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T. Fouchet

Publications and source records attributed to T. Fouchet.

16 recordsLinked to original sources
arXiv2026

New 12C/13C and 14N/15N isotopic ratio measurements in Jupiter's stratosphere revealed by ALMA

The collision of comet SL9 with Jupiter in 1994 changed the chemical composition of the Jovian stratosphere for decades. New molecules were detected minutes after the impacts (HCN, CO, CS, etc.) and some are still present today. They were deposited in the stratosphere at pressures lower than 0.1 mbar and were most probably formed by shock-induced chemistry recombining Jovian and cometary material. However, the question of the origin of these molecules is still not completely understood. One way to address this open question is to determine the isotopic composition of the new molecules. Isotopic ratios have long been measured in the Solar System. They present a variety of values depending on the object or the molecule and therefore trace different reservoirs of material. Derivations of carbon and nitrogen isotopic ratios in HCN four years after SL9 showed atypical depletions in the heavier isotopes that had never been observed before in the Solar System. These results suggested an unusual cometary composition or an unknown fractionation mechanism in the hot and shocked air parcels. We aim to measure carbon and nitrogen isotopic ratios in HCN to shed light on the puzzling results of 1998. With Atacama Large Millimeter/submillimeter Array data from 2017 and radiative-transfer calculations, we derived the abundance of two HCN isotopologues, H13CN and HC15N, at pressures probed from 0.03 to 1.8 mbar. We find 12C/13C = $73\pm5$ and 14N/15N = $245\pm29$, respectively (0.76-0.87) and (0.80-1.00) times the terrestrial references, and (0.69-0.87) and (0.42-0.70) times the solar-Jovian bulk values. In contrast to the strong depletions reported in 1998, our values are instead compatible with an enrichment in the heavier isotopes relative to the Jovian bulk. We interpret these enrichments as the direct signature of the cometary contribution in HCN and/or as 23 years of chemical evolution.

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arXiv2026

Detection of stratospheric HCN and tropospheric CO in Uranus and the implication for their sources

Uranus belongs to the category of ice giants that are common in our Galaxy. However, Uranus is one of the least explored and understood planets in our Solar System. This work aims to constrain the deep oxygen abundance of Uranus to better understand its formation. Another goal concerns the origin of exogeneous species, such as CO and HCN, found in the upper stratospheres of giant planets. We used spectral mapping observations of the CO (J=3-2) and HCN (J=4-3) rotational submillimeter lines obtained with ALMA in 2022 and 2024. We combined them with radiative transfer and thermochemical modeling to determine the tropospheric abundance of CO and the deep O/H ratio of Uranus. We used radiative transfer simulations with physical models of various sources of external CO and HCN to constrain the vertical and meridional distributions of these species and narrow down the nature of their external sources. We also applied a wind retrieval algorithm to search for zonal winds in the stratosphere of Uranus at the levels probed by the CO and HCN lines. We unambiguously detect tropospheric CO for the first time with a mole fraction of 5.8$\pm$0.3 ppb and stratospheric HCN with a mole faction of (1.8$\pm$0.2)$\times10^{-11}$ restricted to pressures lower than 0.2 mbar. Thermochemical calculations suggest that the deep interior of Uranus is enriched in oxygen with respect to the protoplanetary nebula by at least a factor of 52$^{+30}_{-20}$. We also find that the stratospheric CO is rather uniform over the observed latitudes and that the CO lines are best fit by an old comet impact model, in which a large comet hit the planet several centuries ago. CO therefore has a dual origin in Uranus. Finally, we do not detect stratospheric winds from these data, but the CO data indicate that zonal winds in the 10$^\circ$S-10$^\circ$N latitudinal range are likely retrograde at submillibar pressures.

