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T. Danilovich

Publications and source records attributed to T. Danilovich.

At least 19 recordsLinked to original sources

Charting circumstellar chemistry of carbon-rich asymptotic giant branch stars. III. SiO and SiS abundances

The present understanding of C-rich AGB chemistry largely relies on observations of the archetypal carbon star IRC+10216. Current molecular abundance estimates for carbon stars are based either on single-dish spectra sampling a range of excitation conditions, or on interferometric mapping of a few lines. We aim to estimate the circumstellar abundances of SiO, SiS, and their most abundant isotopologues ($^{29}$SiO, $^{30}$SiO, $^{29}$SiS, $^{30}$SiS, and Si$^{34}$S) for a sample of five carbon stars. We derived molecular abundances using detailed 1D non-local thermodynamic equilibrium (non-LTE) radiative transfer (RT) modelling, constrained by both morphological and excitation information obtained from spatially resolved ALMA maps and single-dish observations. We further compared the derived abundances to chemical modelling results. We obtain good fits to the SiO and SiS line profiles, and derived well-constrained abundance profiles and reliable isotopic ratios for all sources except AFGL 3068. While the SiS peak abundances are very similar across the sample (2.0$\times$10$^{-6}-4.7\times$10$^{-6}$), we find that the SiO peak abundances of the rest of the stars are a factor of $\sim$5 larger than that of IRC+10216. The $e$-folding radii ($R_\mathrm{e}$) are in the range 1.3$\times$10$^{16}-7.0\times$10$^{16}$ cm for SiO and 6.0$\times$10$^{15}-1.0\times$10$^{17}$ cm for SiS. The $R_\mathrm{e}$ increases with gas density for both SiO and SiS. Chemical models reproduce the derived SiO abundance profiles well, while over-predicting the SiS $R_\mathrm{e}$ values. Our models highlight the necessity of having spatially resolved observations across a broad range of excitation conditions, while also making evident the limitations inherent in 1D RT modelling using simplified (circum)stellar models. We find that the currently assumed SiS photodissociation rate in chemical models is underestimated.

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ATOMIUM: Inner circumstellar envelopes of oxygen-rich AGB stars as revealed by highly excited SiO lines

Silicon monoxide (SiO) traces the physical conditions and dynamics in the circumstellar envelopes (CSEs) of AGB stars. We present high-resolution ALMA Band 6 observations of highly excited SiO emission in 14 oxygen-rich AGB stars. We cover transitions from v = 0 to v = 8, including first detections of 28SiO v = 3, 4, 8, J = 6-5, 29SiO v = 6, J = 6-5, and 30SiO v = 4, 5, J = 6-5, some of which are masers. The v = 8 transition is the highest v-state observed in an AGB star yet. Masers in v = 0 are detected clearly in V PsA and IRC+10011 and tentatively in T Mic. R Hya exhibits the richest SiO spectrum. SiO J = 6-5 absorption is seen in R Aql, R Hya, S Pav, and T Mic, with features indicative of both infalls and outflows, and tentative detection of 28SiO v = 8, J = 6-5 absorption is found towards S Pav and R Aql. Highly excited SiO emission is often distributed in arcs or clumps with velocity gradients; components in R Hya and U Her align with predicted shock fronts. Detection rates show no significant difference between low and high mass-loss rate stars, although line overlap may affect some intensities. Maser detections appear uncorrelated with pulsation period or phase. The radius enclosing 90 per cent of compact SiO emission shows a tentative correlation with mass-loss rate. These results highlight the role of mass loss and CSE geometry in shaping high-excitation SiO emission.

