arXiv subjects

T. H. Geballe

Publications and source records attributed to T. H. Geballe.

25 records · Page 2Linked to original sources

arXiv2006

The never ending search for high temperature superconductivity

A brief history of the discovery of new superconductors is given. Different types of pairing mechanisms are considered. By comparing Tcs in different cuprate families it is concluded that the pairing in the CuO2 layers must be supplemented by interactions elsewhere in the unit cell. This conclusion is reached simply by considering the significant variations in Tc that are found in structures that have the same sequence of CuO2 layers within the unit cell but have different intervening layers. A quasi-particle is postulated to account for pairing found in the double chain layer of the Pr247 cuprate and may also exist in the CuO2 layers of all the cuprates.

cond-mat.supr-con↗

arXiv2006

Superconducting properties of Tl-doped PbTe

Tl-doped PbTe (Pb_{1-x}Tl_{x}Te) is an anomalous superconductor with a remarkably high maximum T_c value given its relatively low carrier concentration. Here, we present results of systematic measurements of superconducting parameters for this material, for Tl concentrations up to x = 1.4%. We find that it is a Type II, weak-coupled BCS superconductor in the dirty limit and discuss implications for the applicability of the charge Kondo model recently proposed to account for superconductivity in this system.

cond-mat.supr-con↗

arXiv2005

Evidence for charge Kondo effect in superconducting Tl-doped PbTe

We report results of low-temperature thermodynamic and transport measurements of Pb_{1-x}Tl_{x}Te single crystals for Tl concentrations up to the solubility limit of approximately x = 1.5%. For all doped samples, we observe a low-temperature resistivity upturn that scales in magnitude with the Tl concentration. The temperature and field dependence of this upturn are consistent with a charge Kondo effect involving degenerate Tl valence states differing by two electrons, with a characteristic Kondo temperature T_K ~ 6 K. The observation of such an effect supports an electronic pairing mechanism for superconductivity in this material and may account for the anomalously high T_c values.

cond-mat.str-el↗

arXiv2000

Deviations from Matthiessen's Rule for ${\rm SrRuO_3}$ and ${\rm CaRuO_3}$

We have measured the change in the resistivity of thin films of ${\rm SrRuO_3}$ and ${\rm CaRuO_3}$ upon introducing point defects by electron irradiation at low temperatures, and we find significant deviations from Matthiessen's rule. For a fixed irradiation dose, the induced change in resistivity {\it decreases} with increasing temperature. Moreover, for a fixed temperature, the increase in resistivity with irradiation is found to be {\it sublinear}. We suggest that the observed behavior is due to the marked anisotropic scattering of the electrons together with their relatively short mean free path (both characteristic of many metallic oxides including cuprates) which amplify effects related to the Pippard ineffectiveness condition.

cond-mat.str-el↗

arXiv1999

Observation of domain wall resistivity in $\rm SrRuO_3$

$\rm SrRuO_3$ is an itinerant ferromagnet with $T_c \sim 150 \rm K$. When $\rm SrRuO_3$ is cooled through $T_c$ in zero applied magnetic field, a stripe domain structure appears whose orientation is uniquely determined by the large uniaxial magnetocrystalline anisotropy. We find that the ferromagnetic domain walls clearly enhance the resisitivity of $\rm SrRuO_3$ and that the enhancement has different temperature dependence for currents parallel and perpendicular to the domain walls. We discuss possible interpretations of our results.

cond-mat.str-el↗

arXiv1999

Reservoir Layers In High Tc Mercury Cuprates

We put forward the hypothesis that cations with 6s electrons (Hg,Tl,Pb,Bi) in the charge reservoir layers of high Tc cuprate superconductors actively participate in the pairing interaction as negative-U centers. We further argue that the Hg-cuprates are outstanding superconductors (Tc > 160 K) because they can exist as two-site negative-U centers, Hg2+2. Their electrons are less localized than in single-site centers (negative-U or bipolaron) and can have a strong pairing interaction with a smaller increase in effective mass. The Hg2+2 centers are oriented in the x and y directions and can have phase differences compatible with the d-wave symmetry of the CuO2 planes.

cond-mat↗

arXiv1998

Non-Fermi liquid behavior of SrRuO_3 -- evidence from infrared conductivity

The reflectivity of the itinerant ferromagnet SrRuO_3 has been measured between 50 and 25,000 cm-1 at temperatures ranging from 40 to 300 K, and used to obtain conductivity, scattering rate, and effective mass as a function of frequency and temperature. We find that at low temperatures the conductivity falls unusually slowly as a function of frequency (proportional to ω^{-1/2}), and at high temperatures it even appears to increase as a function of frequency in the far-infrared limit. The data suggest that the charge dynamics of SrRuO_3 are substantially different from those of Fermi-liquid metals.

cond-mat.str-el↗