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arXiv2026

Observations of the temporal evolution of Saturn's stratosphere following the Great Storm of 2010-2011. II. Latitudinal distribution of CO and stratospheric winds

Saturn's Great Storm of 2010-2011 has produced two stratospheric hot spots, the "beacons," that eventually merged to produce a gigantic one in April and May 2011. This beacon perturbed stratospheric temperatures, hydrocarbon, and water abundances for several years. We aim to assess whether the beacon induced any perturbation in another oxygen species, namely CO. A second goal is to measure how the vortex perturbed the stratospheric wind regime. We conducted interferometric observations of Saturn in the submillimeter range with SMA and ALMA to spatially resolve the CO (J=3-2) and (J=2-1) emissions, respectively. We used a previously determined CO vertical profile as a template, to search for (i) the meridional distribution of CO and (ii) variations of the CO abundance associated with the storm. The high spatial and spectral resolutions of the ALMA observations enabled us to retrieve the winds from the Doppler shifts induced by the winds on the lines. Despite limitations resulting from the removal of baseline ripples, we find a relatively constant meridional distribution of CO. The average CO mole fraction implied by the adopted and rescaled 220-year-old-comet-impact vertical profile is (1.7$\pm$0.7)$\times10^{-7}$ at 0.3\,mbar, i.e., where the contribution functions peak. We also find that the CO abundance has not been noticeably altered in the beacon. The winds measured at 1\,mbar show striking differences with those measured in 2018, after the demise of the beacon. We find the signature of the vortex as an anticyclonic feature. The equatorial prograde jet is 100 to 200 m.s$^{-1}$ slower, and broader in latitude, than in quiescent conditions. We also detect several prograde jets in the southern hemisphere. Finally, we detect a retrograde jet at 74$^\circ$N which could be a polar jet caused by the interaction of the Saturn magnetosphere with its atmosphere.

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arXiv2023

Composition and thermal properties of Ganymede's surface from JWST/NIRSpec and MIRI observations

JWST NIRSpec IFU (2.9-5.3 mu) and MIRI MRS (4.9-28.5 mu) observations were performed on both the leading and trailing hemispheres of Ganymede with a spectral resolution of ~2700. Reflectance spectra show signatures of water ice, CO2 and H2O2. An absorption feature at 5.9 mu is revealed and is tentatively assigned to sulfuric acid hydrates. The CO2 4.26-mu band shows latitudinal and longitudinal variations in depth, shape and position over the two hemispheres, unveiling different CO2 physical states. In the ice-rich polar regions, which are the most exposed to Jupiter's plasma irradiation, the CO2 band is redshifted with respect to other terrains. In the leading northern polar cap, the CO2 band is dominated by a high wavelength component at ~4.27 mu, consistent with CO2 trapped in amorphous water ice. At equatorial latitudes (and especially on dark terrains) the observed band is broader and shifted towards the blue, suggesting CO2 adsorbed on non-icy materials. Amorphous ice is detected in the ice-rich polar regions, and is especially abundant on the leading northern polar cap. In both hemispheres the north polar cap ice appears to be more processed than the south polar cap. A longitudinal modification of the H2O ice molecular structure and/or nano/micrometre-scale texture, of diurnal or geographic origin, is observed in both hemispheres. Ice frost is observed on the morning limb of the trailing hemisphere, possibly formed during the night from the recondensation of water subliming from the warmer subsurface. Reflectance spectra of the dark terrains are compatible with the presence of Na-/Mg-sulfate salts, sulfuric acid hydrates, and possibly phyllosilicates mixed with fine-grained opaque minerals, having an highly porous texture. Mid-IR brightness temperatures indicate a rough surface and a very low thermal inertia of 20-40 J m-2 s-0.5 K-1, consistent with a porous surface.

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arXiv2022

The CH$_4$ abundance in Jupiter's upper atmosphere

Hydrocarbon species, and in particular CH$_4$, play a key role in the stratosphere--thermosphere boundary of Jupiter, which occurs around the $μ$-bar pressure level. Previous analyses of solar occultation, He and Ly-$α$ airglow, and ISO/SWS measurements of the radiance around 3.3 $μ$m have inferred significantly different methane concentrations. Here we aim to accurately model the CH$_4$ radiance at 3.3 $μ$m measured by ISO/SWS by using a comprehensive non-local thermodynamic equilibrium model and the most recent collisional rates measured in the laboratory for CH$_4$ to shed new light onto the methane concentration in the upper atmosphere of Jupiter. These emission bands have been shown to present a peak contribution precisely at the $μ$-bar level, hence directly probing the region of interest. We find that a high CH$_4$ concentration is necessary to explain the data, in contrast with the most recent analyses, and that the observations favour the lower limit of the latest laboratory measurements of the CH$_4$ collisional relaxation rates. Our results provide precise constraints on the composition and dynamics of the lower atmosphere of Jupiter.

