arXiv subjects

Szymon Królak

Publications and source records attributed to Szymon Królak.

8 recordsLinked to original sources

arXiv2026

Fractionation as a Tool to Control Mn/Al Site Mixing and Magnetism in CaMn_{2+x}Al_{10-x}

We report single crystal growth and physical property characterization of CaMn_{2+x}Al_{10-x} crystals grown using a fractionation approach. Three consecutive batches were obtained from the same initial melt composition, systematically sampling neighboring, narrow regions of the ternary Ca-Mn-Al phase diagram. Single-crystal X-ray diffraction measurements reveal Mn/Al site mixing, with the excess Mn concentration, x, decreasing systematically with decreasing decanting temperature. A low-temperature upturn in magnetization and a maximum in electrical resistivity both become progressively weaker with decreasing excess Mn content, suggesting that the previously reported magnetic properties attributed to stoichiometric CaMn_{2}Al_{10} instead arise from an inhomogeneous distribution of excess Mn atoms. More broadly, the results presented in this work demonstrate how fractionation can help distinguish intrinsic magnetic behavior from disorder-induced effects associated with an inhomogeneous distribution of magnetic ions in materials with a finite width of formation, particularly when itinerant magnetism is under consideration.

cond-mat.mtrl-sci↗

arXiv2026

AC calorimetric study of magneto-quantum oscillations in anisotropic multiband V$_2$Ga$_5$ superconductor

Unlike de Haas--van Alphen measurements, heat-capacity magneto-quantum oscillations directly probe the oscillatory bulk quasiparticle density of states. Here, we report the observation of MQOs in V$_2$Ga$_5$ single crystals studied via highly sensitive ac calorimetry. The strongest MQO signal is observed for a magnetic field applied along the vanadium chains, in excellent agreement with de Haas--van Alphen magnetization data. A single dominant frequency of 126.6 T resolved by fast Fourier transform confirms the true bulk origin of the elliptical $γ$ Fermi-surface pocket located near the Z point of the Brillouin zone. The angular dependence of the FFT frequency closely tracks the anisotropy of the $γ$ pocket, as supported by first-principles calculations. Analysis of the temperature- and field-dependent MQO amplitudes allows the precise determination of the effective cyclotron mass, Dingle temperature, quantum relaxation time, carrier mobility, and electron mean free path. Furthermore, we demonstrate that the net Berry flux is invariant with respect to the magnetic-field orientation, as a consequence of a conserved hybridization phase twist within the $γ$ pocket. These findings establish ac calorimetry as a powerful macroscopic probe of topological orbital hybridization in complex intermetallics.

cond-mat.supr-con↗

arXiv2026

Band-Selective Tunneling and Anisotropic Multiband Superconductivity in V$_2$Ga$_5$

Multiband superconductors with structural anisotropy offer a fertile ground for exploring unconventional quantum states, yet disentangling their directional pairing characteristics remains a formidable challenge. Here, we present a comprehensive thermodynamic and spectroscopic study of the tetragonal intermetallic superconductor $\text{V}_2\text{Ga}_5$ ($T_{\rm c} \approx 3.5$~K), combining first-principles electronic structure calculations with highly sensitive AC calorimetry and directional low-temperature scanning tunneling spectroscopy. By constructing a self-consistent, anisotropic multiband singlet $s$-wave pairing model within the fully symmetric $A_{1g}$ representation, we successfully reconcile the experimental specific heat and upper critical field anomalies. Crucially, we reveal that the apparent reversal of bulk gap hierarchies in directional tunneling experiments is a direct consequence of band-selective tunneling. This effect is governed by an elegant interplay between localized Fermi velocity 'hot spots' and specific Fermi surface topologies, rather than raw thermodynamic gap magnitudes alone. Our findings provide a clear microscopic picture of direction-dependent, band-selective tunneling in a highly uniaxial anisotropic superconductor, demonstrating how orientation-dependent transport constraints shape the observable signatures of multiband quantum condensates.

cond-mat.supr-con↗

arXiv2026

Effect of Pressure and Oxygen-Isotope Substitution on Density-Wave Transitions in La$_4$Ni$_3$O$_{10}$

Understanding the interplay between magnetism and superconductivity in nickelate systems is a key objective in condensed matter physics. Here, we present a systematic muon-spin rotation/relaxation ($μ$SR) and resistivity study of the trilayer Ruddlesden-Popper nickelate La$_4$Ni$_3$O$_{10}$ under ambient and applied pressure, combined with oxygen-isotope substitution. At ambient pressure, two incommensurate spin-density-wave (SDW) transitions are identified at $T_{SDW}\simeq132$ K and $T^\ast\simeq80-90$ K. Comparison of the internal magnetic fields with dipole-field calculations reveals a magnetic structure consistent with antiferromagnetically coupled SDW order on the outer two Ni layers, with smaller moments on the inner layer. Above $T^\ast$, the moments lie mainly in the $ab$ plane, whereas below this temperature they develop a $c$-axis component. The internal fields at the muon stopping sites appear abruptly at $T_{SDW}$, suggesting a first-order-like SDW transition closely linked to the charge-density-wave (CDW) order occurring at the same temperature ($T_{SDW}=T_{CDW}$). Under pressure, all transition temperatures -- $T_{SDW}$, $T^\ast$, and $T_{CDW}$ -- are suppressed at a nearly uniform rate of $\simeq-13$ K/GPa. This contrasts with bilayer La$_3$Ni$_2$O$_7$, where pressure enhances the separation between the SDW and CDW transitions. Oxygen-isotope substitution ($^{16}$O $\rightarrow$ $^{18}$O) shifts $T_{CDW}$ to higher values. The isotope effect on $T_{SDW}$ and $T^\ast$ differs markedly: when CDW and SDW are intertwined, a notable isotope effect is observed on $T_{SDW}$, yielding nearly identical isotope shifts for $T_{CDW}$ and $T_{SDW}$, whereas no isotope effect is detected at $T^\ast$, where the SDW transition occurs independently of the CDW.

