arXiv subjects

T. Frederiksen

Publications and source records attributed to T. Frederiksen.

11 recordsLinked to original sources

arXiv2021

Photon-Emission Statistics induced by Electron Tunnelling in Plasmonic Nanojunctions

We investigate the statistics of photons emitted by tunneling electrons in a single electronic level plasmonic nanojunction. We compute the waiting-time distribution of successive emitted photons $w(τ)$. When the cavity damping rate $κ$ is larger than the electronic tunneling rate $Γ$, we show that in the photon-antibunching regime, $w(τ)$ indicates that the average delay-time between two successive photon emission events is given by $1/Γ$. This is in contrast with the usually considered second-order correlation function of emitted photons, $g^{(2)}(τ)$, which displays the single time scale $1/κ$. Our analysis shows a relevant example for which $w(τ)$ gives independent information on the photon-emission statistics with respect to $g^{(2)}(τ)$, leading to a physical insight on the problem. We discuss how this information can be extracted from experiments even in presence of a non-perfect photon detection yield.

cond-mat.mes-hall↗

arXiv2019

Nanomechanics of a Hydrogen Molecule Suspended between Two Equally Charged Tips

Geometric configuration and energy of a hydrogen molecule centered between two point-shaped tips of equal charge are calculated with the variational quantum Monte-Carlo (QMC) method without the restriction of the Born-Oppenheimer (BO) approximation. Ground state nuclear distribution, stability, and low vibrational excitation are investigated. Ground state results predict significant deviations from the BO treatment that is based on a potential energy surface (PES) obtained with the same QMC accuracy. The quantum mechanical distribution of molecular axis direction and bond length at a sub-nanometer level is fundamental for understanding nanomechanical dynamics with embedded hydrogen. Because of the tips' arrangement, cylindrical symmetry yields a uniform azimuthal distribution of the molecular axis vector relative to the tip-tip axis. With approaching tips towards each other, the QMC sampling shows an increasing loss of spherical symmetry with the molecular axis still uniformly distributed over the azimuthal angle but peaked at the tip-tip direction for negative tip charge while peaked at the equatorial plane for positive charge. This directional behavior can be switched between both stable configurations by changing the sign of the tip charge and by controlling the tip-tip distance. This suggests an application in the field of molecular machines.

cond-mat.mes-hall↗

arXiv2018

Phonon-induced linewidths of graphene electronic states

The linewidths of the electronic bands originating from the electron-phonon coupling in graphene are analyzed based on model tight-binding calculations and experimental angle-resolved photoemission spectroscopy (ARPES) data. Our calculations confirm the prediction that the high-energy optical phonons provide the most essential contribution to the phonon-induced linewidth of the two upper occupied $σ$ bands near the $\barΓ$-point. For larger binding energies of these bands, as well as for the $π$ band, we find evidence for a substantial lifetime broadening from interband scattering $π\rightarrow σ$ and $σ\rightarrow π$, respectively, driven by the out-of-plane ZA acoustic phonons. The essential features of the calculated $σ$ band linewidths are in agreement with recent published ARPES data [F. Mazzola et al., Phys.~Rev.~B. 95, 075430 (2017)] and of the $π$ band linewidth with ARPES data presented here.

cond-mat.mtrl-sci↗

arXiv2014

On the Mechanical and Electronic Properties of Thiolated Gold Nanocrystals

We present a quantitative exploration, combining experiment and simulation, of the mechanical and electronic properties, as well as the modifications induced by an alkylthiolated coating, at the single NP level. We determine the response of the NPs to external pressure in a controlled manner by using an atomic force microscope tip. We find a strong reduction of their Young modulus, as compared to bulk gold, and a significant influence of strain in the electronic properties of the alkylthiolated NPs. Electron transport measurements of tiny molecular junctions (NP/alkylthiol/CAFM tip) show that the effective tunnelling barrier through the adsorbed monolayer strongly decreases with increasing the applied load, which translates in a remarkable and unprecedented increase of the tunnel current. These observations are successfully explained using simulations based on finite element analysis (FEA) and first-principles calculations that permit to consider the coupling between the mechanical response of the system and the electric dipole variations at the interface.

cond-mat.mes-hall↗

arXiv2012

Inelastic shot noise characteristics of nanoscale junctions from first principles

We describe an implementation of ab-initio methodology to compute inelastic shot noise signals due to electron-vibration scattering in nanoscale junctions. The method is based on the framework of non-equilibrium Keldysh Green's functions with a description of electronic structure and nuclear vibrations from density functional theory. Our implementation is illustrated with simulations of electron transport in Au and Pt atomic point contacts. We show that the computed shot noise characteristics of the Au contacts can be understood in terms of a simple two-site tight-binding model representing the two apex atoms of the vibrating nano-junction. We also show that the shot noise characteristics of Pt contacts exhibit more complex features associated with inelastic interchannel scattering. These inelastic noise features are shown to provide additional information about the electron-phonon coupling and the multichannel structure of Pt contacts than what is readily derived from the corresponding conductance characteristics.We finally analyze a set of Au atomic chains of different lengths and strain conditions and provide a quantitative comparison with the recent shot noise experiments reported by Kumar et al. [Phys. Rev. Lett. 108, 146602 (2012)].