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arXiv2022

Thermal structure and aerosols in Mars' atmosphere from TIRVIM/ACS onboard the ExoMars Trace Gas Orbiter : validation of the retrieval algorithm

The Atmospheric Chemistry Suite (ACS) onboard the ExoMars Trace Gas Orbiter (TGO) monitors the Martian atmosphere through different spectral intervals in the infrared light. We present a retrieval algorithm tailored to the analysis of spectra acquired in nadir geometry by TIRVIM, the thermal infrared channel of ACS. Our algorithm simultaneously retrieves vertical profile of atmospheric temperature up to 50 km, surface temperature, and integrated optical depth of dust and water ice clouds. The specificity of the TIRVIM dataset lies in its capacity to resolve the diurnal cycle over a 54 sol period. However, it is uncertain to what extent can the desired atmospheric quantities be accurately estimated at different times of day. Here we first present an Observing System Simulation Experiment (OSSE). We produce synthetic observations at various latitudes, seasons and local times and run our retrieval algorithm on these synthetic data, to evaluate its robustness. Different sources of biases are documented, in particular regarding aerosol retrievals. Atmospheric temperature retrievals are found robust even when dust and/or water ice cloud opacities are not well estimated in our OSSE. We then apply our algorithm to TIRVIM observations in April-May, 2018 and perform a cross-validation of retrieved atmospheric temperature and dust integrated opacity by comparisons with thousands of co-located Mars Climate Sounder (MCS) retrievals. Most differences between TIRVIM and MCS atmospheric temperatures can be attributed to differences in vertical sensitivity. Daytime dust opacities agree well with each other, while biases are found in nighttime dust opacity retrieved from TIRVIM at this season.

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arXiv2021

Pluto's atmosphere observations with ALMA: spatially-resolved maps of CO and HCN emission and first detection of HNC

Following the detection of CO and HCN in Pluto's atmosphere, we report on new ALMA observations of Pluto with two main goals: (i) obtaining spatially-resolved measurements (~0.06'' on the ~0.15'' disk subtended by Pluto and its atmosphere) of CO(3-2) and HCN(4-3) (ii) targetting new chemical compounds, primarily hydrogen isocyanide (HNC). The CO line shows an absorption core at beam positions within Pluto's disk, a direct signature of Pluto's cold mesosphere. Analysis provides tentative evidence for a non-uniform temperature field in the lower atmosphere (near 30 km), with summer pole latitudes being 7$\pm$3.5 K warmer than low latitudes. This unexpected result may point to shorter radiative timescales in the atmosphere than previously thought. The HCN emission is considerably more extended than CO, peaking at radial distances beyond Pluto limb, and providing a new method to determine Pluto's HCN vertical profile in 2017. The mean (column-averaged) location of HCN is at 690+/-75 km altitude, with an upper atmosphere (> 800 km) mixing ratio of ~ 1.8 x 10$^{-4}$. Little or no HCN (<5 x 10$^{-9}$ at 65 km) is present in the lower atmosphere, implying undersaturation of HCN there. The HCN emission appears enhanced above the low-latitude limb, but interpretation, in terms of an enhanced HCN abundance or a warmer upper atmosphere there, is uncertain. The first detection of HNC is reported, with a (7.0$\pm$2.1) x 10$^{12}$ cm$^{-2}$ column density, referred to Pluto surface, and a HNC / HCN ratio of 0.095+/-0.026, very similar to their values in Titan's atmosphere. We also obtain upper limits on CH3CN (< 2.6 x 10$^{13}$ cm$^{-2}$) and CH$_3$CCH (< 8.5 x 10$^{14}$ cm$^{-2}$); the latter value is inconsistent with the reported detection of CH$_3$CCH from New Horizons. These upper limits also point to incomplete resublimation of ice-coated aerosols in the lower atmosphere.

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arXiv2021

First direct measurement of auroral and equatorial jets in the stratosphere of Jupiter

