe-triazole LS state of nanoparticle clusters and individual nanorods of size varying from 20 to 1000 nm. Scanning electron microscopy (SEM) and Raman spectroscopy are performed to determine the size of the nanoparticles/nanorods and to confirm their respective spin state. The magnetic field patterns produced by the nanoparticles/nanorods are imaged by NV magnetic microscopy as a function of applied magnetic field (up to 350 mT) and correlated with SEM and Raman. We found that in most of the nanorods the LS state is slightly paramagnetic, possibly originating from the surface oxidation and/or the greater Fe(III) presence along the nanorod edges. NV measurements on the Fe-triazole LS state nanoparticle clusters revealed both diamagnetic and paramagnetic behavior. Our results highlight the potential of NV quantum sensors to study the magnetic properties of spin crossover molecules and molecular magnets.

cond-mat.mes-hall↗

arXiv2023

Plasmon Enhanced Quantum Properties of Single Photon Emitters with Hybrid Hexagonal Boron Nitride Silver Nanocube Systems

Hexagonal boron nitride (hBN) has emerged as a promising ultrathin host of single photon emitters (SPEs) with favorable quantum properties at room temperature, making it a highly desirable element for integrated quantum photonic networks. One major challenge of using these SPEs in such applications is their low quantum efficiency. Recent studies have reported an improvement in quantum efficiency by up to two orders of magnitude when integrating an ensemble of emitters such as boron vacancy defects in multilayered hBN flakes embedded within metallic nanocavities. However, these experiments have not been extended to SPEs and are mainly focused on multiphoton effects. Here, we study the quantum single photon properties of hybrid nanophotonic structures composed of SPEs created in ultrathin hBN flakes coupled with plasmonic silver nanocubes. We demonstrate > 200% plasmonic enhancement of the SPE properties, manifested by a strong increase in the SPE fluorescence. Such enhancement is explained by rigorous numerical simulations where the hBN flake is in direct contact with the Ag nanocubes that cause the plasmonic effects. The presented strong and fast single photon emission obtained at room-temperature with a compact hybrid nanophotonic platform can be very useful to various emerging applications in quantum optical communications and computing.

physics.optics↗

arXiv2012

Controlled double-slit electron diffraction

Double-slit diffraction is a corner stone of quantum mechanics. It illustrates key features of quantum mechanics: interference and the particle-wave duality of matter. In 1965, Richard Feynman presented a thought experiment to show these features. Here we demonstrate the full realization of his famous thought experiment. By placing a movable mask in front of a double-slit to control the transmission through the individual slits, probability distributions for single- and double-slit arrangements were observed. Also, by recording single electron detection events diffracting through a double-slit, a diffraction pattern was built up from individual events.

quant-ph↗

arXiv2006

Novel Fabrication of Micromechanical Oscillators with Nanoscale Sensitivity at Room Temperature

We report on the design, fabrication, and implementation of ultrasensitive micromechanical oscillators. Our ultrathin single-crystal silicon cantilevers with integrated magnetic structures are the first of their kind: They are fabricated using a novel high-yield process in which magnetic film patterning and deposition are combined with cantilever fabrication. These novel devices have been developed for use as cantilever magnetometers and as force sensors in nuclear magnetic resonance force microscopy (MRFM). These two applications have achieved nanometer-scale resolution using the cantilevers described in this work. Current magnetic moment sensitivity achieved for the devices, when used as magnetometers, is 10^{-15} J/T at room temperature, which is more than a 1000 fold improvement in sensitivity, compared to conventional magnetometers. Current room temperature force sensitivity of MRFM cantilevers is ~10^{-16} N in a 1 Hz bandwidth, which is comparable to the room temperature sensitivities of similar devices of its type. Finite element modeling was used to improve design parameters, ensure that the devices meet experimental demands, and correlate mode shape with observed results. The photolithographic fabrication process was optimized, yielding an average of ~85% and alignment better than 1000 nm. Post-fabrication focused-ion-beam milling was used to further pattern the integrated magnetic structures when nanometer scale dimensions were required.

cond-mat.mes-hall↗