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A surprisingly large asymmetric ejection from Mira A

Stars with masses between roughly 1 and 8~$M_\odot$ end their lives on the asymptotic giant branch (AGB), when intense mass loss takes place. The outflows are generally accepted to be driven by radiation pressure acting on dust grains that form in the dense extended atmospheres created by the action of convection and stellar pulsations. The complex physics underlying convection, stellar pulsations, and dust nucleation precludes predicting AGB mass loss from first principles. We investigated the evolution of two lobes observed to be expanding away from the AGB star Mira~A using images of polarized light obtained at six epochs using SPHERE on the VLT and of molecular emission at two epochs obtained with ALMA. While dust seems confined to the edges of the lobes, gas fills the lobes and displays higher densities than expected at the observed radii based on the large-scale mass-loss rate of Mira~A, with a total gas mass in the lobes of $\sim 2 \times 10^{-5}~M_\odot$. We find the expansion of the lobes to be consistent with both a constant velocity (ejection time in 2010 or 2011) or a decelerating expansion (ejection time in 2012). If ejection events with a similar magnitude happen periodically, we derive periods between 50 and 200~years to account for the mass-loss rate of Mira~A. This periodicity is uncertain because the average mass-loss rate of Mira A on larger scales is uncertain. We find abundances in the lobes of $\sim 1.5 \times 10^{-6}$ and $\sim 2.5 \times 10^{-6}$ for SO and SO$_2$, respectively, and of $2\times10^{-10}$, $6.5\times10^{-10}$, and $4\times10^{-7}$ for AlO, AlF, and PO. The strong variation in brightness of the different features identified in the polarized-light images is puzzling. We suggest that an asymmetric stellar radiation field preferentially illuminates specific regions of the circumstellar envelope at a given time, producing a lighthouse-like effect.

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Sense and Sensitivity - I. Uncertainty analysis of the gas-phase chemistry in AGB outflows

Chemical reaction networks are central to all chemical models. Each rate coefficient has an associated uncertainty, which is generally not taken into account when calculating the chemistry. We performed the first uncertainty analysis of a chemical model of C-rich and O-rich AGB outflows using the Rate22 reaction network. Quantifying the error on the model predictions enables us to determine the need for adding complexity to the model. Using a Monte Carlo sampling method, we quantified the impact of the uncertainties on the chemical kinetic data on the predicted fractional abundances and column densities. The errors are caused by a complex interplay of reactions forming and destroying each species. Parent species show an error on their envelope sizes, which is not caused by the uncertainty on their photodissociation rate, but rather the chemistry reforming the parent after its photodissociation. Using photodissociation models to estimate the envelope size might be an oversimplification. The error on the CO envelope impacts retrieved mass-loss rates by up to a factor of two. For daughter species, the error on the peak fractional abundance ranges from a factor of a few to three orders of magnitude, and is on average about 10\% of its value. This error is positively correlated with the error on the column density. The standard model suffices for many species, e.g., the radial distribution of cyanopolyynes and hydrocarbon radicals around IRC +10216. However, including spherical asymmetries, dust-gas chemistry, and photochemistry induced by a close-by stellar companion are still necessary to explain certain observations.

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The Nearby Evolved Stars Survey III: First data release of JCMT CO-line observations

Low- to intermediate-mass ($\sim$0.8$-$8 M$_\odot$) evolved stars contribute significantly to the chemical enrichment of the interstellar medium in the local Universe, making accurate mass-return estimates in their final stages crucial. The Nearby Evolved Stars Survey (NESS) is a large multi-telescope project targeting a volume-limited sample of $\sim$850 stars within 3 kpc in order to derive the dust and gas return rates in the Solar Neighbourhood, and to constrain the physics underlying these processes. We present an initial analysis of the CO-line observations, including detection statistics, carbon isotopic ratios, initial mass-loss rates, and gas-to-dust ratios. We describe a new data reduction pipeline to analyse the available NESS CO data from the JCMT, measuring line parameters and calculating empirical gas mass-loss rates. We present the first release of the available data on 485 sources, one of the largest homogeneous samples of CO data to date. Comparison with a large literature sample finds that high mass-loss rate and especially carbon-rich sources are over-represented in literature, while NESS is probing significantly more sources at low mass-loss rates, detecting 59 sources in CO for the first time and providing useful upper limits. CO line detection rates are 81% for the CO (2--1) line and 75% for CO (3--2). The majority (82%) of detected lines conform to the expected soft parabola shape, while eleven sources show a double wind. Calculated mass-loss rates show power-law relations with both the dust-production rates and expansion velocities up to $\sim 5 \times 10^{-6}$~\msunyr. Median gas-to-dust ratios of 250 and 680 are found for oxygen-rich and carbon-rich sources, respectively. Our analysis of CO observations in this first data release highlights the importance of our volume-limited approach in characterizing the local AGB population as a whole.