Context. The tropospheric wind pattern in Jupiter consists of alternating prograde and retrograde zonal jets with typical velocities of up to 100 m/s around the equator. At much higher altitudes, in the ionosphere, strong auroral jets have been discovered with velocities of 1-2 km/s. There is no such direct measurement in the stratosphere of the planet. Aims. In this paper, we bridge the altitude gap between these measurements by directly measuring the wind speeds in Jupiter's stratosphere. Methods. We use the Atacama Large Millimeter/submillimeter Array's very high spectral and angular resolution imaging of the stratosphere of Jupiter to retrieve the wind speeds as a function of latitude by fitting the Doppler shifts induced by the winds on the spectral lines. Results. We detect for the first time equatorial zonal jets that reside at 1 mbar, i.e. above the altitudes where Jupiter's Quasi-Quadrennial Oscillation occurs. Most noticeably, we find 300-400 m/s non-zonal winds at 0.1 mbar over the polar regions underneath the main auroral ovals. They are in counter-rotation and lie several hundreds of kilometers below the ionospheric auroral winds. We suspect them to be the lower tail of the ionospheric auroral winds. Conclusions. We detect directly and for the first time strong winds in Jupiter's stratosphere. They are zonal at low-to-mid latitudes and non-zonal at polar latitudes. The wind system found at polar latitudes may help increase the effciency of chemical complexification by confining the photochemical products in a region of large energetic electron precipitation.

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arXiv2020

A stringent upper limit of the PH$_3$ abundance at the cloud top of Venus

Following the announcement of the detection of phosphine (PH$_3$) in the cloud deck of Venus at millimeter wavelengths, we have searched for other possible signatures of this molecule in the infrared range. Since 2012, we have been observing Venus in the thermal infrared at various wavelengths to monitor the behavior of SO$_2$ and H$_2$O at the cloud top. We have identified a spectral interval recorded in March 2015 around 950 cm$^{-1}$ where a PH$_3$ transition is present. From the absence of any feature at this frequency, we derive, on the disk-integrated spectrum, a 3-$σ$ upper limit of 5 ppbv for the PH$_3$ mixing ratio, assumed to be constant throughout the atmosphere. This limit is 4 times lower than the disk-integrated mixing ratio derived at millimeter wavelengths. Our result brings a strong constraint on the maximum PH$_3$ abundance at the cloud top and in the lower mesosphere of Venus.

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arXiv2020

18-year long monitoring of the evolution of H2O vapor in the stratosphere of Jupiter with the Odin space telescope

Comet Shoemaker-Levy 9 impacted Jupiter in July 1994, leaving its stratosphere with several new species, among them water vapor (H2O). With the aid of a photochemical model H2O can be used as a dynamical tracer in the jovian stratosphere. In this paper, we aim at constraining vertical eddy diffusion (Kzz) at the levels where H2O resides. We monitored the H2O disk-averaged emission at 556.936 GHz with the Odin space telescope between 2002 and 2019, covering nearly two decades. We analyzed the data with a combination of 1D photochemical and radiative transfer models to constrain vertical eddy diffusion in the stratosphere of Jupiter. The Odin observations show us that the emission of H2O has an almost linear decrease of about 40% between 2002 and 2019.We can only reproduce our time series if we increase the magnitude of Kzz in the pressure range where H2O diffuses downward from 2002 to 2019, i.e. from ~0.2 mbar to ~5 mbar. However, this modified Kzz is incompatible with hydrocarbon observations. We find that, even if allowance is made for the initially large abundances of H2O and CO at the impact latitudes, the photochemical conversion of H2O to CO2 is not sufficient to explain the progressive decline of the H2O line emission, suggestive of additional loss mechanisms. The Kzz we derived from the Odin observations of H2O can only be viewed as an upper limit in the ~0.2 mbar to ~5 mbar pressure range. The incompatibility between the interpretations made from H2O and hydrocarbon observations probably results from 1D modeling limitations. Meridional variability of H2O, most probably at auroral latitudes, would need to be assessed and compared with that of hydrocarbons to quantify the role of auroral chemistry in the temporal evolution of the H2O abundance since the SL9 impacts. Modeling the temporal evolution of SL9 species with a 2D model would be the next natural step.

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arXiv2019

Herschel map of Saturn's stratospheric water, delivered by the plumes of Enceladus