cond-mat.mes-hall↗

arXiv2011

Engineering Negative Differential Conductance with the Cu(111) Surface State

Low-temperature scanning tunneling microscopy and spectroscopy are employed to investigate electron tunneling from a C60-terminated tip into a Cu(111) surface. Tunneling between a C60 orbital and the Shockley surface states of copper is shown to produce negative differential conductance (NDC) contrary to conventional expectations. NDC can be tuned through barrier thickness or C60 orientation up to complete extinction. The orientation dependence of NDC is a result of a symmetry matching between the molecular tip and the surface states.

cond-mat.mes-hall↗

arXiv2008

Dynamic Jahn-Teller effect in electron transport through single C60 molecules

Scanning tunneling spectra on single C60 molecules that are sufficiently decoupled from the substrate exhibit a characteristic fine structure, which is explained as due to the dynamic Jahn-Teller effect. Using electron-phonon couplings extracted from density functional theory we calculate the tunneling spectrum through the C60- anionic state and find excellent agreement with measured data.

cond-mat.mes-hall↗

arXiv2006

Controlled Contact to a C60 Molecule

The conductance of C60 on Cu(100) is investigated with a low-temperature scanning tunneling microscope. At the transition from tunneling to the contact regime the conductance of C60 adsorbed with a pentagon-hexagon bond rises rapidly to 0.25 conductance quanta G0. An abrupt conductance jump to G0 is observed upon further decreasing the distance between the instrument's tip and the surface. Ab-initio calculations within density functional theory and non-equilibrium Green's function techniques explain the experimental data in terms of the conductance of an essentially undeformed C60. From a detailed analysis of the crossover from tunneling to contact we conclude that the conductance in this region is strongly affected by structural fluctuations which modulate the tip-molecule distance.

cond-mat.mtrl-sci↗

arXiv2005

Effects of Self-field and Low Magnetic Fields on the Normal-Superconducting Phase Transition

Researchers have studied the normal-superconducting phase transition in the high-$T_c$ cuprates in a magnetic field (the vortex-glass or Bose-glass transition) and in zero field. Often, transport measurements in "zero field" are taken in the Earth's ambient field or in the remnant field of a magnet. We show that fields as small as the Earth's field will alter the shape of the current vs. voltage curves and will result in inaccurate values for the critical temperature $T_c$ and the critical exponents $ν$ and $z$, and can even destroy the phase transition. This indicates that without proper screening of the magnetic field it is impossible to determine the true zero-field critical parameters, making correct scaling and other data analysis impossible. We also show, theoretically and experimentally, that the self-field generated by the current flowing in the sample has no effect on the current vs. voltage isotherms.

cond-mat.supr-con↗

arXiv2004

Normal-Superconducting Phase Transition Mimicked by Current Noise

As a superconductor goes from the normal state into the superconducting state, the voltage vs. current characteristics at low currents change from linear to non-linear. We show theoretically and experimentally that the addition of current noise to non-linear voltage vs. current curves will create ohmic behavior. Ohmic response at low currents for temperatures below the critical temperature $T_c$ mimics the phase transition and leads to incorrect values for $T_c$ and the critical exponents $ν$ and $z$. The ohmic response occurs at low currents, when the applied current $I_0$ is smaller than the width of the probability distribution $σ_I$, and will occur in both the zero-field transition and the vortex-glass transition. Our results indicate that the transition temperature and critical exponents extracted from the conventional scaling analysis are inaccurate if current noise is not filtered out. This is a possible explanation for the wide range of critical exponents found in the literature.

cond-mat.supr-con↗

arXiv2004

The zero-field superconducting phase transition obscured by finite-size effects in thick $\mathrm{\bf{YBa_{2}Cu_{3}O_{7-δ}}}$ films

We report on the normal-superconducting phase transition in thick $\mathrm{YBa_{2}Cu_{3}O_{7-δ}}$ films in zero magnetic field. We find significant finite-size effects at low currents even in our thickest films ($d = 3200$ Å). Using data at higher currents, we can unambiguously find $T_c$ and $z$, and show $z = 2.1 \pm 0.15$, as expected for the three-dimensional XY model with diffusive dynamics. The crossover to two-dimensional behavior, seen by other researchers in thinner films ($d \leq 500$ Å), obscures the three-dimensional transition in both zero field and the vortex-glass transition in field, leading to incorrect values of $T_c$ (or $T_g$), $ν$, and $z$. The finite-size effects, usually ignored in thick films, are an explanation for the wide range of critical exponents found in the literature.

cond-mat.supr-con↗