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An accreting dwarf star orbiting the S-type giant star pi1 Gru

Aims. We aim to characterize the properties of the inner companion of the S-type AGB star pi1 Gru and to identify plausible future evolutionary scenarios for this triple system. Methods. We observed pi1 Gru with ALMA and VLT/SPHERE. In addition, we collected archival photometry data and used the Hipparcos-Gaia proper motion anomaly. We derive the best orbital parameters from Bayesian inference. Results. In June-July 2019, the inner companion, pi1 Gru C, was located at 37.4 +/- 2.0 mas from the primary (a projected separation of 6.05 +/- 0.55 au at 161.7 +/- 11.7 pc). The best orbital solution yields a companion mass of 0.86 (+0.22/-0.20) Msun (using the derived mass of the primary) and a semi-major axis of 7.05(+0.54/-0.57) au, corresponding to an orbital period of 11.0 (+1.7/-1.5) yr. The preferred solution is an elliptical orbit with eccentricity e = 0.35(+0.18/-0.17), although a circular orbit cannot be fully excluded. The close companion could be either a K1V (F9.5V to K7V) star or a white dwarf (WD). Ultraviolet and millimeter continuum photometry are consistent with the presence of an accretion disk around the close companion. The ultraviolet emission may originate from hot spots in an overall cooler disk, or from a hot disk if the companion is a WD. Conclusions. Although the close companion and the AGB star are interacting and an accretion disk is observed around the companion, the mass-accretion rate is too low to trigger a Type Ia supernova, but it could produce novae every ~900 yr. Short-wavelength, spatially resolved observations are required to further constrain the nature of the C companion. Searches for close-in companions similar to this system will improve our understanding of the physics of mass and angular momentum transfer, as well as orbital evolution during late evolutionary stages.

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The Nearby Evolved Stars Survey (NESS) V: properties of volume-limited samples of Galactic evolved stars

We provide a meta-study of the statistical and individual properties of two volume-complete sets of evolved stars in the Solar Neighbourhood: (1) 852 stars from the Nearby Evolved Stars Survey (NESS), and (2) a partially overlapping set of 507 evolved stars within 300 pc. We also investigate distance determinations to these stars, their luminosity functions and their spatial distribution. Gaia APSIS GSP-Phot AENEAS temperatures of bright giant stars often appear to be underestimated. Existing literature on AGB stars under-samples both the most and least extreme nearby dust-producing stars. We reproduce the literature star-formation history of the solar neighbourhood, though stellar-evolution models over-predict the number of AGB stars of ages around 500 Myr. The distribution of AGB stars broadly matches the known 300 pc scale height of the Galactic disc and shows concentration in the direction of the Galactic centre. Most dust-producing carbon stars belong to the Galactic thick-disc population.

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Charting circumstellar chemistry of carbon-rich asymptotic giant branch stars. II. Abundances and spatial distributions of CS

