arXiv subjects

T. Butz

Publications and source records attributed to T. Butz.

13 recordsLinked to original sources

arXiv2013

PAC study of the static and dynamic aspects of metal atom inside C60 cage

30 keV 111mCd and 50 keV 199mHg beams from ISOLDE were used to implant on preformed target of C60 with the thickness of 1 mg/cm2. Endofullerene compounds, viz.,111mCd@C60 and 199mHg@C60 formed during implantation were separated by filtration through micropore filter paper followed by solvent extraction. Dried samples of the endofullerene compounds were counted for the coincidence for the 151-245 keV cascade of 111mCd and 374-158 keV cascade for 199mHg for the TDPAC measurement on a six LaBr3 detector system coupled with digital electronics. The results indicate a single site occupied by the Cd atom in the fullerene cage with fast relaxation component which means that the Cd atom does move inside the cage at room temperature. The quadrupole interaction frequency and asymmetry parameter of the Cd atom occupying the site in C60 are WQ=8.14(42) Mrad/s and eta= 0.42(9) respectively with a site population of 28%. Fast relaxation constant is 0.003 ns-1 with a site contribution of 72%. On the other hand, Hg atom has two static sites of quadrupole frequencies, WQ1=281.60(16.9) Mrad/s and WQ2=202.30(22.7) Mrad/s. Respective asymmetry parameters are eta1=0.1(1) and eta2=0.2(1). The static components have a contribution of 40% with the rest 60% coming from the fast relaxing component.

cond-mat.mtrl-sci↗

arXiv2012

Ab-initio study of the relation between electric polarization and electric field gradients in ferroelectrics

The hyperfine interaction between the quadrupole moment of atomic nuclei and the electric field gradient (EFG) provides information on the electronic charge distribution close to a given atomic site. In ferroelectric materials, the loss of inversion symmetry of the electronic charge distribution is necessary for the appearance of the electric polarization. We present first-principles density functional theory calculations of ferroelectrics such as BaTiO3, KNbO3, PbTiO3 and other oxides with perovskite structures, by focusing on both EFG tensors and polarization. We analyze the EFG tensor properties such as orientation and correlation between components and their link with electric polarization. This work supports previous studies of ferroelectric materials where a relation between EFG tensors and polarization was observed, which may be exploited to study ferroelectric order when standard techniques to measure polarization are not easily applied.

cond-mat.mtrl-sci↗

arXiv2009

On the origin of the electric carrier concentration in graphite

We investigate the dependence of the electrical resistivity of $\sim 60 $nm thick single crystalline graphite samples on the defect concentration produced by proton irradiation at very low fluences. We show that the resistivity decreases few percent at room temperature after inducing defects at concentrations as low as $\sim 0.1 $ppm due to the increase in the carrier density, in agreement with theoretical estimates. The overall results indicate that the carrier densities measured in graphite are not intrinsic but related to defects and impurities.

cond-mat.mtrl-sci↗

arXiv2009

The role of hydrogen in room-temperature ferromagnetism at graphite surfaces

We present a x-ray dichroism study of graphite surfaces that addresses the origin and magnitude of ferromagnetism in metal-free carbon. We find that, in addition to carbon $\pi$ states, also hydrogen-mediated electronic states exhibit a net spin polarization with significant magnetic remanence at room temperature. The observed magnetism is restricted to the top $\approx$10 nm of the irradiated sample where the actual magnetization reaches $ \simeq 15$ emu/g at room temperature. We prove that the ferromagnetism found in metal-free untreated graphite is intrinsic and has a similar origin as the one found in proton bombarded graphite.

cond-mat.mtrl-sci↗

arXiv2009

Magnetic order in Graphite: Experimental evidence, intrinsic and extrinsic difficulties

We discuss recently obtained data using different experimental methods including magnetoresistance measurements that indicate the existence of metal-free high-temperature magnetic order in graphite. Intrinsic as well as extrinsic difficulties to trigger magnetic order by irradiation of graphite are discussed in view of recently published theoretical work.

cond-mat.str-el↗

arXiv2008

Enhancement of Jc by Hf -Doping in the Superconductor MgB2: A Hyperfine Interaction Study

Measurements of the critical current density (Jc) by magnetization and the upper critical field (Hc2) by magnetoresistance have been performed for hafnium-doped MgB2. There has been a remarkable enhancement of Jc as compared to that by ion irradiation without any appreciable decrease in Tc, which is beneficial from the point of view of applications. The irreversibility line extracted from Jc shows an upward shift. In addition, there has been an increase in the upper critical field which indicates that Hf partially substitutes for Mg. Hyperfine interaction parameters obtained from time differential perturbed angular correlation (TDPAC) measurements revealed the formation of HfB and HfB2 phases along with the substitution of Hf. A possible explanation is given for the role of these species in the enhancement of Jc in MgB2 superconductor.