Context. The origin of water in the stratospheres of Giant Planets has been an outstanding question ever since its first detection by ISO some 20 years ago. Water can originate from interplanetary dust particles, icy rings and satellites and large comet impacts. Analysis of Herschel Space Observatory observations have proven that the bulk of Jupiter's stratospheric water was delivered by the Shoemaker-Levy 9 impacts in 1994. In 2006, the Cassini mission detected water plumes at the South Pole of Enceladus, placing the moon as a serious candidate for Saturn's stratospheric water. Further evidence was found in 2011, when Herschel demonstrated the presence of a water torus at the orbital distance of Enceladus, fed by the moon's plumes. Finally, water falling from the rings onto Saturn's uppermost atmospheric layers at low latitudes was detected during the final orbits of Cassini's end-of-mission plunge into the atmosphere. Aims. In this paper, we use Herschel mapping observations of water in Saturn's stratosphere to identify its source. Methods. Several empirical models are tested against the Herschel-HIFI and -PACS observations, which were collected on December 30, 2010, and January 2nd, 2011 (respectively). Results. We demonstrate that Saturn's stratospheric water is not uniformly mixed as a function of latitude, but peaking at the equator and decreasing poleward with a Gaussian distribution. We obtain our best fit with an equatorial mole fraction 1.1 ppb and a half-width at half-maximum of 25°, when accounting for a temperature increase in the two warm stratospheric vortices produced by Saturn's Great Storm of 2010-2011. Conclusions. This work demonstrates that Enceladus is the main source of Saturn's stratospheric water.

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arXiv2018

Analysis of HST, VLT and Gemini coordinated observations of Uranus late 2017 : a multi-spectral search for auroral signatures

On 6 Sept. 2017, an exceptional coronal mass ejection departed from the Sun toward the Earth and Uranus, whose magnetospheres are sensitive to the solar wind. The resulting interplanetary shock triggered geomagnetic storm and intense aurora at Earth the next day and was predicted by MHD models to reach Uranus around 10-11 Nov. This event provided a unique opportunity to investigate the auroral response of the asymmetric Uranian magnetosphere in its intermediate equinox-to-solstice configuration. Coordinated multi-spectral observations were acquired with the Hubble Space Telescope (HST) in the far-UV (FUV), with the Very Large Telescope (VLT) and Gemini North in the near-IR (NIR) and with Chandra in the X-ray domain. In this study, we focus on the analysis of NIR images obtained between 9 and 17 Nov. 2017 which are compared to one FUV image acquired on 11 Nov. The latter reveals a bright southern auroral spot in the H2 bands, which we use as a reference to locate auroral precipitations. The NIR images were aimed at mapping H3+ emission from the Uranian ionosphere and at updating the results built from a couple of pioneer images taken 25 years ago. These new high resolution images reveal H3+ from the whole disc although brighter near the southern pole, but show no evidence of localized auroral emission.

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arXiv2017

Scientific rationale for Uranus and Neptune in situ explorations

The ice giants Uranus and Neptune are the least understood class of planets in our solar system but the most frequently observed type of exoplanets. Presumed to have a small rocky core, a deep interior comprising ~70% heavy elements surrounded by a more dilute outer envelope of H2 and He, Uranus and Neptune are fundamentally different from the better-explored gas giants Jupiter and Saturn. Because of the lack of dedicated exploration missions, our knowledge of the composition and atmospheric processes of these distant worlds is primarily derived from remote sensing from Earth-based observatories and space telescopes. As a result, Uranus's and Neptune's physical and atmospheric properties remain poorly constrained and their roles in the evolution of the Solar System not well understood. Exploration of an ice giant system is therefore a high-priority science objective as these systems (including the magnetosphere, satellites, rings, atmosphere, and interior) challenge our understanding of planetary formation and evolution. Here we describe the main scientific goals to be addressed by a future in situ exploration of an ice giant. An atmospheric entry probe targeting the 10-bar level, about 5 scale heights beneath the tropopause, would yield insight into two broad themes: i) the formation history of the ice giants and, in a broader extent, that of the Solar System, and ii) the processes at play in planetary atmospheres. The probe would descend under parachute to measure composition, structure, and dynamics, with data returned to Earth using a Carrier Relay Spacecraft as a relay station. In addition, possible mission concepts and partnerships are presented, and a strawman ice-giant probe payload is described. An ice-giant atmospheric probe could represent a significant ESA contribution to a future NASA ice-giant flagship mission.