The circumstellar envelopes (CSEs) of asymptotic giant branch (AGB) stars harbour a rich variety of molecules and are sites of complex chemistry. Our current understanding of the circumstellar chemical processes of carbon-rich AGB stars is predominantly based on observations of a single star, IRC+10216, often regarded as an archetypical carbon star. We aim to estimate stellar and circumstellar properties for five carbon stars, and constrain their circumstellar CS abundances. This study compares the CS abundances among the sources, informs circumstellar chemical models, and helps to assess if IRC+10216 is a good representative of the physics and chemistry of carbon star CSEs. We modelled the spectral energy distributions (SEDs) and CO line emission to derive the stellar and outflow properties. Using these, we then retrieved CS abundance profiles with detailed radiative transfer modelling, imposing spatial and excitation constraints from ALMA and single-dish observations. We obtain good fits to the SEDs and CO lines for all sources and reproduce the CS line emission across various transitions and apertures, yielding robust estimates of the CS abundance profiles. Peak CS fractional abundances range from 1$\times$10$^{-6}$ - 4$\times$10$^{-6}$, with e-folding radii of 1.8$\times$10$^{16}$ - 6.8$\times$10$^{16}$ cm. We also derive reliable $^{12}$C/$^{13}$C and $^{32}$S/$^{34}$S ratios from CS isotopologue modelling. Our results refine previous single-dish CS abundance estimates and improve the relative uncertainty on the CS e-folding radius for IRAS 07454$-$7112 by a factor of $\sim$2.5. Chemical models reproduce our estimates of the CS radial extent, corroborating the CS photodissociation framework used therein. We find no significant differences between the derived CS abundance profiles for IRC+10216 and the rest of the sample, apart from the expected density-driven variations.

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ATOMIUM: Continuum emission and evidence of dust enhancement from binary motion

Low- and intermediate-mass stars on the asymptotic giant branch (AGB) account for a significant portion of the dust and chemical enrichment in their host galaxy. Here we present ALMA observations of the continuum emission at 1.24 mm around a sample of 17 stars from the ATOMIUM survey. From our analysis of the stellar contributions to the continuum flux, we find that the semi-regular variables all have smaller physical radii and fainter monochromatic luminosities than the Mira variables. Comparing these properties with pulsation periods, we find a positive trend between stellar radius and period only for the Mira variables with periods above 300 days and a positive trend between the period and the monochromatic luminosity only for the red supergiants and the most extreme AGB stars with periods above 500 days. We find that the continuum emission at 1.2 mm can be classified into four groups. "Featureless" continuum emission is confined to the (unresolved) regions close to the star for five stars in our sample, relatively uniform extended flux is seen for four stars, tentative elongated features are seen for three stars, and the remaining five stars have unique or unusual morphological features in their continuum maps. These features can be explained by binary companions to 10 out of the 14 AGB stars in our sample. Based on our results we conclude that there are two modes of dust formation: well established pulsation-enhanced dust formation and our newly proposed companion-enhanced dust formation. If the companion is located close to the AGB star, in the wind acceleration region, then additional dust formed in the wake of the companion can increase the mass lost through the dust driven wind. This explains the different dust morphologies seen around our stars and partly accounts for a large scatter in literature mass-loss rates, especially among semiregular stars with small pulsation periods.

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Chemical tracers of a highly eccentric AGB-main sequence star binary

Binary interactions have been proposed to explain a variety of circumstellar structures seen around evolved stars, including asymptotic giant branch (AGB) stars and planetary nebulae. Studies resolving the circumstellar envelopes of AGB stars have revealed spirals, discs and bipolar outflows, with shaping attributed to interactions with a companion. For the first time, we have used a combined chemical and dynamical analysis to reveal a highly eccentric and long-period orbit for W Aquilae, a binary system containing an AGB star and a main sequence companion. Our results are based on anisotropic SiN emission, the first detections of NS and SiC towards an S-type star, and density structures observed in the CO emission. These features are all interpreted as having formed during periastron interactions. Our astrochemistry-based method can yield stringent constraints on the orbital parameters of long-period binaries containing AGB stars, and will be applicable to other systems.

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Modelling predicts a molecule-rich disk around the AGB star L2 Puppis