cond-mat.supr-con↗

arXiv2026

Possible Proximity to Ferromagnetism in the V$_2$Ga$_5$ Superconductor

Superconductivity and ferromagnetism are generally competing ground states in $d$-electron systems, making their interplay of fundamental interest. We report a comprehensive study of high-quality single- and polycrystalline V$_2$Ga$_5$, a bulk type-II superconductor ($T_c = 3.54 \ K$) with a quasi-one-dimensional crystal structure, supplemented with density functional theory (DFT) calculations, suggesting possible proximity to ferromagnetic order. Below $T \approx 10 \ K$, magnetic susceptibility shows ZFC/FC splitting, along with saturation and hysteresis in $M(H)$. Moreover, electrical transport measurements reveal a magnetic-field-dependent resistivity upturn, while specific heat is enhanced in magnetic fields. DFT calculations show that the Fermi level in V$_2$Ga$_5$ is located at a peak in the density of states, with a small magnetic moment per unit cell comparable to the experimental value. Together, these results indicate the possibility that ferromagnetic correlations develop below $T \approx 10 \ K$, well above $T_c$, with long-range ferromagnetic order suppressed by the superconducting transition.

cond-mat.supr-con↗

arXiv2025

YRu$_3$B$_2$ -- a kagome lattice superconductor

We report the synthesis and physical properties of a polycrystalline, hexagonal boride YRu$_3$B$_2$. Our resistivity and heat capacity measurements indicate that YRu$_3$B$_2$ is a weakly coupled superconductor, with critical temperature $T_c$ = 0.63 K and upper critical field $μ_0 H_{c2}$ (0)=0.11 T. Density functional theory calculations, together with chemical-bonding analysis, reveal that the electronic states at and near the Fermi energy level are dominated by the Ru kagome sublattice.

cond-mat.supr-con↗

arXiv2025

Kondo-like behavior in a mixed valent oxypnictide $\mathrm{La_{3}Cu_{4}P_{4}O_{2}}$

We have synthesized and characterized the physical properties of a layered, mixed valent oxypnictide $\mathrm{La_{3}Cu_{4}P_{4}O_{2}}$ via magnetization, electrical resistivity, and specific heat measurements. Although $\mathrm{La_{3}Cu_{4}P_{4}O_{2}}$ does not exhibit superconductivity down to T = 0.5 K, it demonstrates an intriguing resistivity minimum observed at $\mathrm{T_{min}}$ = 13.7 K. Disappearance of the resistivity minimum under an applied magnetic field of $\mathrm{μ_{0}H}$ = 9 T together with the negative magnetoresistance at low and positive at high temperatures are observed, which are typical for both Kondo-like spin-dependent scattering and 3D weak localization. We argue that the Kondo scattering is a more plausible explanation due to the low-temperature deviation from a Curie-Weiss law observed in the magnetic susceptibility, consistent with the presence of magnetic interactions between paramagnetic $\mathrm{Cu^{2+}}$ ions and Kondo screening of these $\mathrm{Cu^{2+}}$ moments. We supplemented the experimental characterization with a detailed description of chemical bonding, employing density functional theory (DFT) calculations and crystal orbital Hamilton population (COHP) analysis for $\mathrm{La_{3}Cu_{4}P_{4}O_{2}}$ and isostructural $\mathrm{La_{3}Ni_{4}P_{4}O_{2}}$, which is a superconductor with $\mathrm{T_c = 2.2}$ K. Based on the calculations performed, we present the difference between $\mathrm{La_{3}Cu_{4}P_{4}O_{2}}$ and $\mathrm{La_{3}Ni_{4}P_{4}O_{2}}$ in the character of electronic states at the Fermi level. This discrepancy impacts structural stability and may cause a lack of superconductivity in $\mathrm{La_{3}Cu_{4}P_{4}O_{2}}$ down to T = 0.5 K.

cond-mat.str-el↗

arXiv2023

Superconductivity of Ta-Hf and Ta-Zr alloys: Potential alloys for use in superconducting devices

The electronic properties relevant to the superconductivity are reported for bulk Ta-Hf and Ta-Zr body centered cubic alloys, in large part to determine whether their properties are suitable for potential use in superconducting qbits. The body centered cubic unit cell sizes increase with increasing alloying. The results of magnetic susceptibility, electrical resistivity and heat capacity characterization are reported. While elemental Ta is a type I superconductor, the alloys are type II strong coupling superconductors. Although decreasing the electron count per atom is expected to increase the density of electronic states at the Fermi level and thus the superconducting transition temperature (Tc) in these systems, we find that this is not sufficient to explain the significant increases in the superconducting Tc's observed.

cond-mat.supr-con↗