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arXiv2016

Detection of CO and HCN in Pluto's atmosphere with ALMA

Observations of the Pluto-Charon system, acquired with the ALMA interferometer on June 12-13, 2015, have yielded a detection of the CO(3-2) and HCN(4-3) rotational transitions from Pluto, providing a strong confirmation of the presence of CO, and the first observation of HCN, in Pluto's atmosphere. The CO and HCN lines probe Pluto's atmosphere up to ~450 km and ~900 km altitude, respectively. The CO detection yields (i) a much improved determination of the CO mole fraction, as 515+/-40 ppm for a 12 ubar surface pressure (ii) clear evidence for a well-marked temperature decrease (i.e., mesosphere) above the 30-50 km stratopause and a best-determined temperature of 70+/-2 K at 300 km, in agreement with recent inferences from New Horizons / Alice solar occultation data. The HCN line shape implies a high abundance of this species in the upper atmosphere, with a mole fraction >1.5x10-5 above 450 km and a value of 4x10-5 near 800 km. The large HCN abundance and the cold upper atmosphere imply supersaturation of HCN to a degree (7-8 orders of magnitude) hitherto unseen in planetary atmospheres, probably due to the slow kinetics of condensation at the low pressure and temperature conditions of Pluto's upper atmosphere. HCN is also present in the bottom ~100 km of the atmosphere, with a 10-8 - 10-7 mole fraction; this implies either HCN saturation or undersaturation there, depending on the precise stratopause temperature. The HCN column is (1.6+/-0.4)x10^14 cm-2, suggesting a surface-referred net production rate of ~2x10^7 cm-2s-1. Although HCN rotational line cooling affects Pluto's atmosphere heat budget, the amounts determined in this study are insufficient to explain the well-marked mesosphere and upper atmosphere's ~70 K temperature. We finally report an upper limit on the HC3N column density (< 2x10^13 cm-2) and on the HC15N / HC14N ratio (< 1/125).

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arXiv2014

Scientific rationale of Saturn's in situ exploration

Remote sensing observations meet some limitations when used to study the bulk atmospheric composition of the giant planets of our solar system. A remarkable example of the superiority of in situ probe measurements is illustrated by the exploration of Jupiter, where key measurements such as the determination of the noble gases abundances and the precise measurement of the helium mixing ratio have only been made available through in situ measurements by the Galileo probe. This paper describes the main scientific goals to be addressed by the future in situ exploration of Saturn placing the Galileo probe exploration of Jupiter in a broader context and before the future probe exploration of the more remote ice giants. In situ exploration of Saturn's atmosphere addresses two broad themes that are discussed throughout this paper: first, the formation history of our solar system and second, the processes at play in planetary atmospheres. In this context, we detail the reasons why measurements of Saturn's bulk elemental and isotopic composition would place important constraints on the volatile reservoirs in the protosolar nebula. We also show that the in situ measurement of CO (or any other disequilibrium species that is depleted by reaction with water) in Saturn's upper troposphere would constrain its bulk O/H ratio. We highlight the key measurements required to distinguish competing theories to shed light on giant planet formation as a common process in planetary systems with potential applications to most extrasolar systems. In situ measurements of Saturn's stratospheric and tropospheric dynamics, chemistry and cloud-forming processes will provide access to phenomena unreachable to remote sensing studies. Different mission architectures are envisaged, which would benefit from strong international collaborations.

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arXiv2000

Jupiter's hydrocarbons observed with ISO-SWS: vertical profiles of C2H6 and C2H2, detection of CH3C2H

We have analysed the ISO-SWS spectrum of Jupiter in the 12-16 micron range, where several hydrocarbons exhibit rovibrational bands. Using temperature information from the methane and hydrogen emissions, we derive the mixing ratios (q) of acetylene and ethane at two independent pressure levels. For acetylene, we find $q=(8.9^{+1.1}_{-0.6})\times10^{-7}$ at 0.3 mbar and $q=(1.1^{+0.2}_{-0.1})\times10^{-7}$ at 4 mbar, giving a slope $-d\ln q / d\ln P=0.8\pm0.1$, while for ethane $q=(1.0\pm0.2)\times10^{-5}$ at 1 mbar and $q=(2.6^{+0.5}_{-0.6})\times10^{-6}$ at 10 mbar, giving $-d\ln q / d\ln P=0.6\pm0.2$. The ethane slope is consistent with the predictions of Gladstone et al. (1996), but that predicted for acetylene is larger than we observe. This disagreement is best explained by an overestimation of the acetylene production rate compared to that of ethane in the Gladstone et al. (1996) model. At 15.8 micron, methylacetylene is detected for the first time at low jovian latitudes, and a stratospheric column density of $(1.5\pm0.4)\times10^{15}$ molecule.cm-2 is inferred. We also derive an upper limit for the diacetylene column density of $7\times10^{13}$ molecule.cm-2.

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