The nearby oxygen-rich AGB star L2 Pup hosts a well-studied nearly edge-on disk. To date, disks around AGB stars have not been chemically studied in detail. By combining a parameterisation commonly used for protoplanetary disks and archival ALMA observations, we retrieved an updated density and temperature structure of this disk. This physical model was then used as input to the first chemical model of an AGB disk. The model shows that the physical structure of the disk has a large impact on its chemistry, with certain species showing large changes in column density relative to a radial outflow, indicating that chemistry could be used as a tracer of disks that cannot be directly imaged. Despite its oxygen-rich nature, the daughter species formed within the disk are surprisingly carbon-rich. Two chemical regimes can be distinguished: cosmic-ray induced chemistry in the midplane and photochemistry induced by the interstellar radiation field in the outer regions. Certain complex organic molecules are formed in the midplane. This occurs via gas-phase chemistry only, as the disk is too warm for dust-gas chemistry. The photochemistry in the outer regions leads to the efficient formation of (long) carbon-chains. The predictions of the model allow us to tentatively put the disk's age $\lesssim 10^5$ yr. Additional observations are necessary to better constrain the physical structure of L2 Pup's disk and are essential to test the predictions made by the chemical model. Our exploratory work paves the way for a more general study of the chemistry of AGB disks.

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ATOMIUM: Molecular inventory of 17 oxygen-rich evolved stars observed with ALMA

The dusty winds of cool evolved stars are a major contributor of the newly synthesised material enriching the Galaxy and future generations of stars. However, the details of the physics and chemistry behind dust formation and wind launching have yet to be pinpointed. Recent spatially resolved observations show the importance of gaining a more comprehensive view of the circumstellar chemistry, but a comparative study of the intricate interplay between chemistry and physics is still difficult because observational details such as frequencies and angular resolutions are rarely comparable. Aiming to overcome these deficiencies, ATOMIUM is an ALMA Large Programme to study the physics and chemistry of the circumstellar envelopes of a diverse set of oxygen-rich evolved stars under homogeneous observing conditions at three angular resolutions between ~0.02"-1.4". Here we summarize the molecular inventory of these sources, and the correlations between stellar parameters and molecular content. Seventeen oxygen-rich or S-type asymptotic giant branch (AGB) and red supergiant (RSG) stars have been observed in several tunings with ALMA Band 6, targeting a range of molecules to probe the circumstellar envelope and especially the chemistry of dust formation close to the star. We systematically assigned the molecular carriers of the spectral lines and measured their spectroscopic parameters and the angular extent of the emission of each line from integrated intensity maps. Across the ATOMIUM sample, we detect 291 transitions of 24 different molecules and their isotopologues. This includes several first detections in oxygen-rich AGB/RSG stars: PO v=1, SO2 v1=1 and v2=2, and several high energy H2O transitions. We also find several first detections in S-type AGB stars: vibrationally excited HCN v2=2,3 and SiS v=4,5,6, as well as first detections of the molecules SiC, AlCl, and AlF in W Aql...

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The unusual 3D distribution of NaCl around the AGB star IK Tau

NaCl is a diatomic molecule with a large dipole moment, which allows for its detection even at relatively small abundances. It has been detected towards several evolved stars, among which is the AGB star IK Tau, around which it is distributed in several clumps that lie off-center from the star. We aim to study the three-dimensional distribution of NaCl around the AGB star IK Tau, and to obtain the abundance of NaCl relative to H$_2$ for each of the clumps. First, a new value for the maximum expansion velocity is determined. The observed ALMA channel maps are then deprojected to create a three-dimensional model of the distribution of NaCl. This model is then used as input for the radiative transfer modelling code magritte, which is used to obtain the NaCl abundances of each of the clumps by comparing the observations with the results of the magritte simulations. Additionally, the rotational temperature of the clumps is determined using population diagrams. We derive an updated value for the maximum expansion velocity of IK Tau $\upsilon_\mathrm{exp}$ = 28.4 km/s. A spiral-like shape can be discerned in our three-dimensional distribution model of the NaCl. This spiral lies more or less in the plane of the sky. The distribution is also flatter in the line-of-sight direction than in the plane of the sky. We find clump abundances between $9 \times 10^{-9}$ and $5 \times 10^{-8}$ relative to H$_2$, where the relative abundance is typically lower for clumps closer to the star. For the first time, we used deprojection to understand the three-dimensional environment of an AGB star and calculated the fractional abundance of NaCl in clumps surrounding the star.