cond-mat.supr-con↗

arXiv2007

Experimental Evidence for Two-Dimensional Magnetic Order in Proton Bombarded Graphite

We have prepared magnetic graphite samples bombarded by protons at low temperatures and low fluences to attenuate the large thermal annealing produced during irradiation. An overall optimization of sample handling allowed us to find Curie temperatures $ T_c \gtrsim 350$ K at the used fluences. The magnetization versus temperature shows unequivocally a linear dependence, which can be interpreted as due to excitations of spin waves in a two dimensional Heisenberg model with a weak uniaxial anisotropy.

cond-mat.str-el↗

arXiv2007

$π$-Electron Ferromagnetism in Metal Free Carbon Probed by Soft X-Ray Dichroism

Elemental carbon represents a fundamental building block of matter and the possibility of ferromagnetic order in carbon attracted widespread attention. However, the origin of magnetic order in such a light element is only poorly understood and has puzzled researchers. We present a spectromicroscopy study at room temperature of proton irradiated metal free carbon using the elemental and chemical specificity of x-ray magnetic circular dichroism (XMCD). We demonstrate that the magnetic order in the investigated system originates only from the carbon $π$-electron system.

cond-mat.other↗

arXiv2006

Proton-induced magnetic order in carbon: SQUID measurements

In this work we have studied systematically the changes in the magnetic behavior of highly oriented pyrolytic graphite (HOPG) samples after proton irradiation in the MeV energy range. Superconducting quantum interferometer device (SQUID) results obtained from samples with thousands of localized spots of micrometer size as well on samples irradiated with a broad beam confirm previously reported results. Both, the para- and ferromagnetic contributions depend strongly on the irradiation details. The results indicate that the magnetic moment at saturation of spots of micrometer size is of the order of $10^{-10}$ emu.

cond-mat.str-el↗

arXiv2005

3D-Hydrogen Analysis of Ferromagnetic Microstructures in Proton Irradiated Graphite

Recently, magnetic order in highly oriented pyrolytic graphite (HOPG) induced by proton broad- and microbeam irradiation was discovered. Theoretical models propose that hydrogen could play a major role in the magnetism mechanism. We analysed the hydrogen distribution of pristine as well as irradiated HOPG samples, which were implanted to micrometer-sized spots as well as extended areas with various doses of 2.25 MeV protons at the Leipzig microprobe LIPSION. For this we used the sensitive 3D hydrogen microscopy system at the Munich microprobe SNAKE. The background hydrogen level in pristine HOPG is determined to be less than 0.3 at-ppm. About 4.8e15 H-atoms/cm^2 are observed in the near-surface region (4 um depth resolution). The depth profiles of the implants show hydrogen located within a confined peak at the end of range, in agreement with SRIM Monte Carlo simulations, and no evidence of diffusion broadening along the c-axis. At sample with microspots, up to 40 at-% of the implanted hydrogen is not detected, providing support for lateral hydrogen diffusion.

cond-mat.mtrl-sci↗

arXiv2005

Induced Magnetic Order by Ion Irradiation of Carbon-Based Structures

In this chapter we review the magnetic effects produced by proton irradiation on graphite, disordered carbon and fullerene films. The advantage of proton irradiation is twofold: it enables us to make an impurity analysis simultaneously to the implantation of hydrogen. In this chapter we will review the main effects obtained after proton irradiation in different carbon-based structures. This chapter is organized as follows. In section 2 we provide the main characteristics of our irradiation facility. In this section we show an example of element analysis obtained in one of the graphite samples used for the irradiation studies. The irradiation effects are reviewed in section 3. This section is divided in two main subsections that describe the effects in oriented graphite and carbon-based thin films. In section 4 we discuss some of the effects observed after annealing the sample at high temperatures in vacuum or after leaving it at room temperature for a long period of time.

cond-mat.mtrl-sci↗

arXiv2003

Induced Magnetic Ordering by Proton Irradiation in Graphite

We provide evidence that proton irradiation of energy 2.25 MeV on highly-oriented pyrolytic graphite samples triggers ferro- or ferrimagnetism. Measurements performed with a superconducting quantum interferometer device (SQUID) and magnetic force microscopy (MFM) reveal that the magnetic ordering is stable at room temperature.

cond-mat.str-el↗

arXiv2002

Ferromagnetism in Oriented Graphite Samples

We have studied the magnetization of various, well characterized samples of highly oriented pyrolitic graphite (HOPG), Kish graphite and natural graphite to investigate the recently reported ferromagnetic-like signal and its possible relation to ferromagnetic impurities. The magnetization results obtained for HOPG samples for applied fields parallel to the graphene layers - to minimize the diamagnetic background - show no correlation with the magnetic impurity concentration. Our overall results suggest an intrinsic origin for the ferromagnetism found in graphite. We discuss possible origins of the ferromagnetic signal.

cond-mat.str-el↗