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Rotation-tunneling spectrum and astrochemical modeling of dimethylamine, CH$_3$NHCH$_3$, and searches for it in space

Methylamine has been the only simple alkylamine detected in the interstellar medium for a long time. With the recent secure and tentative detections of vinylamine and ethylamine, respectively, dimethylamine has become a promising target for searches in space. Its rotational spectrum, however, has been known only up to 45 GHz until now. Here we investigate the rotation-tunneling spectrum of dimethylamine in selected regions between 76 and 1091 GHz using three different spectrometers in order to facilitate its detection in space. The quantum number range is extended to $J = 61$ and $K_a = 21$, yielding an extensive set of accurate spectroscopic parameters. To search for dimethylamine, we refer to the spectral line survey ReMoCA carried out with the Atacama Large Millimeter/submillimeter Array toward the high-mass star-forming region Sagittarius B2(N) and a spectral line survey of the molecular cloud G+0.693$-$0.027 employing the IRAM 30 m and Yebes 40 m radio telescopes. We report nondetections of dimethylamine toward the hot molecular cores Sgr B2(N1S) and Sgr B2(N2b) as well as G+0.693$-$0.027 which imply that dimethylamine is at least 14, 4.5 and 39 times less abundant than methylamine toward these sources, respectively. The observational results are compared to computational results from a gas-grain astrochemical model. The modeled methylamine to dimethylamine ratios are compatible with the observational lower limits. However, the model produces too much ethylamine compared with methylamine which could mean that the already fairly low levels of dimethylamine in the models may also be too high.

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ATOMIUM: Probing the inner wind of evolved O-rich stars with new, highly excited H$_2$O and OH lines

Water and the hydroxyl radical are major constituents of the envelope of O-rich late-type stars. Transitions involving energy levels that are highly excited have been observed in both H$_2$O and OH. These and more recently discovered transitions can now be observed at a high sensitivity and angular resolution with the ALMA Array. Spectra and maps of H$_2$O and OH observed with an angular resolution of 20 to $\sim$200 mas were obtained at two epochs with the ALMA array. Observations with the Compact Array were also used to check for time variability of water transitions. Radiative transfer models of water were revisited to characterize masing conditions and up-to-date chemical models were used for comparison with our observations. Ten rotational transitions of H$_2$O with energies up to 9000 K were observed in various vibrational states. All but one are new detections in space, and from these we have derived accurate rest frequencies. Hyperfine split $Λ$-doubling transitions in v = 0, J = 27/2 and 29/2 levels of the $^2Π_{3/2}$ state and, $J = 33/2$ and 35/2 of the $^2Π_{1/2}$ state of OH with excitation energies up to 8900 K were also observed. Four of these transitions are new detections in space. Combining our measurements with earlier observations of OH, the v = 0 and v = 1 $Λ$-doubling frequencies have been improved. Our H$_2$O maps show compact emission and extensions up to twelve stellar radii or more. The 268.149 GHz emission line of water in the v$_2$ = 2 state is time variable, tends to be masing with dominant radiative pumping, and is widely excited. The widespread but weaker 262.898 GHz water line in v$_2$ = 1 also shows signs of maser emission. Emission and absorption of both H$_2$O and OH reveal an infall of matter and complex kinematics influenced by binarity. From our observed column densities, we derived OH/H$_2$O abundance ratios in a few stars.

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Sensitivity study of chemistry in AGB outflows using chemical kinetics

Asymptotic Giant Branch (AGB) stars shed a significant amount of their mass in the form of a stellar wind, creating a vast circumstellar envelope (CSE). Owing to the ideal combination of relatively high densities and cool temperatures, CSEs serve as rich astrochemical laboratories. {While the chemical structure of AGB outflows has been modelled and analysed in detail for specific physical setups, there is a lack of understanding regarding the impact of changes in the physical environment on chemical abundances. A systematic sensitivity study is necessary to comprehend the nuances in the physical parameter space, given the complexity of the chemistry. This is crucial for estimating uncertainties associated with simulations and observations. In this work, we present the first sensitivity study of the impact of varying outflow densities and temperature profiles on the chemistry. With the use of a chemical kinetics model, we report on the uncertainty in abundances, given a specific uncertainty on the physical parameters. }Additionally, we analyse the molecular envelope extent of parent species and compare our findings to observational studies. Mapping the impact of differences in physical parameters throughout the CSE on the chemistry is a strong aid to observational studies.

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The VLT/SPHERE view of the ATOMIUM cool evolved star sample. I. Overview: Sample characterization through polarization analysis

Aims. Through the ATOMIUM project, based on an ALMA large program, we aim to present a consistent view of a sample of 17 nearby cool evolved stars (Aymptotic Giant Branch and red supergiant stars). Methods. Here we present VLT/SPHERE-ZIMPOL polarimetric maps obtained in the visible of 14 out of the 17 ATOMIUM sources. They were obtained contemporaneously with the ALMA high spatial resolution data. To help interpret the polarized signal, we produced synthetic maps of light scattering by dust, through 3D radiative transfer simulations with the RADMC3D code. Results. The degree of linear polarization (DoLP) observed by ZIMPOL spreads across several optical filters. We infer that it primarily probes dust located just outside of the point spread function, and in or near the plane of the sky, with a total optical depth close to unity in the line of sight, representing only a fraction of the total circumstellar dust. The maximum DoLP ranges from 0.03-0.38 depending on the source, fractions that can be reproduced by our 3D pilot models for grains composed of common dust species. The spatial structure of the DoLP shows a diverse set of shapes. Only for three sources do we note a correlation between the ALMA CO and SiO lines, which trace the gas density, and the DoLP, which traces the dust. Conclusion. The clumpiness of the DoLP and the lack of a consistent correlation between the gas and the dust location show that, in the inner circumstellar environment (CSE), dust formation occurs at very specific sites. This has potential consequences for the derived mass-loss rates and dust-to-gas ratio in the inner region of the CSE. Except for $π^1$~Gru and perhaps GY Aql, we do not detect interactions between the circumstellar wind and the hypothesized companions that shape the wind at larger scales. This suggests that the orbits of any other companions are tilted out of the plane of the sky.

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ATOMIUM: ALMA tracing the origins of molecules in dust forming oxygen rich M-type stars: Motivation, sample, calibration, and initial results

This overview paper presents ATOMIUM, a Large Programme in Cycle 6 with the Atacama Large Millimeter-submillimeter Array (ALMA). The goal of ATOMIUM is to understand the dynamics and the gas phase and dust formation chemistry in the winds of evolved asymptotic giant branch (AGB) and red supergiant (RSG) stars. A more general aim is to identify chemical processes applicable to other astrophysical environments. 17 oxygen-rich AGB and RSG stars spanning a range in (circum)stellar parameters and evolutionary phases were observed in a homogeneous observing strategy allowing for an unambiguous comparison. Data were obtained between 213.83 and 269.71 GHz at high (0.025-0.050 arcsec), medium (0.13-0.24 arcsec), and low (about 1 arcsec) angular resolution. The sensitivity per 1.3 km/s channel was 1.5-5 mJy/beam. 13 molecules were designated as primary molecules in the survey: CO, SiO, AlO, AlOH, TiO, TiO2, HCN, SO, SO2, SiS, CS, H2O, and NaCl. The scientific motivation, survey design, sample properties, data reduction, and an overview of the data products are described; and we highlight one scientific result - the wind kinematics of the ATOMIUM sources. The ATOMIUM sources often have a slow wind acceleration, and a fraction of the gas reaches a velocity which can be up to a factor of two times larger than previously reported terminal velocities assuming isotropic expansion, and the wind kinematic profiles establish that the radial velocity described by the momentum equation for a spherical wind structure cannot capture the complexity of the velocity field. In 15 sources, some molecular transitions other than 12CO v=0 J=2-1 reach a higher outflow velocity, with a spatial emission zone that is often greater than 30 stellar radii, but much less than the extent of CO. Binary interaction with a (sub)stellar companion might (partly) explain the non-monotonic behaviour of the projected velocity field.

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